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By Loyal Clarke, H. H. Storch

"The discovery of large deposits of polyhalite (K2S04.MgS04.2CaSO4.2H2O) in Texas has led to an investigation of possible industrial proecsses for the extraction of potash from this material. This mineral was first discovored in small quantities in the European potash deposits in or about the year 1800. Chemists fire thought it to be a form of calcium sulphate, but a more accurate analysis by Strohmiyer indicated the composition as given by the above formula.The decomposition of polytalite by aster is very slow and results in the formation of a layer of gypsum at the surface of the polyhalite which retarts the solution of the potaseium and magnesium sulphates. To obtain a substantial yield of K2S04 in solution it is necessary to use large amounts of water at room temperature, for he concentration of K2S04 is limited by the low solubility of syngonite (K2S04.CaS04.H2O) whereas at 100º C. several days boiling are necessary to obtain more than a 6 per cent K2S04 solution even when finely powdered polyhalite is employed.In 1854 H. Rose discovered that calcination, followed by leaching with water, resulted in a larger extraction of the potassium and magnesium sulphates, as compared with leaching without precalcination. During the course of a series of investigations concerning formation of oceanic salt deposits, Van't Hoff and his pupils obtained sufficient data to construct the equilibrium diagram for the system K+Mg+SO4--Ca++.H2O for 25° C. and for 83° C. These data are very well summarized. in the International Critical Tables' and by Boeke and Eitel. From a consideration of the diagrams for 83º C. one would conclude that an extraction of polyhalite with moderate amounts of water at 33º C. would result in a solution whose maximum concentration of K2So4 would be about 3.6 grams per 100 grams of water and of M2SO; about 4.0 grams per 100 grams of water, corresponding to equilibriumwith the solid phases: Polyhalite potassiam-calcium pentasulphate and anhydrite.The fact that it has been found possible to obtain as high as 11.4 grams of K2S04 per 100 grams of water (see table 6) and an equivalent amount of MgSo4 (8.1 grams per 100 grams of water was obtained corresponding to a ratio K2/Mg of 0.98; indicates that the formation of these complex salts is very slow. To be sure, this results was obtained at 100° C. instead of 83º C. However, the work of Anderson and Nestall 9 on the double salts of calcium and potassium sulphates at 100º C. indicates that the diagram at 100º C. C. would not be greatly different from that at 83º C. This slow rate of approach to equilibrium when combined with precalcination of,of polyhzli-,a is the 17,asis of some of the more p:olisinE methods of extracting potash from polyhalite."

Jun 1, 1930

By H. L. Riley, B. W. Gandrud

"INTRODUCTION AND SUMMARYIn connection with a program of research work on coal at its Southern Experiment Station, the Bureau of Mines, in cooperation with the University of Alabama, conducts washability studies of samples of coal from coal fields in Alabama and other Southern States in which commercially important deposits of coal occur. The first such study on coal from a bed in the Arkansas field has been completed, and the results are presented in this report.One of the main objectives of a washability study is to obtain technically and commercially important data in connection with the best methods for preparing and utilizing the Nation's limited reserves of good coking coal. Such information is important from the standpoint of conservation in that it facilitates selection of preparation methods that will yield a good grade of coking coal with a minimum of losses of coal in the rejects.The coal on which this report is based was obtained by underground and tipple sampling at the quality mine of the Quality Excelsior Coal Co. about 3 miles east of Hackett, Ark. This mine operates in the Upper Hartshorne bed, which, as the main source of coal in what is known as the Hackett-Excelsior district, yields an excellent grade of low-volatile coking coal, which is marketed at steel plants in Colorado and California. Production from this bed by the major producers in the Hackett Excelsior district was at the rate of about 125,760 tons annually in 1949, according to the Keystone Coal Buyers Manual. 2/In the laboratory, the tipple sample was crushed to 6-inch top size and screened on a 2-inch round-hole screen. The 2-inch to 0 undersize, amounting to 71.4 percent of the total sample, was fractionated into a series of screen sizes and float-and-sink products to get data for determining the washability characteristics of the coal. Before the screening and float-and-sink tests were made, however, machine cuttings, which are now gobbed underground, were added to the 2-inch to 0 sample. Enough of these cuttings were added so that the resulting mixture was considered representative of what the 2-inch to 0 run-of-mine coal would be if all machine cuttings, including the part now being gobbed, were brought to the tipple as a part of the run-of-mine coal.The mixture obtained referred to in this report as the run-of-mine or raw coal."

Mar 1, 1953

By J. Schlocker

The present emergency has greatly stimulated interest in the light metals - aluminum and magnesium - owing to their extensive use in airplane construction. The $63,000,000 plant being erected in the Las Vegas Valley by Basic Magnesium, Inc., under the auspices of the Defense Plant Corporation,

Jan 1, 1942

Three types of communication systems have become popular in solving communication requirements underground: Loud-speaking pager phones, carrier current phones, and magneto ringing phones. Basically, all three are simply single-channel party line systems. Although these systems are quite reliable, the single channel creates a variety of problems. For example- 1. Since no call is confidential, messages are sometimes purposely made vague, especially if accidents or safety topics are being discussed. 2. A potential user must literally "wait in line" until the channel becomes clear for his use; thus, when foremen have to wait to call in reports or supply requests, this single chan-nel creates a serious productivity bottleneck. 3. In many large mines, there are independent branch lines that must be tied together by a dispatcher, adding further delays to the system. To solve these problems, some mines have installed other phone systems-mostly commercial dial phones in industrial enclosures that offer extra channel capacity and private line features. Others have installed a system that combines both dial- and page-phone features in a single unit. Although these do represent improvements, they do not truly solve the overall problems that face modern mines. Besides extra channels, a communication system should have the following features to enhance productivity and safety: 1. A means of paging a roving miner to alert him that he is wanted on the phone. 2. Wireless-to-wired system interconnects by which a miner can talk on the wired phone system by using a remote portable radio. 3. Remote monitors that alert personnel when there is a toxic or explosive gas buildup. 4. Control interfaces that allow remote control of fans, pumps, or other devices. 5. Transmitters and receivers that can serve as emergency links. 6. Loopback that allows an alternate path of communications if the main path is cut. This chapter focuses on equipment and methods to meet the special communication needs of individuals in various places of the underground mine. The communication requirements can be broken down into four categories: 1. The mine entrance (shaft communication). 2. Permanent and semipermanent locations (shop areas, lunchroom, crusher stations, etc.). 3. Mining areas (the room-and-pillar sections, longwall faces, block caving areas, etc.). 4. Haulageways (tracked trolley haulage, diesel, belt haulage). Methods of implementing systems to meet the communication needs of these areas are described in sections 3.2 through 3.5. Section 3.6 discusses methods of satisfying special communication requirements that exist. Major topics in this category include communications with roving personnel, the isolated miner, and motorman-to-snapper communications. Emergency communication systems are described in section 3.7.Detecting and

Jan 1, 1984

By Bill M. Stewart

The Bureau of Mines conducted laboratory tests to determine the effects on the physical properties of coarse coal waste of adding large amounts of fine coal waste. Maximum laboratory dry density, optimum moisture content, shear strength, and permeability tests were conducted on samples that contained 18 to 60 pct minus No.4 (U.S. Standard sieve size) coal waste. For the nonslaky materials, maximum laboratory densities were highest and permeabilities lowest when the samples contained between 30 and 40 pct minus No.4. Shear strength increased rapidly when the proportion of minus No. 4 was increased from 20 to 40 pct, but then increased only slightly or leveled off when the minus No. 4 was increased to 60 pct. Optimum moisture content and permeability were the physical properties most affected by the addition of fines. Optimum moisture content increased as much as 3 pct, and permeabilities decreased up to three orders of magnitude. Slaky coal waste material had physical property reactions to the addition of fines substantially different from those of nonslaky material.

Jan 1, 1981

By N. A. C. Smith

During the past, six, years, the Bureau of Mines has made and. published several hundred analyses of typical crude oils and 'has developed a system of interpreting the analyses and of classifying crudes. This system is presented here with. It is apparently equate for classifying crude oils into four main groups and has also been found very convenient in studying the geological relationships between crude oils, and the probable refinery yields of valuable products from them. Crude petroleum is morn to be a very complex substance. An analytical statement of its properties must, therefore, consist of two distinct parts, - first, the report of the results of the determinations made by the analyst in the laboratory, - second, the proper arrangement, classification and interpretation of these results so that the analysis, as a mole, will indicate the meaning- and the relative- importance of the essential characteristics of the oil.

Jan 1, 1927

By M. M. Fine

In an experimental study by the Bureau of Mines, in cooperation with National Lead Co., the roast-flotation process was found to be an effective means of upgrading certain cobalt-nickel stockpiles. The research was undertaken to determine whether the process could yield an enriched feed, with a minimum cobalt content of 6.0 percent, for the company refinery. The stockpiles (products of the company Fredericktown, Mo., milling operations) were essentially complex sulfides of cobalt, nickel, copper, lead, and iron, 1 sample of which contained 2.84 percent Co and 3.57 percent Ni. After a controlled oxidizing roast at 400° C., laboratory flotation with conventional sulfhydric reagents yielded an enriched concentrate analyzing 9.22 percent Co and 11.43 percent Ni, with recoveries of 84.9 and 85.8 percent, respectively. These are typical laboratory data; other data indicated higher grades were possible but at reduced recoveries. A brief, continuous campaign verified the applicability of the process to the raw material in question but was not continued long enough to establish optimum conditions. As a consequence, the results of the large-scale tests did not equal those obtained in the laboratory but definitely confirm the beneficiation possible from the roast-flotation process.

Jan 1, 1958

By J. G. Croeni

The titanium-iridium alloy system was investigated to determine whether alloys of this system would merit further development as control-rod material for nuclear reactors. A study was made to determine the titanium-iridium phase diagram by using melting-point, thermal analyses, X-ray diffraction, dilatometric, electrical resistivity, and metallographic techniques. The titanium-iridium alloy system was investigated between 500° and 2,400° C. Results indicate the formation of two intermetallic compounds, Ti3Ir rind TiIr3, and one intermediate solid solution centered about the 50 atomic percent iridium composition. A eutectic reaction occurs at 1,475° C, and 19 atomic percent iridium. The Ti3Ir decomposes peritectically at 1,520° C. The intermediate solid solution exhibits a maxima of 2,140° C. at 50 atomic percent iridium. This phase is also believed to undergo an order-disorder transformation at 1,750° C. Another eutectic reaction takes place at 2,000" C. and 60 atomic percent iridium. The compound TiIr3 formed at 75 atomic percent iridium decomposes peritectically at 2,115° C. Further increases in iridium content result in the formation of an iridium-rich terminal solid solution. Information obtained below 900° C. in titanium-rich alloys indicates that iridium acts as a beta stabilizer in titanium, and the authors believe that a eutectoid decomposition of beta-titanium occurs near 500° C. and 10 atomic percent iridium.

Jan 1, 1962

By Otto Ruhl

"INTRODUCTION With the conclusion of the war and the ensuing readjustment of industry to peacetime conditions, the Bureau of Mines recognized that definite and complete figures on the reserves of zinc and lead ores in the Tri-State District would be needed for an evaluation of the problem of reconversion. In October 1945 its engineers began examination of all the mines and pros¬pects in the Tri-State area and assembling of the basic data for a complete detailed estimate of the reserves of the field. Six to twelve months will be required to complete the report with the personnel available; therefore, it has been deemed advisable to provide as much data as possible for imme¬diate use. Accordingly, a confidential report prepared in January 1944 for the use of and in cooperation with the War Production Board has been brought up to date to form the basis of this preliminary estimate of reserves.The 1944 report has been revised by first subtracting from the reserves then set up for each mill group the amounts mined and milled by those properties for 1944 and 10 months of 1945, with November and December estimated. These production statistics were taken from the monthly reports of the Metal Economics Division of the Bureau of Mines. The remaining reserves were then adjusted by additions of tonnages of new reserves disclosed by developments during the years 1944 and 1945. Such additions were based upon the data furnished by various operators, upon estimates supplied by the Federal Geological Survey District Office at Miami, Okla., and upon estimates of the engineers of the Bureau of Mines Joplin field office.It is apparent from the work so far accomplished in the detailed exami¬nations now under way that the final estimate of reserves will probably be somewhat greater and will differ to a certain degree from these preliminary totals, not only as to the tonnages of ere but also as to grades and distribution by areas. This is due to the fact that all the factors of development, exploration, and geology are being considered in the present examination and report for each individual mine and prospect, whereas the previous reports covered only the immediate development factors surrounding each mill group then in active operation or projected for operation at some early date in accordance with the possible needs for war production."

Aug 1, 1946

By Thomas O. Llewellyn

Laboratory semicontinuous and continuous heavy liquid cyclone separation pilot plant tests were made to determine the feasibility of producing a high-grade kyanite concentrate from a kyanite-quartz rock sample from Graves Mountain, Ga. Use of a three-stage heavy liquid cyclone circuit demonstrated that a 96.4-to 99.0-percent kyanite concentrate could be obtained with recoveries of 95.5 to 96.7 percent. The test work showed that by steam stripping with 6.9 tons of steam per ton of ore and two stages of detergent scrubbing the residual TBE content of kyanite cyclone products was 0.22 pound per ton of ore.

Jan 1, 1971

By Travis Rhoden

Merriam Webster?s Collegiate Dictio­nary (1996) defines team as ?a number of persons associated together in work or activity? and teamwork as ?work done by several associates with each doing a part, but all subordinating personal prominence to the efficiency of the whole? (page 1209). According to Dr. Geller, author of Building Successful Safety Teams: Together Everyone Achieves More (1998), a team of people working together for industrial safety consists of as few as two people or as many as fifteen who have complementary skills, assignments, or abilities for completing a particular task. Effective teams have members who share a common mission and relevant goals, and they share specific methods to reach their goals and accomplish their mission. They also have an evaluation system in place for holding themselves mutually accountable for goal-directed responsibilities.

Nov 1, 1998

By E. J. Ostrowski

The Bureau of Mines experimental blast furnace, Bruceton, Pa., was operated to determine the feasibility of replacing part of the burden coke requirements with solid fuels injected directly into the smelting zone. This report describes preliminary experiments and information resulting from such an interchange. These experiments were made on an all-sinter burden, using two parts sinter to one part fuel. Anthracite fines were injected intermittently into the smelting zone of the furnace by compressed air through auxiliary tuyeres. The interval between injection periods ranged from 5 to 15 minutes. A maximum of 28 percent of the stock column coke bur-den was replaced. This percentage replacement caused furnace malfunction, but the overall percentage of these experiments indicated that 20 to 24 percent of the coke requirements could be replaced in this way. The metallurgical coke consumption was decreased by as much as 377 pounds (25.3 percent) per ton of pig metal produced. Buckwheat anthracite No.4 was used in this experiment; however, such solids as bituminous coal or coke fines also could be used. The frequency as well as the quantity of solid fuel injected has a direct bearing on furnace performance.

Jan 1, 1960

By John B. Shutack

In an effort to improve the performance of the explosive-anchored rock bolt, the Bureau of Mines studied the effect of the detonation velocity of the explosive and type of charge (linear or nonlinear) on the fracturing tendency of the anchor tube. Also, different types of tubing were compared to determine the one most suitable for use as an anchor tube. The Bruceton up-and-down method was applied in tests in which steel shooting blocks having boreholes ranging from 1-3/8 to 2-1/8 inches in diameter were used. Of the four types of tubing evaluated, a welded A-178 tubing that was drawn over a mandrel and renormalized gave the most promising results. The A-179 seamless tubing that is normally used with the explosive bolt was the most inferior. Both types, however, gave significantly better anchorage than the conventional shell when tested in both laboratory and underground experiments. Within the range of velocities studied (5,000 to 7,000 m/sec), the type of explosive showed no significant effect on anchor-tube performance. In general; linear explosive charges provided better anchorage than nonlinear charges.

Jan 1, 1968

By B. S. Covino

The Bureau of Mines has conducted a laboratory and field corrosion test¬ing program to determine materials of construction for the leaching and gas-sparging crystallization environments of the clay-HC1 process in order to more fully utilize the alumina from domestically available kaolinitic clays. Laboratory tests were used to determine the corrosion rates of 22 metals and alloys by weight-loss measurements in these two environments of the process. The results of this laboratory study were used both to suggest metals and alloys for field testing and to determine the effect of the individual solution components on the corrosion behavior of the metals and alloys. Results from the field tests were used to recommend Ta, Ta-2.5W, and Ta-10W for con¬struction of the agitators for the leaching process. The metals and alloys recommended for construction of the gas-sparging crystallizer heat exchangers were Ta, Ta-2.5W, Ta-10W, Nb, Nb-1Zr, Nb-3Zr, Nb-28Ta-10W-1Zr, Nb-10Hf-1Ti, and Zr for the first stage and Ta, Ta-2.5W, Ta-10W, Nb-28Ta-10W-1Zr, Nb, Nb-10Hf-1Ti, and Zr for the second stage.

Jan 1, 1981

By W. N. Poundstone, W. M. Merritts, B. A. Light

A joint investigation by the Bureau of Mines and the Christopher Coal Co. at the Humphrey No. 7 mine, operating in the Pittsburgh coalbed in northern West Virginia, was undertaken to gain more insight concerning the hazardous emission of methane gas in mining. This report describes the equipment, procedure, and results. Horizontal bleeder holes drilled in the faces drained large quantities of methane, eliminating downtime of mining equipment. Also, larger quantities of methane were removed by forcing 14 to 25 g,.p.m. water at 25 to 200 p.s.i. 5 pressure into the bleeder holes. In one infusion test a fluorescein dye was added to the infusion water; in later mining operations, the infusion water was traced for a distance of 1,500 feet. With vacuum pump applied to the horizontal hole the gas-flow rate increased, and the methane content decreased. Tests indicated that methane and water infused in bleeder holes traveled along the bedding planes of the Pittsburgh coalbed at a faster rate than across the planes. Methane associated with coalbeds is produced by the slow decomposition of carbonaceous material in the absence of air and the presence of water. It is lighter than air and, depending on its concentration, forms an inflammable or explosive mixture with air. It is believed that methane is entrapped in and around the pores of the coal and adjacent strata--often under great pressure. In many cases where the strata have been disturbed by geologic movements the

Jan 1, 1962

By Terry J. Close

The highly-mineralized 43,700-ha Rapid River study area, on the southeast side of Hells Canyon Wilderness and west of the village of Cuprum, in Adams County, western-Idaho, was investigated in 1992 by the USBM (U.S. Bureau of Mines) in conjunction with its Idaho Land Assessment Program. The 1992 study updated data gathered during the USBM's 1974-76 Wilderness investigation. The studies consisted of the evaluation of 61 mineralized sites and the estimations of tonnages, grades, and minability of these sites. Most of the sites studied are in two mineralized locales--Windy Ridge and Jackley Mountain. A few isolated sites, peripheral to the two locales, were also examined. The 61 sites contained more than 340 mine and prospect workings, including about 10,300 meters (34,000 feet) of underground workings, plus 134 drill holes.

Jan 1, 1993

By Joseph J. Wallace

1. The Pocahontas No. 3 and Pocahontas No. 6 ere the two most important beds in Mercer County from the standpoint of present production and recoverable reserves. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 tons per acre-foot of coal in place, are estimated at 188 million short tons as of January l, 1953. Of this total, 80 million short tons are in beds 28 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics are too meager to make an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1954

By Rollien R. Wells

THERE are two recognized methods of recording the state of the metallurgical art. One involves delineation of individual advances reported in the literature. This approach is used effectively in the excellent annual reviews published by some of the leading technical journals and in the technology sections of the individual commodity chapters in this volume. In an effort to more clearly indicate the current trend of metallurgical research and development, the authors of this chapter chose the method of discussing generally selected items of interest brought to their attention during 1959. Since technology cannot be confined by dates on a calendar, most of the items mentioned have been in the process of development for several years. No attempt was made to identify the sources of information used here. Material was drawn from many sources : Nonconfidential correspondence and conversations with authorities of the metallurgical fraternity, papers delivered at technical meetings, and articles noted in the technical press, including particularly Engineering and Mining Journal, Metal Progress, Journal of Metals, Mining Engineering, Industrial and Engineering Chemistry, Chemical Engineering, Chemical and Engineering News, Chemical Week, Materials in Design Engineering, Review of Metal Literature, the Canadian Mining and Metallurgical Bulletin, the Mining Journal (British), and the Journal of the Institute of Metals (British).

Jan 1, 1960

By Harold L. Rhodes

Vapor-liquid equilibria data for 65-34-1 and 25-27-48 mole percent helium-nitrogen-methane mixtures are presented for 12 temperatures from 76.5° to 164° K and pressures from 100 to 1,200 psia. These data were obtained in a windowed phase equilibria cell equipped with a vapor recirculating pump. Isobaric and isothermal K-values are plotted for both mixtures. Two isometric plots are included.

Jan 1, 1972

By Ted C. Briggs

Equations for the elastic pressure distortion of the volumes of a Burnett compressibility apparatus are developed and presented in this report for volumes under internal and external applied pressures. An experimental method for the determination of the external pressure distortion coefficients is presented. Young?s modulus and the internal-pressure distortion coefficients are computed from the experimentally determined external-pressure distortion coefficients. The temperature dependence of the pressure distortion coefficients and of Young's modulus is evaluated for the temperature range 0° to 80° C.

Jan 1, 1968