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By T. Johnson, K. Lambrych, D. Kelley

Materials for construction of equipment used in hydrometallurgical plants are selected based on a combination of their ability to perform as required in aggressive process environments as well as their cost. As a material of construction, fiber reinforced plastic (FRP) has been shown to provide equal if not improved durability relative to alternative materials such as corrosion resistant alloys at a considerably lower cost. This is particularly true in the case of equipment used in acid leaching processes for copper, cobalt, nickel and rare earth elements. The selection and extensive use of FRP over alloys in new hydromet plant construction in North and South America illustrates this advantage of FRP effectively. This paper will compare corrosion performance and cost of plant equipment fabricated with stainless steel alloys and FRP made with Epoxy Vinyl Ester thermoset resins. Real world case histories for FRP piping, storage tanks, extraction vessels, and electrowinning cells combined with laboratory based corrosion studies will be reviewed to demonstrate how FRP materials are selected for hydrometallurgical equipment.

Jan 1, 2015

By J-F. Béland, N. Parson

Aluminum extrusions are widely used for automotive crash management systems due to their superior specific energy absorption capabilities, as compared to steel. The Al-Mg-Si alloy series can be readily extruded into complex multi-hollow profiles, as required in crash systems, and can be used to target a range of desired strength levels. This paper focuses on the development of an axial crush test protocol and evaluation of the crush performance of common 6XXX series alloys for a variety of tempers. The observed crush behaviour is then compared to tensile test results.

Jan 1, 2015

By L. Lorio, B. Hilscher, P. Nayak, N. Yoon

"Mining has been a staple to technological advancement ever since the dawn of time. By harnessing the different physical and chemical properties that each mining commodity brings to the table, more and more innovation is developed and manufactured. As these non-renewable resources continue to be extracted, the industry as a whole faces a challenge in finding the next economical deposit as well as declining grade at the current operations. By means of pre-concentration, ore sorting aims to separate the barren material from the valuable ore to reduce energy consumption and tailings generation, while increasing the feed grade, concentrate grade, mill recovery, and revenue. In addition, ore sorting allows the modification of deposit geometallurgy in order to allow the creation of an optimal mill feed. This paper evaluates the applicability and challenges of ore sorting by utilizing the results from four different mines, and reviews them in detail. The mines include one underground and three open pit mines that are precious metal operations. In order to understand the applicability of ore sorting in these operations, initial rock-by-rock test results and different types of assays (atomic adsorption [AA], inductively coupled plasma [ICP], and fire assay) are utilized. Using the assay results, the grade recovery curves for ore sorting are generated and they are further improved by using and developing an ore sorting algorithm, which is discussed in this paper. The application and evaluation of ore sorting in greenfield and brownfield properties will also be discussed. The state of the art ore sorting technologies for both rock-by-rock and bulk sorting are also reviewed in this paper. The future technologies on the horizon, including different combinations of sensors, are explained. The sorting technologies include X-ray transmission (XRT), X-ray fluorescence (XRF), colour, infrared, electromagnetic, and laser induced breakdown spectroscopy (LIBS)."

Jan 1, 2017

By N. Saracoglu, J. P. Golightly, R. H. Wallis, J. J. Brummer

"In January 1974, the Minerals Division of Canadian Occidental Petroleum Ltd. made the strategic decision to add uranium to its active exploration commodities and through compilation studies selected northern Saskatchewan as the most attractive and cost-effective exploration area in Canada. In August 1974, 100 sq. miles were staked adjacent to Gulf Minerals' Rabbit Lake deposit and east of the Esso Minerals Midwest boulder train. Initial exploration was based on geologic models of the Rabbit Lake deposit.In the summer of 1975, surface surveys delineated radon anomalies which were drilled that winter and found to overlie anomalous concentrations of uranium in the regolith which forms the upper unit of the crystalline basement. Within the crystalline basement, one hole intersected graphite and pyrite with anomalous nickel-cobalt-arsenic. Geochemical and radiometric surveys followed in the summer of 1976. Drilling in the winter of 1977 intersected several zones of graphite and also anomalous, but uneconomic, uranium abundances. Also in 1977, Dahlkamp and Tan (1977) described the coincidence of graphite and uranium at Key Lake and ground EM surveys on CanadianOxy claims detected graphite conductors beneath 250 ft of Athabasca sandstone. Inco Limited joined the project in April 1977 as a 50% partner. The project area was then surveyed using the airborne INPUT EM method, which detected 84 miles of conductors, with associated graphitic metasediments. On the ground these were located with MaxMin surveys, and follow-up drilling located the ""Tent"" Lake uranium zone.In 1978, the Midwest and Dawn Lake discoveries were announced, 7 miles and 2 miles west of the Joint Venture (J.V.) claims; and, in part for this reason, the 1979 winter drilling was concentrated on the deeper west side of the property. Exploration hole 102-79 intersected altered and uraniferous rocks, but stepout holes were barren. Drill hole 153-79 tested an under-snow three-station radon anomaly east of hole 102-79 and intersected 33 feet of 7.51 % U3O8, confirming the disco very of the McClean North zone. The geophysical grid of the McClean North conductor system was extended and detailed a strong, continous conductor to the south, called McClean South. This was drilled in January 1980and hole 1004-80intersected 22 feet of 2.95% U3O8."

Jan 1, 1983

By G. M. Scamans

In the past ten years there has been considerable penetration of aluminum automotive body sheet (ABS) into automotive structures. The exponential increase in demand is resulting in major investments in heat treatment and finishing capacity across the globe. Line speed and tonnage throughput is limited by the continuous heat treatment (CHT) floater furnace rather than the cleaning and pretreatment section where electrolytic treatments that offer higher line speeds should come into favour and roll coating of pretreatment should predominate. The capacity limiting surface texturing pass will either be eliminated or moved to the finishing line or a dedicated mill. The key to making aluminum both embedded carbon and cost competitive with steel for more and more affordable classes of vehicles lies in recycling of both prompt scrap and, in the longer term, end of life vehicle scrap. For the first time scrap separation technology is available that can compete effectively with hand sorting and can sort aluminum shredded vehicle scrap into wrought and cast alloys and then into individual alloy groups. The challenge is to use more end of life scrap in alloy formulation whilst at the same time extending the property range in terms of both strength and formability.

Jan 1, 2015

By G. M. Scamans

In the past ten years there has been considerable penetration of aluminum automotive body sheet (ABS) into automotive structures. The exponential increase in demand is resulting in major investments in heat treatment and finishing capacity across the globe. Line speed and tonnage throughput is limited by the continuous heat treatment (CHT) floater furnace rather than the cleaning and pretreatment section where electrolytic treatments that offer higher line speeds should come into favour and roll coating of pretreatment should predominate. The capacity limiting surface texturing pass will either be eliminated or moved to the finishing line or a dedicated mill. The key to making aluminum both embedded carbon and cost competitive with steel for more and more affordable classes of vehicles lies in recycling of both prompt scrap and, in the longer term, end of life vehicle scrap. For the first time scrap separation technology is available that can compete effectively with hand sorting and can sort aluminum shredded vehicle scrap into wrought and cast alloys and then into individual alloy groups. The challenge is to use more end of life scrap in alloy formulation whilst at the same time extending the property range in terms of both strength and formability.

Jan 1, 2015

By R. O. Suzuki, S. Natsui, R. Nashimoto, T. Kumagai, T. Kikuchi, H. Takai

A newly developed computational fluid dynamics model based on a multi-phase particle simulation is presented for predicting the entrainment behavior of liquid metal into slag due to rising single bubble. By comparing results calculated using this model against experimental data, it was found that the transient behavior of bubbles and the two immiscible liquids can be accurately estimated by this method. The rupturing of the thin water film surrounding the bubble was less reliably predicted, but this 3-dimensional unsteady numerical model still nevertheless provides valuable new information for directly predicting the change in the liquid-liquid interface over time. This model predicted the Young-Laplace pressure, and the interface shape was simulated with volume conservation using this model as opposed to the conventional particle method. This simulation model can calculate both of dispersed phase and continuous phase seamlessly.

Jan 1, 2015

By Feng Xue, Mi Xujun, Peng Lijun, Yin Xiangqian, Liu Dongmei, Xie Haofeng, Huang Guojie, Yang Zhen

The Age-hardening Cu-Cr alloys are extensively used in integrated circuit lead frame, railway contact wire, resistance welding electrode and continuous casting mold copper plate, owing to having an excellent combination of high electrical or thermal conductivity and high strength. High temperature performance is very important during the service process. Effect of Magnesium and Zirconium on softening behavior of Cr-Cr alloy are investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). During the softening process in the Cu-Cr alloy, the recrystallization process, grain growth and Cr precipitates coarsening are observed. The addition of Mg or Zr to the Cu-Cr alloy, the resistance to elevated temperature can be significantly improved, owing to being restrained the growth of the precipitates by segregating along precipitates surface. INTRODUCTION Age-hardening Cu-Cr system alloys can be widely uesed in many fileds such as electrodes for spot welding (Hatakeyama et al., 2008; Cheng, Shen & Yu, 2013; Zhou et al., 2016; Chbihi, Sauvage & Blavette, 2012), intergrated circuit lead frame (Hatakeyama et al., 2008; Cheng, Shen & Yu, 2013; Zhou et al., 2016; Liu et al., 2006; Pang et al., Xia et al., 2012; Wang et al., 2009; Huang et al., 2003; Cheng, Yu & Shen, 2014; Zhang et al., 2016; Li et al., 2007) and railway contact wire (Cheng, Shen & Yu, 2013; Zhou et al., 2016; Chbihi, Sauvage & Blavette, 2012; Liu et al., 2006; Pang et al., Xia et al., 2012; Wang et al., 2009; Huang et al., 2003), because it has high strength, good electrical and thermal conductivity. The precipitation behavior of binary or ternary Cu-Cr alloys had been investigated by many researchers (Chbihi, Sauvage & Blavette, 2012; Peng et al., 2017; Batra et al., 2002). In addition, to obtain additional mechanical properties without much deterioration in electrical conductivity, trace addition of alloying elements like Zr, Ag, rare metals (Y and Ce) and Mg are added into Cu-Cr alloy. The addition Mg to Cu-Cr alloy accelerated the process of precipitates nucleation and restrained the growth of the precipitates by segregating along precipitates surface during aging, which enhanced the stability of the deformation microstructure and improved the mechanical properties of the alloy (Zhao et al., 2018). Additional zirconium in Cu-Cr alloy enhances the strength by the decrease in inter-precipitate spacing of Cr precipitates and the formation of Cu5Zr phase (Chihiro, Ryoichi & Kazue, 2008). Owing to the decrease in inter-precipitation spacing of Cr precipitates and to the Ag-atom-drag effect on dislocation motion, the addition of Ag can increase in strength, stress relaxation resistance and without much deterioration in electrical conductivity (Chihiro, Ryoichi & Kazue, 2008). The enhance in strength and electrical conductivity of the Cu-Cr-Zr alloy by adding Ce and Y elements are attributed to removing oxygen and sulfur from as-cast alloy (Li et al., 2006). However, the effect of Mg or Zr element on microstructure and properties of Cu-Cr alloy during the softening process are not clear. Therefore, Microstructure evolution and properties of a Cu-Cr systems alloy were investigated in detail by OM and TEM. The Relationship between microstructure and properties of Cu-Cr systems alloy was also discussed.

Jan 1, 2019

By T. Gerritsen, R. MacRosty, R. Pula, P. Gebski, W. L. Ying

Furnace run-outs can cause extended furnace downtime for repair, while leaks or more severe failures in the cooling system can lead to brick hydration or in severe cases, steam explosions. These incidents can result in lost production, damage to equipment, injuries and casualties. To prevent such incidents, reliable and accurate techniques to monitor the critical components of the furnace such as refractory lining, furnace structure, taphole integrity and main water circuits are required. This paper describes several advanced methods that have been developed to assess the condition of furnace integrity, refractory lining, tapholes and cooling water circuits.

Jan 1, 2015

By R. B. Nourse, S. F. Gwynn-Jones, S. Nikolic, M. L. Bakker, I. McDougall, H. Joubert

"Tenova Pyromet’s core furnace knowhow and expertise has been built within the ferroalloy and nickel/platinum group metal (PGM) industries with the supply of electric furnaces for a number of nickel/PGM operators, including Eastplats, Lonmin, and Anglo-Platinum in South Africa, Mineraçào Serra Da Fortaleza in Brazil, and Norilsk Nickel in Russia. Tenova Pyromet has also supplied the electrode columns and associated electrode equipment – the heart of the electric furnace technology – for cobalt recovery in furnaces in Zambia and the Democratic Republic of the Congo. The quantity and size of projects undertaken by Tenova Pyromet has provided the opportunity to continuously improve furnace designs and the scope of supply, culminating in the most recent nickel/PGM project currently under construction at Northam Platinum. Through this innovative culture, the Tenova Pyromet Base Metals Initiative was formed in 2015 to develop the Novasmelt™ Furnace; a next generation optimised Top Submerged Lance (TSL) furnace design. The combination of Tenova Pyromet’s advanced Novasmelt™ product with our industry leading electric furnace technology are discussed with reference to applications for nickel and cobalt production. Flowsheet arrangements are compared summarising potential capital savings, operating requirements and achievement of downstream product quality.INTRODUCTION Tenova Pyromet is a leading player in the field of smelting technology development and equipment supply. Tenova Pyromet is the result of the union of three furnace suppliers under the Tenova banner: Techint Technologies (Tagliaferri), Core Furnace Systems Corp (Lectromelt) and Pyromet Technologies. The furnace experience of the combined groups dates back over a century with the earliest Lectromelt going into production in the early 1900s. Throughout the modern era, Tenova Pyromet has developed a reputation for providing dependable innovative smelting technology, high quality equipment and sound project execution to a worldwide client base with customer plants operating in Europe, Southern Africa, North America, South America, Russia, Kazakhstan, the Middle East, South Korea, and India. Tenova Pyromet’s core knowledge and expertise was developed in the South African ferroalloy, base metals, and platinum group metals (PGM) smelting industries. Tenova Pyromet has spent considerable effort on development and has contributed significantly to improve the state of the smelting industry. Tenova Pyromet’s electrode columns have become widely renowned and are now providing significant benefits, especially in increased furnace availability, to many smelting furnace operators. The electrode column is the heart of the furnace as it delivers a controlled amount of electrical energy, at an optimum depth in the burden/bath, to the smelting process. Every furnace is custom designed to the specific operating range and optimal operating point of that furnace and process"

Jan 1, 2017

By Christiaan Zeilstra, Jan van der Stel, Koen Meijer, Gerard Louwerse, Tim Peeters

The steel industry is producing about 5% of the world wide CO2 emission. Therefore the European steel industry has defined a research program to reduce the CO2 emission by 50% per ton: ULCOS. Since its start in 2004 ULCOS has identified four technologies for further development. Two of these technologies which produce liquid hot metal are discussed. The ULCOS blast furnace is based on recycling of decarbonated topgas and the capture and storage of CO2. The concept has been demonstrated during three campaigns at LKAB EBF in Luleå, Sweden. The smelting reduction process HIsarna is a combination of the cyclone-technology and Hismelt. The process has been demonstrated successfully in four campaigns at a pilot installation on the IJmuiden steelmaking site.

Jan 1, 2015

By L. Trytten, S. Bass, P. Nawrocki, J. Mercer

The Sherritt Fort Site nickel refinery and fertilizer plant has been operating continuously since 1954. The ammonia leach process uses ammonia and sulphuric acid, producing nickel and cobalt and an ammonium sulphate byproduct. One of the features of an ammonium sulphate based process is the aggressive nature of ammonium sulphate to concrete and structural steel. After six decades of operation, portions of the structural steel and concrete at the Sherritt facility have become degraded. Infrastructure replacement programs started in earnest more than a decade ago with pipe racks and electrical infrastructure, and have now progressed into building steel. Replacing and repairing this infrastructure within the tight constraints of an operating plant poses several difficult challenges. This paper will outline the approach taken to accomplish this difficult work, and discuss key learnings from the ongoing program.

Jan 1, 2015

By L. A. Jameson, J. Awmack, P. J. Lind

"Peñasquito is a polymetallic deposit containing gold, silver, lead, and zinc. The operation is currently the largest producer of gold in Mexico. Over the next few years, the process flowsheet will be expanded beyond the flotation of lead and zinc to include flotation of pyrite from zinc tails and subsequent leaching of the pyrite concentrate. This paper outlines mineralogical leach characterization that has been carried out to improve the understanding of the complex hosting of gold and silver minerals in the ore. Organic carbon that is present in the ore can have an impact on flotation and leaching. Mineralogical techniques used to characterize this deleterious component of the ore are introduced.INTRODUCTION Goldcorp’s Peñasquito operation is located in the Mexican state of Zacatecas, approximately 200 km from the city of Zacatecas as shown in Figure 1. Peñasquito has been in operation since 2009 and is currently Mexico’s largest gold mine. Mining is carried out by open-pit methods, with oxide ore proceeding to a heap leach facility and sulfide ore treated in the sulfide processing plant.The processing capacity of the sulfide plant is 130,000 tonnes of ore per day and in 2016 production amounted to 450,000 ounces of gold, 17.6 million ounces of silver, 109 million lb of contained lead, and 263 million lb of contained zinc in lead and zinc concentrates. GEOLOGY The Peñasquito deposit is hosted in and adjacent to two breccia pipes; Peñasco and Breccia Azul. The two breccia pipes are branches of a larger intrusive-related complex, which is hosted in the sedimentary Caracol formation as illustrated in Figure 2. The regional geology is dominated by Mesozoic sedimentary rocks which comprise a thick series of marine sediments deposited during the Jurassic and Cretaceous periods. A 2 km thick sequence of carbonaceous and calcareous siltstones and interbedded sandstones is underlain by a 1.5 to 2 km thick limestone sequence (Goldcorp Inc., 2015)."

Jan 1, 2017

By Sandeep Singh Sandhu, Karanvir Singh Ghuman, Manjit Singh

"Cobalt based super alloy stellite 6 was weld cladded on AISI 304 L stainless steel using SMAW process in order to improve the wear resistance for tyre crusher blades. Microstructure characterization and micro hardness testing was performed on stellite 6 cladding. The suitable parameters viz. 80 Amp current with arc weaving technique was selected by performing bead on plate experiment were further used for depositing multipass multilayer cladding to achieve full filler chemistry at the top surface. Further GTAW process was used for re-melting the top surface of the cladding. Comparative evaluation of the claddings showed that TIG re-melting resulted in increased microhardness and wear resistance in comparison to as cladded specimens even with lesser deposition of material. It was observed that TIG re-melting improved the hardness from 603 HV0.5 kg to 712 HV0.5 kg. Micro structures of stellite 6 contained cobalt solid solution matrix along with inter dendrite chromium carbides which resulted in the increased micro hardness values. Pin on disc abrasion tests were carried out at room temperature and the worn out surfaces were characterized using SEM and EDS.INTRODUCTIONThe crusher blades are used in many industries for crushing various types of material and its wider applications in tyre rubber crushing mills, metal-powder crushers industries etc. Most of the crusher blades are damaged by the wear and impact loading conditions. It is because of metal to metal abrasion and the temperature also plays a vital role in blunting the cutting edges of these blades. The wear is the major cause which leads to loss of material and thus the productivity that can never be recovered (Kotechi et al., 1992). The wear can be reduced by coating of various super alloys which could reduce the behavior of metal degradation even in aggressive environments. Cladding of cheaper low alloyed material with expensive superalloys to enhance the performance of components at low cost has been investigated by many scholars (Deng et al., 2010, Kennametal, 2007, Lolla et al., 2014, Singhet al., 2014, J.N et al., 2003, Ramkumar et al., 2012). Many researchers have reported that cladding is an application of build-up deposits of specialized alloys to resist abrasion, high temperature corrosion and impact loadings. Cladding is used for providing required mechanical strength properties as well as inhibition of oxidation and other corrosive degradation. Coatings are used to protect the heat affected areas like tubes of fluidized bed combustor etc. (Kirchbner et al., 2008, Wang et al., 1994, Hocking et al., 1993, Ananthapadmanabhan et al., 1991, Staia et al., 2001). Coating techniques are widely used for the protection of turbine engine and boiler tubes against high temperature corrosion attack, power generation equipment, chemical process equipment, aircraft engines, pulp and paper processing equipment, bridges, rollers and concrete reinforcements, orthopedics and dental, land-based and marine turbines, ships. Coatings of stellite 6 are widely used in steam turbine blades and boiler tubes for power generation because of an excellent combination of impact, wear and other properties. It can maintain its properties even at high temperature and in harsh environments (Kobayashiet al., 1999, Alam et al., 2009, Munehru et al., 2009). The loading and unloading conditions experienced by the material may induce the surface cracks which lead to its breakage and leaving large pits in the surface (Meng et al., 1995). Many researchers have reported that the properties of cladded layers can be increased by various techniques such as controlling the current variations, dilution, heat input, laser and other re-melting processes, addition of special alloying elements, speed of weldingetc(C.M Anaet al., 2002, Kumaret al., 1999, Luo et al., 2012, et al., Madadi et al., 2011, Shin et al., 2003, Kuzucu et al., 1997, Sudha et al., 2008, Sawant et al., 2017, Houdkova et al., 2016, Ciubo"

Jan 1, 2017

By A. Khan, C. Ciriello

The purpose of this paper is to demonstrate the value of constraint modelling in optimization of mineral processing systems. This will be achieved by first understanding the overall concept of variation and constraints present in any system. Next, the value of using a Constraint Model in optimization is demonstrated through comparison of business cases. The benefit of understanding the severity of constraints and movement of the bottleneck within a mineral processing system will be understood through the use of a case study. Paper will conclude with a summary of all optimization benefits that utilization of a constraint model can bring.

Jan 1, 2015

By J R. Barber, B. E. Rogers, R. Fukuzawa

Mercury is sometimes present in non-ferrous ores including gold, zinc, copper and lead. The selection and use of appropriate mercury abatement technology is critical for preventing its release to the environment during ore processing and to protect workers from mercury exposure. This paper presents a general decision-making process for mercury abatement technology selection for major emission sources in the gold industry. Mercury abatement can be accomplished through making process changes and/or by adding a process step to an existing system (i.e. "end-of-pipe control"). Advantages and limitations of the technologies along with waste / by-product management options are discussed through case studies of current operating mercury abatement systems.

Jan 1, 2015

By Edouard Asselin, Tasawar Javed

The precipitation of hematite from ferric sulphate - cupric sulphate - lithium chloride acidic solutions was studied in a batch reactor. The effect of several variables on the extent of hematite precipitation as well as on its crystallinity and purity was investigated. The variables studied include: initial ferric concentration (1.5 - 30 g/L), retention time (0 - 12 h), initial sulphuric acid concentration (0 - 30 g/L), temperature (150 - 220 °C) and chloride concentration (0 - 25 g/L). The results show that hematite is preferentially precipitated at lower initial iron concentrations. Longer retention times increased the fraction of hematite in the precipitates but did not affect its crystallinity to a significant extent. On the other hand, higher temperatures increased the purity and crystallinity of the hematite. At lower acid concentrations hematite and goethite were precipitated. However, only hematite was precipitated when the initial acid concentration was > 12.5 g/L. Better crystalline hematite was formed at lower acidities. Increasing chloride concentration increased the amount of hematite and decreased the amount of iron sulphate hydroxide phases, but did not affect the crystallinity of the hematite.

Jan 1, 2015

By R. L. Bruening, R. M. Izatt, N. E. Izatt, S. R. Izatt

"Molecular Recognition Technology (MRT) is a simplified, green chemistry process with applications in selective separations of Ni(II), Co(II), and platinum group metals in primary ore beneficiation processes and secondary recovery operations from spent products, scrap, and environmental waste solutions. Simplification in MRT processes is achieved by non-use of solvents, reduced space requirements, and a simple separation system involving columns packed with metal-selective SuperLig® resins. Minimal waste is generated and metal recovery is achieved at 99% levels from g L-1 to <mg L-1 concentrations. MRT systems are attractive technologically and economically compared with solvent extraction, ion exchange, and precipitation separation processes. Commercial examples of MRT use include removal of impurity metals Cd, Cu, Ni. Fe, and Pb to mg L-1 or lower concentration levels from Co streams to produce battery-grade Co. Highly purified Co is required for optimal function of lithium ion rechargeable batteries and superalloys associated with aerospace and gas turbine operations. Impurity metals are recovered for reuse or proper disposal rather than being discarded to landfill. Green chemistry processes, such as MRT, are needed in metal separations going forward into the 21st century to achieve global metal sustainability in processing of native ore and treatment of secondary sources.INTRODUCTION Maximizing efficiencies of metal separations and optimizing metal recovery rates during separation processes are important goals on the road to achieving metal sustainability. Achievement of these goals is consistent with stated principles of green engineering (O'Connor, Zimmerman, Anastas, & Plata, 2016) and green chemistry (Anastas & Eghbali, 2010). Molecular Recognition Technology (MRT) separation processes using SuperLig® resins have a 25-year record of performing competitive, commercial metal separations with metal recovery rates approaching 100% (Izatt, Izatt, Izatt, Krakowiak, & Bruening, 2017). SuperLig® resins are characterized by high selectivities for specific metals over concentration ranges from g L-1 to mg L-1 or lower. MRT systems use no solvents and are simple in design and operation resulting in reduced capital and operating expenses."

Jan 1, 2017

By A. Navarra, C. Arrancibia, R. Yañez, C. Acuña, F. Valenzuela

"Discrete event simulation (DES) is a suitable framework to evaluate and optimize the dynamics of sulphide smelters. In particular, iron-nickel-copper-cobalt sulphides undergo continual oxidation within a roasting or smelting operation, followed by batch oxidation within the converting operation, thus producing iron-free Bessemer matte (or blister copper, in the case of copper smelters); this semi-finished product undergoes further processing to produce nickel, copper and cobalt products, and to recover precious metals. The juncture between continuous smelting and batch converting is often an appropriate focus for the earliest phases of DES development, since it is typically a major bottleneck within nickel and copper smelters; later phases may include increasing levels of detail for auxiliary unit operations, as well as plant logistics. Moreover, DES can support matte-slag chemistry, including Gibbs free energy balances to determine the iron speciation within the slag. DES is therefore capable of linking the fundamentals of oxidation reactions to the intricacies of plant dynamics.INTRODUCTION Discrete event simulation (DES) is gaining acceptance within the extractive metallurgy community, as a technique that quantifies the system-wide performance of metallurgical plants under conditions of uncertainty (Wheeler & McGinty, 2015). In particular, over 90% of smelters that process nickel-copper-cobalt sulphides and copper sulphides exhibit similar semi-continuous dynamics (Crundwell et al., 2011b; Schlesinger et al., 2011b), in which the converting aisle produces batches of material that are sent for further processing (Figure 1). Thus the tools and practices that are developed for a specific sulphide smelter are often relevant to numerous other smelters.The juncture between continuous smelting and batch converting has long been a focus for discrete event simulation (Welgama et al., 1996). Nonetheless, the broad acceptance of DES in nonferrous smelters has been hindered by interdisciplinary barriers that divide industrial and metallurgical engineers (Navarra et al., 2016; Noorossana et al., 2012); this divide has been less severe in steel plants (Hollocks, 2006). In recent years, DES has been used in copper smelters to analyze crane-and-ladle motions (Coursol et al., 2009a), reverts production and consumption (Noorossana et al., 2012), and innovative control systems (Herrera et al., 2016); additionally, DES models have accounted for shutdowns and random breakdowns to provide realistic assessments of copper smelter capacities, thus guiding equipment upgrades (Campbell et al., 2013; Coursol et al., 2009a). All of these studies feature a Peirce-Smith converting aisle similar to Figure 1 that, under normal operations, constrain the smelter throughput, and are thus a bottleneck (Campbell et al., 2013; Navarra et al., 2016)."

Jan 1, 2017

By Robin Phinney

Certain statements in this presentation may constitute "forward-looking" statements which involve known and unknown risks, uncertainties and other factors which may cause the actual results, pe1formance or achievements of the Corporation, or industry results, to be materially different from any future results, performance or achievements expressed or implied by such forward-looking statements. When used in this presentation, such statements use such words as "may", "would", "could", "will", "intend", "expect", "believe", "plan", "anticipate", "estimate" and other similar terminology. These statements reflect the Corporation&apos;s current expectations regarding future events and operating performance and speak only as of the date of this presentation. Forward-looking statements involve significant risks and uncertainties, should not be read as guarantees of future performance or results, and will not necessa1ily be accurate indications of whether or not such results will be achieved. A number of factors could cause actual results to differ materially from the results discussed in the forward looking statements including, but not limited to, the factors discussed in the Corporation&apos;s annual information form filed on March 9, 2011. Actual results could differ materially from those currently anticipated due to a number of factors and risks. These include, but are not limited to, the failure to obtain necessary regulatory approvals, including environmental approval, the failure to secure full project financing, the failure to implement the recommendations set out in the Technical Report, the failure to raise financing to implement the recommendations in the Technical Report, risks associated with the mining industry in general (e.g., operational risks in development, exploration and production; delays or changes in plans with respect to exploration or development projects or capital expenditures; the uncertainty of estimates and projections relating to production, reserves and resources, costs and expenses; and health, safety and environmental risks), decrease in potash prices and exchange rate fluctuations. Although the forward-looking statements contained in this presentation are based upon what management of the Corporation believes are reasonable assumptions, the Corporation cannot assure shareholders that actual results will be consistent with these fonvard-looking statements. These fon\?ard-looking statements are made as of the date of this presentation and are expressly qualified in their entirety by this cautionary statement. Subject to applicable securities laws, the Corporation assumes no obligation to update or revise them to reflect new events or circumstances. This presentation is a market update based on the Corporation&apos;s public disclosure and does not form a part of any offer of securities, or constitute a solicitation of any offer to purchase or subscribe for securities. Any purchase of securities in the company should be made solely on the basis of information contained in the Corporation&apos;s public record which is available on www.sedar.com .

May 1, 2013