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By Oliver Bowles

"The introduction into mines, quarries and manufacturing plants of machines and tools operated by compressed air has revolutionized methods of operation to an extent comparable only with that occasioned by the invention of explosives and the utilization of electricity. The use of compressed air in pneumatic tools, in rock drills, and for the operation of pumps and other machinery is well known to most miners and quarrymen, but its application as a substitute for explosives for breaking rock in a few granite quarries has received little publicity.In the region of Lithonia, a few miles from Atlanta, Georgia, is a dome of massive granite used widely for building stone and for paving blocks. The most remarkable structural feature of the granite is the absence of joints and sheeting planes. The term ""joints"" is applied to open fractures that commonly occur in rocks, usually vertical in direction or nearly so, and spaced from a few inches to several feet apart. On the Lithonia granite outcrop, however, one may walk over the bare rock surface for hundreds of feet without finding any indications of a joint, ""Sheeting planes"" are open fractures at various levels, approximately parallel with the rock surface. The presence of such planes when spaced several feet apart greatly facilitates quarrying, and where absent, as at Lithonia, the necessary fractures must be made artificially.The forcing of artificial sheeting planes is accomplished as follows: Two holes of about 3-inch diameter arc drilled close together and to a depth of about 8 feet. Two men work at these holes all summer, and sometimes part of a second summer. A very small charge of black blasting powder, not more than a spoonful, is placed in each hole, tamped with clay, and the charges are fired simultaneously with an electric battery. This starts a small fracture running outward from the bottoms of the holes. There is in most granites one direction of easy splitting known among quarrymen as the ""rift"", and as the rift direction in the Lithonia granite is horizontal the fracture follows a horizontal plane,"

Aug 1, 1920

By Mulligan John J.

The Bureau of Mines investigated lode tin deposits on Potato Mountain, Seward Peninsula, Alaska. Tin was found to occur as cassiterite associated with quartz, tourmaline, pyrite, arsenopyrite, and earthy clays, but the deposits lack the varied accessory minerals commonly found in tin districts. The tin-bearing deposits are in metasediments along minor breaks and bedding planes but not in the crushed earthy filling of major faults. Cassiterite and sulfides occur with quartz in veins, both with and without earthy clays, and disseminated through tourmalinized wall rocks. The deposits are characterized by irregular segregations containing 1 to 10 percent tin within zones averaging not over 0.25 percent tin. The largest segregation exposed is on the summit of a low hill on the east-central slopes of Little Potato Mountain; most of the outcroppings are in an area trending east to west, roughly 10 to 30 feet wide and 300 feet long. Sample values ranged as high as 12 percent tin, but the average grade may be about 1 percent tin. The extreme irregularity of both grade and composition precludes a more exact determination. Similar concentrations are scattered for over 1,000 feet to the west and north, but these are smaller and lower in grade. Elsewhere on Potato Mountain, generally similar deposits occur as clusters of veinlets at widely separated points in the metasedimentary walls of major faults.

Jan 1, 1965

By T. M. Barczak

The term "resultant load vector" is defined as the representation of the forces applied to a longwall roof support element by strata activity through a single, quantifiable measure of support resistance. The relatively complex kinematics of the shield structure prohibits determination of support resistance simply from the summation of leg forces. In the research reported in this Bureau of Mines study, the mechanics of the shield structure were evaluated, and a technique was developed whereby the resultant shield loading could be determined by instrumenting supports with pressure transducers and strain gauges to measure leg, canopy capsule, and lemniscate link forces. This technique has been laboratory tested in the Bureau's Mine Roof Simulator. Functional relationships among variables were assessed, and confidence intervals were established for prediction of the resultant load vector parameters. Resultant load measurements were taken on five instrumented shields on an active longwall face in Colorado. Results were analyzed and found to be consistent with shield mechanics and anticipated roof behavior. Benefits to be derived from this research, future efforts, and long-range goals are discussed.

Jan 1, 1986

By N. H. Snyder

Coal analyses help to describe the character of coal as it lies in the ground of as it may he delivered to the user Analyses of samples of coal collected from the face of the bed in mines are plentiful, but available analyses of delivered coal are relatively few, and there is a distinct difference between "mine samples" and "delivered samples.” Mine samples are collected actor drag to a standard method. 13 The sampler cuts a channel. 2 by 6 or 3 by 4 inches from roof to, floor in the face of the bed, and excludes from the sample all partings more than 3/8 inch thick, and any lenses or concretions of sulphur or other impurities more than 2 inches in maximum diameter and 2 inch thick. Analyses of mine samples form a permanent and scientific record of the coal bed at the point sampled, they ale important in determining the character of the coal in any given mine or district These analyses, when the samples are taken by a standard method, are valuable to the operator When compared with analyses of delivered coal they show him whether his mine is being worked efficiently or whether the coal is being properly prepared, which involves the ques¬tion ii Nether he has suitable mechanical appliances for separating the impurities sties. In the purchase of coal, mine samples may serve as a sufficient guide for the experienced buyer who has knowledge of the impurities in the bed, and the degree to which these are eliminated in mining and preparing the coal To the average purchaser, however, unacquainted with these details, dependence on mine samples may be misleading The quality of coal indicated by the base samples call rarely, if ever, be attained in the delivered coal Certain impurities that are eliminated from the formally prepared mine sample may not be eliminated by the miner Some of the roof and floor may also be included if these are soft or flaky When coal prices are high and competition is lessened it is easy for the miner and the management to lower the standards of preparation, and a return to rigid stand¬ards is always difficult. In sampling delivered coal the Bureau of Mines follows a definite procedure. 14 A sample of not leas than 1000 pounds is systematically

Jan 1, 1928

By R. W. Hiteshue, R. W. Fridy, W. Kawa

A study of the production of coronene , a high - melting ( 440 ° C ) , highboiling ( 525 ° C) , polynuclear hydrocarbon , was made by the Bureau of Mines to determine the maximum yield obtainable by the hydrogenation of coal and coalderived materials . Experiments were made with anthracite and bituminous coals and with asphaltenes and centrifuged residue obtained from heavy oil produced in a pilot plant by the hydrogenation of a bituminous coal at 2,000 psi and 480 ° C. With anthracite , yields of coronene of 0.5 to 0.7 wt pct of moistureand ash - free coal were obtained at 6,000 to 8,000 psi , 700 ° to 750 ° C , and a residence time of 30 minutes . With bituminous coal , yields averaging 0.4 wt pct of maf coal were obtained at 6,000 psi , 800 ° C , and 30 minutes ' residence time . With asphaltene and centrifuged residue , yields of less than 0.02 wt pct of maf coal were obtained at 6,000 psi , 700 ° C , and 60 minutes ' residence time .

Jan 1, 1964

By C. Travis Anderson

"A recent critical study by Ralston3 of the iron system points out the importance of and necessity for work upon the preparation of ferrous oxide. Not only are ferrous oxide samples desired for determination of the important physical and chemical properties, such as specific heats and heats of formation, bat also information on the stability and behavior of this material is of considerable technical importance. Related. problems where the properties of Fe0 are important have to do with desulphurization of iron, the formation and occurrence of magnetite in copper smelter slags, and sulphur elimination in copperFerrous oxide also has valuable catalytic properties, as is demonstrated in nitrogen fixation.Pure ferrous oxide has never been prepared in quantities large enough to furnish adequate physical and chemical data on its properties. Only two or three experiments4 have produced a fraction of a gram in a state approximating purity and have collected evidence that has been sufficient proof of their having done so. Ferrous oxide is stable only above about 570°C., and below that splits into magnetite and iron according to the reactionUp to about 1920, those who had endeavored to prepare FeO made no provision for rapid chilling, so that although their product. may have had the proper iron oxygen ratio for FeO, in reality it-probably did not consist of pure FeO. The above reaction is reversible; above 570oC. magnetite and iron are supposed to recombine almost completely, and if so, should constitute a direct and easy method of preparation. The data, however, were somewhat conflicting, and the extent to which the reaction goes in either direction needed checking. Preliminary experiments on the interaction of molten Fe304 with solid Fe gave Fe0 of about 85 per cent purity, corresponding to. the approximate purity obtained by some previous investigators. The present work is concerned chiefly with the results cf repeated interaction between partly reduced magnetite and iron, and the calculations which may be made from such results. Repeated treatments are necessary, because molten impure ferrous oxide and iron can not be kept in contact for more than short periods of time."

Oct 1, 1928

By J. B. F. Champlin

The continuing development of the nuclear industry in the United States requires a program of waste disposal that insures against the release of large amounts of radioactivity to the environment. This paper describes research on one proposed means of disposal of this waste, that of injection into geologic formations at depth. Nuclear production plant wastes were simulated and injected into samples of sedimentary rock obtained from outcrops, quarries, and deep wells. Changes in the chemical and physical characteristics of the rocks caused by the interaction of ions and suspended particles in the waste solutions with the cementing material and claylike particles in the rock are discussed. Laboratory tests show that nuclear wastes can be injected into many natural porous, permeable geologic formations. Injectivity can be maintained over a longer period by monitoring the ionic balance and particle-size distribution of waste streams. The combination of permeability and porosity with low cation-retention capacity, as exhibited by most sandstones, would satisfy the engineering requirements for the subsurface disposal of nuclear waste. Shales and clays with their low permeability and high cation-retention capacity would make excellent confining formations. The amount of cation retained by sedimentary rocks increases with increasing valence or concentration of the cation or decreasing brine concentration. The use of rock cores as model reservoirs had proved successful in determining some of the parameters that need to be considered in full-scale field disposal of wastes.

Jan 1, 1967

By Michael J. Brnich

During the past 15 years the number of reportable mine fires has declined. A decline in the number of reportable fires is a gross indicator that allows experts to say something about the underground coal industry generally: There has been some improvement in overall mine fire preparedness. However, such an indicator is less reliable as a predictor of readiness at any particular operation. An indication of fire fighting preparedness would have to be assessed from evidence gathered at the mine site. In other words, there are two levels from which to view the problem. On a general level, there has been significant improvement in the industry's fire response capabilities over the past two decades. Specifically, however, little data has been gathered on a site-by-site basis to determine what improvements might be made on a local level. These improvements would move beyond regulatory compliance. It is expected that this manuscript, based on work conducted at an underground coal mine in the western United States, will help to focus attention on some central concerns involving this critical issue.

Jan 1, 2006

By M. M. Fine

The results of tests on oxidized lead ores from two properties are reported in this paper. The investigation was on a small laboratory scale only; no pilot-plant tests were made. One sample, from the Magajupa Mining Co., near Duenweg, No., contained coarsely crystalline and disseminated galena and cerussite, so both tabling and flotation were considered in the beneficiation. By this treatment of an ore containing 11.5 percent lead, a recovery of 79.5 percent of the lead was made in a concentrate containing 73.3 percent lead.

Jan 1, 1948

By D. S. Burgess

A commercially available Halon 1301 extinguisher has been evaluated as part of an explosion-suppression system for use in coal mines. Studies were made both of the dispersion pattern of the Halon 1301 at an initial pressure of 280 psig, and of the efficacy of this suppressant against 9.5 percent methane-air flames. These flames were quenched successfully only when the suppressant was applied before the fireball diameter exceeded 18 inches.

Jan 1, 1971

By J. Frederick Stampfer

Current certification testing of self-contained breathing apparatus includes tests with human subjects wearing the apparatus while exercising. During these tests, certain apparatus variables are measured during rest periods. Because of concerns that the present tests may not accurately simulate the stresses to which an apparatus is subjected in the field, the Bureau of Mines proposed new human subject tests. It was also felt that different measurement techniques would supply more reliable data on the apparatus response to these stresses. The Los Alamos National Laboratory was asked by the Bureau to evaluate the proposed tests and monitoring techniques. The major conclusions derived during this study are these: (1) The proposed tests are not too physically demanding. (2) As long as human test subjects are used, a minimum subject weight should be required for certification tests. (3) Important apparatus variables are the breathing resistance, temperature, and carbon dioxide and oxygen concentrations of the inhaled gas. (4) Continuous monitoring should be used, rather than monitoring only during rest periods. (5) New pass/fail criteria based on realistic estimates of the user's physiological requirements, as tempered by present and future engineering limitations, are needed. (6) When available, breathing machines, rather than human subjects, should be used for most certification testing. (7) A more realistic ergonomics test than that proposed is needed. (8) A gas leak test for the system and a facepiece leakage test are also needed.

Jan 1, 1983

By Heinz W. Sternberg

A method for the electrochemical reduction of the benzene ring was developed and applied to the electrochemical reduction of coal. Successive electrochemical reductions of a vitrain from low-volatile bituminous coal in ethylenediamine saturated with lithium chloride resulted in the addition of 53 hydrogens per 100 carbon atoms. Ultimate analyses and pyridine solubility of the vitrain recovered after each reduction showed that hydrogen added at the beginning has a much greater effect on solubility than hydrogen added at a later stage. Surprisingly, the removal of sulfur from the vitrain takes place only after the more reactive aromatic rings are reduced. Nuclear magnetic resonance analysis and average molecular weight determination of the extracts of the reduced vitrain samples, representing about 18 percent of the vitrain, showed that these fractions had 95 percent of their hydrogen content on saturated carbon atoms and an average molecular weight of 800 to 900. A study of the effect of operating variables on current efficiency showed that current efficiency is highest with aluminum as cathode material and with lithium chloride as electrolyte. A substantial increase in current efficiency of difficulty reducible olefinic double bonds was achieved by adding a proton donor. This result is significant in connection with the electrochemical reduction of coal which proceeds from readily reducible aromatic double bonds to difficultly reducible isolated double bonds. It is proposed that reduction is achieved by electrolytically generated and subsequently solvated electrons and hence does not require prior adsorption of the substrate at the electrode surface. This offers a distinct advantage for electrolytic reduction of sparingly or insoluble substrates such as coal.

Jan 1, 1967

By Robert C. Johnson

Domestic byproduct fluorine (in fluosilicic acid) availability at various price levels of aluminum fluoride were determined and a contingency availability curve developed. The supply of byproduct fluosilicic acid is restricted in amount to certain geographic regions, where plants processing phosphate rock are located, and the byproduct can be collected. The maximum possible U.S. annual supply, based on potential plant capacities, is 373,400 tons of fluosilicic acid containing 295,400 tons of fluorine. Based on inputs of 5, la, 25, 50, and 100 thousand tons per year, five levels of producing aluminum fluoride from fluosilicic acid (100 percent) were costed. Based on a 12-percent discounted cash flow rate, including the cost of salvaging the fluosilicic acid, the calculated selling price of aluminum fluoride ranged from $233 per ton to $448 per ton. At the higher price, 98 percent of the potential supply of byproduct fluosilicic acid could be used profitably; at the lower price only 46 percent could be used profitably.

Jan 1, 1973

In 1962 and 1963, two in situ combustion pilot tests were conducted in the shallow Second Venango sand near Reno, Pa. Because of poor oxygen utilization and lack of production response, both tests were considered failures and were terminated. The area was then relatively inactive until late 1966, when a development well drilled near the 1963 test site had surprisingly good production in what was considered to be a pressure-depleted reservoir. Other wells drilled in and around the old thermal pilot areas also came in as good oil producers. This report presents a study of the increased oil production from the Second Venango sand in the Reno area, and the apparent connection of the present production response and the old thermal pilot tests. Apparently combustion occurred in the Second Venango sand after the 1962 and 1963 experiments were terminated and, supported by large volumes of air left in the reservoir after the 1963 test, generated carbon dioxide which helped repressure the formation. This field evidence of combustion warrants another pilot experiment to further explore the use of properly designed in situ combustion techniques in increasing production from the Second Venango sand.

Jan 1, 1971

By T. L. Iapalucci

To determine the behavior of chlorine in coal combustion, the Bureau of Mines burned 10 chlorine-containing coals, high-, medium-, and low-volatile, in a laboratory-scale pulverized-coal combustor. At carbon-combustion efficiencies of 94 to 98 percent, 1.6 to 7.1 percent of the chlorine or an average of 4 percent of the chlorine in the coal was retained in the ash; the balance, predominantly hydrogen chloride, was evolved in the combustion gas. Sulfur retention in the ash ranged from 2.3 to 10.7 percent or an average of 6.3 percent, Addition of alkali and alkaline earth carbonates to a medium-volatile coal containing 0.27 percent chlorine by preferentially reacting with the chlorine increased the Cl/S atom ratio in the ash, Lithium carbonate addition at 0.43 percent and K2C03 at 1.59 percent increased the C1/S ratio in the ash from 0.2 to 0.6.

Jan 1, 1969

By W. K. Collins

Engineered scavenger compounds (ESC's) developed by the U.S. Bureau of Mines are a novel class of compounds that selectively can recover a desired element from a solid or molten alloy. Lithium titanate (L2Ti307 or Li2O?3Ti02) is used as an ESC to recover lithium (Li) from aluminum-lithium (Al-Li) alloys. X-ray diffraction measurements have shown that Li2Ti307 undergoes a phase change during scavenging from an orthorhombic structure to a hexagonal structure. This change is due to the incorporation of lithium in the matrix of the material and the effect of temperature. Although both phases are metastable, the hexagonal phase that forms during the scavenging of lithium from Al-Li alloys appears to be the more stable phase. Recovering lithium from the ESC by electrodeposition does not cause the structure to revert to the orthorhombic phase. The orthorhombic and the hexagonal structures of Li2Ti307 have similar scavenging capacities for lithium. This report proposes a new mechanism for the phase transformation.

Jan 1, 2010

By J. D. Ramsdell

The study described in this report was undertaken to obtain information on the character and effect of antimony additions to titanium. The availability of high-purity, low-hardness titanium metal, resulting from fused-salt electrorefining techniques, permitted a reassessment and evaluation of the physical behavior of titanium-antimony alloys. Alloys, based on several grades of titanium containing up to 10 percent antimony, were arc-melted and processed to sheet by hot and cold rolling. Properties and characteristics were evaluated by hardness tests, hot and cold rollability, annealing treatments, metallographic examination, and tensile tests.

Jan 1, 1960

By W. P. Diamond

The explosion hazard of methane-air mixtures has become an increasingly serious mine planning problem, and an advance assessment of methane gas potential can therefore be essential for a safe and economic mine development program. As part of its coal mine health and safety program, the Bureau of Mines has developed a simple, inexpensive test to measure the methane content of coal samples obtained from exploration cores. The gas content of coal per unit weight as determined by the direct method test can be used as a basis for a preliminary estimate of mine ventilation requirements, and to determine if degasification of the coalbed in advance of mining should be considered. Since the Bureau began measuring the gas content of coal samples in 1972, experience has led to equipment and procedural changes, the most significant of which has been the development of a ball mill for crushing the coal sample to release the residual gas at the end of the desorption test period. This revised procedure replaces the crushing box and graphical methods described in earlier Bureau publications. The results of 583 direct method tests are summarized in tabular form. These results include data on the gas content of 125 coalbeds in 15 States.

Jan 1, 1980

By B. W. Moore

The U.S. Bureau of Mines investigated the separation of heavy rare-earth elements (REE) in an ion-exchange process. An ion-exchange column consisting of two sections, a loading section and a separation section, provides high levels of REE loading and good REE separation with an expected processing cycle of less than a month, while current ion-exchange technology requires more than 5 months. A different resin is used in each section: sulfonic resin in the loading section and iminodiacetic resin in the separation section. The separation section is further divided into two segments: the first conditioned with NH4 and the second with acid. Erbium is loaded onto both segments of the separation column as a retaining ion. Bands of mixed REB eluting between separated bands of pure REB were recycled directly to the column. Without mixed-band recycle, over 80% of the REE eluted from the column was separated into fractions with 99% purity of each element; with such recycle, the percentage of separated elements can be increased to around 90%.

Jan 1, 2010

By H. B. Freeman, E. J. Gleim

During the 12 months ended July 1, 1931, engineers of the Bureau of Mines examined electrical equipment in 80 bituminous-coal mines. The purpose of these examinations was to ascertain the condition of such equipment with respect to possible hazards of gas and dust ignitions, also of shock. Although only 3 of the 80 were being worked with open lights and therefore did not use explosion-proof equipment, there were others where electric cap lamps were used by the men but where it was apparently assumed that conditions as to gas and dust did not require equipment designed to give protection against ignitions. Early in its history the United States Bureau of Mines originated certain standards covering the construction and testing of electrical equipment in order to minimize the dangers of ignitions from exposed electric sparks and flashes ; accordingly, it is comparatively easy to determine wherein a machine built to these standards falls short of continuing to meet them if damaged or neglected. Many so-called flame-proof and dust-proof machines, however, have not been built to any standard comparable with that developed by the Bureau of Mines. In addition, certain machines have parts which pass Bureau of Mines tests, but do not satisfy the full requirements in other respects, and others make no pretense of inclosing the spark-producing parts. It is not uncommon to find two or more of these various types in the same mine with " permissible " machines, the type that has been built to conform to the Bureau of Mines standard. Consequently, inspection of nonpermissible machines becomes somewhat difficult without a standard of comparison. Because of its unprotected condition obviously open-type electrical equipment must be used with great care, if at all, in a mine where precautionary measures are adopted in guarding against gas and dust ignition. The unsafe nature of such equipment is widely recognized. For that reason it is to be installed only where there is no likelihood of gas being present. It is not apparent to some, however, why flame-proof and dust-proof equipment and equipment having tested parts should not be regarded in the same light as permissible equipment.

Jan 1, 1932