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By L. B. Berger

This information circular is a revision of I.C. 7238, Danger from Carbon Monoxide in the Home, by L. B. Berger and H. H. Schrenk, issued in April 1943. Each winter brings its toll of deaths and serious accidents from the deadly gas, carbon monoxide. Newspapers carry warnings to the public of the, dangers of this gas, and frequent news items report the finding of persons dead at unconscious from the effects of carbon monoxide, yet these accidents continue. Either these warnings are not read, or they are unheeded by people who feel that, "It can't happen to me." It can happen to you carbon monoxide is no respecter of persons.

Jan 1, 1954

By W. E. Wallace, C. A. Hill, M. J. Keane

"Diesel exhaust particulate material from exhaust pipe scrapings of two trucks, diluted automobile diesel exhaust particulate material collected on filters, and two oil shale ores were prepared for the Ames mutagenrcity assay by dichloromethane OOP ex¬traction, by dispersion into 0.85% saline, or by dispersion into dipalmitoyl lecithin (DPL) emulsion in saline. Salmonella typhimunum TA98 was used to detect frameshift mutagens in the samples. Samples of diesel soot gave positive mutagenic responses with both DCM extraction and DPL dispersion, with the DPL dispersion giving higher results in some cases. The results suggest that possible mutagens associated with inhaled particles may be dispersed or solubilized into the phospholipid component of pulmonary surfactant and become active in such a phase.INTRODUCTIONThe Ames Salmonella/microsome assay (Ames et al., 1975) has been shown to be a useful test for detecting genotoxic properties of various agents. Hundreds of specific chemicals have been screened (McCann et al., 1975), and the test has been applied for many types of environmental samples. Airborne mutagenic agents, for example, have been found in urban air (Chrisp and Fisher, 1980; Hughes et al., 1980; Ro· senkranz et al., 1978), in diesel engine exhausts (Huisingh et al., 1978), and in the by-products of coal combustion processes (Chrisp et al., 1978).Samples of airborne particles are typically collected on membrane filters, and undergo a rigorous extraction procedure with organic solvents and/or ultrasonic agitation (Clark and Hobbs, 1980). Often extracts are transferred to another solvent that is compatible with the assay system. These extraction procedures, while efficient from an analytical perspective, are not physiologically plausible. The questions that present themselves are whether a demonstrated mutagen can be taken up in vivo and whether the process is quantitatively or qualitatively different from the above laboratory procedure (Wallace et al., 1984).When a particle of respirable size is inhaled to the alveolar region of the lung, its first physiological contact is with pulmonary surfactant that lines the inner surfaces of the alveoli. This surfactant is an aqueous fluid containing proteins, phospholipids, and other components (R. J. King, 1982). The principal phospholipid constituent is L·alpha-phosphatidylcholine, beta,gamma-dipalmitoyl, or dipalmitoyl lecithin (OPL) (l. C. King et al., 1981)."

Jan 1, 1989

By R. W. Watson

This Bureau of Mines report summarizes some recent results on the sensitivity of various experimental explosive systems using ammonium nitrate (AN) as the oxidizing agent. The sensitivity survey included drop-weight and friction testing and sensitivity to initiation by projectile impact and a No.8 blasting cap. It was found that certain types of AN prills can result in cap-sensitive mixtures when combined with No.2 diesel fuel (Fa); prilled AN mixed with nitromethane also result in cap-sensitive mixtures. Mixtures of AN prills and neat 1-and 2-nitropropane were not cap-sensitive, and the use of powdered or grained aluminum in AN-FO did not adversely affect the sensitivity except possibly to increase its sensitivity to friction.

Jan 1, 1974

By A. Wahab Khair, S. Jung

"This paper deals with the fracturing process of laterally confined blocks of coal subjected to impact indentation. During the test, blocks of coal with approximate dimensions of 10 in. x 10 in. x 6 in. were laterally confined to predetermined equivalent in-situ stresses and then subjected to an impact indentation by dropping coal cutting bits (various shapes) attached to a known weight from a known height. During the test a number of parameters, namely surface strains (using strain gages), penetration depth (using L.V.D.T.) and acoustic emission characteristics were measured. After the test, the fractured surfaces were photographed with the aid of a camera attached to a microscope. The fracture, its intensity and extended zone within the coal blocks were mapped using sonic techniques. By correlating measured parameters, fractured zones under a given set of test parameters were identified and characterized.INTRODUCTION To improve the understanding of basic failure mechanisms in coal cutting, a better knowledge of fracture and crack regions caused by the indentation in coal is needed. This study reports the detailed experimental procedure used in fracture analysis of indentation experiments on coal specimens using the Acoustic Emission (A.E. hereafter) and sonic techniques. The relationship between microcracking and the inelastic deformation of rock was confirmed by a series of experiments in which the A. E. generated by the cracking in the rock specimen were recorded and the number of events were compared to the strain measurement. (Scholz, 1967).According to fracture mechanism theory, crack initiation in brittle materials such as rocks begins from ""flaws"" either pre-existing or induced by the indentation process itself. Rocks are pervaded by natural cracks and pores, from which numerous possibilities for crack initiation arise (Lindquist, Lai and Alm, 1984)."

Jan 1, 1989

By E. L. Litchfield

Descriptions are given of the techniques and apparatus used by the Bureau of Mines for determinations of flat plate ignition quenching distance and minimum spark ignition energy. The descriptions include discussions of reaction vessel materials, shapes, and sizes and discussions of electrode configurations. Spherical, hemispherical, or flat plate electrodes are recommended. The preferred metal in electrodes and electrode supports is stainless steel; the flat plate electrodes incorporate flanges of low electrical conductivity which are most frequently formed from glass. Various aspects of the electrical energy supply system are discussed and suitable arrangements of components are indicated. The concept of a thermal relaxation time is introduced as a basis for the choice of a minimum interspark time during the testing of a gas mixture. The following indicate the varied conditions under which these tech were utilized: Mixture pressures between 10 mm Hg and 45 psig, initial temperatures between -78° and +198° C, and gaseous mixtures representing wide ranges of cL.. D reactivity and corrosiveness. Minimum ignition energies were determined which varied from about 10-7 joule to nearly 103 joule.

Jan 1, 1967

By E. G. Valdez

Laboratory research demonstrated that ceramic wall and floor tile can be produced from electric furnace phosphorus slags composed of calcium silicates. Grinding the slag in a pebble mill, followed by magnetic removal of deleterious magnetite, produced a raw material that could be compounded and formed into wall tile by dry pressing, sintering, and glazing. The effects of process variables such as forming pressure and sintering temperature were investigated. Wall tile bodies produced by this method were comparable to commercial tile. The tiles were readily glazed to a smooth shiny finish and met ASTM Specifications C34-62 for structural clay load-bearing tile. The estimated cost of producing wall tile by this method compared favorably with the retail market value for similar wall tile. Addition of borax or other additives to the ground slag followed by dry pressing and firing likewise produced a commercial grade of floor tile.

Jan 1, 1974

By Xavier B. Starnes

"SUMMARYThe J. D. Price property is in Crittenden County, Ky., about 5-1/2 miles west of Marion. The Levias-Crittenden Springs fault system traverses the property. Mines on 3 miles of the same fault system immediately northeast have produced about 250,000 tons of fluorspar ore. The Keystone property, adjacent on the northeast, has produced about 150,000 tons of ore. 3/About 1934, lessees, sank a shaft upon the Price property to a depth of 111.5 feet and crosscut from the bottom of the shaft to the principal fault. No ore was found. Later, in 1942-43, they explored the same fault by core-drilling, but this project also was unsuccessful in finding ore.The author visited the property in September 1944, and subsequently the Bureau further explored the property by core-drilling three holes. No ore was found.ACKNOWLEGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. This ex¬ploratory project was under the general supervision of E. D. Gardner, regional engineer of the Central Region, and 0. M. Bishop, district engineer, Bureau of Mines. The mining branch is under the direction of L. B. Moon. The work on the project was under the direct supervision of Xavier B. Starnes, mining engineer."

Jun 1, 1947

By Clyde L. Brown

Recent developments in portable communication equipment for use in emergency recovery work following mine fires and explosions have wade possible a convenient and dependable means of directing rescue teams working under hazardous conditions. INTRODUCTION Mine rescue and recovery operations following; fires and explosions are frequently conducted under adverse conditions that require the use of oxygen breathing apparatus by members of a 5- or 6-man team. Conventional apparatus used for this purpose for many years was equipped with an oxygen supply adequate for at least 2 hours. The design of the apparatus is such that the nose passages are closed with a clamp, and breathing is accomplished through a mouthpiece connected to the apparatus by tubes and arranged to prevent inhaling air or gases from outside sources. The use of the mouthpiece has presented difficulties in the development of telephone communication because of the wearer's inability to speak while wearing the mouthpiece. The method of conducting operations of rescue teams requires a person to direct operations at a fresh-air base as close to the rescue team as possible. At least one standby rescue team and 2 or 3 other persons assigned to various tasks are stationed at the fresh-air base. An efficient and reliable means of communication between the director of operations and the rescue team is necessary for reasonably safe and efficient work in hazardous areas.

Jan 1, 1957

By Vernon C. Allison

The explosibility of coal dust has long been recognized by competent investigators as constituting one of the dangers of mining coal and in the use of pulverized coal as a fuel in industrial plants. The Bureau of Mines has carried on extensive series of experiments dealing with this subject, and has not only developed methods for the practical prevention of this danger, but in the, course of these experiments has developed a standard method of determining the relative explosibility of coal dusts and other organic dusts.3 Oil shale contains compounds 'of carbon and hydrogen that are either of a petroleum nature and are strongly ,adsorbed upon the incombustible part of the shale, or else are present in the shale as a compound ("kerogen") which has the property of changing into petroleum-like products when acted upon by heat. The oil shales may contain varying amounts of the organic matter, ranging from a trace to more than 66 per cent, depending upon their richness; therefore, it is important to know whether the dusts formed in mining and handling these oil shales are explosive when mixed with air and if so, to indicate remedial measures. This paper gives the results of explosibility tests of several pulverized oil shale's, selected as being typical of those which in the future may be used in commercial shale-oil production test on a sample of typical Colorado oil shale has been., published in an earlier paper.4

Jan 1, 1926

By C. Pritchard

John Marks said in his acceptance of the Hartman Award in 2008, "I guess that without the occasional complaint, your mine is probably over-ventilated" (Marks, 2008). Miners are seldom in this situation and spend much of the time trying to find enough air to keep an operation running. With examination, there are usually changes that can be made to increase the efficiency of ventilation systems. Mine ventilation air is a costly commodity, especially by the time it has been heated or cooled and moved to the bottom of the shaft and through the mine airways. Modifications that result in surplus mine ventilation air could bring financial and environmental benefits. Some issues mine operators have needed to address recently are increased airflow requirements to dilute diesel particulates in metal and nonmetal mines, to ventilate reserves that are deeper, hotter, and further away from fans and shafts, and to meet demands from increased production. This paper discusses successful methods to find additional usable air when there is no extra ventilation capacity. Most of the options presented in this paper are useful for metal/ nonmetal operations but some may be applicable to coal as well.

Jan 1, 2010

The principal activities of the Bureau of Mines Pittsburgh Mining and Safety Research Center during fiscal year 1971 (July 1, 1970, to June 30, 1971) are reviewed in part 1 of this paper. Part 2 summarizes publications during fiscal year 1971.

Jan 1, 1974

By R. W. Stahl

A survey of firefighting facilities and practices in coal mines conducted by the Bureau of Mines3/ showed such variations in equipment and apparent attitude toward fire protection that a comparison with other industry seemed advisable. Although other industry is confined generally to surface operations and the hazards probably are not as great, the same general methods of extinguishment are employed, so that the cost and protection at least should be comparable. An investigation of industry other than mines revealed a generally greater emphasis placed on fire-combating equipment, fire-brigade training, fire-fighting facility inspection, and fire-hazard elimination, as well as a greater average expenditure for fire protection.

Jan 1, 1959

By Richard F. Hewlett

An attempt has been made to fit assay data from an underground copper deposit to a three-dimensional polynomial surface as a means of expressing assay points in terms of their mine coordinates by a mathematical equation. The resulting equation was evaluated to predict the grade trend of the deposit. Although the fit obtained by this initial experiment is not considered accurate enough to provide good predictions about the deposit, the methodology is presented in this preliminary report to show the potential usefulness of the technique in mineral deposit evaluation. The technique also should be useful in determining the grade of blocks of ore for production scheduling and blending problems in open pit operations. Further experimentation is needed to increase the reliability of the computer program, to increase the precision of the method, and to make the solution more flexible for use on other mineral deposits.

Jan 1, 1964

By R. R. Sayers

There is probably no industry , trade , or art in which mercury is used but what has produced some cases of mercury poisoning . This is true of the mining and smelting of mercury , where the hazard has long been recognized . When the ore contains free mercury or the more soluble salts , and when the workings are underground and are poorly ventilated , cases occur , but there are a far greater number of cases among the employees about the reduction works . 3 In 1863 William V. Wells visited the mines at Almaden , * Spain , which were worked by convicts . He reported that the men at the furnaces suffered severely , being able to work only about one week out of four , when it was necessary to transfer them to places where the exposure was less . He states that "pale cadaverous faces and leaden eyes are consequences of even these short periods . " Mercury , like lead , when absorbed in small amounts at intervals , as daily, over an extended period of time will result in symptoms of poisoning . This is due to the fact that the mercury is eliminated from the body more slowly than it is absorbed . The frequency and severity of cases of mercury poisoning are far less with modern methods of mining and recovery of the metal than formerly . However , further reduction is possible and much can be done by both the workmen and the operators by following the proper precautionary measures , some of which are described in this chapter .

May 1, 1922

By A. D. Garman

This paper presents one of a series of digests of foreign mining legislation and court decisions which is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to own and operate mines in various foreign countries . This interpretation of the laws of El Salvador has been prepared from the best available information in Washington , but is released subject to correction and amplification , if necessary , by the proper American diplomatic and consular officers to whom it is being referred through the courtesy of the Department of State . Under the terms of the Code of Commerce ( arts . 12ff . ) , foreigners living in El Salvador can engage in business on the same terms as nationals . This involves ( = $434.00 ) - except for those with a working capital , of less than a thousand pesos inscription in the merchants ' register , which can be refused only in case of manifest disability of a permanent nature .

Sep 1, 1930

By H. H. Schrenk

Much has been written and said concerning tables of permissible or maximum allowable concentrations of various toxic substances in air, but not enough attention has been given to their limitations and how to use them intelligently . There is a tendency to place too much reliance on figures , with little or no consideration of their real meaning . The repeated publication of a figure often adds significance to it far beyond that intended by the original author or publisher . How are these figures referred to as "maximum allowable concentrations " established? What is their real meaning? To answer these questions it is necessary first to define maximum allowable concentration . The usual definition is somewhat as follows : "The average concentration to which an industrial worker can be exposed for 8- hours daily for an indefinite period without injury or occupational disease . This definition is made up of the following items : ( 1 ) Average concentration, ( 2 ) 8 - hour day , ( 3 ) indefinite exposure period , and ( 4 ) lack of injury or occupational disease . There is some controversy regarding item ( 1 ) , items ( 2 ) and ( 3 ) are usually though not invariably accepted , and there is definite disagreement regarding the interpretation of item ( 4 ) . . To reach a more satisfactory interpretation of maximum allowable concentration , attention is directed to ( 1 ) the development of tables of maximum allowable concentrations , ( 2 ) criteria on which limits are based , and (3 ) methods used to obtain data on which limits are based .

May 1, 1948

By F. S. Crawford

Safety devices and guards are often looked upon as the last word in safety by the men around the shop or large industrial plant . However , thorough knowledge of the details of their jobs and of the dangers attending them are even more important . It should be unnecessary for all men to go through the experience of the first man to meet an unknown danger , but that appears to be about the only way by which many learn . Practically every danger connected with the job around a mine , blast furnace , steel mill , foundry , coke oven , cement mill , or other operation , was encountered for the first time by someone , and if he was fairly fortunate he either got hurt or just missed being injured and lived to tell his " budaies " how it happened; he spread the knowledge of that particular danger . Sometimes , but not often , a man can foresee a danger . If he could always be on guard and remember everything he had ever learned and also know everything that had happened to the other fellow , and then let that knowledge keep him aware of the dangers in his own immediate " job , " so that he would work the safe way for both himself and the other fellow , he would have what safety engineers call " safety consciousness . " Being safety conscious is a fine attribute , as it really means knowing all about one's job . A man who is really safety conscious is one of the best and most efficient workmen in the whole plant . The boss wants men of that kindmen who want to learn and who try to learn every little detail about their jobwhere there is danger of spoiling the heat or getting burned by hot metal in a steel plant or of loading rock instead of coal or ore in a mine . Such men know how to do whatever job they are on easily and with the least amount of hard work and at the same time get it done as quickly as possible with safety . A man who is safety conscious has to nearly all intents and purposes developed eyes in the back of his head , if he is in a big mill where there if something going on all around him . These eyes are not real eyes , but they are what might be termed a sixth sense which he has developed by his experience in the mill as well as in other dangerous work which he may have done before in other plants . There may be occasions when a man's safety consciousness will leave him for just a short time ; this is likely to happen when he is thinking about a quarrel he had with his wife which has not been cleared up happily , or perhaps when he has bought too many things on installment and with sickness at home

Apr 1, 1931

By Harry K. James

Experimental studies of the physical and explosion characteristics of pure hydrazine nitrate and multicomponent systems containing hydrazine nitrate, supplemented with an extensive Literature survey, are presented. Such proper- ties as melting point, heat of fusion, density, viscosity, surface tension, thermal stability, decomposition process, detonation velocity, impact sensitivity, and TNT equivalence are included.

Jan 1, 1970

By William J. Campbell

This analytical method development and evaluation was undertaken by the Bureau of Mines to provide accurate determinations of eight minor elements in low-alloy steels prepared from ferrous scrap. Fluorescent X-ray spectrography was the principal method investigated. Confirming analyses were made by conventional instrumental and chemical methods. All X-ray data were processed by a timesharing computer. No corrections were found necessary for inter-element effects or overlapping spectral lines. Concentrations were calculated from the least-square fit of a linear calibration equation derived from measurements on three sets of standard steels. These studies show that X-ray spectrographic analysis of lathe-finished surfaces provides accurate determinations of aluminum, copper, chromium, manganese, nickel, phosphorus, silicon, and tin.

Jan 1, 1973

By R. D. Leitch

The work of the United States Bureau of Mines on stream pollution3 by coal-mine drainage has included a study of seasonal variations in acidity and volume of several streams in Pennsylvania. The acidity of these streams has been determined during the two or three years prior to 1930 and the results may be considered to represent "normal" low water conditions. The summer of 1930, however, was unusually dry and represents what may be termed "extreme" low water conditions on these streams. This report is a comparison of the results obtained for extreme low water of 1930 and for other years. The streams investigated were Buffalo Creek in Somerset County, Indian Creek (lower 5 miles) in Westmoreland County, Little Toby Creek in Elk and Jefferson Counties, Daguscahonda Run in Elk County and West Creek in Elk and Cameron Counties. These will be treated separately in the order given. Most of the descriptive matter and physical data pertinent to the streams and drainage basins are taken from published reports of the Pennsylvania State Water Supply Commission, 1917.4

Jan 1, 1931