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By Long Han, Jianyuan Liu, Ping Ying

"Particle-bed compressive stressing is the main work mechanism of comminution by high pressure grinding rolls(HPGR). An experimental study on comminution and mineral liberation of two copper sulfide ores was carried out using a piston-die compressive stressing rig to simulate the situation of comminution with HPGR as the final-grinding device. The tests carried out include compressive comminution tests on particle-bed with narrow-size feed, and the locked-cycle comminution test on particle-bed with broad-size feed, which was then compared to a corresponding locked-cycle test of ball-mill grinding. The narrow-size feed is made up of particles in the size range 2.36~3.35 mm, whereas the broad-size feed of particles in the size range 0~3.35 mm. The liberation analysis for copper-mineral in the comminution products was accomplished using BPMA system – an automatic mineral liberation analyzer developed by BGRIMM. The influences of the stressing intensity and the method of comminution on the copper mineral liberation are discussed in terms of product size distribution, copper-metal deportation among size fractions, distribution of copper mineral among particle-size and particle-grade classes, degree of mineral liberation in size class as well as degree of mineral liberation overall.INTRODUCTION Traditionally, comminution process commonly applied in mineral processing is a flowsheet consisting of crushing of crude ore with conventional crushers, followed by grinding of the crushed ore in tumbling mills. In last decades, the energy-efficient HPGR (high-pressure grinding rolls) has found its application in mineral processing, mostly as tertiary or quaternary crusher to generate a fine-crushed product either as feed to subsequent grinding or as feed to a pre-beneficiation process before further grinding. Compared with the process of conventional crushing followed by grinding in ball mill, this mode of HPGR-application can achieve energy saving to some extent by reducing particle size of the feed to ball milling, and by reducing amount of the feed to ball milling if a significant portion of tailings in relatively coarse particle-size range can be discarded at the pre-beneficiation stage. In recent years, the approaches of letting HPGR take more comminution work from ball mill by applying it in semi-finish grinding mode or even finish grinding mode have been discussed (Burchardt, 2014). Although HPGR finish-grinding has been successfully applied in the cement industry for grinding of cement clinker and raw materials, this mode of HPGR application has yet rarely been implemented in mineral processing, despite the advantage of more energy-saving and other potential benefits such as preferential breakage, internal damage of particles and enhanced mineral liberation which may lead to a better downstream processing performance. The reasons for the retardation of the progress of this kind of HPGR-application in the mineral industry lies not only in that a finish-grinding with HPGR has to be operated in dry condition whereas most of ore-beneficiation processes like flotation are operated in wet condition, but also in that there are large variety of ore materials with various complexity of processing technology, which need to be addressed on a case-by-case basis with a lot of test work, in order to evaluate the potential advantages or disadvantages of this application."

Jan 1, 2018

By E. L. Chanturiya

The research and characterisation for compositional, physicochemical, structural, electrical and flotation properties of various pyrite samples for a copper-zinc sulfide ore was carried out. Various methods were used during the research, such as optical microscopy, X-ray diffraction, electron probe micro-analysis (EPMA), phase emission analysis, routine chemical analysis, auger electron spectroscopy (AES), scanning electron microscopy (SEM), back-scattered electron images (BSE), potentiometry, and instrumental neutron-activation analysis, flotation. Analysis of obtained results established the interrelation between impurity structures and concentration of electric charge carriers in minerals, Butyl xanthate sorption and flotation yield of pyrite. The research concluded that pyrite samples differ by morphology, micro defects of structure, concentration of donor and acceptor impurities (Co, As, Sb, etc.) and conductivity parameters (thermo-electrical force, specific resistance and concentration of charge carriers The peculiarity of pentagon-dodecahedral pyrite is the high concentration of electric charge carriers (electrons) and the more negative surface potential (by 25–75 mV) in comparison to cubic pyrite. The surface of cubic varieties is more active, therefore it is oxidized in alkaline lime medium much faster, than the surface of pentagon-dodecahedral varieties. This phenomenon is caused by high reaction ability, irregular jointing and defects of cubic pyrite. This promotes the increase of calcium ion sorption on its surface and the decrease of Butyl xanthate sorption. According to this, an increase in alkalinity (lime medium) from a pH of 10.0–11.5 leads to an increase of gold content reporting to the tail of bulk flotation. Gold content is increased from 0.58 g/t (?? 9.5) to 1.9 g/t (?? 11.6), which represents an increase in gold recovery of 24.68 to 79%, respectively.

Jan 1, 2016

By J. M. Jimenez, G. D. Schena, A. J. Cazorla

A full-scale Deister column was operated in parallel with the conventional cleaning bank of cells and a pilot Jameson cell in parallel with the conventional rougher cells. Flotation column performance was appreciably enhanced by use of an improved washing system and an internal launder. The performance of the rougher bank of cells, Jameson cells, cleaner cell bank and column were described by simple linear functions. These allowed calculation of overall circuit recoveries and evaluation of alternative circuits. An evaluation procedure based on a financial criterion is demonstrated with a simplified example, illustrating how revenues and operating margins are often of more concern than concentrate grade and recovery

Jun 18, 1905

By W. R. Reed, D. E. Pollock, T. W. Beck, J. A. Organiscak, J. D. Potts

"In underground continuous mining operations, ventilation, water sprays, and machine-mounted flooded bed scrubbers are the primary means of controlling respirable dust exposures at the working face. Changes in mining arrangements, such as, face ventilation configuration, orientation of crosscuts mined in relation to the section ventilation, and equipment operator positioning, can impact the ability of dust controls to reduce occupational respirable dust exposures. This study reports and analyzes dust concentrations measured by the Office of Mine Safety and Health Research for both remote-controlled continuous mining machine operators and haulage operators at ten U.S. underground mines. Results of these respirable dust surveys show that continuous miner exposures varied little based on depth of cut, but are significantly affected by ventilation configuration. Haulage operators experienced elevated concentrations in blowing face ventilation. The type of cut influenced exposures, with elevated exposures observed for both continuous miner operators and haulage operators when working in crosscuts driven into, or counter to, the section airflow. Individual cuts are highlighted to demonstrate instances of minimal and excessive dust exposure attributable to particular mining configurations. These findings form the basis of recommendations for lowering face worker respirable dust exposures when performing a variety of continuous mining cuts.INTRODUCTION Underground continuous coal mining operations may encounter a wide range of conditions and arrangements during production and development activities. These activities typically produce respirable coal mine dust, putting operators of continuous mining machines and coal haulers at risk for elevated exposures. In order to comply with federal regulations limiting respirable dust exposures for the duration of a working shift, mine operators typically implement ventilation, water sprays, and machine-mounted flooded-bed dust collectors (scrubbers) to dilute and control mine dusts during coal cutting. Nevertheless, changes in operational conditions can limit the ability of these controls to effectively reduce dust exposures. Some examples of conditions that can change during the course of mining include face ventilation configuration, orientation of crosscuts mined in relation to the section ventilation, and operator positioning. Because these arrangements are largely under the control of mine operators, any insight into associated exposures may inform future plans and behaviors, reducing occupational exposures to respirable dust. The objective of this OMSHR study is to evaluate respirable dust exposures associated with a range of continuous mining arrangements by comparing occupational dust concentrations measured during a series of field surveys. These comparisons consider face ventilation configurations, depths of cut, and crosscut mining practices."

Jan 1, 2015

By W. R. Reed, D. E. Pollock, T. W. Beck, J. A. Organiscak, J. D. Potts

In underground continuous mining operations, ventilation, water sprays and machine-mounted flooded-bed scrubbers are the primary means of controlling respirable dust exposures at the working face. Changes in mining arrangements — such as face ventilation configuration, orientation of crosscuts mined in relation to the section ventilation and equipment operator positioning — can have impacts on the ability of dust controls to reduce occupational respirable dust exposures. This study reports and analyzes dust concentrations measured by the Pittsburgh Mining Research Division for remotecontrolled continuous mining machine operators as well as haulage operators at 10 U.S. underground mines. The results of these respirable dust surveys show that continuous miner exposures varied little with depth of cut but are significantly higher with exhaust ventilation. Haulage operators experienced elevated concentrations with blowing face ventilation. Elevated dust concentrations were observed for both continuous miner operators and haulage operators when working in crosscuts driven into or counter to the section airflow. Individual cuts are highlighted to demonstrate instances of minimal and excessive dust exposures attributable to particular mining configurations. These findings form the basis for recommendations for lowering face worker respirable dust exposures.

Jan 1, 2016

By K. Winterton, Carruthers. J.

"Attempts have been made to produce hardened structures of a pseudomorphic type in various carbon and alloy steels. In order to obtain martensite with a fine distribution of cementite, an initial structure of fine lamellar or nodular pearlite is required; this may be obtained by conventional means. This is followed by partial austenitization and quenching.Two methods have been tried to induce partial austenitization:(a) A resistance (direct current) heating method involving rapid entry into the austenite field.(b) A new method, described as the ""threshold"" technique, involving homogenization of temperature just below A 1, followed by entry into the austenite field; two furnaces are required.The resulting structures have been examined for microstructures, hardness, tensile, and impact values. The tensile properties are comparable with those obtainable by conventional treatment methods. Impact values are disappointing, but this is explainable from the nature of the manifold changes occurring."

Jan 1, 1960

By Hong Li, Chenxiao Li, Wenwen Mao, Hua Lu

Directly charging limestone into slag in BOF is a newly emerging technique which broke through the traditional BOF slagging principle. It is necessary to study the decomposition behavior of limestone in converter slag during BOF steelmaking. FeOx, SiO2, MnOx and pre-melting slags were mixed with limestone according to different quality proportion to simulate the environment of limestone in converter slag. TG-DTA results indicated that slag with individual component, including FeOx, SiO2 and MnOx, all had obvious effects on reducing the decomposition temperature of limestone. Pre-melting slags with multiple components had further reducing effects than individual component. XRD results showed converter slag component would react with decomposition product of CaCO3 and generate solid solution or oxide, reducing the activity of CaO and the decomposition temperature of CaCO3.

Mar 1, 2017

By Ram Song, Yohei Harada, Shinji Kumai, Kazuho Otsuka

"Recently, vertical-type high-speed twin-roll casting (HSTRC) has been developed. The HSTRC shows extremely high cooling rates over 1,000 K/s even at the mid-thickness area. The fabricated strip has many metallurgical characteristics; super-saturation of alloying elements, fine solidified structure, and homogeneous distribution of fine constituent particles. In Al-Mn based alloys, the Mn alloying element can be supersaturated in the a-Al matrix and also form Mn-containing constituent particles during solidification. The Mn supersaturation and the distribution of primary/secondary particles in cast products affect the metallurgical behavior in the down-stream processing and can improve mechanical properties of the final products. In this study, Al-Mn based alloy strips were fabricated by HSTRC with various Mn contents. The solidified microstructure, constituent particles and its distribution, and Mn solubility were investigated in the as-cast condition. Due to the high cooling rate of HSTRC, fine constituent particles were homogeneously distributed, and coarse intermetallics were not observed. Mn solid solubility was estimated by electrical conductivity. The estimated Mn solubility was equivalent between strip surface and mid-thickness area.INTRODUCTION Al-Mn based alloys, as non-heat treatable wrought aluminum alloys, are widely used in packaging and heat exchanger for automobile industry. Besides Mn, Al-Mn based alloys often contain Fe and/or Si as alloying elements or natural impurities. During solidification, Mn can be super-saturated in the Al matrix, and also form Mn-containing constituent particles. Additionally, in the subsequent thermal-mechanical processes such as homogenization, rolling, and intermediate annealing, Mn in solid solution precipitates out of the Al matrix as secondary particles. The size, distribution, type, and the amount of dispersoids including constituent particles affect to texture evolution, recrystallization behavior, and final mechanical properties of wrought Al-Mn based alloys (Huang et al., 2016; Huang & Marthinsen, 2015; Engler et al., 1995; Muggerud et al., 2013). Therefore, controlling the initial level of Mn super-saturation and the distribution of constituent particles are important in the cast Al-Mn based alloys."

Jan 1, 2018

By Dong Liang, Honggang Zhong, Zhenxing Yin, Qijie Zhai

"2507 super duplex stainless steel (SDSS) has been widely applied in a marine environment, attributing to its excellent pitting corrosion resistance and mechanical properties which are particularly determined by the nitrogen precipitation behaviors and volume fraction of ferrite. In this paper, various cooling rates were obtained by applying four different moulds with the common gating system. By which the influence of cooling rates on nitrogen precipitation behaviors and the ferrite fraction in cast 2507 SDSS was comparatively investigated. The results showed that nitrogen porosity could easily precipitate in cast 2507 SDSS under standard atmospheric pressure. The number of nitrogen holes increased with decreasing the cooling rates, and the holes mainly distributed in three zones, i.e. the interface between the horizontal and vertical columnar grains, top vertical columnar grains and the final solidification region. Additionally, higher ferrite fraction was obtained with lower cooling rates.IntroductionDuplex stainless steels (DSS) have a dual-phase microstructure consisting of ferrite (d) and aus-tenite (?). Due to the combined advantageous properties of d and ? phase, their application rapid-ly increased in industry [1, 2]. Super duplex Stainless Steel (SDSS) is the third generation of du-plex stainless steels, of which the alloy elements Cr, Ni and N content are higher than the stand-ard 2205 DSS. Because it has high contents of alloy elements, the SDSS has better mechanical properties, and its pitting resistance equivalent number (PREN) reached a point 43. Hence SDSS has been used in petroleum chemical industry, the marine equipment and harsh corrosion environments [3]. SDSS contains ferrite stabilizing elements, such as Cr, Mo and Si, and austenite stabilizing elements like Ni, Mn and N [4]. Many researchers have studied the effects of these elements on the stabilization of d and ? phase and the ratio of the two phases. High nitrogen con-tent is another prominent feature of SDSS. Nitrogen addition to SDSS is very effective for improving its mechanical properties [5] and corrosion resistance [6], such as pitting resistance in NOx environment. To increase the nitrogen content in steels, a lot of work had been done. N. Nakamura and S. Takaki [7] examined the behavior of nitrogen absorption in Fe-23Cr alloy powder by sintering in nitrogen gas atmosphere, they found nitrogen content easily up to 1.0 wt. %. Using devised NH3 gas injection system, W. Park et al. [8] successfully produced austenitic Fe–23.5Cr alloys containing over 3 wt. % of nitrogen. Further-more, W.P. Tong et al. [9] stated that nitrogen percent was extraordinary high (about 10 wt. %) in pure iron plate. However, the above methods are difficult to be applied to large-scale industrial production."

Jan 1, 2012

By Peiwei Hu, Min Lu, Tiejun Chen

Based on the analysis of properties of vanadium tailing (VT), the surface modification study was carried out as a polymer filler. The modification effects of the three kinds of coupling agents on VT and the mechanical properties of polypropylene (PP) composites with a modified vanadium tailing (MVT) were compared to determine the suitable surface modification agent and modification processes for VT. The results show that the best one is aluminate coupling agent DL-411. When the content is 1.2 wt% and the temperature was 100 °C, the activity index of modified vanadium tailing (MVT) is 95.53%. FTIR analysis shows that DL-411 has the strongest binding ability on VT. XRD analysis shows that VT has a heterogeneous nucleation on PP to induced b form formation, and DL-411 could enhance this nucleation. So the composites has higher strength and better toughness. When the content of MVT is 10 phr, the tensile strength, impact strength, flexural strength and flexural modulus of the composites are 47.51 MPa, 38.43 kJ/m2, 59.57 and 1654.36 MPa, respectively.

Mar 1, 2018

By Kirby D. Mellegard, Ralph A. Wagner, Paul E. Senseny

Six creep laws for salt, each fitted to the same laboratory data base, are used in a numerical model of the deformation of an opening in salt to determine the influence of creep law form on the predicted closures. Results show that predicted closures can be very sensitive to the functional form of the creep law chosen to model the laboratory data.

Jan 1, 1982

By C. P. Fang, V. A. Marple, K. L. Rubow

"Studies of the flow fields and particle impaction characteristics are more complicated in multi-nozzle impactors than in single-nozzle impactors, since the jets of air must penetrate cross-flowing air to impinge on the impaction plate. Results of heat and mass transfer analysis are employed to describe the cross-flow pattern in multi-nozzle impactors. A cross-flow parameter has been derived to predict the deflection of the air jet by the cross-flow. This parameter is expressed as a function of the geometric parameters for the multi-nozzle impactor. DnN 4D,, where N is the number of nozzles, Dn the nozzle diameter and D, the nozzle cluster diameter. Empirical particle collection data show that multi-nozzle impactors operate satisfactorily, if the cross-flow parameter is less than a critical value of 1.2. Impactors operating with a cross-flow parameter larger than this critical value are shown to possess poor particle collection characteristics.Inertial impactors of many designs have been used for sampling aerosol particles. Impactors can be single stage, consisting of a nozzle and an impaction plate, or a cascade impactor with several stages in series. The simplest design for a stage is a single nozzle with a flat impaction plate. However, many designs use stages with multiple nozzles of identical size, which allows for compact impactors to be designed at rather substantial flow rates and moderate pressure drops.Nearly all of the theoretical work, and much of the experimental work, has been performed on single-nozzle impactors. The results of single-nozzle impactor analysis are often applied to multiple-nozzle impactors, which are assumed to be a group of individual nozzles, each operating as though they were single nozzles. However, an important fact is often ignored: the interaction of flow from adjacent nozzles can change not only the fluid mechanics in the impaction region, but also the locations of the jet stagnation points, and the impaction characteristics of each nozzle.The effect of multiple nozzles on the particle collection characteristics of impactors has been studied by a few investigators. May (1964), Fletch et al. (1967), Friedrichs (1968), and Vaughan (1986) reported that the quantity of particles in deposits of nozzles in the first two stages of the Andersen multi-nozzle cascade impactor were not equal. The inner deposits appeared to contain fewer particles than the outer ones. However, Vaughan (1986) in addition showed that many of the deposits in the outer three rows were missing on the first stage, even though the outer deposits that were present were larger than the inner deposits.May (1964) conducted experiments and explained the phenomenon of smaller deposits near the center than near the edge. He noted that in Andersen cascade impactors the air issuing from the nozzles moves radially outward along the narrow channel between the nozzle plate and the impaction plate. This flow at 28.31min -1 created a pressure difference of about 1 mm water between the inner and outer sections of the channel. The effect was most pronounced in the first two stages, where the pressure drop across the nozzles was also about 1 mm water. Here, the flow velocities in the nozzles, and hence the deposits, were smallest at the center and increased toward the periphery of the impaction plate. since the pressure drop across the nozzles was the smallest at the center and a maximum at the periphery. This effect was negligible in the lower stages because of a larger pressure drop across the nozzles. According to May (1964), this effect could be eliminated by increasing the nozzle-to-impaction-plate distance to three nozzle diameters and improving the nozzle arrangement to allow air flow to escape to the periphery more easily."

Mar 1, 1992

By Jamal Rostami, Manso Deen Sesay, Sydney Slouka, HUGH MILLER, Anshuman Mohanty, Midhat Sajad, Kun Zhang

The lack of progress in controlling pulmonary diseases such as pneumoconiosis cases in recent years necessitates additional studies on dust generation and the characterization of airborne dust. Studies are underway by a NIOSH-sponsored project to observe the characteristics of the dust generated by pick cutters under various wear levels. This research performed a full-scale linear-cutting-test matrix on eight coal samples with various bit penetrations, spacing, and wear conditions. The specific energy and resulting PSD (particle size distribution) of airborne dust and material left at the cutting surface were measured and analyzed. The dust concentration was determined using the NMAM (NIOSH Manual of Analytical Methods) 0600 method. For fines, the PSD was characterized using Laser Diffraction, measuring percent channel and aerodynamic diameter, while Imagej, a virtual sieving application, was used for larger particles. The results show that for a new bit, as the cutting depth and spacing increase, the specific energy and dust generation decrease. The size and shape of the dust particles have been analyzed, and the observed trends are discussed in this paper.

Feb 1, 2025

By Anil K. Ray

Roof falls are one of the greatest hazards in underground coal mines worldwide. Due to stringent safety measures and extensive support system development, roof falls have been reduced significantly but they still persist in many underground coal mines. Some of the roof falls initiate with cutter roof or guttering. In the past, many factors have been identified as being responsible for the development of cutters and roof fall. These responsible factors can be broadly classified as stress related or non-stress related. In this paper the finer details of mining technique have been taken into consideration for better understanding of cutter roof and roof fall problems. Three dimensional finite difference modeling has been used to explain the mechanism of cutter development. Strain softening material behavior has been used to realistically simulate the cutter formation, and common cutting sequences as implemented in the field have been simulated. This was done with an objective to determine whether the cutting sequence has really any significant control over cutter formation or not. In addition to cutting sequences, the effect of cut length is also studied. The effect of step cutting and turning of crosscut into and away from major and minor horizontal stresses is also examined to see its influence on cutter development.

Jan 1, 2009

By Anil K. Ray

Roof falls are one of the greatest hazards in underground coal mines worldwide. Due to stringent safety measures and extensive support system development, roof falls have been reduced significantly but they still persist in many underground coal mines. Some of the roof falls initiate with cutter roof or guttering. In the past, many factors have been identified as being responsible for the development of cutters and roof fall. These responsible factors can be broadly classified as stress related or non-stress related. In this paper the finer details of mining technique have been taken into consideration for better understanding of cutter roof and roof fall problems. Three dimensional finite difference modeling has been used to explain the mechanism of cutter development. Strain softening material behavior has been used to realistically simulate the cutter formation, and common cutting sequences as implemented in the field have been simulated. This was done with an objective to determine whether the cutting sequence has really any significant control over cutter formation or not. In addition to cutting sequences, the effect of cut length is also studied. The effect of step cutting and turning of crosscut into and away from major and minor horizontal stresses is also examined to see its influence on cutter development.

Jan 1, 2009

By Martin Reyes, Juan Hernández, Julio Cesar Juárez, Isauro Rivera, Ma. de los Ángeles Hernández, Francisco Patiño

The dissolution of Ag contained in metallurgical tailings was studied by adding ions Cu2+ and Zn2+ in S2O3 2- medium. Chemical analysis of mine tailings by cupellation revealed a Ag concentration of 71 g/ton. The XRF and XRD analysis confirmed the preponderance of SiO2 in the mineral matrix. The experimental dissolution process was conducted in alkaline solution using six concentrations of NaOH and five of S2O3 2-, at different temperatures, also using five concentrations of Cu2+ and Zn2+ as a catalyst. The results showed similar values for both systems (96.8% and 97.13%). The ion Cu2+ and Zn2+ increases the dissolution of Ag, and decrease the reaction time of dissolution. Under the conditions used, pH and stirring rate did not affect the dissolution of Ag.

Jan 1, 2015

By D. J. Jr. McAdam

RESULTS of a general survey of corrosion-fatigue phenomena at the Naval Engineering Experiment Station were presented in five previous papers.1-5 In these papers references were given to the work of Haigh in 1917.6 The five papers mentioned gave a general survey of the behavior of metals when tested to failure under simultaneous corrosion and cyclic stress. As a result of this survey the fourth paper gave a tentative analysis of the corrosion-fatigue process. According to this analysis, if the initial stress is below the endurance limit but above the corrosion-fatigue limit, the corrosion-fatigue process is divided into two periods. The first period is the formation of pits. As the initial stress is below the endurance limit, the pitting is assumed to be due to corrosion, not to fatigue. The corrosion pitting, however, is not the ordinary pitting of stressless corrosion, but is an accelerated pitting due to the effect of the cyclic stress on the corrosion. As the pit progresses, both the actual stress and the effective solution pressure increase. The increase of actual stress is due to increasing stress concentration at the bottoms of the pits. The increase of effective solution pressure is due to the increase of actual stress. The mutual intensification of stress and solution pressure continues until the actual stress at the bottoms of the pits surpasses the endurance limit. The second period of corrosion-fatigue then begins. In this period the process is merely fatigue accelerated by the corrosion. The cracks advance at a continually accelerated rate until the specimen breaks.

Jan 1, 1930

By Robert W. Bruhn

Ground movements associated with high extraction underground coal mining, such as pillar retreat and longwall, are some- times large enough to disrupt the ground water regime as well as damage buildings and other surface structures. A U.S. Department of Energy Bureau of Mines- sponsored subsidence study at Kitt Energy Corporation's Kitt No. 1 Mine near Philippi (Barbour County) , West Virginia has provided an opportunity to monitor the ground water response above a mine panel during both developmental and pillar re- treat mining. Findings concerning ground water effects presented in this paper indicate that total extraction mining produced significant water level declines in deep-lying strata but had little effect on water levels at shallower depths. Post-mining values of hydraulic conductivity were typically somewhat higher than pre-mining values. Changes in water chemistry associated with mining were not sufficient to render the water unfit for human consumption.

Jan 1, 1986

By Yoshiharu Tanaka, Keita Morooka, Masaaki Yamamoto, Katsuhiko Kaneko

Smooth blasting is the standard method for underground rock excavation, to reduce over break and remaining rock damage. We already utilized the high accuracy of the electronic delay detonator to investigate its effect on over break remaining rock damage, and surface smoothness. And we presented at 11th annual symposium on Explosives and blasting Research.

Jan 1, 1998

By V. I. Ryaboy, S. A. Kondratyev

"The paper describes influence of desorbed species (DS) of a number of xanthates and higher dialkyldithiophosphates on the collective ability of these reagents. Adsorbed on mineral DS of the reagents in the form of products of non-stoichiometric interaction between xanthates and heavy metal salts can pass to the gas–liquid interface and remove liquid from the layer between mineral particle and water surface. A high-speed video recording displays the process of spreading of DS of xanthates and dialkyldithiophosphates over water at the moment of local rupture of the water layer. Expansion of “dry” spot on the mineral surface after DS of xanthate capture and displace liquid from the layer has been proved with video images. The comparative analysis of collecting ability and dynamic surface activity of dialkyldithiophosphates shows that these characteristics are in good correlation. The forces exerted by spreading film of the reagent’s DS on liquid in the water layer are evaluated, and the water flow rate from the layer is determined. The line of the reduction in thickness of the water layer behind the front of spreading film of DS of dialkyldithiophosphates and xanthates coincides with the line of the increase in their dynamic surface activity. Their force on the liquid volume in the water layer characterizes collecting ability of the DS film of xanthates and dialkyldithiophosphates. It has been supposed that the collecting ability of DS of a reagent is a part of its overall flotation activity, conditioned by surface tension of solution and, thus, defined by the structure of hydrocarbon fragment of the reagent.INTRODUCTIONIt is believed that collecting ability and selectivity of collecting reagents is mainly governed by adsorption of a reagent at the solid–liquid interface. A few studies have shown that activity of collecting reagents at the gas–liquid interface may have deep influence on their collecting capacity and selectivity. Experimental researches have revealed correlation between surface pressure in a carboxylic acid film on liquid’s free surface and floatability of useful components (Kulkarni & Somasundaran, 1975; 1980; Quast, 2006). According to Quast (2006), it is not always that surface pressure of a reagent film influences collecting ability of carboxylic acid. For instance, pH range of adsorption of tetradecanoic acid on hematite does not coincide with pH range of high surface pressure. So, surface properties of this acid contribute little to flotation efficiency.The correlation between reagent film surface pressure and mineral floatability has been reveled for quartz and cationic reagents, too (Bleier, Goddard, & Kulkarni, 1977). Finch & Smith (1973) showed that combination of adsorption of ion–molecular amine complexes on mineral surface and high surface tension of “fresh bubbles” was favorable for flotation performance. The use of bubbles with reduced surface tension resulted in a decrease in quartz floatability."

Jan 1, 2016