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By Michael J. Brnich

Since 1991, Pittsburgh Research Center (PRC- formerly part of the Bureau of Mines) researchers have recorded extensive interviews with 30 individuals who are experts in the area of mine emergency response. These individuals, who have an average of 35 years of mining experience and 29 years of mine emergency response experience, related stories and observations from events that they experienced during their combined 850 plus years in mine emergency response. The purpose of this effort was to gather information that could be passed onto both today?s and tomorrow?s mine emergency responders to train and guide them in handling future events.

Jan 1, 1997

By David J. MacDonald

Stability constants, that is, equilibrium constants for complex-formation reactions, have been determined by a titrimetric method for complexes formed by the transition metal ions Ni2+, Cu2+, Zn2+, and Cd2+ with the structurally analogous bidentate ligands N-ethylethylenediamine and 2-(ethylthio)-ethylamine. The sulfur containing ligand was found to be the weaker of the two chelating agents for each of the four metals. Absorption spectra of the individual complexes have been determined in order to calculate their crystal field stabilization energies. The combined results suggest a linear relation between free energy of chelation and ionic radius of the metal ion.

Jan 1, 1972

By Matthew J. DeMarco, Anthony T. Iannacchione

Coal bumps have presented serious mining problems in the U.S. throughout the 20th Century. Fatalities and injuries have resulted when these destructive events occur at the working face. Persistent bump problems can result in abandonment of large reserves or lead to premature mine closure. Through the years, alternative techniques such as artificial supports, extraction sequencing, destressing, pillar design changes and specific pillar retreat practices have been successfully implemented to mitigate coal mine bumps. Several techniques have evolved for room-and-pillar operations that control the way the roof rock breaks, regulating the manner in which stresses are redistributed in the mined section. Special mine layouts employed in longwall mines have also proved to be successful in safely redistributing or containing excessive loadings. However, with ever increasing production rates, greater overburdens and new mining systems, the need to evolve even more effective bump control designs will continue to challenge the U. S. coal mine industry.

Develop technology for preparing thick corrosion-resistant coatings and electroforms of iron-chromium-nickel alloys. Approach To reduce the United States' dependence upon foreign sources for supplies of strategic and critical metals such as chromium, cobalt, and nickel, new technology must be devised to conserve these valuable commodities. One approach being investigated by the Bureau of Mines is the use of a modified-aqueous-electrodeposition method to prepare thick (-25 µm), complex alloy coatings (e.g., stainless steel composition) with properties similar to the commercial alloys. An alloy coating on a low-alloy steel or carbon steel substrate would require significantly less strategic and critical metals than those contained in an equivalent mass of the commercial alloy. Coatings applied to appropriate mandrel materials make possible the preparation of intricately-shaped alloy electroforms (near-net-shape parts). As a result, the loss of valuable metals associated with machining finished products would be minimized.

Jan 1, 1986

Develop a method for recovering phosphate from a wide variety of complex western phosphate materials, including low-grade ores, tailings, and unused fines. Approach A flotation technique is used for this broad type of extraction. The method includes depression of phosphate minerals and anionic flotation of carbonate minerals, followed by cationic flotation of silicate minerals. How It Works A slurry is prepared for flotation by sizing to remove a low-grade, high-impurity slime fraction. Depending on the material, further sizing and/or grinding steps may be used to produce a size concentrate or to remove gangue. The flotation feed is conditioned with H2SiF6 and a fatty acid emulsion. The H2SiF6 is absorbed chemically to the phosphate mineral surface, making it strongly attracted to water and preventing adsorption of the fatty acid. Under these conditions, the fatty acid is a selective collector for carbonate minerals, which are removed as a froth product. Next, the silicates are floated with an amine reagent added directly to the slurry without additional pulp preparation.

Jan 1, 1982

Improve the safety of salt mine workers by providing a means for quickly identifying areas within the mine that?s how an increased potential for gas and salt outbursts. Approach Outbursts occur in salt mines when a high-pressure pocket of gas is intercepted during the mining process, resulting in a sudden and sometimes catastrophic expulsion of gas and salt. In one case, the amount of gas released through such an event caused an explosion that resulted in five fatalities. The U.S. Bureau of Mines has designed and developed a gas outburst prediction system that can quickly determine the potential instability of areas within rock salt mines. The determination is based on noise measurements obtained from samples of the salt as they are dissolved in water. This system improves upon technology currently available because it provides information in only a few minutes instead of in several days. In addition, present prediction systems are not only time consuming, but expensive because they require laboratory conditions and highly trained personnel to operate them and determine results.

Jan 1, 1989

By M. J. Sapko

The Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) has conducted full-scale explosion experiments, to evaluate the strength characteristics of various seal designs, used for safely isolating worked-out areas in underground coal mines. Large-scale explosion tests conducted within the multiple entry section of PRL's Lake Lynn Experimental Mine (LLEM) is currently the only accepted test method used by the Mine Safety and Health Administration (MSHA), for deeming a seal design suitable for use in American mines. These explosion tests are labour intensive, expensive to conduct, and can interfere with other critical underground safety and health research programs conducted by NIOSH. The PRL has developed an alternative seal evaluation method, based on a hydrostatic pressure loading concept that can facilitate the in situ testing of seals in an operating mine. Two chambers within LLEM and one within PRL's Safety Research Coal Mine (SRCM) were used for hydrostatic pressure loading various seal designs. The results from these chamber tests compare favourably with those from the large-scale explosion tests in the multiple entries. In addition to testing seal designs at the required 20 psi static pressure level, the chamber test approach also allows for the determination of the seal's ultimate design strength. Six-scaling relationships for predicting the strength of seal designs as a function of entry size are also presented.

By Lynn L. Rethi, Barbara Fotta

Recent employment figures (taken from the Mine Safety and Health Administration's database) indicate that the number of independent contractor' employees working in the coal mining industry has doubled over the past ten years. As their numbers increase, they become a more visible segment of the industry. [ ] Increased exposure to mining hazards has also brought an increase in the number of fatalities involving independent contractor workers. One gauge that is traditionally used to evaluate the overall safety of an entity is the "number of fatalities." Over the five-year period from 1985-89, 27 independent contractor employees were fatally injured while working on coal mine property. This number increased to 45 fatalities during the subsequent five-year period from 1990-94. Nearly half of these fatalities (47%) were due to accidents involving powered haulage (See Table); 13% were electrical accidents; and 9% were machinery accidents. Combined, these three accident classifications accounted for 69% of all coal nine independent contractor fatalities. Information taken from fatality data is an important piece of the safety puzzle; however, other variables need to he examined in order to better define contributing factors associated with accidents. More specifically, information on trends in fatal and nonfatal accident and injury data is necessary before deciding what approach should be used to improve safety. In order to implement appropriate safety strategies, it is important for safety practitioners to examine all available lost time accident and injury information. The following coal industry data sites specific and present trends of independent contractor employees working in underground locations at coal mines, surface areas of underground coal mines, surface coal mines, and preparation plants. The data compares employment and accidents for time periods at the beginning and the end of a ten-year span from 1985 to 1994. Because the number of incidents involving independent contractors in certain accident categories during any one year may be small, three-year totals are used; the first three years (1985-87) of the ten-year period are compared with the last three years (1992-94). [ ]

By Benjamin W. Haynes

The Bureau of Mines conducted research to devise technology for increasing the Nation's mineral supply by recovering valuable constituents from currently discarded waste materials. Municipal solid waste (MSW), presently a major disposal problem, represents a significant source of metals, glass, and a combustible fraction that can be used to supplement coal in generating heat and electricity. As part of the total metallurgical system to treat MSW, this study evaluates the combustible fraction of MSW to characterize the various combustible components and to identify the principal sources of elements that eventually may be objectionable from corrosive or environmental considerations. Several possible sources for cadmium, chromium, cobalt, copper, lead, nickel, and zinc have been tentatively identified. These sources are pigments, inks, paper stock, and additives to plastics. A correlation between industry consumption values and measured concentrations in MSW was found for several elements.

Jan 1, 1978

By J. W. Miller

An investigation was begun by the Bureau of Mines in 1948 to determine the preparation characteristics of American coals. Results of the investigation were planned to be reported on a county basis and from the data developed to determine: 1. Which coals either as mined or after beneficiation by conventional preparation are chemically suitable under present standards for producing metallurgical coke. 2. Which coals require special and more intensive treatment in preparation than is now practiced. 3. Which coals cannot be considered potential sources of metallurgical coke, regardless of preparation by present-day methods. This report is one in this county series that describes the preparation characteristics of the coals of Lee County, Va.

Jan 1, 1957

By George S. Koch

The distribution of gold in part of the Getchell mine, Humboldt County, Nev., is presented through the statistical analysis of 956 assays of rock cuttings from wagon-drill holes. Two methods to predict grade in undeveloped parts of the ore body are evaluated, and the possibility of sampling bias is tested. The distribution of gold is compared with that in three other Nevada gold deposits of the same type characterized by gold particles mostly of submicron size associated with carbonaceous rocks, and also with that in deposits with coarse-grained gold. Usually, fewer samples of a given type are required to make a satisfactory grade estimate for submicron deposits than for coarse-grained deposits. The economic consequence is that submicron gold deposits are likely to be less expensive to sample and evaluate than coarse-grained deposits.

Jan 1, 1970

By Fred N. Kissell

Methane flows and pressures were measured in mines in the Pittsburgh, Hartshorne, and Pocahontas No. 3 coalbeds. From the data, the permeability of each of these coal beds was computed. It was found to depend strongly on the type of coal and on the amount of water in the coalbed, and it was found to increase with time. All of the coalbeds had a high-permeability zone adjacent to the face or rib, and the Pittsburgh bed exhibited directional anisotropy. Surprisingly, little or no overburden effect was observed.

Jan 1, 1972

By David C. Oyler, Gregory Hasenfus, Gregory M. Molinda

Few studies have specifically measured and documented the large-scale loading behavior and durability of ventilation stoppings to mining induced movements, particularly from longwalls. Ventilation stoppings are more commonly the concern of ventilation engineers, and ventilation stopping response to ground movement has only been documented in an incidental manner. This paper presents the investigations of underground measurements that have been conducted to determine the loading response of stoppings constructed from lightweight aggregate concrete masonry units (CMU). These investigations have produced some interesting results that may prove beneficial, not only for developing and assessing alternative stopping construction techniques, but also for designing and selecting standard construction methods for use in varying mining conditions. For instance, the interface friction that results from wedging a CMU stopping during construction plays a substantial role in its ability to resist both lateral and vertical loads. Although they are not intended for ground support, the study showed that block stoppings can resist vertical loads of at least 2,700 to 3,000 kN. Asymmetric loading of a stopping may result in localized failure of blocks within a stopping, which, depending on the severity, can be a precursor of impending stopping failure. In addition to measurement results and implications, the paper will also present details of field measurement methods used to assess stopping response. Stopping stiffness and material strength characteristics will also be presented.

This chapter explores leadership behavior in a life-threatening situation-fire in a coal mine. Previous chapters have discussed the database of interviews with miners who escaped from underground fires. Researchers raised questions such as: (1) Who led the miners out of the mine? (2) Did leadership make a difference in the escapes? (3) Was the escape leader the hierarchal leader? (4) What, if any, characteristics did the escape leaders possess? Subsequently, researchers analyzed the mine fire database from a group interaction perspective to address the leadership questions posed. Leadership has been one of the most researched topics of human behavior in the twentieth century. Studies have ranged from individual characteristics of leaders, to situational leadership, to interaction of leader and follower, suggesting different leadership techniques for different followers. The question that emerges here is: Are there different types of leadership that "fit" different kinds of situations? In a crisis situation like that examined in the present study, such information about leadership may significantly improve the chances of escape. To address these issues, the study team looked at the formal authority structure before each fire, considered leadership behavior or lack of leadership during the escapes, and examined those conditions associated with the emergence of leadership. According to Bardo [ 1978], "Emergent behaviors are those forms of action, and the norms, values and beliefs governing those actions, that rise out of the disaster situation." This chapter discusses previous studies in the area of crisis leadership and examines the emergent behaviors of leaders under duress during the mine fire escapes. Previous Studies The research on leadership during emergency situations has consisted mainly of simulation and field studies, with the principal concern being escape from building fires. During the 1980s, Hayashi [1988] created a computer simulation model to evaluate leader behavior in a fire. Although his purpose was to aid in planning for disaster prevention, his findings are relevant because they address the issue of situational leadership in crisis-where a leader changes his or her behavior to fit the situation. Essentially, his simulation model was designed to judge the actions and thinking of leaders. The simulation was tried by 101 subject/leaders 4 times each. The simulation consisted of amaze containing the leader, an informal leader, and 50 evacuees. Interestingly, the results indicated that the leader's actions were not dictated by circumstances. Any differences in behavior were attributed to the individual characteristics of each leader. The study also showed that the worse the situation became, the less individual

Jan 1, 2000

To provide safer and more efficient mine operations by improving the operational performance of underground trolley line communication systems. Approach The dc trolley line provides a convenient means of In-mine communication since it can carry signals to each phone on the system whether the phones are in mine vehicles or in a fixed location such as that of a dispatcher. In many cases, however, the system does not perform satisfactorily. Short communication range, noise, and dead spots commonly interfere with effective communication. These problems are inherent with the trolley line, which was designed to transmit power and not communication Signals. As a power line, the trolley line is connected to rectifiers and feeds many loads such as motors, water pumps, track block lights, etc. Each of these devices represents a low impedance radio frequency (RF) shunt that seriously reduces carrier communication Signals. Performance is therefore often poor and can be improved only if the effects of the various shunts can be reduced. The Bureau of Mines has developed numerous methods applicable to either existing or planned phone systems which can improve communication range and reduce the shunting effects of the various loads.

Jan 1, 1983

By T. F. Tomb

This paper describes field and laboratory investigations conducted on a dust-collection system recently designed for integral use with a continuous mining machine. The results of the field study showed that the average respirable dust concentration measured at the machine operator's position was reduced by about 60 percent (from 8.7 to 3.5 milligrams per cubic meter), and total and respirable dust concentrations in the return air were reduced by approximately 70 percent. The data indicated that approximately 20 percent of the dust generated at the face was not passed through the scrubber. The lab-oratory results showed that the overall efficiency (by particle count) was approximately 80 percent for total dust concentrations (minus 20 micrometers in size) typical of those encountered underground. Calculations based on total dust concentrations measured during the underground study indicated that the respirable mass concentrations of the effluent from the scrubber would still exceed acceptable levels even if scrubbing of all the air at the face were possible.

Jan 1, 1973

By Kenneth O. Bennington

This investigation is part of the Bureau of Mines research effort directed at advancing mineral technology and minimizing energy requirements for extractive metallurgy. The emplacement of the primary minerals petalite (LiAlSi4010) and spodumene (LiAlSi206) in the lithium pegmatites is examined on the basis of their Gibbs energies of formation determined from lithium metastltcate and oxides, using a series of proposed reactions. The reaction between spodumene, quartz, and petalite (LiAlSi206 + 25i02 [=] LiAlSi4010) apparently does not take place in nature but may be proved experimentally.

Jan 1, 1982

By R. L. Montgomery

The heats of solution of erbium chloride in water and in hydrochloric acid and of erbium oxide in hydrochloric acid were determined. The results reveal a discrepancy of 10.5 kcal. per gram-atom between the heats of combustion and solution of erbium reported in the literature, the heat of combustion being more negative. The heat of combustion of erbium t4)4 and its heat of solution in hydrochloric acid (1, 18) have been reported in the literature. The heat of solution of erbium chloride was determined in two studies (2, 19). The present work was undertaken to check the reported heats of solution of erbium chloride and to determine the heat of solution of erbium oxide in hydrochloric acid. The latter quantity permits the heats of combustion and solution of erbium to be compared for mutual consistency. It was also desired to determine the degree of similarity between the thermochemistry of yttrium and erbium.

Jan 1, 1961

By Michael D. Fenton

The very modest-sized mineral industry of Afghanistan was burdened for another year with problems of internal strife occassioned by the presence of Soviet armed forces. Despite this, production of the few traditional commodities continued, and the mineral industry moved to develop additional mines and plants for both traditional and new products with considerable technical and construction assistance from the U.S.S.R. Among the limited range of mineral commodities for which production was reported, there were no startling changes between 1984 and 1985. Production of both coal and natural gas advanced only slightly, despite substantially higher 5-year plan goals, and cement output was down marginally. Probably the most significant development in 1985 was the Possibility that mine and/or smelter production of copper was initiated during the year.

Jan 1, 1987

By Kevin Connor

Exports of agricultural products, mostly coffee, continued to account for more than 90% of Burundi's foreign exchange revenue. The country's ban on commercial mining was lifted in 1987. Mining of peat for fuel, limestone for agriculture, and clay for insecticides continued as in previous years. At yearend, Burundi's external debt stood at almost $700 million.2 Amoco Burundi, a subsidiary of the Amoco Petroleum Co., drilled two exploration wells in northern Lake Tanganyika in 1987. No oil was found, but preliminary findings were encouraging enough that further seismic surveys and offshore and onshore drilling exploration were planned in 1988. Any oil or gas finds would have substantial impact on the Burundian economy because a major portion of the country's trade deficit was directly attributable to petroleum and gas imports. The Zaire Government agreed in June to let Amoco Burundi explore Zaire's side of Tanganyika using the same equipment and personnel being used in Burundi.

Jan 1, 1989