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By S. Y. Tshipeng, A. T. Kaniki

"RÉSUMÉ La lixiviation acide d’un minerai oxydé cupro-cobaltifère en milieu non réducteur et en milieu réducteur en utilisant le Fe2+ et le métabisulfite de sodium (SMBS) a été étudiée et les résultats ont été comparés. Les tests de lixiviation ont été effectués à température ambiante, dans une pulpe à 30 % solide, avec une vitesse d’agitation de 600 tr/min, un potentiel redox de 350 mV pour les tests en milieu réducteur, et un pH de 1,8. Les tests de lixiviation avec usage du SMBS comme réducteur ont donné la meilleure cinétique de lixiviation du cuivre. Pour le cobalt, c’est l’usage du Fe2+ qui a donné la meilleure cinétique de lixiviation. L’augmentation de la dose du fer dans la solution au-delà de 5 g/L a influencé négativement les rendements de lixiviation du cuivre et du cobalt. ABSTRACT Acid leaching of a copper-cobaltiferous oxide ore in a non-reducing environment and in a reducing environment using Fe2+ and sodium metabisulfite (SMBS) was studied and the results compa¬red. The leaching tests were performed at room temperature, in a 30% solids pulp, with a shaking speed of 600 rpm, a redox potential of 350 mV for the tests performed in the reducing environment, and a pH of 1.8. The leaching tests using the SMBS as a reducing agent produced the best copper leaching kinetics. As for cobalt, the best leaching kinetics was achieved using Fe2+. An increase in the amount of iron in the solution above 5 g/L negatively influenced copper and cobalt leaching yields. INTRODUCTION La République Démocratique du Congo (RDC) est un pays reconnu dans le monde pour son sous-sol qui regorge d’énormes quantités de cuivre et de cobalt (USGS, 2014; Palisade Research, 2016). La technique qui semble être la plus recommandée pour extraire à la fois le cuivre et le cobalt des minerais oxydés cupro-cobaltifères est la lixivia-tion acide en milieu réducteur. Cette technique est appliquée par la majorité des sociétés minières qui exploitent ces minerais dans l’ex-province du Katanga en RDC, à savoir: Tenke Fungurume Mining, Mutanda Mining, Kamoto Cop¬per Company, Sicomines, Gécamines, Boss Mining, Chemaf, Ruashi Mining et Somika. L’usage d’un agent réducteur est indispensable pour l’obtention d’un bon rendement de lixiviation du cobalt. En effet, plusieurs chercheurs s’accordent sur le fait que le cobalt trivalent de l’hétérogénite (CoO·2Co2O3·6H2O) est insoluble à l’action de l’acide seul; il ne devient soluble qu’après réduction en cobalt bivalent (Mwema, Mpoyo, & Kafumbila, 2002; Mulaba-Bafubiandi, Ndalamo, & Mamba, 2007; Ferron, 2008; Seo, Choi, Kim, & Tran, 2013; Stuurnam, Ndlovu, & Sibanda, 2014)."

Jan 1, 2018

By V. Songmene, R. Khettabi, J. Masounave, R. D. Njoya

L'augmentation régulière des règlements environnementaux et de la sécurité au travail deviennent de plus en plus strictes. L'usinage fait partie des opérations industrielles qui peuvent causer des problèmes de santé au travail et sur l'environnement. La plupart des particules de poussières produites pendant toutes les opérations d'usinage à sec ou lubrifie causent des nuisances environnementales graves. Le travail propose étudie l’influence des paramètres de coupe, des alliages et des états des matériaux sur la formation des copeaux et sur la génération de poussière lors de l'usinage à sec. Deux modes d'usinage (le fraisage et le perçage) sont abordés. Une loi reliant la ténacité des matériaux aux émissions de poussières est proposée. Les effets des matériaux et de leurs conditions, ainsi que des procédés d'usinage sur la génération des poussières ont été mis en évidence. Des mécanismes de formation de poussières sont identifiés et reliés à la formation des copeaux.

Jan 1, 2006

By M. B. Wechsler

An analysis is developed for determining the maximum loading, as well as the potential uplift of the piles on bridge pier foundations. There are considered piers supported on two through seven rows of piles, and related to two simply supported collinear superstructures of any structural material. The study leads to different types of influence lines for various load combinations. For load combinations containing vertical loads only, the related influence lines are similar to those as for the bending moments of a virtual span covering the two actual spans, as well as the gap between the two superstructures; and, in this case, the heavier loads should be positioned in the vicinity of the pier. While, in the case when vertical loads are acting together with hori­zontal forces, the related influence lines will indicate where the heavier live loads should be positioned. And they will also indicate on which portions of the spans the live load should be avoided.

Jan 1, 1989

Studies were carried out to examine the effect of introducing varying levels of a pisolitic limonite (Yandi) into an Australian iron ore blend. Compared with other ores in the blend Yandi is more porous. This structure is found to have a considerable effect on the sintering behaviour of the blends. Pilot-scale sintering studies and plant trials showed that sinter plant productivity, sinter reducibility and the low-temperature reduction degradation index altered significantly when the level of Yandi in the ore blend exceeded 15 wt%. The improvement in the reducibility is thought to be a direct result of increased porosity in the sinter and the presence of highly reducible pseudo-relict haematite. Plant trials have also shown that operational changes could be made to the sinter plant to avoid potential deterioration of productivity

Dec 1, 1991

By Ghislain Bournival, Seher Ata, Graeme J. Jameson

A common method to prevent bubbles from coalescing in a flotation cell is by the addition of surfactants, called frothers. The gas dispersion properties in a column were tested for solutions of 1-pentanol, tri(propylene glycol) methyl ether, and poly(propylene glycol) in the presence of sodium chloride. The dependency of surfactant on the gas holdup can be divided into regions. It seemed that for a sufficiently low concentration of surfactant, even a stronger surfactant could show a transition in gas holdup from constant/decreasing to increasing with concentration. This region, however, was not marked by a decrease in the average bubble size. In addition, PPG gave higher gas holdup values while averaging larger bubbles. On the other hand, sodium chloride mostly affected the gas holdup when the concentration was high enough to prevent bubble coalescence. Another parameter affecting the gas holdup was the superficial gas velocity. A linear dependency was found between the two under a bubbly flow regime. The current study showed that both surfactants and salt could slightly affect the influence of the superficial gas velocity on the gas holdup.

Jan 1, 2014

By Eugie Kabwe

The velocity of detonation (VOD) is a significant property considered when rating an explosive, and it is quantified as a confined or unconfined velocity. The confined velocity is more significant as explosives are usually used under a definite degree of confinement. This study evaluates the stepwise increment of the air-deck volume from 10 to 30 percent, and its effect on the VOD. The VOD estimation in the 172-mm-diameter explosive column was conducted using the Dáutriche technique. The air-deck volume increment has an attenuation effect on the steady-state VOD, and detonation failure is high at 30 percent air-deck volume. This attenuation effect is directly linked to the explosive’s rating and efficacy. The air-decking approach in this study is different from conventional air-decking techniques in that it does not employ the fixed blasthole parameters, air-deck volume and specific VOD. 

By Eugie Kabwe

The velocity of detonation (VOD) is a significant property considered when rating an explosive. It may be quantified as a confined or unconfined velocity. The confined velocity is the rate at which the detonation wave propagates through an explosive within a blast hole or any restrained space. The unconfined velocity emanates when an explosive is detonated in the open. However, the confined velocity is more significant as explosives are usually employed under a definite degree of confinement. This paper evaluates the increment of air deck volume and its effect on the VOD. The air gap (air deck) volume is increased stepwise from 10 to 30% of the total blast hole volume by reducing the stemming height in the collar zone. Thereafter, the VOD estimation in the 172-mm-diameter explosive column is conducted using the Dáutriche technique. It is observed that the VOD reduced with the increasing air deck volume and detonation failure is high when 30% of the blast hole volume is replaced with air deck. It is deduced that the increment of the air deck volume has an effect on the attenuation of the steady-state VOD.

By Eugie Kabwe

The velocity of detonation (VOD) is a significant property considered when rating an explosive. It may be quantified as a confined or unconfined velocity. The confined velocity is the rate at which the detonation wave propagates through an explosive within a blast hole or any restrained space. The unconfined velocity emanates when an explosive is detonated in the open. However, the confined velocity is more significant as explosives are usually employed under a definite degree of confinement. This paper evaluates the increment of air deck volume and its effect on the VOD. The air gap (air deck) volume is increased stepwise from 10 to 30% of the total blast hole volume by reducing the stemming height in the collar zone. Thereafter, the VOD estimation in the 172-mm-diameter explosive column is conducted using the Dáutriche technique. It is observed that the VOD reduced with the increasing air deck volume and detonation failure is high when 30% of the blast hole volume is replaced with air deck. It is deduced that the increment of the air deck volume has an effect on the attenuation of the steady-state VOD.

By PAITIP THIRAVETYAN, KANJANA KUDPENG

The aim of this study was to investigate the influence of amino acids (glycine, aspartic acid, glutamic acid, lysine and tryptophan) and organic acids (citric, malic, tartaric, fumaric, oxalic, succinic and ascorbic acid) on gold extraction from silicate ore. Use of amino acids to extract gold was preferred compared with organic acids due to the presence of carboxylic group and amine groups in amino acids. Among the assessed amino acids, aspartic acid and glutamic acid had higher capacities to extract gold due to their structures, which lacked aromatic rings and long side chains. Organic acids could also extract gold. In particular, oxalic and succinic acids had the greatest capacity to extract gold versus the other tested organic acids. Moreover, aspartic acid had a greater capacity to extract gold from ores than the same concentration of succinic acid. We confirmed the aspartic acid and succinic acid functional groups by Fourier transform infrared spectroscopy. The findings revealed that aspartic acid had a greater capacity to extract gold than succinic acid due to the presence of both amine and carboxylic groups (succinic acid contained only a carboxylic group). The optimal gold:aspartic acid molar ratio was 1:6 and low concentrations of aspartic acid extracted 35–42%of gold from silicate ore within 15 days. This can be used as an alternative to traditional methods for extracting gold from ore; it is non-toxic to human health and environmentally friendly.

Aug 10, 2021

By PAITIP THIRAVETYAN, KANJANA KUDPENG

The aim of this study is to compare amino acids and organic acids in the extraction of gold from silicate ore. Amino acids were found to have higher efficiency of gold extraction than organic acids at the same acid concentration, which is likely due to amino acids having both carboxylic and amine groups in their structure, while organic acids only have carboxylic groups. Five amino acids (glycine, aspartic acid, glutamic acid, lysine and tryptophan) and seven organic acids (citric, malic, tataric, fumaric, oxalic, succinic and ascorbic acids) were selected to investigate gold extraction efficiency. Aspartic acid was found to have greater capacity to extract gold than succinic acid. The optimal gold to aspartic acid molar ratio was 1:6, and low concentrations of aspartic acid extracted 35 to 42 percent of gold from silicate ore within 15 days. Further studies are needed to increase gold leaching and reduce incubation time. The results imply that aspartic acid can be used as an alternative reagent to traditional methods for extracting gold from ore. This method is nontoxic to humans, is environmentally friendly and can have real applications.

By H. Conrad, K. Jung

"The effect of an external electric field E=5(+) kV/cm applied during the solution heat treatment at 500°-550°C of three commercial Al-Mg-Si alloys (AA6061, AA6022 and AA61l1) on the asquenched resistivity Pw and hardness H.,NULL, w was investigated. It was found that the field gave a significant increase in Pw and in Hv,w, for AA6022 and AA6111, but had no clear effect on AA6061. Thermodynamic analysis gave that the effect of the field on AA6022 and AA6111 was to reduce both the enthalpy ?H, and entropy ?H, of solution. Considering the chemical composition of the three alloys it appears that the influence of the field may depend on the amount of Cu plus excess Si present in the alloy.IntroductionKlypin and Soloviev [1, 2] were the first to report that the application of an external electric field during solution heat treatment (SHT) of Al alloys gave an increase in the as-quenched resistivity and hardness. They attributed these effects of the field to an increase in solubility of the alloying constituents during the SHT. More recently Liu and coworkers [3, 4] also reported an increase in the as-quenched resistivity of Al-Li alloys with application of an electric field during SHT. Further, the present authors [5] found that the application of an electric field during the SHT of the commercial Al-Mg-Si alloys AA6022 and AA61i1 increased their as-quenched resistivity and hardness. Their thermodynamic analysis of the results indicated that the field decreased both the enthalpy ?H, and entropy ?S, of solution."

Jan 1, 2004

By I. M. R. Duarte, J. A. Rodrigues-Carvalho, F. R. S. Rosa, A. B. Pinho

"This paper aims to contribute to the knowledge of the mechanical properties of the shales and greywackes which constitute the flysch-type deposits of the Baixo Alentejo Flysch Group, in the south of Portugal. These formations are flysch-type deposits constituted by sequences of usually thick greywacke beds alternating with thin shale beds, which include sometimes intercalations of conglomerate beds. All the sedimentation of these flysch formations was controlled by tectonics. At the same time, should have occurred along with the first Hercynian deformation phase, a low-grade metamorphic event (chlorite zone), that affected these flysch deposits. This study highlights the influence of anisotropy and heterogeneity of these flysch rocks on their physical and mechanical characteristics. The anisotropy verified in some physical properties and on mechanical properties, due to the foliation makes difficult the sample preparation for the laboratory tests. Besides, it induces a scattering of the properties values measured, as for example, the strength and the deformability. The heterogeneity is related to the main features of these geological formations, which are constituted mostly by thinly stratified greywackes and shale beds, which sometimes may affect the results of the laboratory tests making them less representative. The study is made by using both shales and greywackes that constitute these flysch-type deposits in order to evaluate their geotechnical properties, mainly of the shales. Samples of these two rock materials, are tested accordingly a laboratory testing programme, which includes which included mineralogical analysis (X-ray diffraction), physical tests (bulk density, porosity, and void index) and mechanical tests (uniaxial compression, and deformability tests). INTRODUCTIONOne of the factors that most influence the geomechanical behavior of rocks, as well as rock masses is the anisotropy. The word anisotropy comes from two Greek words ""anisos"" (meaning uneven) and ""tropos"" (meaning direction). A body or material is considered to be anisotropic, where the same property has different values depending in which direction it is measured, therefore, an anisotropic material is one whose magnitude of the properties depends on the direction in which these are studied or measured. Otherwise, it is about an isotropic material. However, the fully isotropic materials are quite rare in nature."

Jan 1, 2015

By K. Ihara, R. Akiyoshi, Y. Takaki, S. Kang, H. Shishido

"Tensile tests and scanning electron microscopy-electron backscattered diffraction (SEM-EBSD) analysis were performed in an Al-Mg-Si alloy to clarify the effect of annealing and cold-rolling reduction on the texture formation. The hot-rolled specimens were cold-rolled with the reduction of 58-75%(CR1), followed by annealing at 773 K for 5 min(IA). The secondary cold-rolling(CR2)for the IA specimens with the reduction of 33–66%, followed by the solution heat treatment(ST), were performed. Focusing on the CR1 and CR2 specimens, the average r-values increased with higher primary and lower secondary cold-rolling reduction, respectively. This was considered to be due to the increase of r-values measured in the direction of 45 degree with respect to rolling direction, caused by the formation of the ß-fiber components (Brass {011}<211>, Copper {112}<111> and S {123}<634>) with high density. Based on the texture analysis of annealed specimens it was suggested that the high density of the ß-fiber components after IA and the small amount of stored strain energy of CR2 introduced by the lower cold-rolling reduction remained the ?-fiber components even after solution treatment.INTRODUCTION Al-Mg-Si alloys have been applied to automobile body applications, due to their excellent paint-bake hardening (age-hardening) and corrosion resistance compared to other aluminum alloy. On the other hand, the mechanical properties and deep drawability of Al-Mg-Si alloys are inferior to those of steels. Thus, it is important to improve the mechanical properties and deep drawability in order to expand the application components. One of the best methods to improve the deep drawability is to increase the Lankford coefficient (r-value). Previous studies reported that the increase of the average r-value ( ) improves the deep drawability. The relationship between the r-value and texture of the alloy is also well known. Inoue et al. reported that the ß-fiber components, such as Brass ({011}<211>), Copper ({112}<111>) and S ({123}<634>), increase the r-value measured in the direction of 45o with respect to the rolling direction. r"

Jan 1, 2018

By Katja Reinharter

Arsenic can be found in different sulfidic copper concentrates and residues, which for several years have commonly been used in copper metallurgy, as the “arsenic-free” resources are getting rare. Due to the high toxicity the removal of arsenic in the copper smelting process is a very important topic. The typical chemical slag and sulfur attack on the refractory material is getting enhanced by the presence of arsenic. This work deals with post-mortem investigations of a magnesia-chromite brick and castable used in copper smelting furnaces showing an additional and increased chemical attack by arsenic. The knowledge on the wear behaviour is not only based on a detailed chemical and mineralogical characterization, but also on thermochemical FactSageTM calculations, which are carried out on provided post-mortem samples. Post-mortem investigations on used refractory materials represent an important prerequisite for the product development, as well as for special engineered lining concepts to support our customers.

By F. Chiesa

Forty aluminium A356 castings were poured on a Low Pressure Permanent Mould industrial machine, 500x700mm in platen size. The 152mm wide casting comprised three steps, 25mm, 13mm, 6mm in thickness and a 2.5mm overflow which allowed to assess the thin wall capability of the process. The casting campaign, which produced 40 parts, allowed to test the influence of various production parameters including the time of application of the pressure in the crucible, artificial cooling of the mould and casting rate. The thermal history in the mould was recorded over the 40 cycles, which allowed to construct a reliable thermal model of the mould/casting assembly. The metallurgical quality of castings representative of the various conditions was assessed in the 25mm, 13mm and 6mm plates. This included measuring the level of microporosity, the dendrite fineness (DAS), along with the tensile properties in the T6 condition. The radiographic quality per ASTM E155 was also determined. Modelling filling and solidification allowed to verify the validity of the predictions based on available relationships relating microporosity, secondary dendrite arm spacing (DAS) and local tensile properties (Quality Index, Q) to the local thermal solidification parameters.

Jan 1, 2007

By P. -É. Boileau, S. Mandapuram, Shiping Ma, S. Rakheja

The absorbed power (PAbs) has been suggested as a better measure of human responses to whole-body vibration, since it relates to the cumulative energy dissipated by the body exposed over a given duration. Moreover, unlike the other measures, the PAbs can adequately account for the intensity of exposure. Although, the vast majority of off-road vehicles impose considerably severe vibration along the horizontal axes, the vast majority of studies on biodynamic response characterization consider only vertical vibration. Only a few studies have reported PAbs responses of the seated human body exposed to horizontal vibration and the major contributing factors [1]. This study aims to characterize the PAbs responses of seated human subjects to horizontal (uncoupled x- and y-axis) vibration as functions of the vibration intensity, subject mass, seat height and the, type of back support. Methods Experiments were conducted using a rigid seat with an adjustable backrest inclination and seat height. The seat was installed on a horizontal vibration simulator and the forces at the seat base and the backrest were measured by three-axis force plates. Two single-axis accelerometers were installed on the seat back and the platform, oriented along the axis of motion. The experiments were performed using three different seat heights (350, 390 and 410 mm), back support conditions (NB- no back support and sitting erect; Wb0- Upper body supported against a vertical back support; and WbA- back supported against an inclined backrest, while sitting relaxed) and three different magnitudes of broad band excitations in the 0.5-10 Hz frequency range (0.25, 0.5 and 1 m/s2 rms acceleration under x-axis and y-axis, applied independently). A total of 8 healthy adult male volunteers with total body mass ranging from 59.4 kg to 92 kg and aged between 21-51 years took part in the experiments. The subjects were seated with their hands in lap, and feet supported on the moving platform for each posture. Each measurement was repeated 2 times, while the data were analysed using a bandwidth of 50 Hz and frequency resolution of 0.0625 Hz. [ ] The data were analyzed to derive the absorbed power characteristics of the body at both seat pan and backrest interfaces, while the coherence among the measured forces and accelerations wer

Jan 6, 2006

By Frederic Dewey

HAVING shown1 the difficulty of assaying so-called cyanide bullion and the extreme variations often found in the results, an investigation was undertaken to discover if possible the causes of these variations by a series of tests upon the specific action of various metals during cupellation. Zinc.-In order to test the effect of zinc, 48 assays were made in sets of 6, 2 rows of 3. The charge for the middle cupels consisted of 500+ mg. Au, 1,125 mg. Ag, 10 mg. Cu. To the end cupels 50, 75, 100 and 125 mg. Zn were added, and a set of each proportion was cupelled with 4 and 8 grants Pb. The cupels were assayed and showed the following gold contents in milligrams, the figures being arranged as the cupels stood in the muffle: TABLE 1 50 Mg. Zn 75 Dig. Zn 100 Mg. Zn 125 Mg. Zn 4 grams, Pb 0.2S 0.25 0.2S 0:29 0.27 0.34 0.33 0.28 0.41 0.31 0:30 0.36 0.30 0.33 0.34 0.31 0.31 0.29 0.35 0.37 0.42 0.41&apos; 0.34 0.38 8 grams, Pb 0.40 0.43 0.42 0.38 0.36 0.43 0.35 0.34 0.41 0.33 0.37 0.37 0.54 0.17 0.59 0.44 0.43 0.43 0.38 0.39 0.41 0.57 0.38 0.46 _ In many instances the zinc does not appear to affect the cupel gold, but various exceptions are apparent, generally in the cupels in the back row. With 100 and 125 mg. Zn, in some cases the Zn burned with its characteristic flame before it could alloy with the other metals. Also, less fusible oxidized lumps were observed during the cupellation and some cupels showed a scum. In order to lessen the premature burning out of the Zn, an alloy of 2 parts Ag to 1 part. Zn was used. A uniform charge of 500,+ mg. Au,

Jan 7, 1917

By Vikram P. Mehrotra

A laboratory investigation was carried out to study the influence of asphalt, bentonite and corn starch binders on the pelletization kinetics of coal fines and on the quality of the resulting pellets. Pellet quality was evaluated in terns of the compression strength, impact resistance (drop test), abrasion resistance and resistance to severe weather conditions. The amount of binder addition did not significantly influence the pellet growth kinetics. However, the pellet quality varied markedly depending upon the type and the amount of binder used. Experimental results are explained on the basis of the mechanism of interaction between the coal particles and the binders. Of the three binders tested, corn starch proved to be the best in all respects but for the resistance to water penetration. Finally, a combination of corn starch (imparting strength) and asphalt emulsion (imparting resistance to water penetration) was found to yield the best quality coal pellets.

Jan 1, 1981

By K. V. S. Sastry, V. P. Mehrotra

A laboratory investigation was carried out to study the influence of asphalt, bentonite, and corn starch binders on the pelletization kinetics of coal fines and on the quality of the resulting pellets. Pellet quality was evaluated in term of the compression strength, impact resistance (drop test), abrasion resistance, and resistance to severe weather conditions. The amount of binder addition did not significantly influence the pellet growth kinetics. However, the pellet quality varied markedly depending upon the type and the amount of binder wed. Experimental results are explained on the basis of the mechanism of interaction between the coal particles and the binders. Of the three binders tested, corn starch proved to be the best in all respects but for the resistance to water penetration. Finally, a combination of corn starch (imparting strength) and asphalt emulsion (imparting resistance to water penetration) was found to yield the best quality coal pellets.

Jan 1, 1983

The recent installation of top gas temperature probes in blast furnaces at Australian Iron & Steel Pty. Ltd. - Port Kembla, has provided the means for studying radial gas flow distribution in blast furnace shafts. This paper describes the top gas temperature probes and outlines their development and results of initial studies aimed at obtaining a suitable relationships between temperature profiles and furnace parameters. The effects of various combinations of burden materials have been outlined by the results reported. The use of probes has also helped to clarify the effect of casting cycles on furnace operation leading to increased emphasis on the reduction of the interval between gun-up and drill-out. Areas for future studies are also broadly Outlined.

Jan 1, 1975