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By J. Drelich, J. D. Miller

The wetting behavior of liquid polymers at solid surfaces and the adhesion forces involved at polymer-filler interfaces should always be considered in the preparation of high-quality polymer composites, including those made with mineral fillers. Spontaneous polymer spreading over the filler surface is a basic condition for the design of polymer-mineral composites. In this regard, the wetting and adhesion characteristics of polymer-mineral systems are reviewed. Based on this review it is clear that several aspects of wetting phenomena at mineral filler surfaces require further systematic study. Specifically, efforts should be made to determine the wetting characteristics of molten polymers at mineral-filler surfaces in greater detail. Also, the effects of mineral-surface contamination (including surface hydration) on wetting and adhesion phenomena need specific investigation. It is expected that an improved fundamental understanding of wetting and adhesion phenomena for polymer-mineral composites will provide the basis for further technological development.

Jan 1, 1996

By Pradip

Chelatang agents, because of their metal specificity, can function as effective mineral processing reagents. A brief review of the work carried out in this area is presented. Some of the salient features of mineral flotation and flocculation with chehting-type reagents, such as bulk us. surface chelation, the role of pH, mineral solubility, solution chemistry of reagents, and temperature, are illustrated with appropriate examples. The problems associated with the commercialization of chelating reagents for ore beneficiation and the research efforts required in this area are also discussed.

Jan 1, 1987

By John R. Marks

The recent trend in the ventilation of deep under- ground metal mines in the United States is to rely more and more on refrigeration for air cooling. This paper describes the layout and the economics of the refrigeration method used by Hecla Mining Company at the Star Mine. An economic analysis must compare the benefits of an engineering system against the costs. The benefits of refrigeration, for example, are increased production rates, a better safety record, improved employee moral, and generally lower airflow requirements. Air-conditioning costs include capital expenditures for equipment, labor and supply costs for maintenance, and power costs for machine operation. A study of whether or not to install refrigeration becomes academic when a mine reaches the critical ventilation depth1 (the depth at which adiabatic compression alone produces station temperatures equal to the desired stope temperatures). Ventilation planning alternatives for such mines, including the Star Mine, are limited to the different methods of refrigeration usage. In this case study of the Star Mine, the refrigeration layout is described in detail. After the system performance is discussed, air-conditioning costs are calculated. The paper then concludes with a cost- benefit analysis of the Star Mine refrigeration system.

Jan 1, 1980

By Charles N. Speltz

The cost of transportation of industrial minerals frequently is higher than the cost of the product. When a mine, industrial-mineral plant, or customer is served by a single railroad, because of the lack of competition, that railroad may in- crease rates and/or reduce service so that the economics of that mine, plant, or customer are affected adversely. Transloading of industrial minerals from rail-to-truck or truck-to-rail to improve economics and sales of product is not a new concept. However, transloading to create competition and reduce freight costs or to improve service is a relatively new concept brought on by the recent mergers of many of the main-line railroads, both in the eastern and western United States. For example, in 1998, with completion of the Burlington Northern/Santa Fe (BNSF) and the Union Pacific/Southern Pacific mergers (UPSP), the western United States has only two main-line railroads. The industrial-mineral producer, to reduce the cost of transportation or increase the level of service, must evaluate potential transloading opportunities in light of higher prices and reduced service brought on by reduced railroad competition. This paper discusses industrial-mineral transloading and examines the case history of the Tucker Hill perlite project in southern Oregon. The Tucker Hill project is a classic study of industrial-minerals transloading where the project would have failed without the transloading.

Jan 1, 1999

By S. K. Kawatra, T. C. Eisele

Microorganisms, such as the bacteria Thiobacillus ferrooxidans, have been reported to depress pyrite flotation (Elzeky and Attia, 1987; Atkins, 1990). However, the depen¬dence of the depression on the type of organism or on suspension pH is still being determined. In this study, the relative effectiveness of various microorganisms (chemolithotrophic bacteria, chemoorganotrophic bacteria and yeast) over the pH range of 2 to 12 was studied. Screen¬ing tests using microflotation showed that every microorgan¬ism tested was capable of depressing naturally hydrophobic pyrite at acidic pH. Larger-scale experiments with both mineral pyrite and coal pyrite using Thiobacillus ferrooxidans and Saccharomyces cerevisiae as depressants, showed that these microorganisms are very effective depressants for mineral pyrite at acid pH, but they are largely ineffective at neutral and alkaline pH, where the mineral pyrite surface is not naturally hydrophobic. The flotation response of the coal pyrite was completely different from the mineral pyrite. The coal pyrite was most floatable near neutral pH, with the floatability decreasing in acidic or alkaline solutions. De¬pression of the coal pyrite by yeast was not selective between the pyrite and the associated coal under the experimental conditions.

Jan 1, 2000

By Nico Bezuidenhout, André M. van Niekerk, Jan J. G. Vermaak

This paper documents empirical evaluations of geochemical data that was recorded during a seven year pilot scale experiment. The experiment was aimed at assessing the effectiveness of natural soil covers for rehabilitation of coal discard facilities. Ten test cells were constructed using different natural soil cover materials and configurations. Results of the evaluation indicate that, although a pH breakthrough was not recorded for the single layer soil cover cells as was the case with the uncovered cells, single soil covers were not effective in preventing ARD oxidation processes. Multi layered soil covers were found to be able to create anaerobic conditions leading to a reduction in ARD oxidation processes and an improvement in leachate quality.

Jan 1, 2000

By T. Carageorgos

The removal of arsenic from process streams as ferric arsenate compounds is being practised by mining industries. Therefore, the solubility and stability of these solids is of considerable importance to the mining plants that have to keep the environment free from pollutants. There is some information on the solubility of the ferric arsenate compounds, mainly on scorodite, obtained from synthetic solution. However, there is not so much work on ferric arsenate compounds formed at high temperatures (175 - 230°C) during the leaching process. In the present work, the solubility of the ferric arsenate compounds formed during acidic pressure oxidation of arsenopyrite is presented. The results of the solubility tests showed that the ferric arsenate compounds formed at high temperatures (200 - 230°C) and high pressures (1034 - 1551 kPa 0,) released arsenic into solution in amounts less than 1.2 ppm and iron in amounts no higher than 1.0 ppm. So, they seem to be potential compounds for arsenic and iron disposal.

Jan 1, 1998

By B. Moudgil, Hassen El-Shall

Particle shape and size distributions are among the most important parameters that affect the filtration efficiency of phosphogypsum in wet- process phosphoric acid production. Cost-effective enhancement in filtration rate is desired by phosphoric acid producers for higher plant capacity and lower operating costs. In this regard, numerous research efforts have been carried out in different laboratories as well as in pilot and plant testing. Nevertheless, changes in phosphogypsum crystal shape and size distribution deserve special attention. In this study, the results obtained in the presence of Crysmod and Hiflo-S5 surfactants are discussed. The influence of such additives on crystal morphology and size distribution are studied under different sulfate contents (supersaturation). The obtained data are correlated with process efficiency parameters such as filtration rate, digestion of rock, and recovery of phosphate values. Up to 60% increase in filtration rate is obtained. In addition, an increase in digestion efficiency and P205 recovery is achieved due to addition of surface active agents. The observed beneficial effects are explained in the light of the changes induced in crystal habit, size, and size distribution.

Jan 1, 1999

By A. Mehmet, W. A. M. te Riele

A pilot-plant investigation in a NIMCIX contactor has shown that activated carbon can extract more than 93% of the gold in return-dam solutions. The average gold concentration in the barren solution was less than 0.003 mg/L from a feed averaging 0.048 mg/L. The carbon was eluted by the Zadra procedure. The operating conditions of the elution-electrowinning circuit are reported, and the elution of the gold and other metals is discussed. The reactivation of the carbon by use of the Rintoul kiln is described, together with the results of reactivation. The consumption of reagents in the process cycle is presented in sufficient detail to allow the economic viability of this technique to he evaluated for the recovery of gold from low-grade solutions.

Jan 1, 1990

By George Bárdossy

Most of the bauxite deposits in Europe belong to the karst type. They are located mainly ill Southern Europe along the Mediterranean Sea and in the Ural Mountains. Lateritic bauxite deposits occur on the Russian Platform, in Poland, Northern Ireland and in Turkey. Tikhvin-type deposits arc found on the Russian Platform. Bauxite formation in Europe started in the Middle Devonian. The main bauxite forming period was the Upper Cretaceous. Very few bauxites are younger than Eocene. Most deposits are covered by overburden of up to 1000 m. Prospecting is carried out by drilling. Several geophysical methods are used to detect the hidden deposits. Geostatistical methods were introduced in several countries for evaluation of the reserves and the geometry of the deposits. Data on bauxite production are given for 1982 and since the beginning of mining in Europe.

Jan 1, 1984

By B. (Manas) Das

Rock characterization for geotechnical purposes using the microhardness technique is discussed in this paper. The concept of rock characterization and its steps are logically developed. The geotechnical properties should be functionally tethered to the technological problems for characterization. The overriding geotechnical concern is rock mass stability. The important factors in this respect are rock properties, structural discontinuities, ground water, field stress, temperature and technological factors. The rock properties are the primary factors and the other factors generally affect rock properties. Of the rock properties the strength and elastic properties can form a basis for rock characterization. The microhardness technique can provide these two properties. Study on coal shows that the microhardness impressions can be used for this purpose. On the basis of this study coals of all ranks can be divided into distinct geotechnical groups. The details of these are discussed in this paper.

Jan 1, 1986

By K. Morsy, S. S. Peng

A new method of pillar stability evaluation was proposed. The unique feature about the method is that it estimates two types of stability factors for the pillar. The first stability factor is to measure how much the applied stress at that point is smaller than its strength, and the second stability factor is to predict whether or not the pillar will fail violently. The strain-softening behavior of coal pillars was simulated by the Drucker-Prager yield criterion. A new algorithm that simulates the strain-hardening behavior of the gob was used. A numerical technique to estimate the local mine stiffness (LMS) was introduced and verified by both numerical and analytical methods. A case of massive pillar failure in a room-and-pillar mine was used to define the stability limits for the proposed method.

Jan 1, 2003

By Gary F. Rajala, Bruce R. Greenwood

INTRODUCTION The Empire Mine is an iron ore mining, concentrating and pelletizing facility operated by The Cleveland-Cliffs Iron Company in the Upper Peninsula of Michigan. Owners of the mine are Inland Steel, LTV Steel, Wheeling-Pittsburgh Steel and Cleveland-Cliff s. The orebody is a fine-grained, low grade iron formation with magnetite as the primary constituent. Also present are iron carbonates, iron silicates, chert, hematite, goethite and quartz. The original six concentrating lines were started in late 1963. Successive expansions of ten lines in 1967, five lines in 1974 and 3 lines in 1979 have resulted in Empire reaching a present annual capacity of 8.0 million long tons of pellets. The Empire flowsheet was developed over several years of laboratory bench testing, pilot plant testing and testing of a full-scale primary autogenous grinding circuit. Since the original flowsheet was established, modifications have been made based on pilot plant and full-scale plant tests. The present flowsheet for three sections of the concentrator consists of one stage of crushing, two stages of closed circuit autogenous grinding, two stages of magnetic separation, one stage of hydraulic concentration and two stages of flotation (rougher and scavenger). The flowsheet for the fourth section of the concentrator (Empire 4) is the same as the first three sections, except a crusher has been added to crush excess pebbles. The Empire 4 flowsheet appears in the at- tached figure. PRIMARY GRINDING CIRCUIT FLOWSHEET Empire has a total of 24 individual grinding lines. However, at the present time, Line 1 is not being used for processing crude ore. The primary mill on Line 1 is now grinding flux stone for fluxed pellet production and the secondary mill is being used as a ball mill to grind rougher flotation tailings prior to a scavenger flotation circuit.

Jan 1, 1992

By J. E. Hoffman, S. P. Sandoval, T. J. Keefe, K. P. V. Lei, O&apos

The U.S. Bureau of Mines investigated the use of the Fe2+/Fe3+-SO2 (FFS) anode reaction in the copper leaching-solvent extraction-electrowinning circuit. The investigation revealed that six process variables, including anode type, Fe 21 concentration, current density, electrolyte temperature, degree of agitation, and manifold injection point were found to influence cell voltage and cell current efficiency. A 47% voltage reduction (0.8 versus 1.5 V) compared to conventional electrowinning with activated lead (ALE) anodes was achieved at a current density of 258 A/m2 (24 A/ft2) with an industrial electrolyte. Current efficiency was maintained above 90%, and S02 above the cell measured less than 1 ppm when activated carbon was used to assist the reduction of Fe" by S02 in the copper electrolyte. Solvent extraction tests showed that Alamine 336 is a stronger H2SO4 extractant than is needed to extract the excess acid produced by the FFS anode reaction.

Jan 1, 1993

By L. Vandamme, J. H. Curran

A fully three-dimensional hydraulic fracture propagation model, based on the Displacement Discontinuity Technique, is briefly described. Using this model, it is shown that the geometry of a propagating fracture is dependent on several factors, among which the fluid pressure distribution within the fracture plays an important role. The containment of hydraulic fractures is found to be dependent on stress and toughness barriers in the formation. Containment is also observed to be more effective with a decrease of the viscosity, pressure or flow rate of the injected fluid. The three-dimensional layout of the fracture is shown to have a definite influence on the width and pressure distributions within the fracture. The examples considered indicate the need for fully three-dimensional models, as complements to the commonly used two-dimensional and pseudo-three-dimensional models.

Jan 1, 1986

By Roy E. Williams, Muriel S. Robinette

Ground-water contamination from uranium operations could be avoided with proper site analysis techniques. Contamination from tailings disposal sites is carried downgradient within permeable hydrostratigraphic units which can be located and delineated with a combination of drill holes and borehole geophysical logs. Engineering safeguards can be designed into a disposal site by determining if permeable hydrostratigraphic units exist which will dominate the flow system and provide seepage paths for contaminates. It is more cost-effective to accurately assess seepage potential with geophysical logs before contamination becomes a problem than to be faced with a major clean-up effort after contamination has occurred. If a uranium waste impoundment already has a ground-water contamination problem, then borehole geophysical logs may be used to delineate the contaminated zones which need to be cleaned up. It is less expensive to withdraw the contaminated plume from only within the affected zones rather than attempt to dewater the entire area. Consequently, the geophysical logs are invaluable in assessing which zones should be pumped and where packers should be set for construction of piezometers to allow monitoring of water-quality changes. A surface geophysical technique is being tested and developed for monitoring of seepage frum uranium tailings impoundments. Geoelectric soundings and profiles from direct current resistivity surveys can locate anomalous areas for the placement of drill holes to better assess seepage. This reconnaissance technique should eliminate random hit-or-miss drilling at sites where monitoring is required. Tests and experiments are being done on developing the capabilities of this technique to incorporate complex resistivity data to assess cultural impedence noise which complicates simple resistivity data.

Jan 1, 1980

By Janusz S. Laskowski

The most important type of potash ores, sylvinite, contains sylvite, halite and a small percentage of insoluble gangue [sulfates (anhydrite), carbonates (dolomite), and clay minerals]. Primary normal long-chain amines are exlusively utilized to float sylvite from halite, but since mines are also adsorbed by insoluble slimes, the process requires prior desliming. This is carried out either by mechanical means, or by flotation of slimes and blocking off the adsorption centers on clays with the use of polyelectrolytes. Fractional crystallization is employed to produce fertilizer grade KC1 from disseminated ores with a high content of slimes. An extender oil is needed in addition to mine to float coarse sylvite fractions. The process is carried out in a saturated brine at mine concentrations exceeding the solubility limit and is strongly affected by temperature fluctuations. All these important features, which make this process differ from a conventional flotation, result from a high electrolyte concentration.

Jan 1, 1994

By Louise H. Michaud

An interactive mine planning system that employs recent advances in 3D computer graphics capabilities and 3D geologic modelling to aid with the tasks involved in producing dragline mine plans was developed. As well as offering large potential saving in the time required to carry out the planning tasks, the system offers immediate visual feedback to the planning engineer. This can greatly aid in the conceptual understanding of complex geology and mine plans. The package incorporates the generation of a three dimensional Gridded Seam Model (GSM) as the basis for the development of the geologic database. This modelling method is capable of accurately representing rugged topography and multiple coal seams, including folding and faulting. The GSM is then integrated with an interactive graphics mine planning system in order to develop one model and one database for the generation of the mine design, the depletion of the coal resources and the movement of spoil material. The gridded structure of the model also provides the foundation on which all mine and spoil pile volumes are calculated.

Jan 1, 1992

By C. Anastasiadis

The wettability of sandstone was investigated using the technique of dielectric spectroscopy in the frequency interval 1kHz-1MHz. The natural wetness of the material was modified to get two different sets of samples, one with sea-water wetness and the other with crude oil wetness. Measurements showed that the electric responses of water-wet and crude oil-wet samples were markedly different beside the fact that the dielectric response of both groups of samples obeys a general fractional power law. The dispersivity, of the complex permittivity component that expresses the material loss with respect to the electric field was found to be the most suitable parameter to check the wettability of the samples.

Jan 1, 2005

By Fred N. Kissell

Work done by Foster-Miller Associates under a Bureau of Mines research contract has developed methods to increase significantly the amount of fresh air that reaches the front of a continuous-mining machine. The emphasis was on removing methane build- ups that occur at the cutterhead. Using a full-scale plywood mockup of a coal mine working face area, the study showed that in many instances only about 20 pct of the fresh air heading towards an exhaust brattice or tubing actually gets to within 1 ft (0.3m) of the face. The key to providing more air at the face is to enhance and move forward the natural airflow pattern. This change in the natural airflow pattern can be accomplished by taking advantage of the air-moving abilities of the conventional water spray. It was discovered that if all the water sprays on the machine were realigned, then ventilation efficiencies of 70 pct or more were achieved regularly. This meant that if 9,000 cfm (4.2 m3/s) was entering the brattice, at least 6,300 cfm (3.0 m3/s) of this was reaching to within 1 ft (0.3m) of the face. This water spray realignment consists of placing a few nozzles on the side of the machine opposite the curtain and also tilting the front sprays slightly towards the curtain side. Recently, two underground tests and two additional independent laboratory tests of the water "Spray Fan" have been completed. In general, they have confirmed the performance of the Spray Fan system, but they also have provided useful information as to its difficulties and limitations.

Jan 1, 1980