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By A. F. Usov

The paper is concerned with an analysis of the experience gained in development of special electro-technical installations applied in electric-pulse destruction of materials. A principle scheme of an electric electric-pulse installation is given, and electric circuit variants of its blocks made on various element bases are discussed. Also assessed are some ideas to further improve the technical and economic characteristics of the equipment.

Jan 1, 2014

The General Electric Co., in cooperation with the Montana School of Mines and under a research grant from the Anaconda Co., is presently experimenting on a new non-explosive method of breaking rock with radio-frequency electrical power. The method is known as electrothermal forcing. It must be understood that present equipment has not been designed to perform primary blasting functions. Its conceived use will be restricted to small pieces of rock too large to pass through a chute or grizzly. However, even this use is still far in the future. Experiments to date have been limited mostly to rock smaller than 18 in.

Jan 11, 1961

By T. R. Raponi, D. Barnes

The Williams Mine mines and mills 6000 t/d (6600 stp’d) of gold ore using SAG/ball milling, leaching and CIP, electrowinning and refining. Electrowinning, high-pressure cathode washing, filtering, retorting and refining are based around the use of knitted stainless steel mesh cathodes. Their primary advantage over conventional steel wool cathodes is that electrowon gold can be washed off and the cathode can then be reused. Typically, the knitted cathodes have a useful life of up to 15 months. Gold production of up to15 t/month (50,000 oz/month) is easily processed with this system. Presented is a description of this operation, including a review of the equipment and performance data.

Jan 1, 1992

The maximum current density at which conventional copper electrowinning plants will result in satisfactory, adherent, and dendrite·free cathodes is determined by the thickness of the diffusion boundary layer. A decrease in the value of that thickness will permit an increase in the current density. This fact is utilized to develop a high current density cell in which the reduction of the boundary layer thickness is accomplished by means of a specially designed electrolyte circulation system. The high current density cell is used to determine the effect of current density on such process parameters as current efficiency, cell voltage, power consumption, and cathode purity. A number of empirical equations are developed for the purpose of estimating the magnitude of these effects.

Jan 1, 1972

By Andersen AK

As part of a research program sponsored by Continental Copper and Steel Industries, Inc. (cos), investigations have been conducted by the Colorado School of Mines Research Foundation, Inc. to study the effect of high current densities on electrolytic processes. The importance of high current densities has long been recognized, particularly in the deposition of copper, and the results of considerable research on the subject have been reported in recent years (19 29 39). This is not surprising because, besides plant capacity, current density is the other major factor which will determine the process economics. In the production of electrolytic copper, current efficiency, steam consumption, number of cells, building area, metal inventory, cathode purity, and power consumption are all affected by current density. The ability to maintain a high current efficiency and satisfactory cathode purity while increasing the current density to twice or three times that commonly practiced could result in considerable saving of capital investment and reduce the operating cost per ton of metal produced. The optimum current density i.e., that current density of which production cost would be at a minimum, can be established from an analysis of the various inter- relating factors (49 59). A review of.all operating electrolytic plants (electrowinning and electrorefining) will indicate that most of these plants are operating at 50% or less of the optimum current density (6). One of the reasons for not using the optimum current density may be attributed to the fact that conventional electrolytic tank- house equipment does not perform satisfactorily at high current density operations. Various investigators (19 79 8) have attempted to overcome this limitation by modifying the design of the electrolytic cell, virtually unchanged since it was first introduced in the late 1800's. Previously, these attempts have not resulted in,a cell design suitable for commercial application. However, recently, a cell has been designed which performs efficiently under such conditions. This is a CCS development (patents applied for).

Jan 1, 1969

By D. J. Fray, F. Tailoka

Microporous ceramic tubes (15 micrometre pore diameter) and PVC membranes (10 micrometre diameter) have been used as spargers in the electrowinning of copper from concentrated and dilute chloride electrolytes. At a current density of 600 A/m2 and a nitrogen gas sparging flow rate (at NTP) of 1.53 cm3/s per unit electrode length, it was possible to electrowin planar rather than powdery deposits with copper concentrations as low as 0.157 M. To obtain a planar deposit at higher concentrations of cupric chloride the most realistic optimum current density appears to be between 1 000 and 1 500 A/m2.

Jan 4, 1993

By J. E. Murphy, L. A. Walters, F. H. Nehl, G. B. Atkinson

The US Bureau of Mines investigated the selective electrowinning of Ag and Au from cyanide solutions contaminated with Cu with the goal of decreasing the amount of Cu codeposited. Decreasing Cu codeposited will reduce refinery costs. Direct current was applied to the cell in pulsed and square wave voltages at 0.7 A h/150 mL of solution. Times tested for each cycle ranged from 1 to 10,000 msecs. Graphite, lead and stainless steel were evaluated as electrode materials. Square wave electrowinning at 70°C (158° F) gave the best separation of Ag and Au from Cu. Applying 2.5 V during the duty cycle, 0.0 V the rest of the period, a duty cycle of 10% to 30%, and a period of 100 msecs to 1000 msecs gave the following results: Ag concentrations decreased from 34 µg/mL to 0.1 µg/mL. Au concentrations decreased from 54 µg/mL to 0.2 µg/mL and Cu concentrations remained almost constant at 560 µg/mL.

Jan 1, 1995

By F. H. Nehl

The U.S. Bureau of Mines investigated the selective electrowinning of Ag and Au from cyanide solutions contaminated with Cu with the goal of decreasing the amount of Cu co-deposited. Decreasing Cu co-deposited will reduce refinery costs. Direct current was applied to the cell in pulsed and square wave voltages at 0.7 A?h per 150 mL of solution. Times tested for each cycle ranged from 1 to 10,000 ms. Graphite, lead, and stainless steel were evaluated as electrode materials. Square wave e1ectrowinning at 70? C gave the best separation of Ag and Au from Cu. Applying 2.5 V during the duty cycle, 0.0 V the rest of the period, a duty cycle of 10 to 30 pct, and a period of 100 ms to 1,000 ms gave the following results: Ag concentrations decreased from 34 µ g/mL to 0.1 µ g/mL, Au concentrations decreased from 54 µ g/mL to 0.2 µ g/mL, and Cu concentrations remained almost constant at 560 µ g/mL.

Jan 1, 1993

A description is given of preliminary work done to identify the problems inherent in electrochemical oxidation of metal sulphides, and particularly in the use of powder compacts as anodes in electrolysis. Lead flotation concentrate pressed into a compact can serve as an anode for direct electrowinning of lead according to the reaction PbS -7 Pb2+ +So +2e. No pYrometallurgical step is required, and sulphur is recovered in elemental form.In the experimental work, electrical conductivity of the compacts was achieved by addition of 5·5 per cent of graphite. After compaction at 10-20 tons/sq. in. the anodes were strong and remained intact throughout the electro-oxidation period. Perchlorate electrolyte was used, but fluosilicate electrolyte is also applicable. A sheet of pure lead formed the starting cathode.As anode potential increased above 1·0 V (v. SHE) PbS04 was formed in increasing amount. At 0·90 V, Pb2+ extraction efficiency was 85 per cent. Anode potential was kept low by electrolysing at 60°C and 15 mA/sq. cm., and by improving the porosity of the compact. Other metal sulphides (Zn, Fe, Cu) in the flotation concentrate also oxidize and release metal ions to the electrolyte, which would need to be purified prior to deposition of lead.Power requirement in a laboratory cell was about 0·24 kWh per lb of lead extracted.

Jan 1, 1972

By B. K. Mishra, Subrat Kumar Padhy, B. C. Tripathy, I. N. Bhattacharya

Manganese is a difficult metal to electrodeposit due to its high electronegativity and continues to possess unique process challenges. Manganese deposits of high quality are electrodeposited on 316 grade stainless steel from sulphate solutions in the presence of organic additives such as tetra ethyl ammonium bromide (TEABr), tetra propyl ammonium bromide (TPABr), and tetra butyl ammonium bromide (TBABr). The concentrations of these additives were examined over a relatively broad range to evaluate their effect on current efficiency, specific energy consumption and deposit morphology of the electrodeposited manganese metal. A maximum current efficiency of 68% was achieved in the presence of TEABr in the bath. X- ray diffraction studies revealed that (330) (411) planes were the most preferred planes of crystal growth during manganese electrowinning at a current density of 500 A/m2 resembling alpha-manganese irrespective of the nature of additive. Scanning electron micrographs showed smooth and uniform deposit morphologies when manganese was electrodeposited in the presence of TEABr.

Jan 1, 2014

By S. J. Im

Bupyung Silver Mines daily treats average 14 tons of concentrates containing 9,000 g Ag per ton. Bupyung Silver Refinery uses Merrill Crowe process to recover the silver from the leach solution containing 1.0 g/l Ag; Series of experiments were carried out to recover the silver from the solution by means of direct electrowinning in place of Merrill Crowe process. The recovery of the silver was 99% when the cell voltage and the retention time were 1.9 v and 3.0 hours, respectively. Power consumption was 3.2 Kwh/kg of Ag. It was found that impurity buildup was not significant during the recycling. The direct operating cost for the electrowinning was evaluated to be $ 0.35/kg of Ag.

Jan 1, 1984

By G A. Challis, A B. Christiel

Microprobe analyses of electrum grains in some Hauraki Au-Ag deposits indicate that gold fineness is in the range of 500 - 800 (50 - 80 per cent Au), but for most deposits the range is usually narrower than this. The electrums contain minor amounts (<0.8 per cent) of copper, arsenic, antimony, mercury, iron, and sulphur. Platinum and palladium were analysed for but were not detected (detection limit 0.24 per cent for Pt or Pd). For some deposits (eg Waihi), the average fineness values for the analysed electrums correspond fairly well with the electrum fineness determined by assay during the historic mining operations.

Jan 1, 1992

By Fardy J. J

Abundance data are presented for a comprehensive range of elements in oil shale samples from deposits located in Queensland. The techniques of instrumental neutron activation analysis and spark source mass spectrometry were used to obtain concentration data for up to 50 trace elements in each shale. These techniques were supplemented by other spectrometric methods to obtain data for major, minor and some trace elements. Sixty-four elements were determined quantitatively. This comprehensive characterisation of oil shale samples from the major deposits in Australia provides inorganic abundance data not previously available. It also provides important background information for processing studies and the associated environmental aspects of shale oil production and waste disposal.

Jan 1, 1986

By I. F. Walder

Mill tailings from skarn-type base metal deposits were studied in order to ascertain potential element mobility in response to weathering. Hypogene ore minerals are sphalerite, galena, and chalcopyrite, showing minor supergene oxidation to smithsonite, cerussite, and covellite. Gangue minerals are pyrite, pyrrhotite, magnetite, hematite, andradite and grossular gamet, hedenbergite, calcite, ankerite, and quartz. Foremost of the eleven tailing piles studied, the hypogene sulfide minerals show no or only incipient post-mining oxidation. Iron oxides and hydroxides form the main oxidation products in the tailings and are enriched in heavy metals. A distinction between pre-and post-mining oxide phases may be obtained based on petrographic observations which distinguish whole-grain versus partial grain replacement. Zn and Cd do not appear to be enriched in the weathering derived oxidation minerals and will be more easily leached from the tailings than other metals.

Jan 1, 1994

By C. J. Johnson, C. J. Bise

"IntroductionCoal extraction by continuous miners (CM) is currently the most common underground method in the US industry and accounts for slightly more than two-thirds of the nation· s deep mining production (National Coal Association, 1987). Even if longwall mining should become more commonplace, it can proceed only af1er ventilation and access entries have been driven by CMs. Since an area of concern continues to be the effects of the dust generated on the health of mineworkers, this paper discusses the relationship between the elemental composition of mining-generated airborne dust sampled from the immediate ventilation return of a CM and laboratory-generated dust derived from channel samples taken from the mines.There are several potential contributions of this type of study to the coal mining industry. First after more fundamental knowledge of the causes of Coal Worker's Pneumoconiosis (CWP) is learned, the laboratory-generated respirable dust could be used to identify a potentially hazardous coal seam. Also, this study could possibly aid in understanding the fundamental causes of CWP by producing mining-simulated samples of coal dust that could be used in epidemiological studies.Further, assuming that there is no difference in the elemental composition of a drill-core sample and a channel sample from the same location a mining company could predict anew mine's respirable dust elemental composition In the immediate ventilation return by using exploratory drill core samples of the roof ,coal, and floor rock to prepare the laboratory dust. Ventilation engineers could then use engineering design and control measures during premine planning to reduce the incidence and severity of CWP by better ventilating the potentially hazardous coal seam. If this proper planning prevented any future changes to the ventilation equipment and mine design, much time and money could be saved.Scope of workTo investigate the variability of the chemical characteristics of respirable dust, airborne dust samples from eight underground coal mines located in the eastern and mid western United States were collected with eight-stage Sierra Model 298 Marple cascade impactors, as well as 25 channel samples of mined material. Each channel sample was removed from the middle of the coal face before mining occurred. Sampling of the mining-generated dust was conducted by Lee ( 1986) by sampling the entire working sections, primarily for characterization purposes, to obtain information on the locational variability of dust characteristics. Research performed for this study used the elemental analyses of the mining-generated dusts he sampled in the immediate ventilation returns of CMs."

Jan 1, 1989

By James R. Craig

The slags generated during gasification of petroleum coke are heterogeneous and con-sist of many different phases. These phases are important because their physical properties affect the operability of gasifiers and because they concentrate many elements that are present in the petroleum coke feed in only minor to trace quantities. An understanding of the chemistry and physical nature of these slag phases is necessary to predict behavior in the gasifier and in considering the ultimate use or disposal of the materials. Slags typically consist of silicate glasses, calcium-silicates, free iron-nickel metallic phases, iron sulfides, and aluminum oxide spinels enriched in iron, chromium, and vanadium. The partitioning of elements among these phases has been analyzed and will be discussed.

Jan 1, 1989

By K. Hawboldt, J. E. Halfyard, C. Bottaro, I. A. Harrison

"The removal of elemental sulfur from leach residues derived from massive sulfide concentrates via hydrometallurgical routes has been demonstrated in a laboratory setting by converting water-insoluble sulfur to water-soluble polysulfides. The approach was applied to leach residue from Vale's nickel hydromet demonstration plant in Argentia, Newfoundland, which contained significant amounts of elemental sulfur. This technique offers an alternative treatment protocol for residues with a sulfur component not amenable to standard flotation/hot filtration processes. The practical considerations of a proposed flow sheet will be discussed including the impact of other sulfur species (e.g. thiosulfate and sulfides) and key process variables. INTRODUCTIONPresently, large scale elemental sulfur extraction from hydrometallurgical leach residue is performed by Teck Resources using a process of sulfur flotation followed by hot filtration (Chalkley et al., 1993). As mentioned, the technique proves viable for residues derived from specific concentrations - in this case zinc - whose residues constituency is primarily elemental sulfur itself. However, problems arise when this constituency is altered as happens when, for example, a mine containing one particular concentrate is mixed or replaced with a differing concentrate from a second mine. Such cases can often strain the effectiveness of current sulfur removal processes (D'Odorico, 2004). If hydrometallurgical residue containing elemental sulfur cannot be effectively treatment by flotation, the residue is stored subaqueously as is the case in some 'grass roots' hydrometallurgical plants (those not coupled with smelting operations). Hydrometallurgical processing of concentrates involving pressure leaching is becoming increasingly common throughout the mining world, the genesis of which can be found in research performed by Sherritt in Fort Saskatchewan since the 1950’s (Ozberk et al., 1995).The investigation of elemental sulfur removal by means other than flotation includes the uses of sulfide salts (NH3S or Na2S) effecting the conversion of hydrophobic elemental sulfur to hydrophilic polysulfides. The work of Kunda et al. (1974) and Olper et al. (2007) shows that elemental sulfur can be quantitatively removed from hydrometallurgical leach residue via the formation of a mixture of polysulfides."

Jan 1, 2012

By M D. Winning

The historical development of the elemental sulphur recovery industry in Western Canada is reviewed for the period 1952 to 1965. A brief technical description of a typical modified Claus sulphur recovery unit is presented. Some predictions are made concerning the future of the elemental sulphur recovery industry in Western Canada. THERE are evidences of sulphur or its compounds having been used for religious and medicinal purposes as far back as we have a recorded knowledge of history. As typical examples, sulphur was burned as a sort of inverse incense to drive away evil spirits at religious festivals, sulphur ointments were used by the early Egyptians to cure eye ailments, and hot sulphur-spring water was used as a cure for a variety of ailments. Thermopyle was called "Hot Gates" be-cause of its fame as a spa as well as a mountain pass. The Romans discovered the sulphur deposits in Sicily and mixed sulphur with bitumen for incendiaries; and, of course, anyone familiar with the travels of Marco Polo knows about the Chinese development of gunpowder, which contains sulphur. In some aspects things haven't changed much today. We still use sulphur-bearing ointments, and we still use the hot sulphur springs such as the one at Banff in Western

Jan 1, 1965

By M. Gensamer

THE PURPOSE OF THIS PAPER is to lay a foundation of elementary theory that might be useful in the discussions which it is hoped will be evoked during this Symposium. It is not my purpose to try to expound the details of the most complete theories as that would be impossible in the time at our disposal and, even if time were available, would probably be of less usefulness than a discussion of the principles underlying the advanced theoretical treatment. I shall try to discuss the fundamental bases for these advanced theories. There exists at the present time very much less need for a detailed description of complete theory than existed when this Symposium was being organized. The reason for this is that a series of papers by L. R. Underwood has been appearing in the magazine Sheet Metal Industries. It is understood that this series will he published soon in the form of a book. Dr. Underwood's articles are complete, critical and well written and it would be hopeless to try to do better in less space. The need, then, is for a brief treatment of basic theory. The objective of any theory of plastic forming- is to enable one to calculate the force and power requirements for the process, and where the deformation is not uniform, to calculate the distribution of strains- In the formed object. We need as the basis for the calculation the relationship between stress and strain in the metal, particularly for the combination of stresses imposed by the forming process. We need to know the stress-strain curve for some simple state of stress, and we need in addition some theory

Jan 1, 1948

By Arnold Blaisonneau, Théophile Guillon, Xavier Rachez, Sylvie Gentier

"L’étude présentée ici vise à étudier l’influence, lors de stimulation hydraulique de puits dans les réservoirs géothermiques de type Enhanced Geothermal System (EGS), du comportement mécanique des zones de failles recoupant le puits sur la réponse hydraulique du réseau de fractures 3D. Dans ce but, un modèle 3D, basé sur la méthode des éléments distincts et dans lequel les zones de failles recoupant le puits sont modélisées par des fractures numériques 2D, est mis en oeuvre. Les modélisations présentées ici visent à caractériser l’influence du comportement mécanique (type de comportement, hétérogénéité) sur la cinétique de la stimulation hydraulique, ainsi que sur son effet spatial autour du puits. INTRODUCTIONPour le développement de l’exploitation géothermique de type Enhanced Geothermal System (EGS), la phase de stimulation conditionne grandement le succés du projet ; en effet, elle a pour objectif d’augmenter l’injectivité et la productivité des puits et doit permettre d’assurer la connexion entre les puits d’injection et de production garantissant ainsi la viabilité technique et économique de l’échangeur. Pour le site EGS de Soultz-sous-Forêts (France), parmi différentes techniques de stimulation, la stimulation hydraulique a été utilisée à cette fin en provoquant une augmentation irréversible de la perméabilité autour des puits. Dans ce type de réservoirs fracturés, le but des stimulations hydrauliques est de réactiver, plus spécifiquement en cisaillement, des structures hydrauliques pré-existantes (fractures, zones de failles etc.) dans le socle cristallin. La compréhension des phénomènes physiques durant la stimulation hydraulique est cruciale pour optimiser cette technologie et pour contrôler/limiter les risques associés (viabilité technique et économique des puits, sismicité induite etc.). C’est notamment le cas pour la relation entre le comportement mécanique des structures stimulées et les conséquences sur le comportement hydraulique dans un contexte tectonique spécifique."

Jan 1, 2015