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By G. Merrington, B. J. Alloway

Tailings from three historical mining areas in the UK were leached in columns under a simulated weathering programme which was chosen to represent periods of 1 and 2 years at 3 different ambient temperatures. The total concentrations of Cd, Cu, Pb and Zn in the primary ore minerals present in the tailings showed only a limited correlation with metal concentrations in the leachate. The leachate from columns of tailings that were maintained at a temperature of 25 (+/-3) degrees C contained, on average, 50% more Pb and 75% more Cu than leachate from tailings that were maintained at a temperature of 10 (+/-3) degrees C. The pH values of leachates from all three types of tailings at 25 (+/-3) degrees C were 0.2 units lower than those from columns maintained at 10 (+/-3) degrees C. The concentration of Cd and Zn in the tailings leachates showed no marked difference at the different temperatures. The composition of the leachate was found to be dependent on the type of gangue mineral, the presence of other sulphide minerals and the formation of secondary iron minerals. A comparison of the concentrations of heavy metals in the leachates produced in the laboratory with those in leachates that were collected in the field over a similar period of time from two of the mine sites showed that concentrations were of a similar order.

Jan 8, 1993

By M. J. Russell, W. E. Stephens, D. B. Mohamad, A. B. MacKenzie

Redox front processes in rocks are important in the context of both radioactive waste disposal and the development of orebodies. Results are presented from a study of the distribution of uranium and thorium and the natural decay series equilibrium about redox fronts in a granite at the Criffel pluton and Craignair quarry, Dalbeattie in southwest Scotland. The results are considered in the context of large scale uranium aqueous transport in the region and compared with those from a previous study of highly developed redox fronts at Pocos de Caldas, Brazil. Results show that the Criffel pluton has experienced a recent and rapid removal of uranium from the uppermost section of the granite whereas thorium has remained relatively immobile. The radium and uranium distributions indicate that diffusion processes probably control the distribution of radionuclides about the front. These processes are similar to those observed at Pocos de Caldas. The trends of concentration and activity ratio about the Dalbeattie redox front are less pronounced than those at Pocos de Caldas owing to the shorter time available for the process and the lower intensity of weathering at Dalbeattie.

Jan 12, 1992

By A. D. Read

Selective flocculation was investigated as a possible method of recovering values from mineral slimes which are too finely divided to be treated by conventional mineral processing methods. It has proved possible to flocculate selectively either haematite or a silicate from a stably dispersed mixture by varying the anionic character of the high-molecular-weight, partially hydrolysed polyacrylamide employed. Different separation methods have been developed for hard and soft water media. Electrokinetic and infrared techniques have been employed to elucidate the mechanism whereby selectivity has been attained in the different cases. The following influences on the various selective flocculation parameters have been investigated: (a) the level of the different reagent additions and (b) the shear conditions during and after flocculant addition. A feature of the particular system studied was the high solids content at which it was possible to achieve good selectivity. Probable reasons for this are advanced, and the possibilities and potentialities of the process are discussed.

Dec 1, 1971

By J. H. Chesters

The main, though rarely mentioned advantage, is likely to be the standardisation of best practice and product. In a batch process conditions vary cyclically, but with a continuous process they would, at least ideally, remain the same for long periods of time. The other main advantages of continuous over batch processes are likely to be reduced operating and capital costs, the improved possibilities for automatic control, and more consistent product quality. Recent developments are surveyed for ironmaking and steelmaking with reference to blast furnaces; solid-product and molten-product direct reduction; the trough-type processes of Thring, Worner, the Japanese National Research Institute for Metals and Glinkov; basic-oxygen furnace (LD) variants; spray steelmaking; continuous casting and vacuum degassing; rolling; and coating. Encouragement in the devleopment of continuous processes may be drawn from the way unexpected difficulties, such as trouble with sulphur and refractories, were tackled and overcome to achieve the float glass process

Dec 1, 1971

By R. Patel, J. Ephraim

The production of titanium dioxide (TiO2) from its minerals such as ilmenite is challenging, and subsequent isolation of titanium from TiO2 is even more difficult because of the metal-oxygen bond strength. Currently, titanium sponge is mainly produced via the Kroll process, which is energy intensive and generates large quantities of waste. A number of international research groups have come up with technologies for the production of titanium metal. However, none of them have been commercialised, because of engineering or economic issues. The team at Bradford have confirmed that ultra-pure titanium powders can be separated from TiO2 powder through metallothermic reduction and are working to scale up the process.

May 1, 2015

By K. El-Barawi, Hussein M. Kamal

Chlorination was performed of iron-rich chromite ore from Barramyia, United Arab Republic (UAR), together with its concentrate. The effects of change of grain size, chlorine gas flow rate, time and temperature were studied. The extent and mechanism of chlorination were followed through chemical and structural analyses of the feeds and complete chemical analysis of the chlorination products. By conducting the chlorination process for short periods at 600°C or lower temperatures, products having high Cr-Fe ratios suitable for ferrochrome production can be obtained.

Dec 1, 1971

By A. C. Dunham, Y. D. Drakapoulos, P. W. Scott

The Pt and Pd occur alloyed with copper in small, irregularly-shaped grains, 0.25-5.0 micrometers in maximum dimensions. Grains of unalloyed native copper are also present. The grains are completely surrounded by or marginal to magnetite with inclusions of Ni-Fe-Co sulphides and native Ni-Fe, which is apparently a product of the serpentinisation process. Crystallisation of the Pt-Pd-enriched copper probably occurred at the same time, at low temperature, but the previous form of the Pt and Pd is unknown as no earlier PGE phases have been found. While Pt and Pd minerals are usually important in early-magmatic base-metal sulphides, Pt alloyed with Cu is extremely rare and apparently occurs only very late in the paragenetic sequence. A Cu alloy with Pd dominant over Pt and only minor amounts of other elements appears not to have been reported

Jun 14, 1905

By J. M. Smith

This resume provides an account of the work of the Bureau and it's establishment by an Act of Parliament in August 1916. The Medical Bureau is concerned solely with the administration of the medical provisions of the Act. Its main functions are to conduct and to direct or control the medical examinations provided for in the Act. The paper covers the changes in type of silicosis, classification into the three legal stages of silicosis, cancer of the lung and tuberculosis.

Jan 1, 1947

The mineralogical composition of the ore was determined and the mineral phases with which nickel is associated were identified. The ore was prepared by grinding to -420 micrometres and classification into granulometric fractions. Prior to the main series of experiments the effect of agitation rate on nickel recovery was investigated. The influence of sulphuric acid concentration, temperature and particle size on the kinetics of nickel extraction was then studied, both quantitatively and qualitatively, over fixed value intervals. Application of the initial rate method enabled determination both of the order of reaction with respect to sulphuric acid concentration and the activation energy for the dissolution of nickel. The results indicate that a physical mechanism can be ruled out as the rate-determining step in the extraction of nickel from the ore and that a chemical mechanism is more likely

Dec 1, 1991

By V. E. Ross

A comparison was made of three methods for determining the contributions of true flotation and entrainment during batch flotation tests. In the first method size-by-size recoveries are measured in both the presence and the absence of a collector, a frother being present in both tests. In the second method the mass of solids and water recovered after a chosen time of flotation is varied by changing the rate of froth removal and the depth of the froth. The third method uses a transfer factor to describe the classification of solids and water, and hence the changes in the composition of the pulp, during a single flotation test. Batch flotation tests were carried out with artificial mixtures of pyrite and gangue, the amount of floated material recovered being calculated according to each of the three methods. The discrepancies betweeen the calculated amounts are analysed in terms of the assumptions that are made for the various methods and the most suitable conditions for the application of each method are identified

Dec 1, 1991

By L. Wade, R. Wang, M. A. Horton

Laboratory methods to find the mechanical properties of rock are inherently biased towards stronger strata, which best survive the sample preparation process. Geophysical techniques are not subject to such bias and may be used to predict mechanical properties rapidly and cheaply. Samples (151) were obtained from a borehole that had been comprehensively geophysically logged. The mechanical properties of the samples were established in the laboratory and correlated with the geophysical responses of the strata from which they came. The results indicate that, for homogeneous strata at least, it is possible to predict the unconfined compressive strength reasonably well from sonic travel time measurements made in the field. Predictions of static Young's modulus may also be made from this data source, but with a lesser degree of confidence. A multivariate regression equation is presented which relates down-hole sonic travel time to unconfined compressive strength, depth and the frequency of fractures in the rock mass. This equation may offer potential for the prediction of the mechanical rock properties of fractured and layered strata.

Jan 4, 1993

By J. H. E. Jeffes, K. T. Jacob

The activity coefficients of oxygen in liquid Pb-Sn alloys have been measured between 550 and 1100°C by use of solid oxide galvanic cells: Pt, Ni-NiO | Zr02 Solid electrolyte | O (Pb + Sn), Cermet, Pt; and Pt, Fe-FeO | Zr02 Solid electrolyte | 0(Pb + Sn), Cermet, Pt. Alcock and Richardson's quasi-chemical equation, with the coordination number of atoms set to 2, is found to predict successfully the activity coefficients of oxygen in these alloys. The relative partial molar enthalpy and entropy of oxygen at 1 atom per cent in the alloys have been calculated from the variation of the activity coefficient with temperature. The addition of Sn to an unsaturated solution of O in Pb is shown to decrease significantly both the partial molar enthalpy and entropy of O. As the measurements were restricted to a narrow range between 750 and 1100°C in Pb-rich alloys, however, the pronounced variation of the partial molar enthalpy of O with temperature at constant alloy composition predicted by the quasi-chemical model could not be verified.

Dec 1, 1971

By R. W. Ruddle

The advent of new methods of roasting, “flash roasting and fluidisation”, which are now under development, combined with the use of oxygen-enriched air, may markedly increase the SO2 content of roaster smokes. Skogmo suggests that the production of smokes containing as much as 50 per cent SO2 should be feasible. The use of flash smelting processes may well enable a similar increase in the SO2 content of smelter smokes to be made. In this event the recovery of sulphur would be greatly cheapened and the process might well be much more economic, even if allowance is made for the cost of generating the oxygen

Jan 1, 1953

By D. Mireku-Gyimah, R. S. Suglo

Ghana contains auriferous belts which cover 51 800 km2 of its small area of 239 400 km2. From 1493 to 1600 35.5% of the world gold production was from the Gold Coast (renamed Ghana in 1957). This dropped to 8.9% from 1701-1800. For the past fifteen years annual production has averaged less than 2% of the world total. By 1985 only four gold mines were operating, compared with 45 in 1934 and 11 in 1945. Since 1987 Ghana has experienced a boom in gold mining activities. By 1991, 83 new companies had acquired prospecting licences. At least five new companies have started large-scale production. About 650 licensed small-scale mining groups are in operation. The economic and technological factors that have contributed to the decline of gold production in Ghana are discussed. A summary is given of the methods used to mine and recover gold. These cover small-scale workings, dredging, open cast operations and underground mining. The advantages and disadvantages of these technologies and the future of gold mining in Ghana are considered.

Jan 4, 1993

By A. G. Waters, N. J. Bristow

A comparative study was made of an untreated and a heated haematite ore and a sinter produced from a feed consisting of 100% ore, to study the influence on reduction behaviour of sinter bonding phases such as SFCA (silico-ferrite of calcium and alumina). Under low-temperature reduction conditions the order of increasing reducibility followed that of increasing porosity and surface area but under similar conditions at 900 degrees C the sinter exhibited higher reducibility than the ores even though the total porosity and chemical reducibility of the individual phases were lower. This behaviour can be explained in terms of the higher total porosity of the natural ore at low temperatures and the higher level of fine pores in the sinter at high temperatures due to the presence of SFCA, which acts to support the fine (c.0.1 micrometre) pores created by the reduction process. This leads to the conclusion that the main role of SFCA in sinter during high-temperature reduction is to maintain a high level of fine porosity. Some implications of this work for granule design and sintering practice are discussed

Apr 1, 1991

By A. H. G. Mitchell

Gold-poor and gold-rich porphyry and epithermal gold-silver deposits of Caenozoic and Cretaceous age in the western Pacific and central and eastern Europe are confined to predominantly andesitic continental margins and island arcs. The arc volcanic rocks overlie a complex non-oceanic basement of stacked nappes, the uppermost of which is often ophiolitic. The emplacement of ophiolite triggered a reversal of tectonic polarity, subduction and arc magmatism. Andesitic volcanism and the formation of a strato-volcano were followed by the ascent of magma and porphyry copper mineralisation. Regional propylitic alteration came from convecting, predominantly meteoric fluids. Magmatic degassing caused advanced argillic alteration. This is commonly unmineralised in perched water tables, but may sometimes host high sulphidation gold or enargite gold at deeper levels within the propylitic zone. The onset of extensional stress after the andesitic volcanism allowed meteoric water to circulate to depths of 5 km or more, with consequent cooling of an ascending magma body at depth and the development of low sulphidation epithermal gold mineralisation near and immediately above the sub-volcanic basement surface. All andesitic arcs are mineralised. Regional controls on their ore potential include the level of erosion and geological features in the basement that focus the ascent of fluids. Differences between the mineralisation of the European and the western Pacific arcs may reflect the presence of older, more granitic basements in many of the European arcs.

Jan 12, 1992

By G. E. Pearse

Reports, discussions, a written contribution and two written replies are presented from 11 sessions on: Safety and compressed air; Ground movements; Geotechnical; Channel Tunnel (2 sessions); Machines; Case histories; Transport tunnels; Case studies; Site investigation; and Undersea tunnels

Jun 13, 1905

By R. G. Jones

Chris Hinde talks us through his career from BSc in Mining Engineering to roles with Golder Associates, Schroder Securities, Mining Journal and SNL. He discusses the issues facing the mining industry.

May 1, 2015

By D G. Jefferies

This paper covers National Grid's role in the electricity market, the growth of competition in both generation and supply in that market, and the resulting impact on fuel usage, prices and the environment. It also considers other, external influencing factors on the electricity supply industry, as well as the growing trend towards globalization.

Jan 12, 1997

By M. D. Pritzker

Shrinking-core models are used to describe the physico-chemical processes that are associated with many metallurgical gas-solid and liquid-solid reactions. The models can be used to evaluate rate constants and effective diffusion coefficients from experimental data. This work generalises the model for diffusion through a product layer to cases where the transport of more than one species is rate-controlling

Jul 1, 1991