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By Mike Treffy

El presente texto describe las características geoquímicas de las rocas ígneas del tipo HHPG (High Heat Producing Granites) en los Andes peruanos. Dichas rocas tienen diferentes edades geológicas y están relacionadas a los depósitos minerales como estaño, plata, cobre, zinc, plomo, uranio, etc y están ubicadas al extremo sur de la Cordillera Oriental y norte del Batolito de la Cordillera Blanca. Asímismo, en base al procesamiento geoquímico de la de ANDESDATA, se demuestra que estos granitos y rocas volcánicas félsicas corresponden a diferentes series magmáticas y que este tipo de rocas pueden relacionarse a altas concentraciones de plata, oro, cobre, zinc, molibdeno, uranio, favoreciendo la circulación de fluidos hidrotermales a grandes distancias de las intrusiones y rocas volcánicas bastante diferenciadas.

Sep 21, 2013

By Tiago Nunes Lima

Novas ligas de Ti estão sendo desenvolvidas como uma alternativa para aplicação em implantes cirúrgicos e em componentes estruturais por possuírem propriedades atraentes em comparação à liga Ti6Al4V, com destaque ao menor módulo de elasticidade, menor citotoxicidade, maior resistência à corrosão e propriedades mecânicas similares, alta resiliência e elevada formabilidade. Este estudo tem como objetivo observar as características mecânicas de ligas Ti35Nb2Sn deformadas a frio e seguidas de envelhecimento. A liga foi laminada a frio com 80% de redução e envelhecida a 400 ºC por 48 horas. Foram realizados ensaios de tração, dureza, metalografia e análise das superfícies de fratura. A liga laminada apresentou uma maior relação de resistência à tração pelo módulo de elasticidade e maior ductilidade do que a liga envelhecida.

Aug 16, 2017

By Juliana Mesquita de Andrade

Em sistemas cerâmicos policristalinos as homojunções e heterojunções podem apresentar comportamento elétrico desde completamente ôhmico até com elevada característica retificadora, que no limite é a base do comportamento varistor, o qual é o dispositivo de proteção de sistemas e equipamentos eletro-eletrônicos contra sobretensões mais utilizado. Os óxidos de zinco (ZnO) e de estanho (SnO2) são, individualmente, base dos varistores com melhores comportamentos elétricos. Este trabalho, com base nas caracterizações estruturais por técnicas de microscopia eletrônica de varredura e análises termodilatométricas, e na caracterização elétrica e dielétrica, avalia as propriedades varistoras de cerâmicas à base do sistema misto ZnO-SnO2. Verifica-se a formação de um sistema polifásico apresentando homojunções e heterojunções com diferentes características morfológicas e graus de densificação, exibindo ainda comportamento eletrotérmico com predomínio de características varistoras em função da dopagem da matriz mista ZnO-SnO2. Os resultados obtidos evidenciam a tendência da formação de espinélio (Zn2SnO4) em presença de grãos de SnO2 e do estabelecimento de comportamento varistor (coeficiente de não-linearidade > 10), que pode ser aperfeiçoado por dopagem adicional e por tratamentos térmicos, principalmente quanto à redução da corrente de fuga e da ampliação e estabilização da região não-linear da curva tensão x corrente elétrica.

Aug 7, 2018

By Jean-François Dorion

La corrosivité des environnements miniers souterrains est un phénomène peu étudié au Canada. En plus de détériorer les systèmes de soutènement, la corrosion s?attaque aussi à divers installations et équipements souterrains. Cette étude, débutée en janvier 2007, est l?établissement d?une banque de données afin de caractériser les environnements miniers souterrains selon leur potentiel de corrosivité pour les systèmes de support de terrains. Pour ce faire, cinq (5) mines ont été sélectionnées afin de comparer les environnements : Laronde, Géant-Dormant, Niobec, Mouska et Doyon. À chacune des mines, trois (3) endroits ont été étudiés. Les résultats préliminaires démontrent une grande variabilité des conditions d?une mine à l?autre ainsi qu?à l?intérieur même d?une mine. La minéralogie des roches et du gisement influence la composition des eaux souterraines et la présence des sulfures joue un rôle important sur l?agressivité de l?eau et de l?air des mines de l?étude. Afin de déterminer le potentiel de corrosivité, plusieurs paramètres doivent être considérés et la mine doit être zonée selon l?agressivité des endroits.

Feb 1, 2008

By Réal Tanguay, Mathieu Piché, Jacques Carignan, Charles Beaudry, André Bonenfant

"Le gisement Isle-Dieu est situé sur le flanc sud de l'anticlinal de Galinée. La stratigraphie locale comprend, de bas en haut, la rhyolite du Groupe du Lac Watson surmontée par le basalte du Groupe de Wabassee. Un horizon repère, siliceux et sulfure, d'origine sédimentaire, appelé ""Tuffite Clef', est présent au sommet du Groupe du Lac Watson et pend à 45° vers le sud.Le gisement Isle-Dieu est constitué par une lentille qui recoupe, en partie, la ""Tuffite Clef"". Elle est séparée en deux trorçons par un dyke de tonalite. Les données obtenues à partir des forages effectues à travers la rhyolite sous-jacente permettent de définir les zonations chimiques et pétrographiques de la cheminée d’altération.Ces transformation minéralogiques et chimiques sont caractérisées par un enrichissement en MgO, Fe2O3, MnO et un appauvrissement en CaO, SiO2 et Na2O. La zonation spatiale de ces altérations permet de mettre en évidence la géométrie et l'extension des conduits hydrothermaux. L'épaisseur maximale des sulfures massifs au sein de la lentille est en étroite relation avec l’importance des zones d'altération. Les patrons de variations chimiques dénotent une orientation préférentielle WNW des conduits hydrothermaux. Les parties les plus altérées et les plus déformées présentent localement de fortes variations positives en Zr, Nb, et terres-rares; ces concentrations sont vraisemblablement imputables a /' enrichissement résultant de la diminution du volume lors de l'altération.L'étude pétrographique montre que la porosité et la perméabilité du milieu ont joué un rôle important dans la circulation des fluides car les roches de la cheminée présentent des phénomènes de dévitrification, de bréchification et de microfracturation très prononces. La nature magnésienne de certaines chlorites et la perméabilité accrue du milieu semblent en accord avec le modelé propose par Roberts et Reardon, ( 1978 )"

Jan 1, 1990

By Gabriel Gonçalves Pessoa de Castro

O trabalho teve por objetivo produzir uma liga Al AA1070 com microestrutura ultrafina via prensagem por canais equiangulares. O processo empregou a rota C com 2 passes consecutivos a frio e acumulou uma deformação ?2 = 2,38. O material de partida é proveniente de um processo de laminação a quente na qual a microestrutura resultante era composta de grãos grosseiros com tamanho de grão de 14,5 ± 19,1 ?m e dureza de 31,1 ± 1,9 Vickers. Foi realizada a caracterização microestrutural com o auxílio das técnicas de microscopia eletrônica de varredura (MEV) e de difração de elétrons retroespalhados. O comportamento mecânico das amostras foi avaliado por ensaios de dureza Vickers, a fim de se determinar a energia armazenada durante os passes. Os resultados obtidos mostraram que o material de partida apresentou estrutura parcialmente recristalizada, decorrente do processo termomecânico de laminação. A deformação cisalhante severa que ocorre na interseção entre os canais durante o processamento via ECAP permitiu um intenso refinamento de grãos. O tamanho de grão após o 2° passe foi da ordem de 1,6 ± 1,7 µm. A dureza após o 1° passe quase dobrou em relação ao material de partida, mas praticamente se manteve no passe seguinte, sugerindo uma possível estabilidade. Pode-se concluir que ocorreu um considerável refinamento do tamanho de grão em função da elevada fragmentação e rotação da subestrutura após os passes de deformação.

Aug 8, 2018

By Mark Cadzow, Rodney Lamb

CARBAD is a recently developed Australian process for the recovery of gold and platinum group metals (PGM). The process relies on the selective agglomeration phenomena of the gold and PGM to capture the mineral in a carbon-hydrocarbon media. The precious minerals are then extracted from the loaded media by a solvent gold room process producing a relatively pure concentrate. The media is then reformed and recycled. The process development from batch test work to a 5 t/h commercial scale CARBAD plant is discussed. The operation and results of processing a variety of ore types at several alluvial and hardrock gold mines is examined. The operating and capital costs for the CARBAD process shows that it is significantly less than that the conventional CIP/CIL. The environmental safety of the process is a major feature where precious metal deposits are located within urban environments or within wilderness areas.

Jan 1, 1989

By Maria José Santos Lima

A pesquisa e o desenvolvimento de Materiais nanoestruturados vêm crescendo significativamente nos últimos anos. Estes materiais apresentam propriedades significativamente modificadas em comparação às dos materiais convencionais, devido às dimensões extremamente reduzidas dos cristalitos. O carbeto de Tântalo (TaC) é um material extremamente duro, apresentando elevada dureza, elevado ponto de fusão, elevada estabilidade química, boa resistência ao ataque químico e choque térmico e excelente resistência à oxidação e corrosão. Desta forma este trabalho teve como objetivo a obtenção de TaC nanoestruturado a partir do precursor tris(oxalato)oxitantalato de amônio hidratado, através de reação gás-sólido a baixa temperatura (1.000°C) e curto tempo de reação. Os materiais obtidos foram caracterizados através de difração de Raios-X (DRX), Refinamento Rietveld, Microscopia Eletrônica de Varredura (MEV), Espectroscopia de Infravermelho (espectroscopia IV), Termogravimétrica (TG). Através das analises de DRX e do refinamento Reitiveld para o TaC com S = 1,1584 observou-se a formação do carbeto de tântalo puro com estrutura cúbica e tamanho médio de cristalitos na ordem de 12,5 nanômetros.

Aug 7, 2018

By Sander Mul, Michael Brandner, Armin Paar

Graphitic HSS roll grades such as ESW’s brand VANIMO can be considered as the latest developments for the last finishing stands in hot strip mills. These roll grades are developed on the basis of the alloying concept of (Carbide Enhanced) Indefinite Chill work roll materials. During the development of VANIMO, the amounts and types of carbide forming elements were increased and adjusted into the direction of cast HSS roll grades. The microstructure of graphitic HSS roll grades therefore consists of tempered martensite, cementite and several different carbide types as well as a well-defined amount of free graphite. The main purpose of graphitic HSS roll grades is to combine the high surface quality of Indefinite Chill alloys as well as the high wear resistance of HSS roll grades. Several systematic steps were taken to increase the wear performance from Carbide-Enhanced Indefinite Chill grades to the more advanced VANIC grade and further on to the highest alloyed roll grade VANIMO. In every development step, the surface quality of the roll grades was carefully monitored. The decision to invest in new testing equipment at ESW’s plant was driven by the wish to see microstructural effects of different alloys in a macroscopic dimension. Usually samples are taken from cast rolls and investigation is done in comparably small areas compared to the total surface of a roll. Rolling of strip is done with the entire barrel, so effects of alloy and microstructure can appear anywhere on the barrel surface. To ensure better understanding and deeper knowledge about influences of alloying trials we decided to install the last version of LRI (Lismar Roll Inspection). LRI includes the latest technology of Eddy Current with an enormous resolution. Depending on the formation of carbide precipitations, carbide network as well as matrix and free graphite, the EC test can detect smallest differences. The possibility to analyze the different results of EC and UT surface wave inspection will be discussed. A few examples of surface effects in the mill application will be discussed and improvement strategies explained.

Oct 1, 2019

By Walter Crafts, C. M. Offenhauer

IN the course of study of the heat-treatment of low-alloy steels, the behavior of alloy carbides at subcritical temperatures was found to vary from that indicated by published investigations. In order to establish the ranges of formation of carbides in low-chromium steels, a series of steels containing up to 0.60 per cent carbon and 7.5 per cent chromium has been investigated with respect to the type of carbide formed after quenching and tempering at subcritical temperatures. The types of carbide formed as products of austenite transformation to pearlitic and pseudomartensitic structures have also been determined. There have been numerous investigations of the carbides in chromium steels and diagrams of the iron-chromium-carbon system.1 Westgren, Phragmén and Negresco2 identified the following carbides in chromium steels: [Cementite Fe3C (containing up to about 15 per cent Cr) Trigonal carbide Cr7C3 (containing up to about 55 per cent Fe) Cubic carbide Cr4C (or Cr23C3) (containing up to about 25 per cent Fe) Orthorhombic carbide . Cr3C2 (containing only a few per cent Fe)] The most complete information on the iron-chromium-carbon system was supplied by Tofaute, Sponheuer and Bennek3 and by Tofaute, Küttner and Büttinghaus.4 By means of dilatometric and microscopic studies, sections of the diagram were established. This diagram showed the presence of the special carbide Cr7Ca in steels containing about 2.5 per cent to 12 per cent chromium in low-carbon steels and from about 5 to 20 per cent chromium in r per cent carbon alloys from A1 to room temperature. The present investigation has shown that a carbide inversion from Fe3C to Cr7Ca occurs in chromium steels containing more than about 1 per cent chromium after hardening and tempering at subcritical temperatures above about 500°C. The type of carbide observed to be more stable in quenched and tempered specimens was also found to be produced by direct austenite transformation in corresponding ranges of temperature and composition. EXPERIMENTAL PROCEDURE The steels used in these experiments were made in magnesia-lined crucibles in high-frequency furnaces and were poured into 2-in. ingots. The ingots were forged into 1-in. round bars, and all heat-treatments were conducted on specimens of this section .size. Sections of the bar stock 8 in. long were hardened in air, oil or water depending on the composition, after heating to a temperature sufficiently high to dissolve the carbides. The low-carbon and low-chromium steels were not entirely martensitic after quenching, and contained some ferrite and pseudomartensite. No pearlite was observed in the microstructures after auenchine. The quenched bars were cut into

Jan 1, 1942

By Liang Li

Thermodynamic analysis and experiments were conducted in order to verify the feasibility of preparing crude titanium tetrachloride (TiCl4) via the carbochlorination of low-grade titanium slag in molten salt. Titanium slag, assaying 74.6 wt% TiO2 with high calcium and magnesium oxide impurities, was treated by an optimized carbochlorination process in NaCl molten salt. These impurities in the titanium slag were chloridized simultaneously, and chlorination products FeCl2, MnCl2, MgCl2, CaCl2 and CrCl3 were collected in the furnace slag. XRD and SEM/ EDS analysis of residue shown that SiO2 and Al2O3 in titanium slag were difficult to chlorinate completely. Theoretical calculations and industrial-scale experimental studies reveal the content of TiCl4 in the products was more than 98.8 wt% and thus proved the feasibility of utilizing low-grade titanium slag for TiCl4 preparation by molten salt chlorination technology.

By Mei Song, Qingyu Deng, Xuewei Lv, Lu Liu, Chenguang Bai, Meilong Hu

"The carbochlorination of several silica materials was carried out in the temperature range from 900 °C to 1200 °C. In this study, silica oxides and gaseous chlorine with carbon as reductant were used. The optimal carbon silica mole ratio in different temperature was calculated by Factsage software and the results showed that the optimal values are 1.2, 1.4, 1.6, 1.8 at 900 °C, 1000 °C, 1100 °C, 1200 °C, respectively. According to the experiments, the chlorination ratios of several silica materials were increased with temperature increasing. In the same temperature, the chlorination ratio of diatomite is the maximum and the chlorination ratio reaches 79%% when C/SiO2 reaches 3 at 1100 °C.1, IntroductionPolycrystalline silicon is the main material to manufacture the silicon polished section, solar battery[1] and high purity silicon wafers[2], also which is the most basic function material of semi-conductor industry, electronic information industry and solar photovoltaic battery industry[3]. The conventional manufacturing process of polycrystalline silicon would be divided into three parts: the improved Siemens method, which was introduced and became the main process to produce the polysilicon products in China. Silane method and fluidized bed method. Silicon tetrachloride and chlorosilans have been employed as by-products in several fields like electronic, telecounications and metallurgy[4-6]• At present, the main applications of silicon tetrachloride include production of trichlorosilane by catalytic hydrogenation, synthesis of fumed silica and ethyl orthosilicate, production of optical fiber grade silicon tetrachloride.The conventional routes for the silicon tetrachloride production have been reported, including the direct chlorination and the chlorination process of ferrosilicon, abandon catalyst and silica[7]."

Jan 1, 2013

. F. W. SPERR, JR.,* Pittsburgh, Pa.--Mr. Malcolmson states that the Carbocoal process produces ammonium sulfate in excess of that normally recovered in the ordinary byproduct coke process. Table 3 indicates that 20,000 to 25,000 lb. of sulfate of ammonia are obtained in carbonizing 1000 tons of Clinchfield coal. This is a high-grade coal and yields from 26 to 28 lb. of ammonium sulfate per ton in a modern byproduct coke oven. On the next page, 21 lb. is stated as the yield of ammonium sulfate per short ton of raw coal; this is less than the average production from any well operated byproduct coke-oven plant treating coal of the character usually coked, in Pennsylvania and Ohio. The statement as to the comparative yields of light oil is somewhat misleading in view of the results obtained during the past year or two by the more modern byproduct coke plants. The plants put in operation by the H. Koppers Co., during the past two years, are producing about 3.5 gal. of light oil per short ton of coal, and several of these plants are producing more than 4 gal. per ton. The yield of pure toluene runs from 0.45 gal. to 0.55 gal. per ton. .The quality of the light oil .obtained from the Carbocoal process is of much greater importance than would be inferred by one not closely familiar with the subject. The presence of paraffins in the benzol and toluol fractions seriously detracts from their commercial value; the benzol and toluol fractions derived fro in the Carbocoal process contain about 50 per cent, of paraffins. It should be thoroughly understood what these paraffins are. They are simply hydrocarbons that go to make up ordinary petroleum, and if a successful method for the removal of paraffins from benzol and toluol has been developed, this can at once be applied to several well known processes by which benzol and toluol can be made directly from petroleum, which have as yet been total failures on account of the contamination of these products by paraffins.

Jan 11, 1918

By W. R. Boehme

The test work was done in two parts. In Part I, five 6 x 16 mesh activated coconut shell carbon samples made by four different manufacturers were evaluated as to their gold loading rate and total gold loading. The five carbon samples tested are not identified by manufacturer and are simply designated as Types A through E. Then from the carbons tested, a suitable highly active carbon was selected for subsequent studies on impurity effects upon loading, Part II. Test Procedures The procedures and tests descriptions are given for the ultimate gold carbon loading tests and the dynamic gold carbon loading tests.

Jan 1, 1983

By B. Pesic

This is an extension of the work on recovery of silver and manganese from Ag-Mn ores, and recovery of silver and gallium from flue dust from phosphate industry. Carbon adsorption was considered as the most adequate method for recovery of silver from thiourea leach solutions. For this reason it was decided to examine the characteristics of adsorption of silver on activated carbon. Coconut hard shell activated carbon was used for this study. Ag(TU)2C1 complex was dissolved into thiourea solution to give 2 gpl stock solution. Thy studied parameters were: loading isotherms at 25°C, 35°C, and 45°C, initial kinetics as a function of thiourea concentration, temperature, pH, N2, and O2. It was found that the loading capacity of carbon for silver and thiourea was 137-150 mg/g and 514 mg/g, respectively, at 25 °C.

Jan 1, 1986

By J. Bullón, A. Pérez

Some years ago, Ferroatlantica developed a new type of electrode known as the ELSA electrode. In this electrode there is a central graphite core that provides support, surrounded by an annulus of Søderberg paste that gets baked during operation. This technology has been implemented on several silicon furnaces around the world, and was reported on during the previous Infacon conference. In all electrodes, but particularly in the ELSA electrode, the quality and consistency of the paste are important for correct operation. As the type of paste varies between customers and between countries, Ferroatlantica has developed a quality control procedure for their customers of this technology. This procedure is geared to the point of view of the customer rather than the paste producer. The analysis is based on the desired flow pattern of the raw paste and on the desired mechanical and electrical properties of the baked paste, as experience has shown that these are the most important parameters to monitor in order to avoid having problems with the resulting electrodes. This paper discusses these methods of paste analysis in the light of complementary studies that have been done when there has been an electrode breakage in the different plants.

Jan 1, 2007

Table 1.-Salient statistics of carbon black produced from natural gas and liquid hydrocarbons in the United States [ ]

Jan 1, 1967

By Donald S. Colby

CARBON-BLACK shipments, which had declined in the latter art of 1953, remained low in 1954 until after settlement of the labor strike that occurred in the rubber industry in July and August. The production of new model automobiles in the last quarter of the year spurred the demand for rubber tires and consequently the demand for carbon black. Total shipments of 1,498 million pounds for the year were 4 percent below 1953.

Jan 1, 1958

By Ivan F. Avery

DOMESTIC production of carbon black increased 4 percent in 1962 to 2,056 million pounds. Furnace black output was 8 percent, or 132 million pounds, above that in 1961 and accounted for 90 percent of total carbon black production. Channel black output continued to decline and was 55 million pounds less than in 1961. Carbon black shipments during the year totaled 2,082 million pounds and were 5 percent above those of 1961. About one-fifth of these shipments were exported; the balance were sold domestically. An increase of 180 million pounds in domestic sales was partially offset by a decline of 80 million pounds in exports. Total value of carbon black production in 1962 was $145 million. The average value per pound of 7.06 cents was 0.24 cent per pound less than in 1961. Producers' stocks declined 26 million pounds during the year.

Jan 1, 1963

By William B. Harper

Domestic sales of carbon black sustained the upward movement for the 4th consecutive year, reflecting the increased sales of motor vehicles during the same period. Sales of carbon black in the domestic market topped 2 billion pounds for the first time during 1965 and have more than doubled the output of 20 years earlier. By far the largest user of carbon black is the rubber industry. That use accounted for more than 94 percent of the carbon black consumption with the bulk of it being used in tire casings and tubes. Thus demand for carbon black is naturally sensitive to trends in the sales of passenger cars and other motor vehicles, Manufacturers of inks, paints, plastics, paper chemicals, and food are also important users of carbon black.

Jan 1, 1967