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By K. Morita, S. Ueda, Y. Matsuki

Tellurium has mainly been used as an alloying element for resulfurized free-machining steel. It globularizes MnS inclusions and improves both machinability and mechanical properties of such steel. This effect is quite sensitive to tellurium concentration.Therefore,its incorporation should be controlled accurately during the secondary refining process, using the thermodynamic properties of tellurium in molten iron. In the present study, Wagner’s interaction parameters of various elements on tellurium were experimentally evaluated by vapor-liquid equilibration, and the vapor pressure of tellurium was controlled using the transpiration method. The values obtained were compared with those of oxygen and sulfur, and they were found to be correlated with the standard Gibbs energy of formation of the corresponding oxides, sulfides, and tellurides.The results indicate that the relations described here could provide estimates of interaction parameters that have not been experimentally determined thus far by using available thermodynamic quantities.

Mar 1, 2017

By A. Garassino

A pile design was performed for a thermal power station in Egypt and more than 4000 piles were to be driven. Technical economical reasons suggested the choice of driven composite LACOR piles designed for very high specific loads. Some uncertainties on the behaviour of the pile soil system suggested to perform a test on an instrumented pile. Scope of the test was to verify the possibility of developping the required bearing capacity within the range of the allowable pile settlements values and the effect of the pile joint enlargement on that portion of skin friction to be developped by the upper pile section.

Jan 1, 1991

By J. B. Clemmer

PRODUCTION of magnesium metal in the United States during the past decade has increased from less than 600,000 lb. in 1928 to more than 4,800,000 lb. in 1938.1 The growing industry has stimulated interest in methods of production and in sources of raw material. All of the present domestic production is from brines. However, the availability of large tonnages of magnesite in the state of Washington, together with the possibility of cheap power, have created interest in the utilization of magnesite for the production of magnesium metal as well as for other purposes. Magnesite, the carbonate of magnesium (MgC03), usually is associated with lime-stone (CaCO3) and dolomite (MgC03 CaCO3). It occurs in crystalline and microcrystalline (sometimes termed amor-phous) forms.2 The more common crystal-line mineral is found in various shades of white, gray, yellow and brown, the colors being due to impurities, chiefly iron. Magnesite has a hardness of 3.5 to 4.5 and a specific gravity of 3.0 to 3.1. It forms rhombohedral crystals in the hexagonal system, having a vitreous, pearly luster. The quarries and mines of the Northwest Magnesite Co. near Chewelah, Wash., are large producers of magnesite for refractories.

Jan 1, 1940

There is no other effective way for study ing firedamp and coaldust explosions than to produce controlled explosions in a pre-monitor- ed environment - either mine openings kept for the purpose, or special surface galleries. Such explosion testing facilities have been employed historically at Buxton in U.K., with lesser known installations at Bruceton, U.S.A., Tremonia, West Germany, Katowice-Mikolow, Poland and elsewhere. Both firedamp and coal dust explosions are studied. Normally coal dust explosions are initiated by somewhat standardised methane air mixtures, by explosives, or purely by coal dust. Various structures and suppression installations are installed in roadways and galleries prior to explosion to simulate destruction and suppression, and the results of such tests form the basis of suppression installations, especially stone dust barriers and water barriers. Other data collected from these experiments include rev- ersals of explosion waves, pressures and temperatures and duration of explosion waves, analyses of aftergases etc. Other uses of explosion testing galleries include testing of explosives, electrical equipment and frictional . sparking.

Jan 1, 1981

By E. L. Burwell

Preliminary results of an in situ oil shale retorting experiment conducted by the Bureau of Mines in a shallow bed of Green River oil shale at Rock Springs, Sweetwater County, Wyo., are described. Eleven wells were drilled into a 20-ft-thick section of the shale lying between 68 and 88 It deep, and attempts were made to connect the wells through the shale with a fracture system created by application of high-voltage electricity (electro-linking), hydraulic fracturing, and explosive fracturing. Ignition of the shale through the central well was easily achieved with a propane burner, and shale oil began to collect in three wells within 3 hours. Propane injection was discontinued after 7 days, and combustion continues, although attempts to control the direction of the combustion front have been unsuccessful. Production rates as high as 4 ½ barrels of nil per day have been recorded, but too little is known about underground conditions to permit an estimate of recovery efficiency at this time.

Jan 1, 1969

By Y. Foucaud, C. Eswaraiah, L. Filippov

Enhanced gravity separators such as Falcon concentrator which uses additional centrifugal force, are the most common gravity concentration techniques used for fine particles processing. Hence, understanding the kinetics and separation mechanisms within these separators is of paramount interest. Recent research yielded a predictive physical model for the Falcon Ultra Fine (UF) which however does not explain some results obtained with industrial ores. This study aims to identify the mechanisms involved in Falcon UF separation with the objective of confirming or rejecting the hypotheses on which the current model is built and suggesting potential points of improvement. The Falcon UF kinetics is investigated through the processing of complex low-grade and fine-grained ores from the Altenberg tin deposit (Germany), the Tabuaço tungsten deposit (Portugal) as well as a synthetic iron ore. Saturation tests are performed on the Falcon UF by controlling the separation efficiency in terms of recovery and enrichment ratio with time or feed mass. Results show an evolution of Falcon UF performance with time in contradiction with the stationary separation hypothesis on which the physical model is based. Observation of the concentrate bed suggests the presence of erosion figures in furrows which may play locally an active role in the separation. In terms of Falcon UF separation timing, three phases can be distinguished. First, upon initial feeding of the bowl, a bed quickly grows unselectively and ultra-fine particles are ejected from the bowl until the bed reaches its final profile. Next, actual separation occurs with selective concentration of dense particles. Finally, capture sites saturate and recovery drops. The evolution of partition curves over time confirms the existence of two separation mechanisms. First, differential particles settling within the flowing film responsible for the ejection of small size particles during the whole separation cycle which is already accounted for in the physical model. The second mechanism involved may be explained by the action of lift force, neglected in the physical model, which acts preferentially on coarse particles deposited at the surface of the bed resulting in coarser particles being rejected in the tailings. Hence, the addition of a lift force component to the existing model is suggested to account for this second separation mechanism.

Jan 1, 2018

By Jelke Dijkstra

This paper presents the results of model pile load tests in a photoelastic material. The soil in this test is represented by an assembly of photoelastically sensitive glass particles, which allows for optical measurements of stresses. In the same test setup, displacements around the pile are measured using digital image correlation (DIC). During the pile installation stresses and strains are recorded. Tests were performed in loose and medium dense particle assemblies. The development of stresses and strains around the pile tip and pile shaft are quantified and presented in this paper. For the loose conditions the results show a small influence on the stress state. For the medium dense conditions a clear stress change is observed.

Jan 1, 2006

By J. Dionne

"Next to the actual mine of Les Explorations Muscocho Ltée in Montauban, Quebéc, you could find a total of 364 000 tons of flotation tailings assaying 1.4 Au g/t et 82 g Ag/t to the south of the municipality. This tailings pile is what is left of previous operations. Preliminary leaching tests on these tailings in laboratory columns gave interesting results which led to tests in larger columns in 1984 and to a pilot test on a 750 ton heap in Montauban during the summer of 1985.This paper briefly describes the columns tests performed at the Centre de Recherches minérales and the heap leaching test designed and conducted by SOQUEM in Montauban. It also presents the results obtained.RESUMEPrès de la mine actuelle de Les Explorations Muscocho Ltée à Montauban, Quebéc, se trouvent, au pied du village, 364 000 tonnes de rejets de flottation titrant environ 1,4 g Au/t et 82 g Ag/t. Ce tonnage de rejets représente ce qui reste de l'opération des anciennes mines de Montauban.Des essais préliminaires de lixiviation en colonne sur ces rejets ont donné des résultats encourageants. Ils ont été suivis en 1984 par des essais en colonnes plus volumineuses et par un essai pilote à Montauban en 1985 sur une pile de rejets de 750 tonnes.Ce te x te donne une brève de script ion des essais en colonne effectues au Centre de Recherches minérales et de l’essai pilote planifie et exécute à Montauban par SOQUEM. Il présente les résultats obtenus."

Jan 1, 1987

By O. Salami, G. Xu

Fire accident is one of the most classic safety concerns in underground mines both in the USA and abroad. It may occur from pool fires due to leakages in hose or pipes, vehicle fires, or fires in tires and conveyor belts in the underground mines. It may also result from the storage of flammable materials such as gasoline, diesel, and explosives in the underground. When fire occurs in an underground mine, it releases heat, smoke, and other toxic gases such as carbon monoxide, and methane to the surrounding thereby making life unbearable to the miners. Furthermore, smoke greatly impact visibility in the underground which makes evacuation even more onerous and challenging. To this end, a thorough investigation of fire behavior and spread of toxic gases in a practical underground mine is imperative to develop a reliable emergency evacuation plan in an event of fire disaster in the underground mine. The objective of this study is to investigate temperature variation and CO spread along mine airways by conducting full-scale fire experiment in the underground mine. The results presented from this study are crucial to developing evacuation plans in underground mines. In addition, the findings from this study could be used to validate existing evacuation models.

Mar 2, 2022

By Y. S. Sun, Northeastern University, W. B. Li, P. Gao, Z. Y. Zhang, J. W. Yu

"The boron-bearing iron concentrate was extracted from ludwigite ore by the process of magnetic-gravity separation. In order to fully utilize the refractory ore and meet the boron consumption of China, a novel process for separation of boron from iron in boron-bearing iron concentrate was proposed in this paper. In particular, laboratory scale experiments of improving boron reactivity were performed. Fine boron-bearing iron concentrate briquettes were reduced by bituminous coal completely at 1125 °C for 150 min. The effect of sodium carbonate, which was used as an additive in the roasting process, was investigated. The addition of sodium carbonate decreased the boron reactivity and facilitated the volatilization of boron. The influence of diverse cooling methods of the reduced samples on the boron reactivity was studied. The results indicated that boron reactivity could reach up to 80.76% when the reduced samples were cooled by rapid water quenching. In addition, the magnetic material containing 92.71 % Fe with a recovery of 95.11 % and boron-rich non-magnetic material containing 14.51% B2O3 with a recovery 88.85% could be obtained by low-intensity magnetic separation. The magnetic material and boron-rich non-magnetic material were good raw materials for steel-making and borax production, respectively.INTRODUCTION Ludwigite ore is abundant in Liaoning province of China, with 28.43 Mt B2O3 accounting for 57% of the boron resources of the country (Liu et al., 2006). However, it has not yet been utilized on an industrial scale due to its complex mineralogy and fine mineral dissemination (Wang, Wang, Ding, Ma & Xue, 2012). At present, boron-bearing iron concentrate and boron concentrate can be obtained from ludwigite ore using magnetic-gravity separation. The boron concentrate contains B2O3 12%~16%, which can be used as a high-quality raw material for the boron chemical industry after activated roasting, but the B2O3 content in the iron concentrate reaches up to 4%~6%. In order to further separate boron and iron from boron-bearing iron concentrate, a blast furnace and a solid pre-reduction followed by electric arc furnace melting have been proposed (Liu, Cui & Zhang, 1998; Wang et al., 2012). However, both of these two current routes face the same crucial problem that molten boron-rich slag has to be cooled slowly to obtain the alkali-dissolution activity of boron, which affects the yield of boron resource."

Jan 1, 2016

By G. G. Krishna Murthy

Several experiments were carried out to simulate the bath smelting reactions where iron oxide particles were dropped on to an iron-carbon bath containing molten CaO-SiO2-Al2O3 slag layer on its surface. The composition of the slags used in the experiments was %CaO:46.1; %SiO2:41.7; and %A1203:12.2. Experiments were con¬ducted with carbon saturated iron melts contained in either a pure graphite crucible whose walls were covered with a pure alumina tube, or a pure flat bottom alumina crucible, at 1723-1823 K. Degree of reduction of a pure iron oxide particle was linear with time in the initial stages (up to about 20% oxygen of the original pellet was reduced). The rate of reduction of smaller oxide pellets was smaller than that of a bigger pellet - the time for complete reduction of a 5.6 g wustite pellet was smaller than that for a 1.2 g wustite pellet. It was also established that the interaction rates obtained by adding a molten pure oxide particle of given weight to the system were lower than that determined by using a solid oxide particle of same weight. The overall rates of reduction decreased with decreasing the bath temperature. The experimentally determined rates of reduction based on the time for 70% reduction were influenced substantially by addition of slag up to about 50 g on to a bath of 78.8 mm in diameter, and remained constant when slag present on the bath surface was between 50 g and 200 g.

Jan 1, 1993

The slags produced by the Imperial Smelting Process (ISP) are based on the system ZnO-?FeO?-Al2O3-CaO-SiO2. The slag chemistry is important to the process since it determines the fluxing practice and the operating temperature of the furnace required to produce fluid slag. The paper presents the results of the first systematic experimental investigation of these ZnO-containing slags in equilibrium with metallic iron, and provides information on the primary phase fields and liquidus temperatures in these slags over the range of compositions used in ISP practice. A feature of the slags is the presence of alumina, which has a major influence instabilizing the spinel phase. This information presented in the form of pseudo-ternary sections ZnO-?FeO?-(Al2O3+CaO+SiO2) enabling the data to be readily used by plant engineers. Keywords: liquidus temperature, ISP, EPMA, ZnO-?FeO?-Al2O3-CaO-SiO2, phase equilibria.

Jan 1, 2004

By M. A. Kader, M. A. Islam, P. J. Hazell, M. Saadatfar, J. P. Escobedo, A. D. Brown

The dynamic pore collapse mechanisms and energy absorption capacity of closed-cell aluminium foams subjected to low velocity impacts have been investigated. Impact experiments were carried out using an instrumented drop-tower with two impactor geometries: a 50 mm square flat steel impactor to investigate pore collapse mechanisms and a 20 mm diameter hemispherical steel impactortostudy indentation resistance.X-ray computedtomography was utilized to generate views of the deformation field within the impacted specimen. The results show that the strain rate and incident impact energy influence the energy absorption capacities of closed-cell aluminium foams. Furthermore, damage initiation, propagation and cell collapse mechanisms under drop weight impact have been elucidated.

Mar 1, 2017

By A. Shibayama

Soil contamination by organic compounds is one of the most concerned issues on polluted soil. It is well known that there are limited methods to remediate the contaminated soil on site. Especially, the in-situ method for contaminated soil is too difficult to de-contaminate the organic pollutant. In this study, the fundamental ability of soil remediation, which aimed to decrease oil concentration in, in-situ process, have been researched by using a high pressure gas generated from ?crush composition? on artificially oil contaminated soil. The n-hexadecane (n-C16H34) and other organic compounds were selected as soil oil contaminators, gravimetric analysis by soxhlet extraction and GC-MS were used as qualitative and quantitative analysing methods. For the experimental examination, the influences on the difference in the concentration of n-hexadecane (and other organics), the tamping amount, position and repetition of crush composition in soil, and scale (size) of experimental model were investigated. The n-hexadecane concentration reduced by the explosive effect of crush composition showed a reasonable decrease of about 30 wt%~60 wt% compared to the initial n-hexadecane. The removed amount of n-hexadecane and distance from explosion point of the crush composition was related in scale and model of contaminated soil.

Jan 1, 2014

By Minna Rämä

Iron containing leach residues like jarosite and goethite from electrolytic zinc production contain many valuable metals and harmful substances. These metals and substances should be removed in order to obtain an acceptable, stable and reusable product, and maximize economic feasibility as well as minimize environmental footprint. In this work, the processing of jarosite leach residue was studied in laboratory scale experiments under oxidizing and reducing conditions at high temperatures. First, the pretreated material was melted and oxidized to produce a melt of metal oxides. Second, the oxide melt was reduced in CO–CO2 atmosphere. Target after the reduction step was to obtain a clean slag and a liquid metal or speiss phase that collects the valuable metals, such as silver. The kinetics of the thermal processing were studied for determining optimal times and conditions for the aforementioned process steps. The preliminary results show that the process is thermodynamically feasible, and the desired phases can be obtained in the experimental conditions investigated.

By Patrick M. Eduafo, Brajendra Mishra, Mark L. Strauss

Direct acid leaching of rare earth metals (REMs) from waste lamp phosphors is non-selective, leading to co-dissolution of impurities mainly calcium, phosphorus, silicon, iron and zinc. Calcining the phosphor powder at different temperatures followed by leaching with HCl isn’t efficient for the extraction of all the chief rare earths especially cerium (Ce), lanthanum (La) and terbium (Tb). Therefore, multi-stage leaching operations are required for the separation of the REMs in phosphor dust. This paper will outline a new process for extracting Ce, La, Tb, Eu and Y from waste fluorescent lamps using a three-stage leaching and separation process. A flowsheet has been developed which shows this process is selective and efficient.

Jan 1, 2015

By J. F. White

An experimental study was undertaken to evaluate the feasibility of a selective chloridizing roasting pre?treatment process for the elimination of impurities from zinc feed?stocks prior to recovering zinc by conventional unit operations. In this investigation, a number of chemistries that might serve as a basis for such a pre? treatment process were examined. A variety of chloridizing agents were admixed with EAF dust to promote the selective removal of lead and cadmium by the formation of volatile metal chlorides, he results of the experimentation firmly establish that selective chloridizing roasting is a technically feasible means of eliminating lead and cadmium from EAF dust. Excellent extraction efficiencies were accomplished with a number of chloride additives; as high as 98 percent lead extraction and 88 percent cadmium extraction were attained with minimal zinc losses, Continuous pilot?scale tests reinforced the trends established by laboratory?scale experimentation, Attempts of chlorine elimination using pyrohydrolysis were less successful. The extent of chlorine elimination was found to be highly dependent upon EAF dust sample type and treatment temperature.

Jan 1, 1996

By S. Nikolic, O. O. Kehinde-Philllps, O. T. Djamgouz, D. H. Rousell

"A bulk mining method is employed at the Lockerby mine resulting in the formation of large muck-piles. If these muckpiles remain in the stopes for some time they may agglomerate to the extent that the muck cannot be removed by a scooptram. A laboratory investigation was undertaken with sulphide material from the mine in order to detemine the time that oxidation begins and the flowability of the material as a f unction of several factors. The laboratory results are applied to the conditions in the muck-piles.The time of the beginning of oxidation of the material decreases as the sulphide composition, water content and availability of air increases. Oxidation is retarded by the addition of a copper sulphate solution instead of water. The unconfined yield force (strength} of the material increases with an increase in the sulphide composition, water content and time. The material ceases to be free-flowing before there is visible evidence of oxidation and this suggests that oxidation actually begins earlier and that agglomeration is also due to the capillary action of water.Broken ore should be removed from the stope prior to the time a muck-pile ceases to be free -flowing-perhaps as early as two days f or high-grade ore and 5 days f or low-grade ore. In order to control dust, 1.4 weight per cent of a 5 per cent solution of copper sulphate should be added 10 the muck-pile rather than water. This inhibits oxidation and increases the time that a muck-pile remains free-flowing."

Jan 1, 1984

By Neel Gupta, Brijes Mishra

Coal mining activity disturbs the natural equilibrium of in situ stress state such that the induced stresses deform the surrounding rock mass. Although the installation of roof supports typically prevents rock deformation, rock mass failure may still occur in bolted roof. The erratic failure of rock mass after few days to months and years of excavation is the result of time-dependent deformation of roof rock under constant surrounding stresses. In the current research, the triaxial laboratory creep experiments proved that Marcellus shale exhibits time-dependent deformation under constant stress that was smaller than the failure strength. However, unlike conventional experimental results, the time-dependent deformation did not depend on the level of constant stress. The often-neglected initial state of specimens and intrinsic heterogeneity highly influenced the time-dependent failure of Marcellus shale.

Jul 27, 2021

By Ki-Bok Min, Seokwon Jeon, Seung-Beum Choi, Taehyun Kim

"In order to investigate anisotropic characteristics of Boryeong shale in Korea, which clearly shows transverse isotropy, a series of experimental tests were carried out. Using Brazilian test, five elastic constants and tensile strength of the shale were evaluated. Elastic constants were determined by iterative procedure and in order to perform this procedure, constitutive model was modified to fit the experimental condition. The anisotropic ratios of elastic constants were evaluated and the applicability of the methodology was assessed. Apparent Brazilian tensile strength profile was investigated and the ratio of the maximum to minimum tensile strength was estimated. Results showed that the tested rock type had low to moderate anisotropic characteristics.INTRODUCTIONMechanical, thermal and hydraulic characteristics of many rocks vary according to direction, which is known as inherent anisotropy, and it is originated from stratified and/or foliated structure of intact rock and discontinuity of rock mass. Anisotropy is one of the long standing issues of rock mechanics field and it has to be taken into account in several engineering fields such as civil, mining and petroleum engineering. An anisotropic medium has 21 independent elastic constants without any assumption of symmetry. If a material has any symmetry, the number of elastic constants required to define its behavior reduces and eventually two constants are necessary if it has complete symmetry, which is known as isotropy. An anisotropic medium that has remarkable planar structure due to its stratification and foliation such as bedding is often called as a transversely isotropic medium. Transversely isotropic model is frequently adopted in many applications especially for sedimentary rock formation and five elastic constants are required to establish the constitutive model."

Jan 1, 2015