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By J. A. du Plessis, C. Dorfling

Selenium, tellurium and other precious metals (OPMs, namely Rh, Ru and Ir) dissolve in the final leaching stage of base metal refineries. Se and Te are typically removed from the copper sulphate leach solution by precipitation with sulphurous acid. Recovery of dissolved OPMs is desirable because it will reduce OPM inventory and losses. Thiourea is an effective OPM precipitation reagent, but yields insufficient Te removal. Copper is known to enhance Te precipitation when using sulphurous acid as precipitation reagent. The primary objective of this project was to evaluate whether simultaneous precipitation of Se, Te and OPMs using thiourea with metallic copper as precipitation reagents is possible. Batch precipitation tests were performed to evaluate the effect of temperature (50 – 70°C), thiourea addition (160 – 430% excess) and copper addition (2 – 8 g/L) on Se, Te and OPM precipitation. Increasing the temperature from 50°C to 70°C resulted in an average increase of 55.6 percentage points for Se precipitation and 13.5 – 23.5 percentage points for OPM precipitation. The copper addition did not have a significant impact on the precipitation behaviour. Increasing the thiourea addition increased the precipitation of Se and Te, especially when the copper addition was low; Rh and Ru precipitation also increased with up to 10 and 12 percentage points, respectively. Despite these observations, the precipitation of Se was significantly faster when no thiourea was added. It is not currently clear why thiourea appears to inhibit the Se precipitation by reaction with metallic copper. In general, Te precipitation was low (less than 30%) at the conditions investigated. Simultaneous precipitation of Se, Te and OPMs at temperatures below 80°C does not appear to be a viable option; a multiple stage operation for sequential removal of Se and Te with copper followed by OPM precipitation with thiourea would be required.

Jan 1, 2016

By H. R. Stockford

"A pyroxenite-carbonatite complex containing extensive pyrochlore mineralization was discovered during January, 1966, within an exploratory license area held by Consolidated Morrison Explorations Limited. Located 32 miles south of Moosonee, Ontario, the deposit was found under 100 feet of glacial till and Paleozoic sedimentary cover using airborne and ground magnetometer surveys. Exploratory and detailed drilling, totalling 47,625 feet in 85 holes, was completed in outlining the deposit to a maximum depth of 900 feet. Pyrochlore reserves are estimated at 62,000,000 tons averaging 0.52 per cent Cb,05 to a depth of 825 feet. Included in this tonnage is a high-grade section containing 10,000 tons per vertical foot grading 0.82 per cent Cb20 5• The deposit is still open at depth and the intrusive complex has by no means been fully explored.The columbium (niobium) mineralization occurs in a lineated calcite-dolomite host rock which has been intruded along a fault zone within a northeast-trending granulite belt. Potassium-argon dating indicates an age of 1655 million years.Preliminary studies suggest that the complex was intruded in a series of pulses in the form of a partially crystallized mush. The James Bay intrusive is unusual in that it is linear in form and contains only two main rock types - p•yroxenite and carbonatite. Nepheline-bearing syenites and associated rocks are notably absent. Moreover, the pyrochlore is essentially non-radioactive and free from many of the impurities generally associated with other pyrochlores. A test shaft to investigate soil conditions and to provide a 250-ton bulk sample was completed during 1968. Subsequent pilot-plant operations indicate that good quality pyrochlore concelttrates can be produced from this deposit."

Jan 1, 1972

By K. C. Corin, Z. G. Song, J. Y. Liu, M. W. Zhang, State Key Laboratory of Mineral Processing-BGRIMM, J. G. Wiese

"In the present study effect of grinding media on flotation of two mineral systems have been investigated, viz. sulphide minerals (including a pure chalcopyrite and pyrite mineral, and two different base metal sulphide ores), and oxide minerals (quartz, hematite and cassiterite). It was shown that mild steel media milling produced lower recoveries in the case of chalcopyrite and pyrite, as compared to the case of milling using ceramic media. For oxide minerals, the effects of using mild steel media as opposed to ceramic media were not as significant as was for the sulphides, although, after mild steel milling, at acidic pHs their recoveries were significantly reduced. For two base metal sulphide ores, viz. Nkomati and Dexing ores, the differences resulting from different milling media , although marginal, were opposite for each of these ores.For oxide minerals XPS showed that oxides and hydroxides of iron (e.g. FeOOH) adsorbed on the surfaces of the minerals. In the case of the Nkomati ore, adding Fe2+ or F3+ ions after milling with chrome steel media resulted in reduced talc (gangue) recovery, but increased water recovery and reduced concentrate grades. Further investigations are currently in progress to examine the Fe ions effect on the talc surfaces and froth properties.INTRODUCTIONGrinding of ores is necessary to liberate the valuable minerals from its gangues to allow for their selective recovery during mineral processing such as flotation. The grinding process inevitably involves contact of the ores with the surface of the grinding device and the grinding media. Accompanied by grinding, several phenomena can occur including the grinding medium wear, formation of precipitated species on the ore surfaces, chemical reaction, galvanic effects, changes in the Eh of solution, etc. There is a considerable body of literature on the differences observed in the flotation of various ores after milling using various grinding media. Laboratory studies have used balls or rods made from mild steel, ceramic, stainless steel or chrome steel to investigate the effects of different grinding media on mineral flotation. It is found that the interactions between the ore and the grinding environment can affect flotation separation of sulphide (Wei and Sandenbergh, 2007; Bruckard, 2011), oxide (He et al., 2014) and carbonate minerals (Song, 2009 and 2010). For example, mild steel milling produces relatively high concentrations of Fe ions in the pulp, affecting the recoveries of minerals compared to the case of ceramic media. On the other hand, the stainless steel media or chrome media are reported to be beneficial to the recovery of sulphides, when compared to the cases of using mild or carbon steel media (Rey and Formanek, 1960; Peng et al., 2003a,b; Huang and Grano, 2006; Bruckard, 2011). It is not clear, however, whether these Fe ions may affect the surface properties of the minerals involved or the general pulp/froth behaviour and hence their floatability. In addition, in the study of an low-S PGE ore carried out by Miettunen et al. (2012), forged media grinding in the CO2 atmosphere led to the highest Pt and Pd grades and recoveries, but the high chrome grinding media gave lower flotation recoveries than those using the forged media."

Jan 1, 2016

By J. C. Murray

Introductory: In dealing with a topic so large, one that involves such a multiplicity of details, and that also has certain controversial aspects, it is quite impracticable within the limits of this article to touch upon many most interesting phases and incidents. Also, to bring out the actual truth, it is necessary to make certain categorical statements. The writer believes that all such statements made here-under are supported by facts. Again, however, it is out of the question to cite all the proof. The writer, therefore, will gladly answer any pertinent criticisms or questions and thus supplement the unavoidable brevity of this paper. Controversial points will take care of themselves. Historical: For present purposes the history of gold mining in Nova Scotia may best be summed up in a very few paragraphs, in some of which the writer quotes freely from recent reports compiled by himself. The first material discovery of gold was made in the year 1860. As this and rapidly succeeding discoveries were looked upon as bonanzas, the claims were fixed at a size of 20 by 50 feet, and a yearly rental of $20 was charged. Later the claims (areas) were increased in size to 50 by 150 feet. In the year 1866 a temporarily successful company, so we are informed by a contemporary writer, owned a mill and mining plant worth $6,000. As this fact is cited with admiration, it is apparent that most of the mining and milling must have been done in a very primitive manner indeed.

Jan 1, 1926

By H. Westengen

The AE alloy family exhibits remarkable combinations of properties when utilized as high pressure die castings. This performance relies on the fact that the rapid cooling rate resulting from the direct contact between the molten alloy and the steel die walls effectively refines the structure through rapid solidification. Furthermore, the rare earth additions modify the solidification pattern, dramatically reducing the solidification interval. A solid shell forms at temperatures exceeding 500C, reducing the tendency for die sticking and inverse segregation. As a result, the die castability is excellent, giving parts with a smooth and shiny surface. Unlike other magnesium die casting alloys developed to improve elevated temperature creep properties, AE alloys do not suffer from the commonly observed tendency to introduce brittleness. This feature is attributed to the fact that the massive magnesium- aluminium intermetallic phase is substituted by a finely dispersed lamellar structure of Al-RE intermetallics. The resulting combination of excellent elevated temperature properties and good ductility, as well as excellent corrosion resistance, means superiority of these alloys for demanding automotive engine and chassis applications.

Jan 1, 2006

By Jr. Carmichael

"THE MAYO AREA was prospected as early as 1887. The first major activity started in 1898, when the Stewart River and its tributaries were examined for placer deposits, and in succeeding years the district became a small producer of placer gold. The first discovery of the lead-zinc-silver mineralization which has become the main interest of the district occurred in 1906, when a vein was found in the canyon of Galena Creek on the northwest slope of Galena Hill. This deposit was later known as the Silver King mine. In 1919 further discoveries were made on Keno Hill, approximately 15 miles east of the Silver King, the most important being the No.9 vein. Directly or indirectly, these finds are attributable to the search for placer gold, as galena was frequently found in the stream gravels.The 1919 Keno Hill discoveries were acquired by Yukon Gold Co. and operated through a subsidiary, Keno Hill Ltd., from 1920 to 1923. Most of the production came from No.9 vein. In 1921 Treadwell Yukon Corporation entered the field and acquired the Ladue mine. This company continued to operate for 21 years. It acquired in succession the Ladue, Sadie, Friendship, Lucky Queen, Elsa, Silver King, and Calumet mines. Its record of successful operations is very largely the achievement of the late Livingston Wernecke. Under his direction, the Treadwell Yukon Corp. produced metals with a gross value in excess of $21,000,000, in the face of greater transportation problems than exist today and with considerably lower metal prices.Treadwell Yukon ceased operations in 1942. Its entire assets were acquired in 1946 by United Keno Hill Mines Ltd., which has substantially increased the original holdings. It has drawn the bulk of its production from the Hector mine, adjacent to the Calumet. The Hector was not developed by Treadwell Yukon because of legal disputes among the vendors. It has proven to be the largest deposit yet discovered in the district."

Jan 1, 1949

By S. Steinlechner

"Today the common recycling technologies of automotive catalysts are either energy intensive pyrometallurgical processes generating huge amounts of residues or hydrometallurgical ones which have to cope with effluent problems. Next to that, other valuable metals beside PGMs such as rare earths from the wash coat are not recovered.Therefore, the present paper introduces a hydrometallurgical concept developed in cooperation with the company Railly & Hill for the recovery of the PGMs as well as cerium from the wash coat of the catalysts in a closed loop. Next to the process concept, the required parameters for the different steps are discussed, including the chemical reactions, leaching efficiencies and mass flows, which form the basis for an economic estimation of the concept.Contrary to the pyrometallurgical recycling where the monolith is completely melted down to slag which is typically dumped, in this process the remaining monolith forms an utilizable product for the ceramics/refractory industry. As a result of the closed loop of the leaching media an environmentally friendly process was developed from which nearly no new residues or effluents are generated, with a sustainable usage of chemicals."

Jan 1, 2014

By Stanley W. Holmes

"The discovery of extensive uranium mineralization on the Pronto property in April 1953 initiated a program of staking, exploration, and development unparalleled in Canadian mining history. Within twelve months of the discovery hole, sufficient ore had been blocked out to merit a 55-million-dollar contract with Eldorado Mining & Refining Co. On October 15, 1955, two years and four months after discovery, Pronto went into production with a mill rated at 1,000 to 1,500 tons per day. The property is on the southern edge of the Algoma uranium district, 10 miles east of the town of Blind River and close to the Canadian Pacific Railway and Highway 17. Docking facilities for Great Lakes steamers are avail-able at Spragge, 4 miles to the east.The data and conclusions presented in this paper are based on field studies, drill hole information, and underground development. The ideas of ore genesis are those of the writer, and will undoubtedly be modified as more detailed studies and research are carried out. Because of security regulations, information pertaining to grade and tonnage will not be discussed.GeologyThe general geology of the Algoma basin has been outlined in a pre-ceding paper (Joubin and James). The description below is concerned essentially with the rocks most closely associated with the Pronto deposit. They may be grouped in three structural and lithological units: (1) the pre-Huronian basement, (2) the Mississagi formation, the lowest member of the Huronian sediments lying unconformably on the basement, and (3) a series of basic intrusives cutting (I) and (2). Most of the uranium mineralization occurs in a quartz-pebble conglomerate forming the basal member of the Mississagi quartzite."

Jan 1, 1949

By W. G. Millar

Until a fire occurs, insurance and prevention work are often looked on as unavoidable necessities, but as insurance is back of all business credit, it is essential to know that in case of damage money will be available to cover the loss; while the interruption of production, often caused by a fire, brings home the realization that if prevention work avoids such an interruption, it is well worth while. Fire insurance is a legal contract guaranteeing the payment of large amounts to an owner, but it is possible there is no other important contract that receives so little consideration. Although previously carried on elsewhere, it is only of recent years that insurance engineering has been actively followed up in Canada, with inspections of an owner's property carried out for his benefit. Now inspections of this kind are made, advice on fire prevention and protection work ?is available, reports with recommendations with regard to the above are furnished periodically, and with this method applied the owner receives the broadest possible cover and security at the lowest cost. Rates are set by the underwriters by rating schedules which charge for defects in a building and allow credits for protection and other favourable features . These schedules are based on the past record of loss of mining properties as a class, so that a fire in another mining property indirectly affects you, but the amount paid is reduced in proportion as your property is improved. The writer feels, from personal experience, that there is no industry where fire prevention receives more attention than the mining industry, and it is a pleasure to advise that, due to this co-operation, some reduction in the basis rates for mining risks is now being made by the underwriters.

Jan 1, 1928

By John C. Lyons

"The Wabana iron ore deposits occur as flat-dipping beds of oolitic hematite and chamosite, of Lower Ordovician age, which outcrop for 3 miles along the northwest coast of Bell Island, Conception Bay, Newfound-land, about 16 miles from St. John's.The deposits occur in three zones, Upper, Middle, and Lower beds, separated respectively by 30 feet and 215 feet of shale and sandstone. They are primary sediments laid down in a shallow tidal basin by the precipitating action of a marine environment on iron-rich fresh waters flowing into the basin.The ore-bearing zones, while of wide areal extent, are not uniform beds of hematite that can be mined wholesale. The action of waves and currents during sedimentation; the delta pattern, velocity, and transporting power of streams flowing into the basin; the contours and oscillations of the sea bottom on which the sediments were laid have all been fundamental in the emplacement of richer and thicker mineable sections, and of lean zones so intercalated with shale as to be unmineable.The preservation of the deposits is due to their location in the Conception Bay syncline and to a considerable upthrust of the country east of the bay in post-Ordovician time.The hematite deposits were first recognized as such in 1892, and soon after were acquired by the Nova Scotia Steel and Coal Co. They are now being mined by Dominion Wabana Iron Ore, Limfred, a wholly owned subsidiary of the Dominion Steel and Coal Corporation, Limited. Production started in 1895, and up to the end of 1955 totaled 58,588,516 long tons of hematite ore, having an average dry analysis of about 51 5 per cent iron, 11 8 per cent silica, 0·9 per cent phosphorus, and l ·5 per cent moisture. About 40 per cent of the total tonnage mined has come from surface stripping and on-shore mines. These areas have now been almost completely depleted, and operations are confined to submarine mines extending for two miles off shore under the waters of Conception Bay. Three sub-marine slopes are currently in operation, Nos. 3 and 4 working in the Lower Bed and No. 6 in the Middle Bed. A general picture of the workings is shown in isometric projection in Figure 1. Submarine mining has been entirely by the room-and-pillar method, with an extraction of 60 per cent. The deepest workings, at a vertical depth of 1,850 feet below sea-level, have a rock cover of about 1,500 feet. No mining is done in areas where the rock cover is less than 200 feet. To date mining has explored six square miles of a potential area that may exceed 50 square miles."

Jan 1, 1949

By C. Acuña

The case is presented that the key role of frother is control of bubble size in the pulp zone. Compared to water alone, the addition of frother produces a narrower distribution and finer bubble size. An empirical model is presented for bubble size as a function of frother type using a normalized concentration. The model provides a benchmark for assessing operations. There is no agreed upon mechanism of how frothers act to reduce bubble size. Prevention of coalescence is a common explanation and this action is illustrated. The case against the 'coalescence' model alone is presented and a breakup mechanism is introduced based on pilot cell and single bubble studies. Phenomena associated with bubble shape, velocity and surface flows are used to illustrate the force associated with surface tension gradients. Breakup mechanisms resulting from this force are proposed. The concept can be extended to high salt concentrations which also promote small bubbles.

Jan 1, 2007

By Alireza Golabchi

The AEC (Architecture, Engineering, Construction) industry is an information intensive industry and all related processes employed during different phases of a project, including planning, designing, building, manufacturing, occupying, and maintenance, involve vast amounts of data that is used for a wide variety of purposes. Building Information Modeling (BIM) is a powerful shared knowledge resource which stores this data to support decision making about a facility through all these different phases in its life cycle. Nowadays, BIM is mostly used in the design and construction phases while it can also be highly beneficial beyond those stages. For example, in the Operation and Maintenance (O&M) phase, BIM could be used for automated facilities management or robotic inspection to provide semantic knowledge for navigation. For any implementation not related to the original intent of the BIM (design), organizations need to be able to represent their project data in a common interpretable form, which provides the possibility of an accurate exchange of data among different software products and platforms, known as interoperability. This study has investigated the current state of interoperability between software products used as Building Information Modeling tools. The main focus has been on a popularly used format for BIM models, Industry Foundation Classes (IFC), since it has been specifically developed to enable standardized data exchange. The research methodology involved a comprehensive literature review and the gathering of all fragmented prior research related to the field in order to develop a consistent understanding of the current state of knowledge. This was accompanied with a detailed case study that evaluated and compared two dominant pieces of BIM software, Revit and Bentley, and examined their interoperability strengths and weaknesses while using the IFC format.

Aug 1, 2013

By The Staff

Introduction In this paper it is proposed to discuss briefly some of the problems confronting the management of a gold mine in choosing a method of milling to recover the gold from various classes of ore. In order to simplify the discussion, the more common types of gold ores are classified from a metallurgical point of view as follows: Class 1?A: Free-milling ores which require only relatively coarse crushing. B: Free-milling ores which require finer grinding to release the gold. Class 2?A: Gold ores which contain the gold partly in the flee state and partly associated with a small amount of iron sulphide, and which do not require fine grinding. B: Gold ores similar to 2A, but which require fine grinding. Class 3?A: Gold ores containing copper in quantities insufficient to interfere to a serious extent with cyanidation. Gold ores containing copper in sufficient quantity to interfere with cyanidation but in which a large proportion of the gold is in the free state, the remainder being chiefly associated with the copper mineral, chalcopyrite. Gold ores containing copper and other sulphides, such as pyrite, etc., in which the gold is principally associated with these sulphides.

Jan 1, 1931

By V. L. Mitsopoulos

This paper provides a summary of tailings disposal techniques and the improvements that have been made through the introduction of thickened tailings disposal. The general properties and characteristics of thickened tailings are described, as is a design process for selecting appropriate technologies for thickening, pumping, transporting and storing tailings. The factors affecting the selection of an appropriate disposal site and operational considerations for the effective utilisation of tailings storage areas are also documented.

Jan 1, 2006

"A numerical procedure based on Smoothed Particle Hydrodynamics (SPH) is developed for rock blasting phenomena involving multiple intersecting joints. In this procedure, an elasto-plastic damage constitutive model has been applied in the framework of SPH to simulate yielding response of the surrounding rock medium. In this paper, a square shape rock medium with centrally located emulsion explosive in a borehole is numerically blasted with and without the presence of two diagonal rock joints. The model is simulated by assuming all four sides of the rock medium as free surfaces. The paper elaborates the propagation of stress wave, expansion dynamics of gaseous products, and development of fracture, fragmentation of the medium and dissipation of energy due to damage.INTRODUCTIONDamage prediction of rock mass and its mean fragmentation size are of important to design blast parameters for a given explosive. Current blasting practice solely depends on empirical relationships between fragmentation sizes to those blast design parameters while mathematical descriptions of the physical laws governing the process of rock blasting are limited. A constitutive relationship based on properties of explosives and rock mass is of special interest because of its capabilities in describing the key features of rock fracture and fragmentation, resulting in understanding of the physical process involved in rock blasting. It is well known that blast-induced damage and fragmentation of rock mass occur due to detonation induced stress wave and product gas driven fracture propagation. Nevertheless, the fundamental mechanism of the failure process and the behavior of rock characteristics under these two different loading are not well understood in many cases, which are closely related to growth of fractures and interaction of cracks under different loading conditions.Continuum damage mechanics is considered to be appropriate to describe the failure process under such high-amplitude stress wave. Based on this approach, several theoretical models have been developed to analyze the dynamic damage of brittle material such as rock and concrete with microstructure (Chen, 1999; Taylor et al., 1986; Wu et al., 2004; Yazdchi et al., 1996). These models are mostly based on the theory of damage mechanics or fracture mechanics with some statistical treatment to incorporate random distribution of microcracks. In the application of fracture mechanics theory, sometimes it is difficult to estimate the micromechanical parameters such as crack density and fracture toughness in different modes. In this study, damage in rock material is evaluated according to the earlier model developed by Grady and Kipp (1980), which is a fracture model coupled with a material description for stress wave propagation to predict quantitatively fracture and fragmentation under explosive loading conditions."

Jan 1, 2015

By J. B. Mawdsley

From the view point of the mining engineer, the square-set method of stoping as practised at Butte, Montana, is one ?of the outstanding features of well conducted mining operations in that camp. The following information was obtained in the course of two months underground work in the Granite Mountain mine, during the summer of 1920, which is one of the properties of the North Butte Mining Company, situated on the well known Speculator vein. Most of the information was derived from personal observation and from discussions with various miners and with members of the staff. Geology The copper mining area of the Butte district is some two miles long by one and a half miles wide, a mineralized area in a great batholith of monzonite granite, locally known as the Boulder batholith. This extensive body of granite is traversed by several series of mineralized fault-fissures which differ in strike but generally dip steeply. Geologists agree that following the formation of the fissures, alkaline solutions ascended and decomposed the felspathic portions of the granite in the immediate vicinity of the fissure walls, and that these alkaline solutions were followed by cupiferous solutions which filled the fissures and replaced the granite next to the walls. A zone of oxidized ore, varying in thickness from 10 to 400 feet, overlies a sulphide zone containing chalcocite, enargite, bornite and chalcopyrite, with a small amount of quartz gangue. The veins are from 3 to 100 feet in width and contain, on the average, 3 per cent of copper, 2 ounces of silver, and 15 cents in gold per ton.

Jan 1, 1925

By T. V. Lord

Minerals containing uranium have been successfully pre-concentrated by flotation at Queen's University, Kingston. In particular, uraninite, uranothorite, euxenite, and fergusonite, have responded to flotation to yield grades of 0.2 to 6.0 .per cent U .o. with recoveries of 85 to 98 per cent, from heads analysing approximately 0.10 per cent U3Os. Of the ten or so radioactive samples examined to date, two distinct groups were recognizable, firstly, those samples in which uranium was the sole constituent of economic interest, and, secondly, those in which Columbium (with minor amount of tantalum) was present in addition to uranium. For the purpose of this paper, the results of investigation on two samples of each of the above groups have been selected as typical.

Jan 1, 1945

Access to accurate real-time information is critical to maintaining efficiency and competitiveness in any modern minerals processing facility. At MMG LXML Sepon Copper Operation in Lao P.D.R., controlling the copper grade of the feed to the leaching circuit is paramount for maximising productivity and copper recovery. Since 2008, real-time analysis data has been available to process engineers from the Geoscan on-belt analyser installed on the Copper Mill feed conveyor. Access to accurate real-time results from the Geoscan has allowed the process engineers to strictly control blending based on copper grade to overcome variability in the plant feed, where conventional sampling and laboratory analysis is difficult, error prone and time consuming. In addition to enjoying these benefits since the Geoscan’s installation, in recent times the process engineers have expanded the use of the Geoscan by observing elemental results other than copper grade to control different aspects of the operation, focussing on the reduction of Gangue Acid Consumption. This paper discusses the process of expanding the Geoscan use at the operation, including an explanation of the calibration process. Additionally, a brief description of the Geoscan and its use at MMG LXML Sepon Copper Operation is provided, as well as a summary of recent calibration and analysis results. A discussion of future works concludes the paper.

Jan 1, 2016

By C. O. Swanson

Introduction It is thirty-odd years since I first entered the mining field by working underground at Anyox, which makes 1t clear that I can qualify as one of the older generation and claim the privilege of dealing in generalities and broad impressions. In this position I find it interesting to re~ view the salient changes that have taken place during the past quarter-century and indulge in some speculations concerning the future, with the hope that my comments may be of value to others engaged in the field of mining geology. As indicated by the title, the treatment is a perspective from a single viewpoint rather than an attempt to give a complete and impartial analysis. This plan, while deficient in some respects, has the advantage of being more specific than one based on .a. compilation of opinions. An additional advantage is brevity, which would be difficult to obtain on a subject of this scope if it were viewed from all angles. In conformity with the general plan, specific references to the literature have been avoided as much as possible, although a number of publications of general nature are listed at the end of the paper. This procedure is intended to give credit to the sources used without making them in any way responsible for the interpretation. The starting point for the discussion is the situation as it existed twenty-five years ago, when, as a recent graduate, I first had a fairly complete picture of it. However there is one impression of an earlier; stage that seems worth mentioning. In one of my first courses in geology the statement was made that some of the leading authorities of the previous generation, who guided geological thought at about the beginning of the century, were inclined to question the value of an association with mining. This attitude was no doubt exceptional, and certainly it was not adopted by the students who laid the groundwork for mining geology in North America. But its existence even in a limited circle is significant m showing how far the application of geology has advanced as the result of the investigations started during the first part of this century.

Jan 1, 1949

By A. Alfantazi, E. Asselin

"The corrosion of commercially pure titanium (CP-Ti) was studied from room temperature up to medium temperature (~160°C) under conditions relevant to medium temperature chalcopyrite leaching processes. The corrosion rates were measured by immersion and electrochemical tests in sulfuric acid. The influences of chloride, cupric and ferric ions on the corrosion rate and behavior were also investigated. Corrosion of the CP-Ti did not account for the total current density measured by linear polarization tests. The corrosion rates of CP-Ti under medium temperature leaching conditions were surprisingly high. The corrosion rate measured in ferric containing solution at 160°C was approximately 20 mm/yr.INTRODUCTIONTitanium exhibits excellent corrosion resistance in many aggressive environments because of the formation of a very chemically stable, highly adherent, and protective oxide film on its surface (Mitsuo et al., 2002). Because titanium is the only metal available at a reasonable cost that resists the high temperature corrosive slurries in many leaching processes, it is often chosen as autoclave liner material where it is subjected to severe conditions of acidity, temperature and pressure (Grauman and Say, 2000).A number of distinctly different hydrometallurgical processes for the pressure leaching of chalcopyrite have been developed and patented by various companies and they can be classified into low, medium and high temperature regimes (McDonald and Muir, 2007). For example, chalcopyrite concentrate may be processed at medium temperatures (115-175°C) and pressures of 800-2200 kPa (Dreisinger, D., 2006; Sahu and Asselin, 2011). The lixiviant may contain 20 to 55 g/L sulfuric acid, 8 to 12 g/L chloride ions, 10-25 g/L Cu2+ (Jones, 1995, 1997, 1999), and less than 1 g/L Fe3+ (Defreyne et al., 2005). The amount of these additions is determined by the grade of the ores and details are shown in Table 1."

Jan 1, 2012