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By K. Ebrahimi-Nasrabadi

The dependence between the extent of conversion of cryptocrystalline magnesite to caustic magnesia was studied experimentally in the temperature range of 400?1200 °C and for calcination times up to 8 h. A TGA?DTA analysis showed that decomposition begins at temperatures as low as 340 °C and is completed at 600 °C. Measurements of specific surface area (SSA), iodine adsorption number (IN), crystallite size, and loss on ignition were carried out to characterize the product quality. It was found that while all the parameters are dependent on the extent of calcination, densification of the product caused by grain coarsening affects their final values. As a consequence, SSA and IN went through a maximum with time. The study showed that high quality caustic calcined magnesia can be produced in a narrow range of temperature (600?650 °C) and time (1?4 h). Medium quality caustic calcined magnesia can be made within a wider range of parameters.

Aug 1, 2013

By David Sanscartier, Elizaveta Petelina, Alexey Klyashtorin

This paper provides an overview of the radiological risk mitigation approach applied by the Saskatchewan Research Council (SRC) for the remediation of 35 legacy uranium mine sites in northern Saskatchewan where uranium exploration and extraction took place in the 1950–60s. Mining activities resulted in an irregular increase of the gamma radiation dose rate (up to 18 μSv/h). The radiological objectives for the sites include a gamma dose rate at a spot (<2.5 μSv/h above local background), and the dose rate averaged over a hectare (<1 μSv/h above local background). These objectives are generally achievable at the impacted sites through the installation of shielding soil cover. This method may be impractical for site areas with rough terrain (e.g., steep slopes) and/or difficult access. A risk assessment approach is applied to determine if these areas can be safely left uncovered or if additional mitigation measures should be implemented. The risk assessment approach is based on two factors: (i) the ambient radiation dose rates collected through gamma surveys, and (ii) actual land use data collected through various surveys of activities of local community members at the sites. Exposure scenarios based on four land uses are applied to estimate a potential annual dose load for members of the public. The estimated doses are compared with the criterion of 0.3 mSv/a recommended by the Canadian Guidelines for the Management of Naturally Occurring Radioactive Materials (NORM). If the criteria are not satisfied, a mitigation plan is developed, and post-remediation gamma levels are modelled using GIS tools to evaluate the performance of the proposed mitigations. The proposed approach allows the team to optimize resources for the site remediation so that public exposure to NORM are as low as reasonably achievable after remediation.

Jan 1, 2020

By W. B. Timm

Introduction In preparing this paper on Recent Developments in Gold Milling Practice, the idea occurred to me that possibly the best way to deal with the subject would be to take you in thought on a visit to the principal gold mining camps of the Dominion, starting at the east and finishing up in the west, and noting, as we go, the outstanding improvements that have been made in the last few years in the practice of gold milling. Before beginning this tour, I desire to emphasize the debt this country, and particularly our mining industry, owes to that body of trained and experienced men, little heard of, but who, working quietly on their problems, are responsible for these improvements. The metallurgists, to whom I refer, have solved many difficult problems for the mining industry, in connection with the treatment of our complex ores; for instance, the silver-cobalt ores of the Cobalt district, the gold ores of the Porcupine district, the gold-telluride ores of the Kirkland Lake? district, the copper-gold ores of Noranda, the arsenical-gold ores of the Beattie mine, the copper-zinc ores of Flin Flon, and the lead-zinc ores of Kimberley. In doing so, they have maintained the high technical standards of the profession, and the practices thus evolved are noteworthy for their high degree of efficiency. When the price of gold increased from $20.67 to $35.00 an ounce, what had formerly been thought to be a low tailing became almost an ore, so that the metallurgists are now busily engaged upon the problem of putting this railing back in its proper place of being a tailing once more, or from its value, at the present price, of anywhere from 50 cents to a dollar or so per ton, to a few cents per ton. Owing to the changing prices of the metals in the world&apos;s markets, still greater improvements in metallurgical practices are imperative. An important contributory factor towards improvement in ore dressing is the aid furnished by the microscope in the examination of ores and mill products. By making possible the determination of the mineral constituents of the ore, their association, and grain size, it gives the investigator a knowledge of his problem, before he does any actual test work. In the Mines Branch laboratories at Ottawa, its use has enabled us to predict how an ore should respond to various methods of treatment.

Jan 1, 1935

By James D. Hall

THE Dome ore-bodies are more or less isolated and are mined. by shrinkage stoping. An interwoven system of veins is mined at Hollinger &apos;.1.nd requires close filling. Deep mining is the problem at McIntyre. Dome ore contains a large amount of free gold, which is recovered on blankets. An all-cyanide flow-sheet is \lSed in the Hollinger mill. Flotation concentration is an important feature of McIntyre mill operation. Therefore, these three mines afford an unusual opportunity to compare gold mining and milling methods. The purpose of this paper is to describe the conditions existing at the Dome, Hollinger, and McIntyre mines and to outline the mining and milling practice at each property. Figures 3, 4, 5, and 7 are reproduced from the Canadian Mining ]011rna/, September, 1935 (Young, A. W., Mining at Hollinger), and Figures 8 to 11 from the Engineering and Mining Journal, November, 1933 (Keeley, D. E., Development and Mining at McIntyre). The photographs (Figures 6, 12, and 13) are by The Canadian Government Motion Picture Bureau. Diagrams of the several mill flow-sheets, which formed a part of the original paper, are not reproduced here. They will be found in Dorr&apos;s Cyanidation and Concentration of Gold and Silver Ores.

Jan 1, 1938

By F. J. Alcock

The Appalachian region of Canada comprises the three maritime provinces; Nova Scotia; New Brunswick; and Prince Edward Island; and that; part of the Province of Quebec lying south and east of Logan's fault. This; major thrust runs in a gently curving line from lake Champlain to Quebec; city and thence down the valley of the St. Lawrence to pass between Anticosti; island and Gaspe peninsula. To the northwest lies the St. Lawrence; Lowland division of the Interior Plains geological province; a region underlain; largely by early Palxozoic strata; which for the most part lie horizontal; or with low dips; where faults occur they are predominantly of the normal; type; and only locally are the beds cut by intrusive rocks. To the southeast; on the other side of the fault zone; an entirely different set of conditions is; encountered. There; Lower Devonian and older strata stand at high angles; are sheared and thrust faulted; and are intruded in many places by granitic; igneous bodies. The present paper is designed to outline briefly the geological; and structural history of this geological province and to emphasize; the part that structural conditions have played in connection with mineral; deposition.

Jan 1, 1954

By N. Wachgama, J. P. T. Kapusta, R. U. Pagador

The Thai Copper Industries smelter (Thai Copper) is located some 200 km southeast of Bangkok near the MapTaPhut deep sea port in one of the industrial centres of Thailand. Although construction of the complex started in the mid 1990s, the smelter, acid plant and refinery were completed in 2004. Thai Copper is a state-of-the-art copper smelter processing imported concentrates with a total yearly capacity of 165,000 tonnes of cathodes. It employs the El Teniente Technology where concentrates are blended and smelted continuously in a primary smelting reactor to produce high grade matte or white metal. The white metal is converted in batches to blister copper in Hoboken siphon converters equipped with Air Liquide Shrouded Injector (ALS I) Technology for sonic injection of oxygen enriched air. Final refining is carried out in two anode furnaces prior to anode casting and electrorefining. Thai Copper and Air Liquide Canada executed a technical assistance agreement in late 2005. Pre-commissioning of the shrouded injectors took place in July and November 2006 while hot commissioning occurred in December 2006. This paper presents the major technical aspects of the joint commissioning, including the establishment of operating practices specific to shrouded injection converting. Preliminary results of this first commercial implementation of ALSI Technology in copper converting are also provided.

Jan 1, 2007

Keeping the sediment on the mine site and out of the water course is essential from the regulatory, environmental and sustainability perspectives. Regulation of this aspect of mining is embedded in environmental legislation and government receiving water quality standards, and government control has apparently been considered to be the most appropriate method to define mine site discharge standards and the environmental implications of sediment in downstream watercourses. A literature search for guidelines for the site specific design and operation of sediment ponds treating mine site runoff to remove total suspended solids, turbidity and flocculant-induced toxicity, revealed little information on the mining industry?s and government?s roles in defining the ?how to achieve? related to sediment pond design. Is there a need or reason for an industry-driven leadership to clearly define the ?how to? keep the sediment on the mine site and out of the water course? Currently, this issue is addressed in Canada by a federal mining regulation for metal mines which specifies discharge quality for sediment. This paper focuses on the method used in British Columbia, Canada, to regulate and provide a scientific methodology to control the discharge of sediment from mine sites. Management plans relative to this topic are discussed and are considered to have value from the exploration, construction, operation and the onset of closure phases. In addition, the balance and linkage between the erosion control management plan and the sediment pond management plan are discussed in terms of how they may be designed to complement each other to lower the risk of exceeding discharge and receiving water quality standards. If there were an industry-driven standard, or guidance document relative to addressing sediment release, it would benefit mining companies by eliminating the repetitive analysis of this topic for each new mine, mine expansion, and mine modification; also, government may often replace certain aspects of permitting with a regulation, if there is a government/industry established standard defining Best Achievable Technology (e.g. the Canadian Metal Mining Effluent Regulations).

Aug 1, 2013

By N. Behnood, W. Pascheto

"Laboratory wear tests are important tools that can be used for the evaluation of materials for wear applications and mitigation of wear problems in the mining industry. However, laboratory test parameters must be fully characterized and test results must be carefully interpreted if a material selection is to be made. Failure to do so may lead to erroneous conclusions. Suitable lab-oratory tests are valid only if they reflect the field conditions to which materials are subjected. Therefore, it is important to know, in detail, the field conditions, as well as the wear test techniques being considered. It is important to recognize the limitations of the various wear tests and the wear test data published in the literature. This work will review present wear testing technology, including the various wear tests avail-able, wear test equipment and test limitations. Several wear test procedures will be related to common equipment used in the mining industry.IntroductionThis paper will concentrate on non-lubricated wear mechanisms, because they are the most costly to the mining industry. Very frequently we are faced with the task of selecting materials for wear applications or improving existing systems that are giving poor performance. There are plenty of examples in the literature of practical wear cases and ranking of materials for wear applications. It is also very common to find materials manufacturers’ data -sheets listing wear tests results by comparing their materials performances against those of competitors. Much of the published wear data lack the description of the type of wear test, test parameters and the type of wear mechanism to which the data should be applied (if any).Before considering wear test data for a specific problem one should ask which type of wear mechanism is involved? What type of test and what test parameters were used to produce the results? Even if the type of wear tests and parameters are known, how accurate and useful are the published wear data? How are the results related to a particular type of wear? It is important to point out that even the standardized wear tests, such as those in ASTM standards, have limitations. Such limitations are recognized and clearly spelled out in the standards themselves. Basically, wear tests may lead to erroneous results if the test is not able to repro-duce the same wear mechanisms encountered in the field. Therefore, the use of published results may be helpful, as a starting point, but may be of little value for a final material selection.This work will discuss the main types of non-lubricated wear mechanisms encountered in the mining industry. In addition, it will discuss the many wear tests available and their correlation with the various types of wear mechanisms. The limitations of several standardized wear tests and the limitation of using published wear data will also be discussed."

Jan 1, 1997

By George Kellock

Introductory The Alberta Provincial Government has contemplated a revision of the Mines Act for some time past, and it is understood that a definite decision has now been made to do this at the next session of the Legislature. The Operators&apos; and Miners&apos; organizations of the Province have been asked, or at least have been given the opportunity, to submit their views and ideas relative to the proposed changes. The operators have already drafted out a number of changes which they feel would improve the Act from the standpoint of safety and practicability, and this paper has been prepared so that the general membership of the Rocky Mountain Branch of the Institute, which is composed largely of the operating and certificated officials of the mines, might have an opportunity to discuss, criticize, and improve upon the suggested changes which the operators are putting forward.

Jan 1, 1929

By H. J. McQueen

Pyro-reduction of ores to metal products developed markedly through the industrial revolution into the great depression. Nineteenth century resource and environmental sustainability were haphazardly improved by many process changes, although the motivation was primarily reduction in labor, feed stocks and fuel. Some notable achievements were coke and hot air for blast furnaces (later from waste heat stoves), puddling of wrought iron and steel ingot production with convertors advancing into oxygen use and continuous slab, billet and strip casting. Although advances in one sector were often counteracted by fall-backs in others, there was progress in that the resource consumption and pollution per unit of production was decreased. Improvements in the 2 decades following WW2 were mixed but popular notice of environmental hazards forced governments to legislate pollution controls and initiate steps in resource conservation. The energy crisis of the 1970’s saw an industrial energy-saving campaign and legislation of technology assessment procedures. Up until mid 18th Century, the training of iron masters depended on apprenticeship with some formalized knowledge from medieval books such as those of Biringuccio (1540) and Agricola (1556). The advances were very slow partly due to absence of scientific concepts of the smelting process. Nevertheless, some iron masters succeeded in improving the process and described procedures to instruct others. With the surge of steam power and the reverberatory puddling process for ductile wrought iron (WI), machinery changed from wood (iron strap reinforced) to WI machinery. With the clarification of the reduction and oxidation mechanisms by Cavendish and Lavoisier (~1780), productivity in iron production surged. The mechanical testing and microscopy of Kirkaldy (1862) spurred understanding of processing and properties of WI and steel. The various forms of C in steels were determined by chemists at the end of the 19th Century. It also became possible to control metal and slag chemistry in the open hearth furnace. But understanding of the transformations during heat treatment of steel only came in the first decades of the 20th Century.

Jan 1, 2012

By E. L. Bruce

EUROPEAN Russia is mainly a great plain, the average elevation of which is only 600 feet above sea level and the maximum elevation less than 1,200 feet (Figure 1). The main divide between the Arctic ocean and the Black sea and Caspian sea is an indistinguishable topographic feature from which the Dneiper and Don rivers flow southward to the Black sea and the Volga river to the Caspian. The valleys of these rivers are but little below the general level (Figure 2). To the south, this great, rolling plain is broken by a low ridge of Precambrian gneisses and intrusive rocks. The Crimea is an upland from which the descent to the Black Sea coast is precipitous (Figure 3). The Ukrainian Soviet Socialist Republic occupies the southern part of the plain. It is the southwestern unit of the Union, bordered by Rumania and Poland on the west and by the Crimean Soviet Socialist Republic on the south.

Jan 1, 1938

The goal of this presentation is to firstly, review mine effluent permits in a number of regulatory jurisdictions; and secondly, to develop a strategy for incorporating the regulatory requirements into the environmental assessment (EA) process for new mine proposals. The focus was on the province of British Columbia (BC) and their recent initiative on the One Project, One Process initiative. This task was approached by reviewing mine effluent permits for various regulatory jurisdictions and comparing them to BC mine effluent permits. This comparison revealed a variety of approaches for designing mine effluent permits, but there is a common scientific approach, which supports the conclusion that the permitting of mine site discharges can be designed based on a scientific approach. This approach is expected to: (a) achieve sound environmental protection, (b) demonstrate the application of Best Achievable Technology, (c) incorporate sound sustainability approaches, (d) incorporate regulatory objectives, and (e) create efficiencies for the regulator and mining industry. There is an essential precursor to developing a sciencebased effluent permit for which the proponent must provide: (1) the necessary technical assessment information to demonstrate the mine effluent permit application will result in an environmentally protective effluent discharge, to the satisfaction of the permitting agency; (2) the necessary level of detail for essential mitigation pollution control works to demonstrate how they will be operated to achieve the necessary treatment goals; (3) the necessary level of detail for non-treatment mitigation (passive treatment, or passive pollution control); and (4) the necessary level of detail to demonstrate how pollutants will be prevented from being mobilized (or being generated) from ore and waste materials, or, if the pollutant originates from an added milling reagent, how the reagent will be reduced. While (active) mitigation pollution control equipment is more definable in an effluent permit, non-treatment mitigation is more nebulous in terms of defining in a mine effluent permit; it is therefore recommended that appropriate management plans be developed for essential mitigation pollution control and non-treatment mitigation (passive treatment) and submitted with the proponent?s EA/effluent permit application packages. Major deficits in adequate active and passive pollution control will inevitably lead to regulatory impediments to developing a permit and allowing a mine to be developed, although EA processes strive to preclude major permit information gaps; the onus is on the proponent to provide complete information in this area. Hence the importance of EA processes ensuring that the major technical information requirements for effluent permit development are included in the EA phase. Recently, this aspect of the mine EA process has taken on a new role under the political efforts of One Project, One Review Process (Canadian) and One Project, One Process (in BC). These initiatives translate, in part, to ?synchronous permitting? (in BC): effluent permitting, for example, may be initiated shortly after the proponent submits the EA application to Ministry of Environment.

Aug 1, 2013

By Rolf Andreas Lauten, Adam Pratomo, Dani Ramdani, Helminton Sitanggang

A universal challenge for the mineral processing industry is the diminishment of high grade ores. Instead, low grade ores, sometimes also containing problematic gangue minerals is the reality. With lower head grades the industry has to put more effort into processing to maintain the output and achieve suitable recoveries. In an effort to reduce the impact of declining head grade, a biopolymer was evaluated as an additive in the gold leaching operation at Antam Pongkor in Indonesia. Laboratory testing revealed that biopolymer usage lead to an increased gold recovery without apparent negative impact on the other parts of the process. Further plant trials revealed both a recovery increase around 1.3% and higher throughput (9%) in the presence of the biopolymer. Some scenarios that can explain these findings will be discussed.

Jan 1, 2014

By H. C. M. Gordon

IT is essential to the success of any mining op::ration that the roadways through which the material wrought and ocher materials and supplies are to be transported should be kept in such condition that this transportation cart be effected rapidly and without difficulty. The longer the roadway and the greater the tonnage to be taken over it, the more necessary it becomes chat the construction and maintenance of the road be such chat traffic delays can be reduced co a minimum. le is proposed co deal with the development and construction of roadways serving longwall operations and, since a recreating system of longwall is worked, as a rule, only where roadways driven in the solid coal can be readily maintained, the discussion will be confined co advancing longwall roads which are driven through areas from which the coal seam has been totally extracted. In order to construct a roadway through extracted ground in such a manner that it will remain in a state of reasonably good repair without undue maintenance, it is necessary chat everything possible be done to bring the overlying strata co a state of equilibrium as quickly as this can be effected, and the operations should be so planned that future workings will not disturb the equilibrium so set up more than can be avoided. Obviously, the readiest way to obtain a stable roadway is to develop it by tunnelling through a settled waste. However, this cannot always be done, as some of the roadways must be developed and constructed as the walls progress, but level or lateral cut-offs can be constructed in this manner. Main-slope roads can be developed in a similar manner after the coal has been extracted and a waste formed for at !east five hundred feet on either side of the line of the permanent roadway from temporary subsidiary roads developed for this purpose along one or other of the flanks of the waste to be formed. This interval must be obtained in order chat the lacer extraction of the seam will not set up movements in the waste immediately overlying or adjacent to the constructed roadway, thus upsetting the equilibrium of the strata and distorting the road.

Jan 1, 1940

By F. Barriga-Ordonez, J. A. Finch, L. Calzado, S. R. (Ram) Rao

Sludge, formed by lime treatment of acidic drainage and stored in tailing ponds of the Sudbury region, contains 5-7% Ni, mostly in a mix of hydroxides with Fe (~ 10%), Mg (~ 10%) and Cu (-0.5%), and Ca (-3.5%) as sulphate. Investigations were conducted to recover nickel by a 2-stage process. In the first stage, the sludge was leached with sulphuric acid at pH 3.2. About 90% of the nickel was extracted, producing a solution, which contained mainly nickel (2 g/L) and magnesium (3.7 g/L). In the second stage, nickel was separated by treating with ozone which recovered 99% of the nickel in the Ni(III) oxidation state as -85% pure nickel oxide-hydroxide (NiOOH) precipitate. The oxide settled and filtered readily. A potential use of the product in battery making is suggested. The leach residue contained 0.5% Ni making it less toxic for disposal. Some physical properties of nickel oxy-hydroxide and process parameters including ozone consumption will be discussed.

Jan 1, 2005

By Minghao Hu, Hongbo Zhao, Jun Wang, Wenqing Qin, Rui Liao, Central South University

"In the present work, X-ray diffraction (XRD) analysis, X-ray photoelectron spectroscopy (XPS) analysis and electrochemical analysis were carried out to investigate the intermediate species and electrochemical dissolution process of chalcopyrite in the presence of sulfur and iron oxidizing microorganisms. For bioleaching of chalcopyrite by the sulfur oxidizing microorganism Acidithiobacillus caldus, the redox potential was always lower than the appropriate value and chalcopyrite was mainly directly oxidized to polysulfide (Sn 2-), thus resulting in low copper extraction. As for bioleaching of chalcopyrite by the iron oxidizing microorganism Leptospirillum ferriphilum, chalcopyrite was mainly directly oxidized to polysulfide at the initial stage where redox potential was lower than the appropriate value and resulted in low dissolution rate. At the middle stage where redox potential was appropriate (about 350–480 mV vs. Ag/AgCl), chalcopyrite was mainly transformed to intermediate species of Cu2S rather than polysulfide, thus resulting in high dissolution rate. At the later stage where redox potential was higher than the appropriate value, chalcopyrite was mainly directly oxidized to polysulfide which caused the later passivation of chalcopyrite. Finally, a model of electrochemical dissolution process of chalcopyrite in the presence of sulfur and iron oxidizing microorganisms was provided.INTRODUCTIONBiohydrometallurgy is considered as one promising mineral processing technique in processing low grade ores due to the advantages of simplicity, low cost and eco-friendly. Chalcopyrite (CuFeS2) is the most abundant copper-bearing resource, accounting for appropriately 70% of the known reserves in the world, while is recalcitrant to bio-hydrometallurgy mainly due to the coated passivation layer (Klauber, 2008; Li, Kawashima, Li, Chandra, & Gerson, 2013). However, the detailed dissolution and passivation mechanisms of chalcopyrite bioleaching are still uncertain. The microorganisms assisting chalcopyrite dissolution can be mainly classified into three types, including mesophilic microorganisms (e.g., Acidithiobacillus ferrooxidans, Acidithiobacillus thiooxidans and Leptospirillum ferrooxidans), moderately thermophilic microorganisms (e.g., Acidithiobacillus caldus, Sulfobacillus thermosulfidooxidans and Leptospirillum ferriphilum), and extremely thermophilic microorganisms (e.g., Metallosphaera sedula, Sulfolobus sp., Acidianus sp., and Sulfurcoccus mirabilis). Moderately thermophilic microorganisms have a better prospect in the future industrial application of chalcopyrite bio-hydrometallurgy (Olson, Brierley, & Brierley, 2003; Rohwerder, Gehrke, Kinzler, & Sand, 2003). Hence, investigating the detailed dissolution and passivation mechanisms of chalcopyrite bioleaching by moderately thermophilic microorganisms is of important significance, which will provide essential information for promoting chalcopyrite bioleaching by moderately thermophilic microorganisms in laboratory or industrial plant."

Jan 1, 2016

By J A. Gilliand

Mineralogical cross sections of orebodies on the 300-,600- and 900-foot levels of the Coronation mine have been interpreted in terms of centers of mineralization. The maximum concentration of chalcopyrite occurs closest to these centers, with pyrite and pyrrhotite concentrated some distance away. The magnetite concentrations are farthest removed from the centers. A hydrous halide fluid model is established. Attempts to explain the observed mineralogy by the action of temperature gradients on the fluid model were unsuccessful. Likewise, the action of diffusion alone on the fluid model cannot explain the observed mineral distribution. The concept of attenuation is introduced-i.e., the rate of diffusion of a particle species is related to the product r2 I/ M, the attenuation coefficient, where r is the particle radius and M its molecular weight. Attenuation, acting on the fluid model alone, will not produce the observed mineral distribution, but, when considered together with the action of temperature gradients, the observed mineralogy can be well explained by the combined effects of these two processes on the assumed fluid model.

Jan 1, 1965

By Francis Breton, Daniel Larouche, Pierre Heugue, Rémi Martinez

"Nowadays, in order to fit environmental restrictions, automotive markets are demanding cast aluminum alloys working at high temperature (180–300°C). New generations of alloys are required for higher strength components in engine downsizing or start-stop systems which lead to higher loading and higher specific power and stretch current materials to their limits. Recently, transition metals, such as zirconium and vanadium, have been added as alloying elements into an AlSi7Cu3.5Mg0.1 alloy to improve physical, mechanical, thermodynamic properties with the aim of increasing service life of parts. In such alloys, the best mechanical properties are associated with the formation of precipitates through an optimum heat treatment sequence, including: solutionizing, quenching and artificial aging. This study is focused on the modified AlSi7Cu3.5Mg0.1 cast alloy with Mn, Zr and V additions for high temperature application. The characterization of the cast alloy in this study, firstly, helps to evaluate and understand its performance both chemically and structurally according to their physical state: as-cast or as-quenched. Comparison of precipitation kinetics between a binary Al-3.5%wt.Cu alloy and the AlSi7Cu3.5Mg0.1 (Mn, Zr, V) alloy has been characterized by differential scanning calorimetry, TEM observations and micro-hardness testing. The Kissinger analysis was applied to extract activation energies from non-isothermal DSC runs conducted at different stationary heating rates. The study focuses on the impact of the chemical composition such as Si content on the kinetics parameters.INTRODUCTION Pure metal Aluminum shows poor mechanical properties and its malleability is high, that is why alloying elements are added to the mixture before casting to improve physical, mechanical and thermodynamic properties (Javidani, 2015); such as Silicon (Si) for casting properties (castability, cold crack capability, wear resistance, shrinkage behavior), Magnesium (Mg) and Copper (Cu) to generate precipitation hardening systems. Aluminum hypoeutectic alloys (<12% Silicon) with Cu, Mg additions used in the automotive industry for manufacturing mechanical parts (Larouche & Javidani, 2014) are mostly subject, after casting, to precipitation hardening heat treatment (Mohamed & Samuel, 2012) according to specifications and associated standards. The best mechanical properties are associated with the formation of precipitates through an optimum heat treatment sequence, generally including: solutionizing, water quenching and artificial aging (Manente & Timelli, 2011). Hypoeutectic aluminum-copper alloy with amount of Cu around 1 to 4.5wt% is an elementary case for precipitation in heat treatable aluminum alloys. Researchers essentially focused their work on the full precipitation sequence of binary Al-Cu alloy during aging which is presented below."

Jan 1, 2018

By A Frydrychewicz, J. Mirza, J. Lipkowski

The objective of this work was to understand the mechanisms of action of additives, such as thiourea, that enhance gold leaching in thiosulfate solution. The leaching reaction and surface passivation were investigated using linear sweep voltammetry. Leaching currents were determined using analysis of current-potential curves and the mixed potential theory. The gold-electrolyte interface was further characterized with surface enhanced Raman spectroscopy. The results show how thiourea prevents formation of oxysulfur compounds, which passivate the gold surface. Other molecules such as 3- m ercaptopropionic acid and L-cysteine were also studied as possible additives to prevent passive layer formation.

Jan 1, 2011

By D. Hu, L. Matzar, J. Hampton, M. Gutierrez

Nanodarcy permeability is common in many oil- and gas-bearing formations requiring unconventional stimulation technologies, such as hydraulic fracturing (HF), which can connect the isolated hydrocarbon-rich pores with a wellbore through induced fracture networks. Even though a dense induced fracture network is capable of accessing economic amounts of hydrocarbons, much of the rock between and very close to the fracture network is still un-accessed and contains extremely low permeability. Inducing fracture networks into brittle rock can create large amounts of micro failures in surrounding regions that are not connected to the wellbore, as can be seen in Fig. 1(a) from the very wide acoustic emissions (AEs) cloud associated with a narrow fracture generation. It is possible in certain types of rock to increase the effective matrix permeability in localized regions based on the damage associated with the surrounding hydraulic fractures and subsequent high stress concentrations along localized pre-existing potential failure zones. To study this problem, laboratory HF tests were performed at true-triaxial stress state in brittle crystalline rock while monitoring AEs. The AE associated with HF was analyzed for source parameters using the moment tensor inversion method called Simplified Green’s Functions for Moment Tensor Analysis (SiGMA). Using the moment tensor for each individual AE event, the mode of failure was determined. Crack slip directions and crack face normal directions were also found, along with the relative volume of individual micro failures as well as a damage parameter. The associated source parameters were used to classify differing regions of damage in the sample induced from HF and correlate these regions of differing damage to the effective drainage region. Shown in Fig. 1(b) is a near-wellbore (NWB) region that contained three times larger average relative volumetric deformation of individual tensile AE events than the average tensile AE event volume from the entire sample. Because of the large difference in micro fracture volumetric deformation for the NWB region compared to the entire sample, predictions of HF induced damage must be included in reservoir drainage predictions.

Jan 1, 2015