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By M. R. Julien, A. Maqsoud, J. Martschuk, B. Bussière

Acid mine drainage (AMD) from mine wastes is one of the most challenging environmental problems currently facing the mining industry. When mining wastes have the potential to produce AMD, the effluents produced have to be managed to meet existing regulations on water quality. The LTA impoundment (property of Barrick Gold Corp.) located near Malartic, Quebec, contains sulphide tailings that have the potential to generate an acidic leachate. The closure option selected by Barrick was to construct a cover with capillary barrier effects (CCBE), in which the moisture- retaining layer is made of non-acid-generating tailings. Since its construction in 1996, the cover has been monitored to evaluate its performance. For that purpose, various parameters have been measured, including the volumetric water content and matric suction in the different layers of the cover. This paper presents some of the main results from the monitoring program that started eight years ago. The results show that the cover is able to maintain a high degree of saturation in its moisture- retaining layer, acting as an oxygen barrier. The actual performance of the CCBE on the flat surface of the 60 ha site is better than expected at the design stage. The only concern with the LTA cover is the effect of slopes that can reduce the performance of the CCBE during dry periods. However, these effects appear only for short periods of time, and are limited to very localized areas, so that they do not significantly affect the overall performance of the CCBE and its ability to limit the production of AMD.

Jan 1, 2006

By V. Loya

Metallic foams (MF) are relatively new materials with a combination of attractive properties (permeability, high surface area, thermal and chemical stability, etc,), They can be produced from different materials and can be manufactured using various processes, Due to their unique properties, they find applications in different sectors of engineering, such as energy absorption, filtration, heat dissipation, etc, For many applications, the permeability is an important parameter to characterize and optimize, Most of the recent literature on the subject studied the permeability in the low velocity range. The present study was carried out to have a better understanding of permeability for greater velocity ranges, An equipment was designed and built for this purpose, Pressure drop measurements were made across the thickness of open-cell nickel foams, Pore and window sizes were measured by image analysis on SEM micrographs, The experimental results are in relatively good agreement with the Hazen-Dupuit-Darcy model (R2>98%), The permeability is affected by pore size, porosity and the normalized projected area of the connecting pores (ie. windows).

Jan 1, 2005

By N. R. Andrade-Gonzalez

In this paper, the effect of magnesium and strontium additions on the heat treatment behaviour of cast A319,2 alloy was investigated, Permanent mold samples were heat treated at 495 °C for 4 and 24 h, then quenched in hot water and aged at 180 °C and 220 °C for different temperatures, It is found that multiple aging peaks are present in the age-hardening curves of Al-Si-Cu alloys, mainly when Mg and Mg-Sr are added, The results of electron probe microanalysis (EPMA) observations reveal that the age-hardening behaviour is related to the precipitation sequence of alloys, For the Al-Si-Cu alloy, the first aging peak is the result of the high-density GP zones, while the subsequent peaks arise from metastable phases, Obvious intervals during the transition from GP zones to metastable phases may be the main reason of the formation of multiple aging peaks, It is seen that addition of Mg (-0,40 wt %) leads to the precipitation of coarse Al5Mg8SioCu2 particles. When modifying the high Mg alloys, Cu-intermetallics segregate in areas away from the growing Al-Si eutectic regions, Modification with strontium retards the precipitation of the silicon out of the matrix.

Jan 1, 2005

By V. G. c Papangelakis, M. Huang

A conductivity cell, developed previously, was employed in an effort to investigate the inter-relation between electrical conductivity and acidity of sulphuric acid - metal sulphate solutions at high temperatures. The measured solutions include the H2SO4-H2O, MgSO4-H2O, H2SO4-MgSO4-H2O, H2SO4-MgSO4-Al2(SO4)3-H2O solutions. All solutions reported in this paper were measured from 15 to 250 °C at equilibrium vapour pressure. The maximum measured concentrations of H2SO4, MgSO4 and Al2(SO4)3 were 0.45 m, 0.30 m and 0.10 m, respectively. It was found that, from 15 to 250°C, there is a linear relationship between H2SO4 concentration and electrical conductivities for acid concentration up to 0.45 m. At 250 °C and constant H2SO4 concentration, the solution conductivity drops with the increase of MgSO4 concentration. Lt is suggested that this drop is caused by a decrease in the concentration of H. Finally, an empirical model was developed based on the available measurements. This model has been tested against real laterite leach solutions where sulphuric acid and metal sulphates are dominant electrolytes. The average difference between the estimate acid concentration from this model and the one from titration was less than 5%.

Jan 1, 2004

By G. C. Nowlan, A. Illis, H. J. Koehler

At its iron ore recovery plant at Copper Cliff, INCO produces about 17 million pounds per year of a pure, acid-soluble, dense nickel oxide from nickeliferous pyrrhotite. The process used is also applicable to a broad range of ammoniacal nickel-bearing streams. The product has been widely accepted by the chemical, ceramic and electronic industries.

Jan 1, 1970

By J. J. Quinn

Several mineral flotation plants utilize process water with high soluble salt content. The processing of semi-soluble minerals, the use of recycle streams, sea or well water give rise to this situation. It is unclear as to the overall effect on flotation response though there does seem to be evidence of bubble size reduction, increased froth stability and reduced reagent dosage. The present work aims to quantify the effects of salts present in process water on gas dispersion (bubble size and gas holdup) and froth properties. The salts examined were NaCI, CaCl2, Na2SO4, Na2S2O3 and Al2(SO4)3. Tests were conducted to determine the effects of salt type and concentration on gas holdup and bubble size distribution. The salts containing multivalent ions had a greater impact than the monovalent ions, in keeping with the literature. A relationship between gas holdup and ionic strength was established. The concentration of frother (methyl isobutyl carbinol, MIBC) giving equivalent gas holdup was determined. The effect of salt and frother combinations was also explored.Proposed mechanisms for coalescence inhibition in salt solutions are briefly reviewed in light of the current findings.

Jan 1, 2006

By S. Hunt, S. Jayasekera, J. Kyle, N. Perera, K. Stone

A preliminary investigation has been conducted to determine the conditions for the precipitation of phosphate from the liquor produced after a hydrochloric acid pre-leach and rare-earth recovery from a rare earth containing fluorapatite concentrate from the Nolans rare earth deposit in the Northern Territory of Australia. The results show that at 50oC the phosphate can be precipitated in two stages using limestone to produce a Stage 1 precipitate containing most of the impurities including iron (94%), aluminium (92%), fluoride (98%), uranium (84%) and thorium (94%), followed by a relatively pure Stage 2 dicalcium phosphate precipitate (DCP) containing only 0.05% Fe, 0.05% Al, 0.1% F, 0.01% U, and <0.01% Th. The initial Stage 1 precipitate contained about 25% of the phosphate while the remaining 75% reported to the Stage 2 phosphate precipitate. Depending on the required radioactivity specifications, the amount of phosphate in the Stage 1 precipitate could be reduced. Reagent requirements were 11.4 kg limestone (as pure CaCO3) per cubic metre of solution for the Stage 1 precipitate and 39.7 kg limestone (as pure CaCO3) per cubic metre for Stage 2. The analysis of radionuclide balance indicated that radionuclides deported mainly to the final filtrate (86.4%) compared to Stage 1 precipitate (5.4%) and Stage 2 precipitate (8.2%). Settling and pressure filtration tests indicated the precipitates were both readily settled and filtered. The final moisture contents of the Stage 1 and Stage 2 precipitates were 62.5% and 49.3%, respectively.

Jan 1, 2014

By A. Gauthier, J .. E. Muir, M. Cormier

Falconbridge's Lac Shortt gold deposit is located in Gand Township, some 25 km north-east of Desmaraisville, The deposit was outlined in i980 by a drilling program me conducted by Falconbridge Ltd. in a joint venture with Corporation Falconbridge Copper after three years of systematic exploration by Falconbridge Ltd. in the Desmaraisville area. The gold bearing structure had previously been drilled by three other exploration companies. As based on an underground development programme conducted by Corporation Falconbridge Copper, the "in-si tu" mineral inventory to a depth of 500 metres at a cut-off grade of 3.0 g/t is estimated at 1 937 605 tonnes at a grade of 6.4 g/t (uncut) and 6.0 g/t (cut). Regionally, the stratigraphy consists of thick sequences of volcanic and volcanosedimentary rocks intruded by numerous and voluminous mafic (gabbro), felsic (granodiorite, syenite) and anorthositic intrusions. Structurally, at least two fold sets and one major fault system (E-NE) are present. Minor fault systems oriented E-NE and N-NW also occur. Mine stratigraphy can be divided into 1) - the hangingwall; 2) - ore zone; 3) - footwall. Hanging wall rocks include: a) green lapilli and blocky tuff b) transition zone c) green mica crystal tuff and d) red dolomitic tuff. Ore zone rocks include: a) bleached mafic tuff b) barren carbonates, c) pyritic dolomitic tuff (?) and d) brick-red syenite. Footwall rocks include: a) magnetic lava (so-called diorite), b) mafic lapilli and blocky tuff and c) alkali basalt, Native gold is the only gold mineral so far identified and it occurs both as free grains in gangue and as micro-inclusions in pyrite. Two geochemical groups were identified in the main rock units: 1) Alkali-rich rocks cons is ting of the ore zone and foot wall rocks and 2) Subalkaline group consisting of the hanging wall rocks. Ore analysis also shows Ba, Sr, W, Zr, REE and F enrichment in the ore zone. Footwall rocks are enriched in Na20. Present geological and geochemical data do not permit a clear interpretation of the formation for the Lac Shortt gold deposit but suggest it is a volcanic-hosted stratabound type. The bulk of the mineralization is associated with an exhalative phase following alkalic, carbonic, hydrothermal activity and part of the mineralization is associated with a late intrusive phase.

Jan 1, 1984

By M. H. Colebrook

Nickel laterites contain about 70% of all continental or terrestrial nickel resources; therefore the recovery of nickel from lateritic ores has large economic significance. The processing of lateritic ores involves the preparation and movement of concentrated aqueous suspensions. However due to complex characteristics and non-Newtonian properties, ranging from shear-thinning to shear-thickening and from thixotropic to rheopectic, a basic understanding of the flow behaviour must be developed. This understanding will assist in the development of new plants and the operation of existing plants. The work in this paper involves the characterization of three ore types from the Vermelho ore deposit to categorize them as rheologically simple to complex. Rheological testing was also conducted on pure mineral samples that represent the main minerals in these samples. The results show that the rheological properties of the ore types can be related to the surface properties and physical characteristics of the main mineral constituents.

Jan 1, 2006

By G. P. Gu, B. Fang, R. W. Revie, M. Elboujdaini

Stress-corrosion cracking (SCC) tests were conducted in the near-neutral pH standard solution, NS4, and in an actual soil solution, using four-point bending at high a stress ratio and low frequency conditions very similar to those of operational pipelines. Pitting incubation appeared first and then pitting initiated and grew in both solutions although there were many more pits on the specimen tested in soil purged with 5% CO2 + 95% N2 than in the specimen tested in NS4 solution purged with the same gas. These observations show that samples in soil solution are more susceptible to pitting than those in NS4 solution. When the pit reached a critical size, the increased stress concentration around the pits, resulted in the transition to a crack.

Jan 1, 2005

By D. A. Beattie

Three novel dextrin polymers of varying functional group chemistry but similar molecular weight have been used to depress talc in single and mixed mineral studies. The mixed mineral system was a model sulphide ore consisting of talc, pentlandite, and chalcopyrite. Adsorption isotherms for the three polymers on both valuable and gangue mineral phases were determined to give initial clues as to the ability of the polymers to depress talc. Flotation testing revealed a distinct hierarchy of effectiveness of the polymers in the depression of talc in the single mineral system (MP Dextrin > CM Dextrin > Dextrin TYM), reflecting the observed adsorption affinity and adsorbed amount of the polymers on talc. However, a different order of effectiveness was observed for talc depression in the mixed mineral system (CM Dextrin > MP Dextrin > Dextrin TYM). Competition between the valuable and gangue mineral phases for uptake of MP Dextrin is responsible for its observed decrease in efficiency in mixed mineral flotation. All three polymers were found to be reasonably selective in their action, although at high dosages the polymers began to affect the flotation of the valuable minerals.

Jan 1, 2006

By R. E. Whitehead

"Abstract - Alkali-alumina and MgO-alumina plots are an effective instrument for displaying chemical and mineralogical compositions of altered and unaltered rhyolites and rhyodacites. They reveal that most supposedly unaltered rhyolites, apart from those of Cenozoic age, have undergone losses in Na2O and gains in K2O. The extreme loss of Na2O from highly altered rhyolites immediately adjacent to VMS deposits is strikingly illustrated by alkali-alumina plots. MgO/Al2O3 vs. K2O/Al2O3 diagrams display a strong negative correlation between MgO and K2O that results from the conversion of sericite to chlorite. A similar negative correlation between MgO and whole-rock d18O is apparent on plots of these two parameters. Alkali-alumina plots underscore problems in selecting appropriate precursor compositions required for mass-balance calculations. Molar ratio plots are a viable alternative to such calculations. Sommaire -Les diagrammes alcali-alumine et MgO-alumine constituent un instrument efficace pour la représentation des compositions chimiques et minéralogiques des rhyolites et rhyodacites altérées et fraîches.Ces diagrammes révèlent qu’à l&apos;exception de celles d’âge Cénozoïque, la plupart des rhyolites qualifiées de fraîches ont subi une perte de Na2O et un gain de K2O. L’intense perte en Na2O que l’on note dans les rhyolites fortement altérées associées aux gîtes de type SMV est particulièrement bien mise en évidence par le diagramme alcali-alumine. Le diagramme MgO/Al2O3 vs. K2O/Al2O3 montre une forte corrélation inverse entre le MgO et le K2O due à la conversion de la séricite en chlorite. Une corrélation inverse analogue entre le MgO et le d18O de la roche totale s’observe sur un graphe comparant ces deux paramètres. L’usage du diagramme alcali-alumine fait ressortir combien il peut être difficile de choisir un précurseur de composition appropriée pour des calculs de balance de masse. Les diagrammes de rapport molaire constituent une alternative à de tels calculs."

Jan 1, 2006

By S. Kelebek

Batch flotation tests were carried out using samples from stockpiles that were up to 1.5 months old as well as fresh samples oxidized in the lab for up to six months. Head grades and size distributions of samples were equalized whenever possible. The samples from stockpiles and oxidation experiments produced inferior nickel grade-recovery compared to the fresh sample. The poorer grade-recovery performance was attributable to two factors. First, a significant dilution effect was observed due to complete flotation of pyrrhotite. Secondly, the same stockpiling conditions caused nickel losses that were attributable to non-floatability of some pentlandite. Application of a high pH of 10 compared to the regular pH of 9.2 slowed down pyrrhotite flotation kinetics, but was not able to prevent complete flotation after 8 minutes. The samples oxidized in the lab did not match full characteristics of stockpile samples. They provided somewhat better selectivity for pentlandite. Some correlations were observed on a qualitative basis between surface characteristics such as elemental sulphur formation, activation and flotation behaviour. Oxidation conditions, which induce floatability on pyrrhotite while causing incremental loss in pentlandite floatability appear to be the root cause of difficulties in the processing of oxidized forms of these ores.

Jan 1, 2006

By AN. Kumar

Two fabrication stages in the manufacture of pipelines are identified as causing significant deterioration of the steel plates, namely cold bending and welding. The objectives of this work include quantitative assessment of the degradation of the quality of the steel plate by the loss of fracture toughness, and an estimation of the safe working pressure. The study was conducted on three API grade steels: X42, X46 and X60. After cold bending by the UO technique, various welding technique were employed for joining of the bend plates along the pipe length. A crack-tip opening displacement parameter (CTOD) was used at the onset of initiation and at the first load maxima as the criterion for assessing the toughness degradation under various fabrication stages and regime (such as WZ, HAZ and parent body). In addition, strength, hardness and impact energy values were determined to check the degree of degradation. Microstructural and microfractographic investigation of the fractured samples were also carried out in the scanning electron microscope (SEM). X60 grade steel plate suffers from CTOD toughness loss by around 38 and 55% after welding and cold bending, respectively, for the conditions studied. A combined effect of the two stages results in a loss in toughness by around 70% for the same steel. In X42 grade, the loss in impact energy ranges from 78 to 35 J due to electrical-resistance welding study (ERW). Crack resistance curves are also obtained for the steels to study the crack growth resistance behaviour and to supplement the information on crack initiation behaviour. The orientation of the pearlite banding, as observed on the fracture plane with respect to notch front and applied loading direction appears to have a strong influence on the microvoid-coalescence mechanism of fracture as well as the toughness values. An integrated analysis of the performance of pipelines, considering all these key factors, is discussed.

Jan 1, 2005

By CIM Mineral Resource

On January 9, 2018, the Canadian Institute of Mining, Metallurgy and Petroleum (CIM) Council formed the CIM Mineral Resources and Mineral Reserves Committee (CIM MRMR Committee), which is a combination of the previous Standing Committee on Reserve Definitions and the Best Practices Committee. As part of its mandate, the CIM MRMR Committee updates guidelines for use by Industry, which include the Uranium Practice Guidelines. The 2024 CIM Uranium Leading Practice Guidelines were adopted by CIM Council on November 22, 2024, and supersedes the 2003 version. The main principles and guidelines relating to preparation of Mineral Resource and Mineral Reserve (MRMR) estimates are provided in the CIM Estimation of Mineral Resources and Mineral Reserves Best Practices Guidelines (MRMR BP Guidelines, as updated from time to time). The MRMR BP Guidelines provide information pertaining to metalliferous and other deposits and many sections are readily applicable to the preparation of MRMR estimates for uranium deposits. However, additional guidance is appropriate for uranium deposits due to the radioactive nature of uranium, and its amenability, in some cases, to in situ recovery (ISR) mining methods.

Nov 1, 2024

The Cadia mine is shifting from the open pit operation to the Cadia East underground block cave. The resulting increase in milled tonnes and the decrease in fines production through shifting to block caving require an increase of over 25% in installed power. This expansion is being accomplished via the installation of up-front crushing and HPGR milling of the ore, with the SAG mill receiving a secondary crushed feed. This design, criteria and rationale for selection is presented. Over the coming years, the mine will further expand capacity. The target is to accomplish this with minimal addition of installed power or use of fresh water. This presents a challenge that epitomizes the future constraints on our resource dependent and intensive industry. The approach and proposed options to this longer-term expansion are also presented.

Jan 1, 2012

By H. Jung

The microstructures and grain sizes of nanocrystalline Co and Co-1.1 wt % P alloys were characterized by X-ray diffraction. The corrosion properties of as-deposited and annealed Co-l.l wt % P alloys and pure nanocrystalline Co were studied in a deaerated 0.1M H2SO4 solution using electrochemical measurements and XPS surface analysis. Potentiodynamic polarization testing and impedance measurements revealed that an addition of P to pure nanocrystalline Co improved the anodic-corrosion resistance, however, this enhanced corrosion resistance was compromised by the heat treatment process at 350 and 800°C. The corroded surface of annealed nanocrystalline Co-1.1 wt % P at 350°C exhibited a more porous P-enriched layer compared with the as-deposited case. A sample annealed at 800°C corroded uniformly showing second-phase precipitates. The enhanced corrosion resistance of as-deposited nanocrystalline Co-1.1 wt % P was attributed to the elemental P on the surface that acted to hinder the anodic dissolution kinetics of surface Co following an initial selective dissolution of Co. However, at a higher anodic overpotential region, the superior corrosion resistance of Co-l.l wt% P alloys did not last because of the formation of a non-protective surface film consisting of mainly hypophosphite and phosphate as well as elemental P.

Jan 1, 2005

Adsorption of guar gum was investigated on model minerals typically found in water-insoluble slimes of potash ores. The ionic strength of the adsorption mixtures was varied from distilled water to saturated NaC1 and KC1. The tests were also performed using a saturated brine. The adsorption density of guar gum on illite, dolomite, and kaolinite was found to be not only a function of total ionic strength but also of the type of electrolyte present in solution. Generally, the adsorption of the polymer on the clay minerals was higher in KC1 solutions than in NaCI, but the differences gradually disappeared when the electrolyte concentration approached saturation. The results were analyzed in terms of chaotropic (K ) or kosmotropic (Na&apos;) properties of background counter-ions and their different behaviors at the hydrated mineral-water interface. Guar gum adsorption on dolomite was related to the presence of calcium and magnesium sites on the mineral surface, and to the cis-configuration of OH groups of mannose units. Based on viscosity measurements, it was suggested that guar gum macromolecules form entanglements in NaCI solutions (and distilled water), but individual molecules exist in KC1 solutions thus creating different modes of adsorption of guar gum from concentrated NaCl and KCl solutions.

Jan 1, 2006

By Martin P. Raffield

Placer Domes? Campbell Mine, situated in northwestern Ontario, is undergoing an assessment of the efficiency of the operation which is necessitated by the low gold price and a reducing ore reserve grade. A decision has recently been taken to move away from a functional based departmental structure (underground, engineering, geology, etc.) towards a team-based system where crews, engineers, geologists and supervisors are responsible for the planning and operation of a particular area of the mine. The objective is to improve communication and understanding of the goals and achievements and to ensure a forum is available for the generation of ideas. It is intended to increase the accountability and decision-making ability of the teams in an effort to achieve the mines? safety and production targets. This paper presents a critical review of the progress of this organisational change process and its successes and failures at the time of writing.

Oct 1, 2001

By D. J. Wesolowski, D. A. Palmer, P. Bénézeth, S. Hilic

The equilibrium solubilities of gibbsite, Al(OH)3, and boehmite, A1OOH, have been extensively studied in our laboratory from 30 to 90°C, and 100 to 300°C, respectively, to ionic strengths of 5 mol.kg-1 (NaC1) over a wide range of pH. The resulting solubility constants have been treated with consistent empirical models that incorporate appropriate experimental data taken from the literature. These studies were initiated in part to understand and quantify scale formation in geothermal fields as a result of fluid re-injection from electric power generating plants. Most of the experimental results were obtained through application of a unique potentiometric method that allows for rapid, precise measurement of the in situ pH and allows the approach to equilibrium to be monitored from under- and super-saturation. The experimental program was extended to deal with more basic solutions (e.g., five molal NaOH), in which the dissolution of boehmite was measured for application to the refining of bauxite by the Bayer process. More recent results in strong caustic solutions at temperatures below 90°C were obtained to investigate the dissolution of aluminum-containing sludge from holding tanks at the Savannah River waste reprocessing site. In this case the solubility enhancing effects (kinetic and equilibrium) of triethanolamine were also established and quantified. Finally, potentiometric solubility experiments were conducted (50°C in 0.l mol-kg-1, NaCl) on aluminum alloy sheets to identify mainly the nature of the aluminum oxide/hydroxide surface layer formed under these conditions.

Jan 1, 2004