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By Sutham Niyomwas

Synthesis of alumina-mullite-silicon carbide composite (Al2O3-Al6Si2O13-SiCw) was obtained in situ by carbothermal reduction of a mixture of kaolin and two different silica sources. The carbothermal reduction was carried out in a horizontal tube furnace under flow of argon gas. The standard Gibbs energy minimization method was used to calculate the equilibrium composition of the reacting species. The synthesized products were mixtures of alumina, mullite and silicon carbide in the form of whiskers. The effects of adding two different silica sources of rice husk ash and silica powder to the mixture of kaolin and activated carbon were investigated. XRD and SEM analyses indicate complete reaction of precursors to yield Al2O3- Al6Si2O13-SiC as product powders, with the SiC having whisker morphology.

Jan 1, 2006

By S. Ganguly, R. Kononov

Carbothermal reduction of manganese oxides and manganese ores in the solid state was studied in hydrogen, helium and argon at different temperatures, ore compositions and carbon to manganese oxide ratios. Wesselsore (South Africa) and two grades of the Groote Eylandt ore (Australia) with different level of impurities were examined. Ores were characterised by XRD, X-ray fluorescence, optical microscopy and scanning electronmicroscopy. Isothermal and temperature programmed carbothermal reduction experiments were conducted in a fixed bed reactor in a vertical tube furnace, with on-line monitoring of gas composition by the CO-CO2 infrared sensor. The reduced samples were characterised by XRD, SEM and LECO analyses. Extent of reduction was calculated using data on the off-gas composition, and LECO carbon and oxygen contents in the reduced sample. Manganese oxides in the ore were reduced to a-Mn and carbides Mn23C6 and Mn7C3 depending on the carbon to ore ratio. The reduction rate of manganese ores in hydrogen was higher than in helium and argon. Key words: Manganese, Carbothermal Reduction, Hydrogen, Argon, Carbon Monoxide, Helium, Kinetics.

Jan 1, 2007

By F. Awotwe-Appiah, P. Koshy, A. Y. Fosu, J. Dankwah, J. R. Dankwah

Ghana currently exports its bauxite raw without any value addition. Gradual depletion of high grade bauxite (with high alumina content) and the emergence of low grade bauxite (with high iron oxide content) calls for novel and inexpensive ways to recover alumina from these low grade ores. Bauxite users have indicated their willingness to pay 10% to 50% higher for a corresponding reduction in impurities by a similar amount. This project therefore investigates the carbothermal upgrading of the Ghana Awaso bauxite using waste polypropylene as reductant in a locally designed gas-fired furnace. Composite pellets of low grade bauxite sample (assaying 45% Al2O3) containing pulverised waste polypropylene were formed, oven dried, placed in fireclay crucible and fired for 30 minutes. The magnetic fraction after reduction was separated by a Low Intensity Magnet and weighed. It was observed that up to 97% of the iron oxides (occurring as hematite and goethite) could be separated into the magnetic fraction as magnetite leaving a nonmagnetic fraction with over 98% Al2O3 as opposed to the 45% Al2O3 in the as-received bauxite sample. This research direction provides yet another simple but effective way for simultaneously upgrading low grade bauxite and recycling waste polypropylene, whilst at the same time decreasing the amount of waste material generated as red mud after the Bayer process.

Jan 1, 2015

By W. K. Connor, O&apos

The Bureau of Mines has conducted beneficiation, carbothermic reduction, and leaching tests of Mn oxide ores as part of its evaluation of the Mn and Co resources of the West- Central Arkansas District. The major Mn oxides in the ore include cryptomelane, psilomelane, pyrolusite, and lithiophorite. Cobalt is contained within the Mn oxides. Nonbeneficiated ore was reduced at 800' C with coal and leached in ammonium sulfate and ammonium carbonate leach liquors. Ore concentrates were calcined at 600" C prior to reduction under the same conditions as the raw ore. Head analyses reported up to 21 ptt Mn and 0.11 pct Co. Extractions of 70 to 90 pct Mn and 40 to 60 pct Co were achieved.

Jan 1, 1992

By Derek Caizergues, Hurman Eric

The principle of carbothermic reduction has been around for many years. In principle it is a simple process, yet with a multitude of problems. The temperature required to affect reduction is in the region of 2200ºC and results in aluminium oxy-carbide formation rather than metallic aluminium. From a thermodynamic point of view, reducing the temperatures of reaction which would suppress oxy-carbide formation would only be possible by lowering the total pressure of the system. A decrease in thermodynamic activity of product aluminium by dissolving it in another phase would also help preventing the formation of oxy-carbides and would also increase the yield of the reduction reaction. Thus experiments have been conducted at around 1700ºC to determine the possibility of carbothermic reduction of alumina under the presence of a metallic solvent. Total pressure of the system was reduced to around 30kPa and metallic nickel, iron, copper and tin were selected as the solvent. The highest recovery of aluminium was achieved with the nickel solvent followed by iron, copper and tin. This ranking for the first three was also in accord with the extent of negative deviation form ideality in the respective binary solutions of these solvents with aluminium. The tin-aluminium system displays positive deviation form ideality. The rate and extent of reduction was found to be highly dependent on temperature and pressure. The pseudo first order reaction rate was found to be applicable to the process in all the solvents used. Rate constants were calculated and it is also suggested that the reduction was controlled primarily by the chemical reaction rate.

Jan 1, 2003

By Animesh Jha

The carbothermic reduction of chalcopyrite has been studied in the temperature range 1073 to 1273K in presence of lime. The role of lime during the reduction process is explained and the phase equilibria leading to the metallisation of copper and iron are discussed. The effect of coal and carbon monoxide on the reduction process have been studied and the rate governing steps are identified. This investigation also cites examples of possible mechanisms of physical separation of metallic Cu from iron during the reduction process.

Jan 1, 1992

By B. L. Chulu

In the carbothermic reduction of lead sulfate to produce lead, the inclusion of soda ash (Na,CO,) in the charge provides for the control of sulfur dioxide in the effluent gas. An important mechanism in the process appears to be the carbothermic reduction of the sodium carbonate whereby sodium gas and carbon monoxide are produced. These intermediates then participate in the reduction of the lead sulfate to produce lead metal and stable sulfur species in the molten slag phase. In addition, there is some evidence that the presence of lead metal in the charge may also serve to increase the lead recovery in the process. These aspects were investigated by conducting laboratory-scale smelting tests with small charges (;3g), at 1173°K(9000C). Recovery did not exceed 74w% and the role of incipient lead metal in the charge could not be clearly assessed.

Jan 1, 1993

By Fernanda da Silva Machado

Em um mundo de recursos naturais decrescentes, com a intensificação das indústrias automatizadas de todos os tipos (I4) e contínuo aumento da população, é necessário desenvolver melhores caminhos para a geração e distribuição de riquezas. Uma das alternativas para este objetivo é o conceito da Economia Circular. Este artigo apresenta um exemplo focado na intensificação do uso de resíduos de biomassa na produção integrada de aço exclusivamente baseada na combinação de reatores industriais existentes em um layout que favorece o conceito da economia circular. O ferro também é obtido do processamento tradicional de sucata, reprocessamento de resíduos de ferro e óxidos de ferro, como a escória, pequenos óxidos de ferro, reversos metálicos, resíduos da indústria siderúrgica integrada tradicional. Os resíduos de biomassa são provenientes da demolição de casas de madeira, e outros resíduos de biomassa, como limpeza florestal para evitar-se incêndios, resíduos de moinhos, paletes usados e qualquer outra fonte de biomassa. As combinações dos reatores tornaram-se possíveis devido à nova versão do processo de Carbonização Contínua, Carboval, um reator especialmente projetado da tecnologia Lambiotte tradicional, para produzir, de preferência, o carvão vegetal que possui as mesmas características necessárias para alimentar o Mini Alto Forno tradicional a base de carvão.

Oct 30, 2017

The nature of adsorbed calcium carboxylates (oleate and stearate) has been investigated by in-situ/ex-situ Fourier transform infrared internal reflection spectroscopy (FTIR/IRS). Previous spectroscopic studies in alkaline solution have shown that adsorbed carboxylate is characterized by a C-O stretching vibration at about 1550 em?1 for less than monolayer coverage. Similar results were found in this study. More specifically, in this study such a singlet at 1550 cm-1 was found for LB monolayers of calcium distearate transferred as a condensed layer at a high film pressure to the surfaces of fluorite and germanium. Normally the spectrum of bulk calcium distearate reveals a doublet at 1575 and 1540 cm-1, characteristic of a three dimensional 7-fold coordination for calcium carboxylate complexes. This doublet is generally found for carboxylate multilayers formed by spontaneous adsorption at the surface of calcium minerals. In this regard, the spectral evidence suggests that whenever the calcium dicarboxylate is constrained at a surface as a condensed layer, the 7-fold coordination can not be satisfied and the surface carboxylate is forced into a two dimensional symmetrical coordination with a singlet at 1550 cm-1. On the other hand, if the Langmuir-Blodgett (LB) monolayer calcium distearate film is transferred at a low film pressure the doublet is observed. This analysis is further confirmed by the spectral results for LB transferred calcium distearate monolayers at a hydrophobic silicon surface. Even though these are condensed monolayers formed at high film pressure, the carboxylate group, oriented away from the surface, is no longer constrained by the surface force field, and thus exhibits the characteristic doublet of the bulk calcium distearate salt.

Jan 1, 1998

By M Kim, J Park, I-K Suh, E Kim, J Lee

One of the key technologies in developing hydrogen-enriched ironmaking operations is the control of the carburisation, melting, and dripping behaviour of the iron ore burden materials. When a hot compacted iron (HCI) is charged in the blast furnace or the FINEX Melter-Gasifier, iron oxide reduction, the reduced iron’s carburisation, and the melting of iron and slag occur successively. This study investigated the reduction, carburisation, melting and dripping behaviour of HCI under a COH2 gas mixture using the high-temperature X-ray radiographic technique. Under 100 per cent CO gas atmosphere, the dripping temperature was 1410°C. When 5 per cent H2 was introduced, the dripping temperature slightly decreased to 1400°C. Furthermore, the dripping temperature gradually increased as the H2 gas composition increased. As 30 per cent H2 was introduced, the dripping temperature reached 1414°C. The carbon concentration in the drained metal samples gradually increased with increasing H2 composition. It is considered that H2 decreased FeO content in the slag, yielding the increased melting temperature and viscosity of the slag. On the other hand, H2 accelerated the carburisation of the reduced iron by CO gas, enabling the homogenisation of the oxide materials to form a liquid phase. Therefore, it is considered that introducing H2 in the reactor is helpful to increase productivity and energy efficiency by accelerating the liquid phase’s formation.

Aug 21, 2024

By B. Anameric, S. K. Kawatra, K. B. Rundman

The iron nugget process is an economical, environmentally friendly, cokeless, single-step pig iron making process. Residence time dependent process requirements for production of pig iron nuggets at a fixed furnace temperature (1425 C) were investigated. Three chemically and physically different products were produced after complete reduction to iron, depending on the residence time in the furnace. These products were direct reduced iron (DRI), transition direct reduced iron (TDRI), and pig iron nuggets (PIN). The increase in the carbon content of the system as a function of residence time was detected by optical microscopy and Microhardness measurements. Sufficient carbon dissolution for the production of pig iron nuggets was obtained after 40 minutes residence time. The pig iron nuggets produced had chemical and physical properties similar to blast furnace pig iron. They were liquid state products and slag was completely separated from the metal.

Jan 1, 2005

By William Faulkner

El presente texto señala la recuperación de metales preciosos mediante la cianuración, donde se combina este proceso con la adsorción en carbón activado granulado. Así, de los ocho países productores de los Estados Unidos de Norteamérica, todos usan actualmente carbón activado en pulpa y/o en columnas. Durante el transcurso del último año, las siguientes nuevas plantas de recuperación de oro en Norteamérica han seleccionado el método del carbón para recuperar oro: Golden Sunlight (Montana), Getty Mining (Utah), Noranda (California), Amoco/Dowe (Ontario, Canadá). Por ello, antes de revisar los dos procesos de aplicación del carbón activado granulado, es decir, directamente en la pulpa y aplicado en columnas a soluciones ricas de tanques o pilas, conviene examinar la historia y desarrollo de los medios de adsorción para la recuperación de metales preciosos.

Jan 1, 1985

By B. Caldwell

"The CompanyCardinal River Coals is jointly owned by Luscar Ltd. and the Consolidated Coal Company of Canada (Consol). The Luscar mine is operated by Luscar Ltd. and is located 40 km south of Hinton near Cadomin, Alberta (Fig. 1). The plant sits on the old townsite of Luscar, Alberta, which was founded in order to develop the coal in 1912 (Fig. 2). Initially, the coal was mined by Luscar Ltd. for heating and steam generation and used quite heavily by the railways for their steam locomotives. In 1955, the mine was decommissioned as the demand for coal for tl1ese purposes had dropped off. In 1969, the mine was re-established by Cardinal River to provide metallurgical coking coal for its customers in Japan. The coal is mined from the 13m thick Jewel Seam by open pit methods at a 10 to 1 stripping ratio. The run-of-mine coal is then cleaned to meet customer demands.The PlantThe clean coal preparation facilities at Cardinal River were extended in 1980 in order to increase the feed rate from 450 t/h to 800 t/h. The extension is a separate plant which can be operated on its own or in parallel with the old plant. In addition, modifications have been made to the fine coal circuit (hydrocyclones added), the coarse refuse circuit, (refuse bucks replaced by a refuse conveyor which backfills a pit), and the fine refuse circuit (solid bowl refuse centrifuges, refuse classifying cyclones, and hydra-rake thickener no longer utilized) since the plant was built in 1969. The plant production of 3 M t per year with a yield of 78% is achieved by first screening and breaking the run-of-mine material to a top size of 1 ½ in. The feed is then slurried, sized, and processed in three different washing circuits. The washed coal is mechanically dewatered, thermally dried, and then stored in a 14 500 t capacity silo or on a 300 000 t stockpile. The fine refuse is thickened and pumped to the same pit to which the coarse refuse is being conveyed"

Jan 1, 2000

By C. R. Stelck

"AbstractThe Cardium formation of northeastern British •Columbia •contains an erosional unconformity that becomes progressively more severe northward until, •at Liard river, the stratigraphic hiatus eliminates the underlying Lower •Cardium sandstone, the Kaskapau formation, and the upper Dunvegan sandstones. The area of unconformity roughly coincides with the distribution of the continental facies of the earlier Dunvegan formation. Along Wapiti river, the zone fossil Scaphites ventricosus Meek and Hayden is found in the Bad-heart member of the overlying Wapiabi shale; Scaphites :preventricosus. Cobban marks the base of the Wapiabi shale; Scaphites cf. corvensis •Cobban is found in the middle shale member of the •Cardium formation. The log of the Red-Willow No. 1 well shows close similarity to the outcrop sections south of Wapiti river. The Cardium formation is mainly late Turonian in age. Two other pre-Cardium Turonian sands of north-eastern British Columbia are named the Wartenbe and Tuskoola sands.IntroductionTHE Upper Cretaceous Cardium (Bighorn) sandstone formation of the Foothills of northeastern British Columbia carries within its formational limits an erosional unconformity. The unconformity decreases to the southeast, becoming in immediate shoreline regions, now under the plains, a minor diastem. Such diastems, or stratigraphic intervals of non-deposition, occurring in the shallow unda-zone are paralleled in the deeper portions of the unda-zone by the phenomena of sub-aqueous winnowing. '.This winnowing and re-working •at critical depths creates sand areas with porosity."

Jan 1, 1955

By A Van Kersen, J Hodson

Waihi Gold Mining Co Ltd [WGM], operated by Normandy Mining, has been internationally recognised for its achievements in environmental management at the Martha Mine at Waihi. In a proactive approach to dealing with community concerns regarding blast vibrations on the North Wall cutback, trials were performed using the Cardox System [Cardox], to determine feasibility of achieving economic fragmentation of andesite overburden whilst bettering management levels of 5 mm/s peak particle velocity. Cardox is a non-explosive pressure breaking system which uses high pressure CO2, Results against conventional Ammonium Nitrate/Fuel Oil [ANFO] using a variety of delays showed that conventional blasting techniques could produce marginal fragmentation within the management levels with occasional excursions, whereas Cardox produced the required fragmentation while not registering on the vibration monitoring equipment. Fragmentation to enable normal excavation by a Hitachi EXII00 hydraulic excavator was achieved with a yield of 16m3 per round. The trails indicated that fragmentation with Cardox at the yields required of over 18m3 per round was possible with further product development. The trial demonstrated that non-explosive pressure breaking is feasible and its application warranted where environmental concerns affect the cost-benefit economics of production blasting in sensitive areas.

Jan 1, 2001

By R. J. Roman

Introduction This paper attempts to describe the characteristics of the industrial minerals segment of the minerals industry that make it different from the other segments. Also described are the trends, strengths, and shortcomings in the industrial minerals segment. This may help professionals in the minerals industry determine if there is a place for them in industrial minerals. Industry Overview It is difficult to generalize when describing the industrial minerals industry. Some products, such as cement and potash, are produced exclusively by large, well capitalized and technically sophisticated companies. Others, such as sand and gravel, are generally produced by small, family-owned companies operating on a shoestring budget. Still other products, such as feldspar, are produced by both types of companies. Not only are the companies vastly different, the products and marketing of their products are also different. Industrial mineral products are sold based on their physical characteristics (abrasives), or their chemical characteristics (trona), or both (glass sand). Marketing can be direct by the producing plant, a corporate office handling products form several plants, or through distributors. The geologic, mining, and processing skills needed can be minimal or sophisticated. There can even be large differences in the technical skills needed in two plants producing the same product. One feldspar producer may only need to mine and grind his ore, while another may use a delicate flotation process. One easy generalization is that there are industrial mineral operations in all geographic locations. A second is that industrial minerals offers more opportunities to entrepreneurs than the metals field because of the variety in the sizes and types of operations. Industry Growth Industrial minerals must be considered a mature industry. Consequently, little exciting growth can be expected. Over the past 30 years, industry sales have grown at a rate of 6.2%, compared to a 6.7% growth rate of the GNP (Kliff, 1978). A 3.8% growth rate has been forecast for the remainder of this century. The fortunes of those plants producing a product for local consumption will depend on the prosperity of the local economy. The fortunes of those plants that sell into the national market will depend on their competitiveness in their industry. Major industrial mineral products are shown in Table 1. The first three commodities account for 66% of the industrial minerals market. Typically, deposits of stone, sand and gravel, and the limestone, silica, and clay needed for cement are easy to find and mine. Role of Mining Engineers and Geologists Because a sophisticated techcical knowledge of geology or mining is not required, very few geologists and mining engineers are employed in industrial minerals. Geologists working for these companies function less as geologists than managers and executives dealing with permitting and land acquisition. Likewise, mining is done mostly by open-pit methods. It is generally supervised by an individual experienced in the operation and maintenance of heavy equipment, not a mining engineer trained in rock mechanics or computer methods of mine planning. What of the geologists and mining engineers employed by the industrial minerals industry? Many gained their positions as a result of their experience dealing with the regulatory agencies that control the operations of all mines and mills. Their technical expertise in geology or mining becomes only a side benefit. Finding and mining industrial minerals does not generally require the concentrated efforts of geologists and mining engineers. But the processing of the ores does

Jan 2, 1985

By T. Iwanowski

Stress wave measurements and calculations are often used to make a safe determination of the bearing capacity and the integrity of driven piles. Some applications to the restoration of old buildings in the Old Town of Stockholm are referred to and especially analyses of measurements combined with simulations are discussed here.

Jan 1, 1991

By F. X. Meyer

THE United States Smelting Refining and Mining Company maintains an ore-purchasing department for procurement of custom tonnages of milling and smelting ores and concentrates for treatment at its Midvale plant. Arrangements with other companies provide for treatment of Company and custom zinc concentrates. Location of the Midvale plant in the heart of the Western mining country makes it possible to serve shippers from these nine producing states: Arizona, California, Colorado, Idaho, Montana, Nevada, Oregon, Utah, and Washington. Shipments from most of these states travel over main-line railroads, delivery being made at Midvale within a short time after billing of the shipment. Shipments varying in size from a few sacks to carloads can be handled at

Jan 1, 1948

By Luis Fortunato Rioja

Southern Peru, es una empresa minera que explota cobre a Tajo Abierto, en cuyo proceso de explotación del mineral se utiliza un sistema mecánico manual de introducción de las barras de acero a los molinos que genera una serie de problemas como el mayor empleo de mano de obra, carguío mecánico manual, inseguridad y la elevada pérdida de producción anual. En ese sentido, el presente trabajo señala el uso del equipo “Fighter Bull" para introducir las barras al molino en el menor tiempo posible. El diseño de este equipo se desarrolló en los Talleres de Maestranza de Toquepala de nuestra empresa Southern Peru Copper Corporation y permite reducir en gran porcentaje las pérdidas de producción de molienda de mineral y no produce riesgos de accidentes de accidentes para los trabajadores.

Sep 19, 2006

By F. Habashi

"The rare earths industry started in Austria in 1887 by Carl Auer von Welsbach (1858-1929) Professor of Chemistry at the University of Vienna. The process was based on monazite sand transported from Brazil as shipping ballast free of charge. This made possible producing thorium, cerium, and other rare earths at a low cost, thus permitting the growth of the industry. However, once the Brazilian authorities realized the strategic importance of the sand, shipping was stopped. Brazil then started its own processing of the sand in 1949. The background for Auer’s work, the role of Robert Bunsen in Heidelberg, and the invention of the spectroscope will be presented. INTRODUCTIONHeidelberg on the Neckar (Figure 1) was the meeting place for chemistry students from all over Europe in the nineteenth century. Her university founded in 1386 had already a famous professor of chemistry and medecine in the Faculty of Medicine by the name Leopold Gmelin whose three - volume Handbuch der theoretischen Chemie appeared in 1817-1819, that became later a multi-volume monumental work. As successor to Gmelin came Robert Bunsen (Figure 2) in 1852 who made this university town the Mecca of chemistry students. One of his students, the English Henry Roscoe (1833-1915) who became later a distinguished professor in Manchester, described him as follows: ""As an investigator he was great, as a teacher he was greater, as a man and a friend he was greatest""."

Jan 1, 2012