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By Mohammed Al Maadheedi

This paper explores the capacity effects of a square steel plate welded at the ground surface on a driven open-ended steel pile (i.e. the plate would touch the ground surface after the pile achieves the required penetration). A series of strain-controlled, 1-g laboratory tests were undertaken on piles with and without a square steel plate attached. The piles were driven in dry, loosely packed, uniform sand. Two plates were used, one with a breadth equal to two times the diameter of the pile (2D) and the other with a breadth equal to three times the diameter of the piles (3D). A 20% increase in capacity was recorded for the 2D plate, and a 110% increase in capacity was recorded for the 3D plate when compared to the pile without an attached steel plate. The back-analysis of the results allowed the derivation of a new expression to calculate the capacity of bearing plates, which accounted for the effects of sands compaction and dilation. By extrapolating the findings of these tests to a hypothetical scenario, a model design problem was described where the length of a pile can be reduced by 20% to 60% (depending on the load) by using a plate attached to the pile. The results of this study can help designers to minimise penetration depth; thus, achieving a more economical and sustainable design.

By Christopher Jon Preston

This paper describes a type of ammonium nitrate (AN) produced in a patented experimental atomization/aerodynamic process. This AN exhibits outstanding properties for use as a main ingredient to a new family of AN-based commercial explosives. Micro-particle ammonium nitrate (MP-AN) is produced by atomizing either an 83% or 85% AN solution which has been doped with a two component surfactant NSol 1000 (NSol). NSol imparts some water-resistance as well as provides a means of increasing density and bulk strength. Increased detonation velocities, well in the range of emulsion explosives, can be achieved. The maximum manufacturing temperature is less than 100°C. The methodology has the potential of being environmentally friendly since any effluent can be recycled back into a make-up tank to be re-used by the closed loop method. The process has a small footprint.

Jan 1, 2015

By R. Hazael, R. Alford, R. Critchley

The ability to compare explosives is fundamental. Numerous methods are used and while simple conversion factors are often used, the use of TNT Equivalency (TNTe) is not a simple subject as explosives exhibit very different equivalencies depending on whether the pressure or impulse are being considered as well as other conditions. The scaled distance has been found to have a significant effect on the TNTe but due to the difficulty of taking measurements at very close ranges, no TNTe have been quoted for charges in direct contact (Z=0). This paper describes the use of a ballistic pendulum to measure the impulse from contact charges and presents some surprising results that require a two-stage propulsion, as originally described by Backofen, to be explained.

Jan 1, 2024

By Margreth Tadie, Chalwe Chibwe

Physicochemical properties of copper electrolytes are a strong fundamental consideration in electrodeposition processes during electro-purification and recovery of copper. Their influence extends to mass transfer as well as energy consumption during the electrodeposition process. In this study, the influence of electrolyte composition on electrolyte physicochemical properties was investigated to review the existing literature data. This review of data is considered necessary as more and more electrowinning models are being developed for process prediction and optimisation and a need of such data is required for accurate prediction of physicochemical properties. The major components of importance to the formation of smooth high-quality and high-purity copper cathodes at optimum current efficiency are considered the species in solution. These include Cu ions, Fe ions (major impurity), H2SO4, and a smoothing agent additive. A 5-factor, 2- and 3-level experimental design was employed to determine the effect of copper (35 and 45 g/l), sulphuric acid (160 and 180 g/l), iron (1, 3, and 6 g/l), polyacrylamide additive (2, 5, and 10 mg/ l), and temperature (45 and 55 °C) on electrolyte density, conductivity, and the diffusion coefficient in synthetic copper electrowinning electrolytes. The major species in a copper electrowinning electrolyte are found to be the most relevant for prediction of physicochemical properties. These results indicate that relatively simple empirical models are sufficient for modelling of the electrolyte domain in electrowinning, without the need for the generation of vast amounts of complex experimental data.

Feb 1, 2021

By N. P. Reddy

This paper describes an experimental setup for multiple-fan ventilation systems at the ventilation laboratory of the WVU Department of Mining Engineering. Housed in a 30 ft by 70 ft room, the experimental setup consists of three 18 in. variable-speed axial-flow fans, the 18 in. diameter fiberglass tubing and fittings for arranging networks, and the pitot tube measuring and data acquisition system. The fiberglass tubing and fans can be organized into the non-planner network of two fans or three-fans. It is mainly designed for studying the characteristic curves, operating points, and fan stall for the multiple-fan ventilation system.

Jan 1, 1992

By M. Nilmani, J. Sofra

The transverse distributions of the solids discharge velocity and mass flux at the discharge end of vertical and inclined lances were measured in order to detennine the transverse distributions of the axial momentum flux, which is a dominant factor influencing the penetration behaviour of particles into melts during submerged injection. The effects of gas velocity (10 - 30 m/s), solids loading (5 - 10), lance length (0.15 - 1.0 m), lance inclination (vertical downward - horizontal) and particle density (2500 - 8900 kg/m3 ) were investigated, while the lance diameter and particle size were fixed at 10 mm and 220 µm respectively. The particle velocities and mass fluxes were measured by image analysis of particles illuminated in a laser-generated light sheet aligned vertically through the axis of the lance at the discharge point. The particle discharge velocity profiles for vertical downward flows were synunetrical about the centre-line of the lance, with the maximum velocities occurring at the centre-line. The velocities increased with increasing gas velocity, increasing lance length and decreasing particle density in accordance with previous observations. The transverse mass flux profiles were also synunetrical for vertical downward flows, however at the lower gas velocities the peaks in the profiles were displaced from the centre-line of the lance by a fractional diameter of about 0.15. The particle discharge velocity profiles become increasingly asynunetric as the lance orientation was changed from vertical to horizontal, with higher particle velocities present near the top wall of the lance. The mass flux profile also became asyrrunetric as the horizontal orientation was approached, however in this case, the profile became biased towards the bottom of the lance. The effect was much more pronounced for a gas velocity of 10 m/s than for 30 m/s, showing the relatively stronger gravitational influence as the velocity was reduced.

Jan 1, 1996

By Guanghua Ai, Xiong Huang, Huashan Yan, Ting Li, Tingsheng Qiu

"Cyanide tailings of gold and silver concentrates contain considerable quantities of copper-lead-zinc sulfide minerals that can be recovered. However, the strong inhibition effect of cyanide often makes it difficult to recover these sulfide minerals effectively. In this research, a sample of cyanide tailings was investigated based on the principles of process mineralogy; activating flotation tests were carried out for the target minerals in the tailings, and the activation mechanism of the activator and its influence on the target minerals were investigated by Fourier transform infrared spectroscopy (FTIR). Mixed flotation of copper and zinc was carried out using QJ-01, a combined agent containing sulfite, as the activator of copper and zinc minerals, and ammonium dibutyl dithiophosphate (ADD) and butyl xanthate (BX) as the combined collector. Copper concentrate was obtained from the mixed concentrate by using a combined inhibitor of sodium sulfide and zinc sulfate to inhibit the zinc mineral. Zinc concentrate was extracted from the copper tailings by using copper sulfate as the activator and BX as the collector. The flotation test yielded copper concentrate with a grade of 22.56% and recovery of 76.96%, and zinc concentrate with a grade of 42.56% and recovery of 82.29%, which shows that comprehensive recovery of the sulfide minerals – copper and zinc –from the cyanide tailings was realized. The FTIR analysis showed that CN- was chemisorbed on the surface of chalcopyrite and sphalerite following cyanide treatment, while the combined activator QJ-01 containing sulfite reduced CN- into SCN- and weakened the complexing ability of CN- with metal ions on the mineral surface, thus achieving a good activation effect on chalcopyrite and sphalerite. The results of this study can provide practical guidance in increasing the resource utilization ratio of cyanide tailings in gold mines, and thus contribute to alleviating environmental problems caused by stockpiling cyanide tailings. INTRODUCTION Cyanidation, the most widely used technology for extraction of gold, has several advantages such as high recovery, process maturity, low cost, etc. According to available data, the annual discharge of cyanide tailings from China's gold mines exceeds 20 million tons (Li et al., 2011). Lower grades of exploitable gold ore entail increased discharge of cyanide tailings. Huge quantities of cyanide tailings are regarded as waste and stored, resulting in significant wastage of land resources. Moreover, residual beneficiation reagents, cyanide ions, and heavy metal ions in cyanide tailings cause severe pollution of water and land (Laitos et al., 2013; Donato et al., 2007; Mudder and Botz, 2004). In addition, cyanide tailings often contain valuable elements such as gold, silver, copper, lead, zinc, sulfur, and iron, which, if not recycled, would result in considerable wastage of resources. Hence, it is imperative to study the reduction and safety of cyanide tailings, and the mineral resources present in them."

Jan 1, 2018

This paper presents the findings from an experimental study of the effects of shock and gas penetration breakage mechanisms in rick blasting. A blasthole liner method, which realistically seperated these two basic sources of energy in blasting, was developed and utilized. The use of four different explosives with contrasting detonation behaviour produced a wide variation in the nature of explosive energy transfer to the rock. Through extensive field experiments it was found that, relative to low VOD dynamite, the high VOD emulsion imparted greater shock to the rock and therefore produced finer fragmentation and greater back damage. The comparatively lower heave energy of the emulsion caused less immediate blast results were obtained with watergel and ANFO explosives, which have detonation behaviour and energy partitioning charecteristics lying between emulsions and dynamite.

Jan 1, 1990

By M. Boher, J. Lehmann, M. C. Kaerlé

"In the production of high quality steel, the understanding of the interactions between liquid steel and refractories and of their effect on steel purity and cleanness are becoming more and more important.An experimental study has been per-formed in order to estimate the importance of the reaction between a MgO-based tundish refractory and an Al-killed steel. The results show a pollution of the liquid steel:•the silicon content of the liquid steel increases due to the reduction of the silica of the refractory by the aluminum contained in the steel; and•a reoxidation of the steel occurs and the formation of an oxide layer on the refracto-ry, mainly composed of spinel crystals and of Ca-aluminates is observed.The transfer mechanisms of the various elements are analyzed."

Jan 1, 1997

By Shailendra Chawla, Ashok Jaiswal, Sonu

Side spalling/skin failure occurs due to the high-induced stress in underground structures. In such cases, rock bolting or other support systems are being used to control the skin failure or spalling of the pillar. The nature of these support systems is passive, which acts during the deformation. These support systems restrict the displacement considerably of the side/or roof surface of the excavation. Ultimately, it improves the stability of the structure because of the increment in residual strength of rock mass. It is noted that these passive support systems give very low confinement in the range of 0–0.015 MPa at the onset of failure. As the level of confinement will be very low and dependent with progress of failure, triaxial test was not found practically suitable. Thus, an alternative procedure of testing has been proposed. In the procedure, sides of sample have been restricted little bit by using adhesive tape. It provides the limited boundness on the lateral direction (LBLD) of rock specimen. The uniaxial compression strength (UCS) test has been performed on 30 numbers of cylindrical rock specimens using the servo-controlled stiff testing machine. Specifically, two rock types (medium-coarse–grained and coarse-grained rocks) were studied in terms of stress–strain behaviour so that a full residual strength envelope for each specimen was obtained. This study reveals that the residual strength of limited confined rock specimens has been significantly increased as compared to unconfined rock for both groups of rock types. The average residual strength of LBLD specimens of fine-grained rock and medium coarse-grained rock has been increased around 12 times, and five times as compared to unconfined rock, respectively. The average peak strength of LBLD rock specimens has been increased in the range of 30.5 to 48.6% for coarse-grained rock. The results of this study have been presented in terms of peak strength, residual strength and Young’s modulus of rock, and the post-peak failure behaviour of rock specimens was also critically analysed through a stress–strain curve.

Mar 21, 2024

By Youjun Tao

Falcon centrifugal gravity separation tests were conducted to study desulfurization and de-ashing performance with different size fractions of a high-sulfur Chinese -0.5mm fine coal in a dense medium. Performance indicators such as combustible recovery, ash and sulfur rejection, and desulfurization efficiency were used to evaluate the separation efficiency. The results show that for -0.5 mm coal particles, all performance indicators except ash rejection are higher for the Falcon concentrator than for flotation. More specifically, for the +0.125 mm size fraction, Falcon centrifugal separation produced better ash and sulfur rejection performance than froth flotation. However, the Falcon concentrator also showed higher combustible recovery but lower ash and sulfur rejection than froth flotation for the -0.125 mm size fraction.

Aug 1, 2013

By M. Dayne Aldridge

A description is given of an experimental ventilation control system designed, built, and tested by WVU under United States Bureau of Mines sponsorship. A description is given of the control, system used and the mine-wide microcomputer-based ventilation monitoring system used with it. Test results of experiments conducted with this system at Eastern Associated Coal Corporation's Federal No. 2 underground coal mine are presented. In addition, a brief description is given of a new microprocessor based system presently being tested.

Jan 1, 1980

By Randy Ynchausti

ERIC GUTIERREZ, Knowledgescape: Our next speaker is Randy Ynchausti. He's the director of development, Knowledgescape systems division, of EIMCO Process Equip- ment Company. The title of Randy's talk is "An Expert Control System for Phosphate Beneficiation." RANDY YNCHAUSTI: System integration. How does the systems integrator survive when caught between plant engineers, plant management, and third-party engineering firms, and stay within the budget of the corporate goals? I'm not sure that anyone knows how to do all of that on one project. Results are critical when we talk about how systems integrators work with operating people, how the operating people want systems integrators to work with them, and how both groups work together so that at the end of a project, you have been provided with solutions that meet your needs and solve your problems at a fair price. How does the integrator's role change when working with different types of professionals, such as plant managers, plant engineers, engineering firms, or other system integrators? Finally, what is the dynamics of people working with machines and providing services and solving needs? The average number of employees per pound of copper processed has decreased significantly during the past 15 years. I would dare to generalize and say that the average number of employees per whatever unit of measure we have in whatever industry we work in has decreased over the last 15 years. From a system integrator's perspective, there are some clients who lack a bit of internal expertise as corporate downsizing occurs, and that's one reason why we go out to system integrators or third-party vendors and buy things from them to solve our problems. Downsizing really amounts to savings, but more than that, I think Brian expressed this and I agree with him, it also amounts to a cost. Unfortunately, most of us count the savings and none of us count the cost in that approach. It's easy to count the savings, which is one reason why we count it so quickly. Maybe that also accounts for why we set our pencils down so quickly after we get that dollar value. Maybe we should pick that pencil up every once in awhile and refigure the expense, the cost to us, and determine what we're going to pay during the next year or two or three in losing that expense, or that staff. A broad experience base accumulated over projects at various plants helps system integrators to provide services to clients. This experience enables the system integrator to

Jan 1, 1998

By A. V. Z. Brink

Rock engineering risk is defined in this paper as a function of the potential ground motion; the vulnerability of the workplace; exposure of people; and a general term – quality of information. The paper describes the development of prototype software that is a combination between an expert system approach for determining overall risk assessment, a risk control recommendation and a basic GIS (Graphic Information System) approach for graphically overlying input parameters and the output risk. The expert system uses a Bayesian probabilistic approach to combine various workplace-related information, a quantified seismological environment and the exposure of underground staff to provide an overall RE risk rating. The risk assessment is dynamic in that it is recalculated each time that any of the input parameters change, for example each time a seismic event is recorded in the area of interest. The code was tested on a data set from Savuka Gold. As risk assessment is not an absolute prediction of a specific outcome, it is therefore not possible to relate to individual case studies and the reliability of this method would only be determined after an extensive period of use with appropiate back-analysis. Le risque dans le génie minier est défini dans cette étude comme une fonction du mouvement potentiel de terrain ; la vulnérabilité du lieu de travail ; l’exposition des personnes ; et un terme général – la qualité de l’information. L’étude présente décrit le développement d’un logiciel prototype qui est une combinaison entre une démarche de système expert pour déterminer une évaluation générale du risque, une recommandation pour le contrôle du risque, et une démarche de SIG (Système d’Information Géographique) pour superposer graphiquement les paramètres d’entrée et le risque de sortie. Le système expert utilise une méthode de probabilité bayésienne pour combiner des informations variées sur le lieu de travail, des données quantifiées sur l’environnement sismique, et l’exposition du personnel travaillant sous terre, pour finalement produire un classement général de risque minier (RE). L’évaluation du risque est dynamique en ce sens qu’elle est recalculée à chaque fois qu’un des paramètres d’entrée change, par exemple à chaque fois qu’un évènement sismique est enregistré dans la région. Le code fut testé sur un ensemble de données obtenues de Savuka Gold. Comme l’évaluation du risque ne constitue pas une prédiction absolue d’un résultat spécifique, elle est par conséquent difficile à rattacher à des cas individuels et la validité de cette méthode ne pourrait être déterminée qu’après une longue période d’utilisation avec analyse rétrospective appropriée. Das Gesteinstechnikrisiko wird in dieser Arbeit als Funktion einer möglichen Bodenbewegung definiert; die Anfaälligkeit des Arbeitsplatzes; das Ausgesetztsein der Belegschaft; und ein genreller Begriff - Qualität der Informationen. Das Papier beschreibt die Entwicklung einer Prototyp-Software, die eine Kombination zwischen einem Expertensystemzugang für die Bestimmung der gesamten Risikobeurteilung ist, eine Empfehlung zur Risikokontrolle und eines fundamentalen GIS (graphisches Informationssystem) Zuganges für graphisch darüberliegende Eingangsparameter und das Outputrisiko. Das Expertensystem verwendet eine bayesische Wahrscheinlichkeitsannäherung, um verschiedene mit dem Arbeitsplatz in Verbindung stehende Informationen, ein quantitativ bestimmtes seismologisches Umfeld und das Ausgesetztsein des Untertag-Personals zu kombinieren, um eine gesamte RE-Risikobewertung zur Verfügung zu stellen. Die Risikobeurteilung ist insoferne dynamisch,daß sie stets nachkalkuliert wird wenn sich irgendeiner der Eingangsparameter ändert, z.B. jedesmal wenn ein seismischer Fall im Interessensbereich aufgezeichnet wird. Der Code wurde auf einem Datenbestand von Savuka Gold geprüft. Da die Risikobeurteilung nicht eine absolute Vorhersage eines spezifischen Resultates ist, es ist folglich nicht möglich, sich auf einzelne Fallstudien zu beziehen und die Zuverlässigkeit dieser Methode könnte nur nach einer umfangreichen Benutzungsdauer mit geeigneter Postanalyse bestimmt werden.

Jan 1, 2003

By John D. Carriere, Jean Leung, Daniel. Laguitton, Michael .. J. Burrows

"The objective of this expert system application in a copper-zinc concentrator, is to increase the availability of assay data through substitution for erroneous data. The assay data is used by the Operations personnel and automatic process control strategies to control flotation circuit performance. Two online X-ray fluorescence analysis systems analyze 24 streams across four divisions to provide the required data. Data availability of individual streams average 90% while the resulting circuit availabilities are 70%. The unavailability of correct data results from mechanical, X-ray or process problems. The erroneous data can be identified by process experts using knowledge relating stream interdependencies and historical process behaviour. An expert system was devised to provide real time identification of erroneous data and substitute for that data with the ultimate aim of improving metallurgical response by both the operator and automatic control systems.The paper discusses the early development work and architecture of the knowledge base designed using Neuron Data's expert shell NEXPERT.INTRODUCTIONThis paper describes the early development of an expert system (ES) prototype at the Kidd Creek concentrator. The project is a joint undertaking of the Kidd Creek Division of Falconbridge Limited and CANMET. Kidd Creek entered into the project to apply heuristic rules to the XRF assay data to improve the metallurgical control of the flotation process by increasing availability of analysis data. This project provided a problem of suitable size and future expandability while making use of a wide base of in-house expertise and experience. Another important benefit is the introduction of expert system technology to the site providing tools and experience for future system selection and technology application. CANMET has an on-going interest in assessing various aspects of ES technology (hardware, software, knowledge engineering, integration) while addressing problems in process operations that could most readily benefit from the technique. CANMET's role in the project was to provide project assistance, financial support, substitution algorithm assistance and software for data substitution. The knowledge bases (rules) have now been completed and are to be tested in the online environment."

Jan 1, 1989

By Wang Yingmin, Xu Zhuyun

There are 3 steps in the process of forming a mine ventilation system, (1) selecting a reasonable ventilation pattern (included pit shaft arrangement); (2) optimizing of the ventilation network and (3) computing and outputting the flow splitting results of the network with the optimal ventilating equipments selected. In the past, the first step was relied on artificial decision-making. In order to design a common ventilation system, some ventilation experts were needed to participate or do some examinations. Even so, the design made was reasonable only for those experts. If there is a mistake in the first step, then even the followed 2 steps are best done, the losses are very difficult to retrieve. So that, the first step is very important. The development of expert systems provided an efficient means and tool for all engineering fields. This paper presents an expert system of selecting mine ventilation pattern and pit shaft arrangement. After testing many times, it is shown that the system can perform the first step of designing a mine ventilation system, and can help the experts doing their study works more efficiently.

Jan 1, 1991

By Andrew L. Mular, Robert P. Edwards

"The operation of flotation circuits is often regarded as a combination of art and science. Expert systems offer a method by which the art may be captured and supervisory control of flotation circuits fully realized. Operating knowledge, the art, can be consistently employed to enhance regulatory control through the judicious application of an expert system. Using an expert system, a supervisory control routine was developed, and success- fully implemented, in the copper flotation circuit at Brenda Mines Ltd.The expert system ran in conjunction with regulatory PI controllers on a personal computer. The expert system received assays via an on-stream analyzer and adjusted regulatory loop set points as required in real-time. From its commissioning in November, 1989, to the end of the mine 's operation in June, 1990, it was enthusiastically embraced by the operators and attained operating levels superior to those achievable manually.IntroductionExpert system (ES) software springs from research into artificial intelligence and is currently making significant inroads into business and industry. ES proponents make many attractive claims; they are a means of capturing the knowledge of experts and they can be programmed by non-programmers. To date, most uses of this software in the process industry are in off-line applications, meaning that the applications are not tied directly to operating (on-line) environments. Moreover, in on-line environments, they are typically employed as advisors and only suggest changes. Human operators are required to close-the-loop to the process. Yet, an ES should be applicable to operating environments and, if the claims of the proponents are valid, should also be better than existing tools. As an intelligent controller an ES must use the knowledge of experienced operators, apply it directly to a process and do this without the intervention of human operators. On-line applications have been successfully employed in the closed loop control of SAG circuits (Herbst et al., 1989) and flotation circuits (Hales, 1989). Harris and Kosick (1988)detail an implementation for flotation control at the Polaris Mine."

Jan 1, 1992

By A. L. Mular, R. P. Edwards

"The operation of flotation circuits is often regarded as a combination of art and science. Expert systems offer a method by which the art may be captured and supervisory control of flotation circuits fully realized. Operating knowledge, the art, can be consistently employed to enhance regulatory control through the judicious application of an expert system. Using an expert system, a supervisory control routine was developed, and successfully implemented, in the copper flotation circuit at Brenda Mines Ltd.The expert system ran in conjunction with regulatory PI controllers on a personal computer. The expert system received assays via an on-stream analyzer and adjusted regulatory loop setpoints as required in real-time. From its commissioning in November 1989, to the end of the mine's operation in June, 1990, the ES was enthusiastically embraced by the operators and attained operating levels superior to those achievable manually.INTRODUCTIONExpert system (ES) software springs from research into artificial intelligence and is currently making significant inroads into business and industry. Proponents of ES's make many attractive claims; they are a means of capturing the knowledge of experts and they can be programmed by non-programmers. To date, most uses of this software in the process industry are in off-line applications, meaning that the applications are not tied directly to operating (on-line) environments. Moreover, in on-line environments, they are typically employed as advisors and only suggest changes. Human operators are required to close-the-loop to the process. Yet, ES's should be applicable to operating environments and, if the claims of the proponents are valid, should also be better than existing tools. As an intelligent controller an ES must use the knowledge of experienced operators, apply it directly to a process and do this without the intervention of human operators. On-line applications have been successfully employed in the closed loop control of SAG circuits (Herbst et al., 1989) and flotation circuits (Hales, 1989). Harris and Kosick (1988) detail an implementation for flotation control at the Polaris Mine."

Jan 1, 1991

By Fabjanczyk MW, Aziz NI, Hii J

The paper presents the results of a series of pull out tests performed on roof reinforcement systems currently being adopted in mines in Australia 7mm wire, dividag bar, 15.2mm strand cable, and birdcage cable. The study also investigated the load deformation chara- cteristics and the various design parameters controlling the effectiveness of a cable-grout system. Suggestions for continued work are Highlighted.

Jan 1, 1986

By D. A. Stanley, B. J. Scheiner, P. M. Brown

The Bureau of Mines (USBM), US Department of the Interior, has developed a method of dewatering clay slurries based on flocculation by high-molecular-weight polymers and water removal from the formed flocs using a trommel or hydrosieve. The exchange ion on the clays affects their dewaterability. Metal ions in solution and on the exchange sites of smectite clays are known to act as Lewis acids. Recent work has determined that these ions can be titrated with high-molecular-weight polymers. The relative acidity of the exchange ion and the basicity of the polymer determined by the new method give insight into the dewatering mechanism.

Jan 1, 1990