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By J. W. Gálvez

Entre los años 1929 y 1938 se realizaron estudios sobre el problema de los humos en La Oroya y de la construcción del Cottrell de Reverberos, la ampliación del Cottrell de Arsénico y la construcción de las 21 Unidades del Cottrell Central como unidades contrarrestadoras de los humos de mangas y de los convertidores. En ese sentido, el presente texto describe el acondicionamiento de los humos con vapor de agua para ser tratadas en las unidades de precipitación electrostática denominada Cottrell. Para ello, el trabajo se divide en cuatro partes: la primera, describe el circuito de los humos (cobre y plomo) y las unidades de precipitación; la segunda, señala el funcionamiento de la precipitación electrostática; la tercera, refiere los problemas del procesador electrostático y la última, señala la modernización de las unidades de Cottrell.

Nov 20, 1967

By L. Thomas, A. Argyn, B. Mbao, G. Longo Banza

Since the first application of solvent extraction as part of the hydrometallurgical processing of copper, several studies have been carried out to optimize extractant formulations. In 2006, Solvay developed the ACORGA® OPT series of solvent-extraction reagents to optimize copper transfer by use of a blended formulation containing both aldoxime and ketoxime as well as selected modifiers. The incorporation of selected modifiers in these blended reagents resulted in increased copper transfer, due to the interaction between the modifier and oximes within the blend. By changing the ketoxime concentration and ratio of modifier to aldoxime, the strength of the formulation was optimized to enhance copper transfer and improve Cu:Fe selectivity. This formulation is well known in the African region under the ACORGA® OPT5540 name and provides the best performance at the conditions of agitated leach plants with pregnant leach solutions that fluctuate in Cu grade and pH. This paper discusses advantages of using ACORGA® OPT5540 in the Copperbelt

Jan 1, 2023

By James A. Jessop

The Bureau of Mines is investigating the use of geophysical methods to determine rock mass characteristics, particularly rock quality, lithology, and fracture parameters that are important for determining the feasibility of in situ leaching operations. As part of this research, two Bureau-developed crosshole geophysical systems are described that can be used for site investigation and rock mass characterization. Results are given for performance tests at field sites in Arizona and Texas and for correlations between the crosshole seismic data with fracture frequency, rock quality, and lithologic variation. Recommendations are made for using elastic waveform propagation characteristics and dynamic elastic properties for improving rock mass characterization in the geomechanical assessment of in situ leaching deposits.

Jan 1, 1990

By H. V. Fairbanks

It is estimated that millions of tons of coal fines are unsaleable each year due to difficulty of drying them economically with conventional mechanical dewatering and thermal drying equipment. The difficulty is due to the fact that coal of small particle size presents a large surface area with polar groups which have a great affinity for water. In order to remove this water thermally, a high temperature is necessary which oxidizes the surface of the coal. This substantially reduces the heating value of the coal. If drying could be satisfactorily carried out at a lower temperature, much more of the heating value of the coal fines could be retained. It was conjectured that acoustic energy applied during the drying process might prove to be of value since acoustic energy has the property of producing cavitation at a liquid-solid interface when the intensity is sufficiently great. This cavitation process produces water at room temperature which can be carried away from the solid surface by a flow of relatively cool air. Hence, moisture removal is made possible at a lower temperature.

Jan 1, 1966

By Harold V. Fairbanks

This investigation included a study of three different methods for the acoustic drying of ultrafine coals. Ultrafine coal being defined as coal which passes through a 100 mesh sieve. The first method employed stationary drying of small coal samples in sound fields having frequencies of 12,000 cps and 20,000 cps. Sound intensities up to 150 db were used. The second method employed the use of rotary drying kilns. The effect of such variables as temperature, sound intensity, coal feed rate, air flow rate, and initial moisture content were studied. The third method employed the use of a multi-tiered, vibrating screen dryer. The effect of initial moisture content and residence time were studied.

Jan 1, 1970

By Arthur E. Lord, W. Martin McCabe, Robert M. Koerner

Following the driving of each new section of tunnel, a prompt decision is required regarding the type and extent of primary support to control convergence and prevent ground failure. Sometime thereafter, the effectiveness of the in-place support must be evaluated over the entire length of excavation. It is therefore extremely desirable to have available a lightweight, portable, easy to install and interpret, cost effective monitoring system to assist with these ground control functions. Such a system can be assembled based on the acoustic emission (or microseismic) technique. This monitoring technique uses a piezoelectric transducer to detect subaudible noises associated with deformation of and/or crack propagation in the soil or rock being monitored. After detection, the signals are then amplified, filtered and electronically counted to provide a quantified assessment of the stability of the structure. In the simplest sense, the absence of emission, or counts, signifies no deformation and thus stability. Conversely, the occurrance of counts signifies instability to varying degrees. The higher the count rate, the greater the instability and the need for immediate or additional support. Described in this paper is an overview of the acoustic emission (microseismic) method, details of its use in a laboratory study measuring convergence and stand-up time in soil, and the behavior of rock samples under similar stress conditions. Field use of the method is recommended for ground control monitoring in tunnels, and some suggestions regarding monitoring procedure are presented.

Jan 1, 1979

By Matej Petružálek, Tomáš Svitek, Tomáš Lokajícek

"Migmatite from the Skalka region (Czech Republic) was chosen as the experimental rock material. It has macroscopically visible plane parallel structure (foliation). The foliation was caused mainly by biotite grains arrangement. The cylindrical samples of migmatite with subhorizontal, subvertical and oblique foliation were uniaxially loaded up to the failure. Network of 8 broad band sensors was employed for acoustic emission monitoring and ultrasonic sounding. A grid search method with anisotropic velocity model was used for AE hypocenters localization. The source types of successfully localized events were determined from the average first arrival amplitude. Structural anisotropy of tested rock material caused the anisotropy of its mechanical properties (peak strength, Young’s modulus) as well as a different way of fracturing process in dependence on the angle between axial stress and foliation plane. The combination of splitting, shearing and sliding was found to control the fracturing of sample with subhorizontal foliation. The shearing and sliding was dominant in fracturing of samples with oblique foliation. With greater dip of foliation, the role of sliding increased at the expense of shearing. Due to the favorably oriented system of microcracks already present, the shearing and splitting was at the same level during fracturing of the sample with subvertical foliation before nucleation began.INTRODUCTIONThe process of failure of low porosity rocks depends on their mechanical properties and actual stress and temperature condition. At the low pressure and low temperature, the most common way is brittle failure, which is a progressive process requiring the initiation, growth and coalescence of cracks (Lockner, 1993). Stress strain behavior of low porosity crystalline rocks, during the laboratory compression experiments, is divided into four characteristic stages: crack closure, elastic region, stable crack growth and unstable crack growth which leads to the brittle failure, Brace et al. (1966) , Bieniawski (1967), Lajtai (1974), Cai et al. (2004), Nicksiar and Martin, 2012 and 2013.The fracturing process of stressed rock begins with the crack initiation (sci), which for low porosity rocks occurs approximately at 40-50% of peak strength (sp) (Cai et al., 2004; Nicksiar and Martin, 2013). After the sci, the dilatancy begins and stable crack growth follows up to the crack damage threshold (scd), which is approximately at 80% of sp (Cai et al., 2004). After crossing the crack damage level, there is an unstable crack growth accompanied with nucleation of fault plane (sn) at 97-100% of sp. (Rao et al., 2011). The stress drop accompanied with formation of macro scale shear failure plane follows after peak stress is crossed."

Jan 1, 2015

Acoustic Emission Monitoring of Froth Flotation

Sep 13, 2010

The acoustic signals emitted from a laboratory-scale ball mill were used for the estimation of the comminution of two complex sulphide ores, viz. Merensky and UG2 ores from the Bushveld Igneous Complex in South Africa. The digital acoustic signals were transformed to power spectral densities that could be related to particle size distributions (-75 µm to 4000 µm) in the mill by use of continuum regression. This approach is more general than principal component regression methods or Kalman filtering used previously and resulted in significantly more accurate calibration in the case of the Merensky ore, where approximately 93.4% of the variance in the particle size distributions could be explained. With fewer data available, the variance in the particle size distributions in the UG2ore could be explained less accurately (82.4%), but still satisfactorily. In addition, smaller particle sizes (less than 300 µm) could be modelled more accurately in the case of the UG2 ore.

Jan 1, 2000

By S. MacGregor

The role of horizontal stress, its orientation and magnitude, in defining the behaviour of strata in underground coal mines has been well established. Poor panel layouts have led to gate end stress concentrations, roof falls and lost production. The ability to define the horizontal stress regime over a mine site has historically been limited to point measurements, in part due to technology and cost. Recent advances in the application of geophysical tools, notably the acoustic scanner (borehole televiewer) have resulted in a new technique to conduct stress measurements. By quantifying the nature of borehole breakout and the mechanical properties of rocks in which they occur, this technique provides the ability to: obtain a vastly greater number of measurements, both at different depths and spatial distribution, than other techniques such as overcoring or hydraulic fracturing readily obtain depth versus stress relationships define geotechnical domains on the basis of stress direction and in-situ stress magnitude for mine planning purposes This paper presents an overview of the technique and presents case histories in its application at a mine site in the Sydney Basin, Australia.

Jan 1, 2002

By A. McLean, S. Dawson, N. D. G. Mountford

"IntroductionIn order to predict the accepted industrial practice for the year 2000, it may be helpful to first consider the rate of development of scientific knowledge. If the speed with which man can travel on commercial vehicles is taken as a criterion for determining the rate of progression, then it can be seen from Figure 1 that advancement in our present century is very rapid. Likewise, if computer technology is used as a criterion for the measurement of scientific advancement, it becomes evident that technological evolution can be highly exponential. These two examples are sufficient to demonstrate that engineers and managers cannot afford to regard scientific development as being linear with respect to time if they are to avoid underestimating the needs of society.Within this framework of overall development, the time required for individual ideas to progress from inception to regular application has decreased considerably. For example, X-rays first discovered by Roentgen in the 1890's and now used widely in medicine and engineering, required a developmental period of some eighty years. The motorcar evolved from early beginnings at the turn of the century to a position of great social impact in sixty years. Rectifier materials used in high frequency radar to the present explosion in communications, required forty years. As illustrated in Figure 2, the period is shortening rapidly.The use of sound waves appears to be following a similar path. There is now a considerable body of knowledge concerning their behaviour and exceptional advances have been made. In medicine and engineering the sonic approach to examination is well established, and acoustic testing forms the basis of several diagnostic and quality control applications. With respect to metals engineering, ultrasonic testing has contributed to the understanding of the relationship between the size and number of internal defects and the probability of premature failure. This has allowed the designer to incorporate appropriate safety factors in his designs; but more importantly, the realization of the deleterious effect of inclusions on the performance of the final product has resulted in a continuous pressure on the material suppliers to reduce the number of defects in their products.It is not only the designer who is demanding defect free material but also the fabricator, as material breakdown during manufacture can be prohibitively expensive. Examples of this can be found in both the aluminum and steel industries where ultra clean sheet is required to ensure that rejections are minimized during beverage can manufacture and other deep drawing operations."

Jan 1, 1988

By A Sadri, S Smith

In the metal and mineral industry, different empirical techniques are used to estimate the remaining thickness of the lining within an operating furnace. The disadvantage and costly factor when using these methods is that production needs to be halted. Hatch has developed an accurate and reliable technique based on stress wave propagation principles to determine the condition of the remaining lining whilst the furnace remains online and operational.The technique involves test data collected and compiled to generate 3D imagery used to assist operators and maintenance planning personnel with valuable information showing areas of metal penetration in the lining, remaining lining thickness, exact location of voids, cracks, poor contacts and deterioration due to chemical attack. In this paper, the principals of the AU-E technique will be explained both theoretically and practically. In addition, the use of ultrasound technology for determining the condition of copper cooling elements will be briefly addressed.

Jan 1, 2006

By Dale S. Hursh, William A. Brooks

Introduction US dependence on external energy sources is dangerous because of unstable political situations existing in key energy exporting countries. So, recent national energy policies call for increased reliance on domestic energy sources. Coal ranks as the most feasible domestic energy source due to its abundant reserves and continental distribution. But to efficiently extract these coal reserves, huge sums of capital funds are needed. Due to the depressed economy, lenders of capital funds are forced to be more stringent with loan applications. This results in fewer loans granted. In many cases, it is uncertain if funding can be obtained. Furthermore, the greatest level of domestic mine financing is expected to be in the coal sector. Demand for capital in the domestic coal industry is anticipated to increase 80% by 1990. The Chase Manhattan Bank in New York warns that these future needs cannot be met by the present capital markets. This article analyzes the current and expected situations of the capital markets available to the domestic coal industry, including: • current and expected future types of financing used in the domestic coal industry; • problems the domestic coal industry may encounter as it seeks capital; and • the future availability of capital funds as concluded from analysis of the first two items. Background Information Regardless of industry, all projects or ventures can be divided into four basic stages: generation; evaluation; selection; and execution. Within the mining industry, one can break down these stages to draw a clear picture of mine development, as shown in Fig. 1. Each successive stage has a corresponding risk level. This risk level defines the type of financing available to the mine operator. Mining Venture Risks A coal mining venture can be characterized by its unique blend of technical and financial risk. As the mine moves through different development stages, varying proportions of each of these risks are encountered. It is these risks that the lender evaluates to determine project suitability. For a coal mining venture, the major complexities generally occur with the technical risk. These include: • quantifying the coal reserves: • assessing the feasibility of the mining method; and • evaluating the design of the wash plant. The reserve risk is gauged by the amount of measured, mineable, and saleable reserves. The greater the latter amounts, the lower the risk. Secure title to the reserves plus title for any surface areas required are also of concern to the banker. Feasibility of the mining method and evaluation of the wash plant design should verify that the project can be completed according to the engineered spec-

Jan 9, 1982

By Jom Gentry

Acrylamide chemical grout (C3H2NO) has been successfully used for over 50 years to control groundwater and stop infiltration. This paper will address three unique projects involving the control of groundwater with each study providing special circumstances and geological conditions: encapsulation of radioactive hazardous waste in the United States, a tailings dam for a large copper/gold mine in Argentina and 27 miles of leaking subway in Canada. The primary reasons for selecting acrylamide grout were based on the following characteristics: thinnest chemical grout on the market, a true solution grout which contains no suspended solids in the blended product, flexible gel set times, and a 362 year half-life in soil as determined by the U.S. Department of Energy.

By Daniel Magill, Jim Gentry

"Acrylamide chemical grout (C3H2NO) has been successfully used for over 50 years to control groundwater and stop infiltration. This paper will address three unique projects involving the control of groundwater with each study providing special circumstances and geological conditions: encapsulation of radioactive hazardous waste in the United States, a tailings dam for a large copper/gold mine in Argentina and 27 miles of leaking subway in Canada. The primary reasons for selecting acrylamide grout were based on the following characteristics: thinnest chemical grout on the market, a true solution grout which contains no suspended solids in the blended product, flexible gel set times, and a 362 year half-life in soil as determined by the U.S. Department of Energy.INTRODUCTIONChemical grouting has been successfully used for over fifty years to control the movement of groundwater in a wide variety of applications including:•, Hazardous Waste Containment•, Subways & Tunnels•, Mines & Tailings Dams•, Concrete & Earthen Dams•, Underwater Structures•, Beneath/Around Underground Structures•, Mainline Sewers, Laterals, Manholes•, Large Soil Stabilization ProjectsThis presentation will review three projects where chemical grout was utilized to address some very difficult water control challenges, each providing special circumstances and geological conditions:1. Pre-construction seepage control at a mine tailings dam2. 27 miles of leaking subway3. Encapsulation of radio-active hazardous wasteThe reasons for selecting acrylamide grout as the solution for controlling groundwater in these selected projects were based on the following characteristics:1. Acrylamide grout is the thinnest chemical grout on the market2. No suspended solids which allows acrylamide grout to travel anywhere water can travel3. Flexible gel set times from 5 seconds to 10+ hours4. U.S. Department of Energy studies conclude that acrylamide chemical grout has a 362 year half-life in soil and can reduce the permeability of rock/soil to less than 10-8 meters per second (m/s)"

Jan 1, 2017

By B. Mishra

Several reactive metal purification processes using molten salts generate effluent from which significant quantities of metal can be recovered prior to discardinglrecycling the salt. A Salt-scrub [SS] process has been applied where the reactive metals are recovered as a metal-gallium alloy by calciothermic reduction of the metal compounds. The SS alloy compositions were produced by mixing, pressing and sintering the metal-powders. Measurement of metal recovery has been studied for cerium, silver, tin and lead. The process has been optimized for variables such as the metal quantity per kg of effluent salt, amount of excess calcium over stoichiometry, stirring rate and time and holding time at reduction temperature. Over ninety-seven percent metal recovery has been obtained under optimized conditions. The development of an alloy for efficient Salt Scrub processing reduces a major contaminated waste disposal problem as well as recovering the valuable reactive metal. Surrogate metals have been used in this work to study the behavior of plutonium.

Jan 1, 1994

By S. J. Liu

The conventional collector for bauxite mineral is oleic acid, which is highly insoluble and must be used in high dosage in bauxite flotation operations, that is the great drawback of oleic acid in use. A series of hydroxamic acid were synthesized, and their collecting ability to certain minerals in bauxite: diaspore, kaolinite were studied. The collecting power of various reagents to diaspore in an incremental sequence were shown as follows: benzyl hydroxamic acid<amylic hydroxamic ac-id<heptylic hydroxamic acid<oleic acid<octylic hydroxamic acid; while the incremental sequence of the collecting power to kaolinite was like this: benzyl hydroxamic acid<amylic hydroxamic ac-id<heptylic hydroxamic acid<octylic hydroxamic acid<oleic acid. It could be seen that octylic hydroxamic acid had the capability of high collectivity and good selectivity, and octylic hydroxamic acid was chosen to use in the following experiments. Reduced zeta potential showed the adsorption of the anionic collector on the mineral. By the adsorptive capability and IR tests, the adsorption of octylic hydroxamic acid on diaspore was determined to be chemical absorption, which was greater than that of oleic acid, as it was physical absorption. Results of floatation experiments on manually mixed minerals indicated that the collectivity and selectivity of octylic hydroxamic acid were better than oleic acid.

Jan 1, 2014

By T. Clinton Taylor

QUALITATIVELY, galena (native lead sulfide) reacts with aqueous solutions of the xanthates,1 and has its surface sufficiently altered so that there is a tendency for air bubbles to attach themselves to the mineral crystals where there was no such effect before the treatment. This property is utilized in froth flotation operations where the mineral sulfide particles are raised into the froth and the gangue whose surface is not altered remains behind. The results of a study of this reaction were reported" recently and certain tentative suggestions about the interaction of galena and the alkali xanthates were offered. In this paper, there is set down the results of a detailed quantitative investigation of the ions involved in this inter-action with a view to finding out more about the condition existing imme-diately at the surface of a crystal like a heavy metal sulfide after treatment with an organic reagent. Past experimental experience showed that finely ground galena shaken with aqueous potassium xanthate abstracts xanthate ion and at the same time sulfate ion, reducing ions of the type (SmOn)= where the ratio of m to n is less than 4:1 (as in sulfate), sometimes hydroxyl ion are thrown into solution.,

Jan 1, 1933

By W. H. Bassett

In considering the effects of reducing gases on hot solid copper the following conclusions have been reached. (1) Depth of deoxidation of copper heated in reducing gas is greater the smaller the amount of cuprous oxide originally present in the copper, the range studied being from 0.015 to 0.136 per cent. oxygen. It is suggested that the reason for this difference in depth of deoxidation is that, when the copper is low in cuprous oxide, the reducing gas is diluted less by the gas that is formed in the reaction than when the copper is high in cuprous oxide; and the greater the concentration of the reducing gas the deeper the deoxidation. (2) The rate of deoxidation is much mire rapid at the beginning of exposure than at the end, a condition especially noticeable at temperatures around 900° C.; that is, deoxidation is retarded as the depth penetrated by the reducing gas increases. (3) Within the accuracy of the experiments arsenic in copper up to 0.5 per cent. has no tendency to increase or decrease the action of a reducing gas on the cuprous oxide present in the copper. IN 1912 pieces of 0.365-in. hard copper rod 1/2 in. long were heated in a porcelain tube in an electric furnace, while illuminating gas was passed through. An approximate analysis of this gas is: FIG. 1.-EFFECT OF TIME AND TEMPERATURE ON DEOXIDATION RATE OF 0.365-IN. COPPER BY ILLUMINATING GAS; COPPER PLUS SILVER, 99.983 PER CENT. Hydrogen 38 per cent., carbon monoxide 30 per cent., illuminants 13 per cent., methane 10 per cent., ethane 3 per cent., carbon dioxide 3 per cent., nitrogen 2 per cent., oxygen 0.4 per cent. After heating for various lengths of time at various temperatures, samples were quenched

Jan 1, 1926

By W. C. Schroeder

PRACTICAL experience has shown that at elevated temperatures solu-tions containing sodium hydroxide may attack stressed steel in a manner that cannot be explained in terms of ordinary corrosion. Because the ductility of the metal has been greatly reduced during the reaction, the entire phenomenon is usually called "embrittlement." Thus, after several years of operation caustic evaporators have been so badly embrittled that rivets could be cracked off with the blow of a hammer. Since fine intergranular cracks are almost always present in the zone of fracture, it has often been assumed that a process of selective corrosion in grain boundaries was responsible for the failure, although this has not been clearly proved experimentally. Concentrations of sodium hydroxide below those necessary for the uniform, rapid attack of the steel surface are reported to be most effective in producing embrittlement2,3. In the operation of steam boilers a similar type of failure has been found, mainly in riveted seams or other capillary spaces where the solu-tion may concentrate and where high stresses may also exist. It is believed that in such localized areas the dissolved solids may reach a value many times the few hundred parts per million prevalent in the body of the boiler. While this type of boiler failure has been the subject of investigation for a period of 20 years&apos;, an understanding of its mecha-

Jan 1, 1936