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By V. G. Papangelakis, G. P. Demopoulos

"Recovery of gold from refractory ores and concentrates presently constitutes one of the most important, challenging, and exciting areas of R&D activity in the gold processing industry. New technologies are being tested for the treatment of refractory gold materials, some of which have been advanced to the level of commercial operation. In this paper, some recent technological developments in the hydrometallurgical processing of pyritic matrix-refractory gold ores are highlighted. Key operational steps of each of the alternate hydrometallurgical technologies are analyzed and potential advantages and drawbacks are identified. The processes which are reviewed are: hydro chemical oxidation, biochemical oxidation and pressure oxidation. INTRODUCTIONOver the years the term ""refractory"" has been applied in gold ore processing to denote situations in which straightforward cyanidation failed to yield high gold recoveries. A number of mineralogical and chemical factors may be responsible for this ""refractoriness"" problem. A systematic classification of the different options for their treatment has been discussed in a recent review paper. In this paper, the pretreatment of the submicroscopic gold encapsulated within the matrix of pyrite and arsenopyrite minerals is considered. This type of gold is the ultimate refractory material because complete breakdown by reaction of the host mineral structure is required.The method which has been traditionally applied for the treatment of pyritic-type refractory gold ores is an oxidation roast (single stage or double stage depending on the As content) of a flotation concentrate to produce a porous calcine, the latter being more amenable to cyanidation. Despite its established practice, oxidation roasting is not considered particularly attractive with today's standards for high product recovery and clean environment. Roasting is known to be very sensitive to heating parameters and feed composition and deviation from optimum conditions can result in reduction in permeability which is translated to incomplete gold liberation."

Jan 1, 1989

By Ellis Thomson

The microscope is now used extensively not only in the examination of solid ore but also in the determination of fragmental mill products. It has therefore become a matter of paramount importance to be able to mount and polish fragmental as well as solid specimens in the easiest and most efficient way, so that the minerals present may be readily determined. In the case of the solid ore the ordinary mount of plasticine set on a glass or metal slide serves for most practical purposes. An improvement on this is furnished by the small brass container inside of which the specimen is mounted in a cementing medium of sealing wax. The latter is the method in use at Harvard University. It has the advantage of uniform height, thus obviating the necessity of a slide of any sort. It is also easily catalogued as the brass holder may be stamped with a convenient series of letters and numbers that will serve as a label. Other advantages of this type are the ease with which any particular part of the section may be re-located, the excellent storing facilities afforded by mounts of uniform size, and the possibility of polishing ten or a dozen sections at the same time by means of a holder which is placed over the polishing wheel, is geared with it, but revolves the opposite way.

Jan 1, 1926

By V. G. Papangelakis, T. Clark, G. Kolliopoulos

Sustainability of the hydrometallurgical industry requires the development of processes for effective water recovery; if process water is recovered and recycled, fresh water intakes will be reduced. Forward osmosis (FO) is an innovative membrane process that promises to recover water from industrial process aqueous streams or seawater with less energy input compared to reverse osmosis (RO) and evaporation; the energy efficiency relies on the spontaneity of the process (no energy input required). The driving force of the process is the osmotic pressure gradient between a dilute feed solution (process water) and a concentrated draw solution. The draw solution is an engineered aqueous solution that contains a highly soluble chemical reagent that is able to osmotically "draw" only water from the dilute stream, through a semi-permeable membrane, leaving behind a small volume of concentrated brine. The draw solute is separated and recovered for reuse, leaving behind water. The main energy requirements of the FO process arise from the separation and the regeneration of the solute chemicals from the diluted draw solution. This work focuses on the evaluation of aqueous carbonated trimethylamine (TMAH:HCO3) as the draw solution and reports recent findings on the separation efficiency of TMA and CO2 from the solution.

Jan 1, 2015

By Steve Forgeron, Brendan MacKenzie, Kevin MacPherson

"The geological composition of strata immediately adjacent to coal seams has a significant effect on the safe and efficient extraction of coal from underground mines of the Sydney coalfield. Geological features such as paleo-sandstone river channels, seam splits, floor rolls, paleo-soils and stone-filled rupture features can rapidly alter the competency of immediate roof and floor strata, significantly reduce the height of the coal seam, cause rapid variations in seam gradient and influence the in situ and run-of-mine quality of the coal.The impact of these features on the over-all mining operation can be significantly reduced if mine management can be for-warned of their impending occurrence. Using the information acquired from boreholes, geological mapping, x-ray diffraction analyses, microscopic studies, geophysical logs and seismic surveys, sedimentary models have been constructed which enable the mine geologist to predict, with increasing accuracy, the future occurrence of deleterious geological features ahead of the working face."

Jan 1, 1986

Up to thirty years ago, coal preparation in western Canada, except at four plants, had not included actual coal washing. The exceptions were at Nanaimo and Royston, B.C., where tub washers and wet tables were in use; at Hosmer, B.C., using. Robinson cones; and at Leitch Collieries, Passburg, Alta., using a feldspar jig. The two last named collieries had a short life and were not operating in 1920. The industry was divided, as at the present day, into two sections, steam (bituminous) coal and domestic (largely sub-bituminous) coal, the first generally supplying industrial needs and the second householcl and other heating requirements. The two sections overlap to some small degree today as prepared sizes, chiefly stoker, and briquettes, from steam coal are shipped for house-hold use, and domestic slacks are used in certain industrial plants. The .domestic operator, for reasons shown later, was not primarily concerned with actual coal washing as a phase of coal preparation, and bent his efforts to improvement of screening and loading plants, with hand-picking of coarse sizes. The bituminous operator, on the other hand, felt it necessary by 1920 to consider coal washing. When the mines were comparatively young, coal quality could be controlled to a considerable degree by selective mining, by leaving behind some of the seam or by-passing districts in a mine where the coal was of inferior quality to that in other districts. This obviously had its limitations, and so the next step was coal washing.

Jan 1, 1952

By Syamujulu. M

Subsequent to the unbundling of the Zambia Consolidated Copper Mines (ZCCM) and the privatization of its constituent parts, the Konkola Copper Mines (KCM) represents a third of the original conglomerate. Now run by private hands as a sub group of Vedanta Resources Plc of India, KCM is strategizing on how best to deal with the operational issues of the organisation to resolve some of the difficult, logistical, environmental, mineralogical and metallurgical problems being encountered to tum them into opportunities as the company turns around. This paper reviews the options being put in place to provide appropriate solutions and strategies including the treatment of the highly siliceous low energy copper belt concentrates in its mining operations in Zambia.

Jan 1, 2007

By H. D. S. Miller

"Artificial stope support has become an essential component of many underground mining operations. Because the use of cable bolts in open stopes is a relatively new concept, most support is still designed by trial and error or by rules of thumb. This often results in costly overdesigned support or inadequate support which leads to stope failure.This paper proposes guidelines to determine support requirements using the stability graph method. The stability graph method is an empirical open stope design technique that takes into account the key factors that influence stope stability. The factors for the design of a cable bolt support system include bolt length, bolt intensity and the original rock mass competency and can be estimated using empirically calibrated charts. The empirical charts were developed based on more than 60 case histories of cable bolting success and failure in Canadian open Slope mines.The concept of pre reinforcement and supp ort stiffness will also be discussed.INTRODUCTIONArtificial support, in the form of rock anchors, has become an important component of all underground mining operations because its stabilizing effect contributes to make underground workings safer. There are several types of rock anchors featuring different properties and having a variety of functions. This paper focusses on grouted cable bolt applications in large open stope mining. Such a support system may improve the competency of the disturbed rock mass to a point approaching the undisturbed rock quality by limiting joint movement and dilation. This results in more stable, possibly larger and, thus, more efficient production stopes."

Jan 1, 1989

By M. E. Holuszko

Although there is no widely accepted rigorous definition of handleability, the handling coal characteristics often referred to as handleability define whether a coal has the ability to flow unhindered through the processing and transportation systems. The handleability may be severely affected if fine coal particles tend to aggregate. In the pelletization process, the rolling action of the drum is applied to bring the individual particles into proximity with each other so that they can aggregate and form pellets. Because of apparent similarities between these two processes, the pelletization tests are carried out in parallel to the handleability tests in this project, and the pelletization results are used to explain coal handleability properties.

Jan 1, 2004

By H. Wilton Clark

"IntroductionTHE CANADIAN use of short-period delay-action detonators in coal shooting has been carried on for about two years, mostly in British Columbia, and this is a preliminary report on progress to date. Entire coal faces are being shot successfully with one application of electric current.The electric blasting cap came into use about the beginning of the century. The low-tension electric cap, the type most commonly used, consists essentially of a metal tube containing an initiating explosive. Two wires lead into the end of the cap and are connected inside the cap with a short 'bridge wire .of very high resistance. This •bridge wire is buried in a match-head of a readily ignitable powder composition. When current goes through the lead wires, the bridge wire becomes extremely hot and sets• off the match-head which, in turn, ignites the powder just below it in the tube. This explosion sets off the main charge of explosive. Thus, by connecting a group of caps to a source of electric .current, a number of charges could be exploded simultaneously. This immediately became of great value to mine and quarry operators. Explosives could now be used to break up large masses of material at one time, as against the older, slow method .of blasting small amounts with single charges.The next step was to develop a delay detonator which would allow charges of explosive to fire one after the other, one or two seconds apart. Such detonators allowed first blasts to relieve some rock burden before the next charge fired, giving the second charge an easier task in forcing out more rock, and so on for the rest of the series of charges."

Jan 1, 1953

By J. C. Allan

THE purpose of this paper is to outline the pogress made in the development o the gravity separation method o ore dressing known as Sink-and-Float, which, in the opinion of the writers, has now reached a stage justifying the claim that this new method marks a highly important advance in the technique . The essential feature of the newest development of this process is the extremely accurate separation achieved. This is responsible for higher extraction in the sink-and-float unit on coarse sizes and, in consequence, for substantially higher overall recoveries. Whilst this is the most remarkable feature of the new process, it has further important contributions to make to ore dressing under the following heads: (1) The introduction of the sink-and-float separator as a buffer helps to iron-out irregularities in the mill feed. By supplying a concentrate of constant grade to the flotation section, the process also indirectly improves overall recovery. (2) The addition of a sink-and-float unit to an existing mill results in substantial increase in capacity at low per ton capital cost. (3) Where the plant can be installed underground for the pre-treatment of low-grade ores, there is a saving in hoisting costs, and excellent 'fill' is provided near the point of use. ( 4) Low-grade mixed oxide-sulphide copper ores may be pre-concentrated, thereby producing a flotation feed sufficiently rich to render the oxide residue from such flotation economic for subsequent treatment by leaching or other methods. (5) Application of the process eliminates hard gangue constituents which cause high grinding costs, or gangue constituents which adversely affect flotation. The plant is compact and easily controlled. No highly skilled operators or expensive reagents are required, and the labour and power per ton are low. The separator is extremely flexible, working equally efficiently on any throughput up to its maximum capacity.

Jan 1, 1940

By W. E. Selnes

Introduction In 1938, a survey conducted by the Ontario Mining Association revealed a rather startling fact. Injuries incurred in chute pulling were more numerous than those from any other single cause. This report prompted Mr. W. B. Paton, then Inspector of Mines for Manitoba, to make a similar survey of the mines of his Province. It indicated that, in Manitoba mines, chute accidents ranked second only to those from falls off roofs and sides. Why has the mining industry been so slow to recognize the dangers of chute pulling? A partial answer may be the lack of any systematic classification of accidents according to their real cause. The result has been to attribute to other causes injuries which were a direct outcome of chute pulling, and, indeed, has made it difficult to analyze accidents in the industry as a whole. Perhaps, too, because chutes are generally located in the comparative safety? of the drifts, there has been a tendency to consider the occupation as not very hazardous. Not until enough statistics were obtained on this particular task could it be appraised correctly. The Mining Association's survey has been most helpful, and latterly the industry has done a great deal toward analyzing the causes of chute accidents and toward determining an effective means of overcoming them. Much, however, remains to be done. An effort will be made in this paper to outline methods which have been found successful in materially reducing the number of injuries. Qualifications of the Chute Puller First of all it must be realized that chute-pulling is a specialized occupation. The men require proper training for the job, just as in other mining operations. Care must, therefore, be taken to choose persons whose qualifications fit them for the job. Chute-pulling is an integral part of the general mining operation and cannot be considered as isolated from the tasks of other workers. One of the essential qualifications of a chute-puller is a sufficient knowledge of mining operations to appreciate the effect his work will have on the safety of others in the vicinity. He must take the necessary precautions, by verbal warnings, by placing barricades and signs, or by personally guarding the chutes, to prevent accidents to fellow workers.

Jan 1, 1947

By B. McKevitt, P. Abbasi

The ion exchange process (IX) is applied in the mining industry for the removal of impurities from process streams, treatment of waste solutions prior to disposal and the recovery of valuable metals. Extensive studies have been performed with the goal of modeling of IX for the case of a single metal loading onto iminodiacetic resin in the hydrogen form. However, in a real system, a resin may be saturated by impurities (iron, calcium, magnesium, manganese), which are then displaced by the metal of interest. The present study provides an insight into the Fe2+ loading process onto iminodiacetic ion exchange resin under the infinite solution volume condition. The study involves the measurement of iron loading under a variety of experimental conditions as well as an attempt to model the loading process using the hybrid correlation advanced by McKevitt (2012). The importance of the experimental and modeling work are discussed in the context of resin in pulp recovery of nickel.

Jan 1, 2014

By G. Binks

In 1997, the Zinifex Hobart Smelter ceased ocean disposal of jarosite and the flowsheet was converted to reject iron as paragoethite. This paper describes the evolution of the flowsheet since the changeover and considers future flowsheet developments. The major change to the flowsheet has been an increase in the silica content of the calcine resulting from treating increasing levels of Century concentrate. The high silica levels impacted on the paragoethite precipitation stage, causing a deterioration in the settling and filtration characteristics of the paragoethite and an increase in the contained zinc level. The implementation of a two stage neutral leach step has enabled the flowsheet to cope with the higher input silica levels. Future developments include an understanding of the form of the zinc in the paragoethite and options to lower the zinc level to improve the overall zinc recovery.

Jan 1, 2006

By D. Campbell

Mining activity is increasing in northern boreal and subarctic regions of Canada. This is the case in the far north of Ontario, especially in and near the Hudson Bay Lowland (HBL). De Beers Canada opened the Victor diamond mine in the centre of the HBL in 2008, and advanced exploration and impact assessments are occurring to the west in the ?Ring of Fire? for ferrochrome, nickel/copper, iron/ vanadium and platinum-group elements, making it one of the richest mineral finds in Canada in recent years. However, the HBL is also a near-pristine, sensitive environment. Its peatlands forms the third largest wetland in the world and are globally important stores of terrestrial carbon. Human populations in the region are sparse, consisting almost entirely of First Nations communities. Local First Nations also have a strong land ethic and greatly influence mining developments. Through formal agreements, they have insisted on a gold standard for environmental management, including a small mine footprint and the return to representative native ecosystems after mine closure. However, knowledge on the revegetation of subarctic and northern boreal ecosystems is limited. Here, we are conducting research at the Victor mine to develop gold standard protocols for the revegetation of disturbed peatlands and mine waste uplands and present a summary of results. We first tested existing protocols for peatland restoration from southeastern Canada. We collected peat-forming plants from nearby muskeg, spread them sparsely over disturbed peatlands and applied a light phosphate fertilizer, but unlike southern protocols, no mulch appeared to be required to produce a representative cover of peat-forming plants within three years. A bigger challenge is the reclamation of uplands made of mine waste back to representative ecosystems. We first characterized reference conditions for uplands in the HBL, which are scarce in the region. Nearby natural uplands were divided into two classes, interior uplands and uplands along river valleys. Multiple parameters were examined at these sites including soil development, bulk density, soil chemistry in the rooting horizons, plant cover by stratum, plant species composition and dead wood. The mean condition and, more importantly, the range of these parameters allow us to set broad targets for progressive reclamation, which will facilitate success. Finally, we characterized local upland plant species through their functional traits to determine their likely abilities to colonize, grow and contribute to ecosystem processes. A classification of species by these simple functional attributes will help restoration managers to select candidate species to meet different goals at different successional stages (i.e. good versus poor dispersers or establishers). Research into these protocols remain in the early stages, but show promise that gold standards can be achieved to ensure that mining wastes can be reclaimed to productive ecosystems.

Aug 1, 2013

By E. Chiyangwa, L. Schoeman

The commercially successful electrowinning and refining of metals typically requires the optimization of the electrolyte composition and operating parameters to produce high quality compact electroplated metal. The prediction of the effect of the electrolyte composition on the structure and morphology of the plated metal remains a challenge. Initial work on the use of polarization measurements to predict and control plating behaviour in electrowinning plants involved potentiodynamic polarization but proved unsatisfactory as accurate and repeatable predictions could not be achieved. The aim of the present work was to develop a reliable galvanodynamic technique specifically applicable to the plating of zinc from sulfate electrolytes with which plant operation may be controlled and optimized. Initial results indicated that plating and nucleation potentials could be measured accurately and repeatably and that the relationship between the two could be used as a predictive tool for the effect of electrolyte composition on the quality of zinc electrodeposits.

Jan 1, 2014

By A. M. Simons

Cyanide destruction by Caro’s acid is one process commonly employed by gold operations to meet regulatory requirements and/or the International Cyanide Management Code compliance for weak acid dissociable (WAD) cyanide in cyanidation tails or waste water from such operations. Typically smallscale bench tests to evaluate and assess the suitability of the Caro’s acid destruction process are conducted. Additionally, the experimental procedure used during these preliminary investigations may also differ from that implemented at the full-scale. This paper presents the results from a fundamental investigation of the Caro’s acid process to establish a more detailed understanding of the impact that the experimental procedure has on the destruction of cyanide. In particular, it was found that the control of pH was important to avoid copper(I) cyanide precipitation at low pH and maximise WAD cyanide destruction. Residual peroxide in the preparation of Caro’s acid has the potential for subsequent cyanide destruction and could be exploited.

Jan 1, 2014

By A. Garnier, K. Tremblay-Bouliane, B. Gaillet, S. Moineau, D. Tremblay

"A heptapeptide library displayed on M13 bacteriophages (phages) was screened to identify peptide sequences able to selectively bind to gold, chalcopyrite, sphalerite, pyrite, and silica ores, and to evaluate phage potential as bioflotation reagents. Many peptide sequences were isolated through biopanning and differed from known sequences. Adsorption isotherms were determined and a receptor/ligand interaction model was identified and used to compare affinity of peptide sequences toward ores. Some phage sequences have slightly lower affinity to sphalerite than other sulphides. Adsorption was higher on sulphides than on silica. Induction time measurements suggested filamentous M13 phages lower hydrophobicity of the ore surface.RÉSUMÉ Une librairie d’heptapeptides présentés sur des bactériophages M13 (phages) a été criblée afin d’identifier les séquences peptidiques affinitaires à des minerais d’or, de chalcopyrite, de sphalérite, de pyrite et de silice et d’évaluer le potentiel de ces phages en tant que de bio-réactifs de flottation. De nombreuses séquences peptidiques ont été isolées par bio-criblage et différenciées d’autres séquences connues. Des isothermes d’adsorption ont été déterminées et un modèle d’interaction récepteur–ligand a été identifié et utilisé pour comparer l’affinité des séquences peptidiques par rapport aux minerais. Certaines séquences de phages possèdent une affinité légèrement inférieure pour la sphalérite comparativement aux autres sulfures. L’adsorption sur les sulfures était plus élevée que sur la silice. Des mesures de temps d’induction suggèrent que les phages filamenteux M13 diminuent l’hydrophobicité de la surface des minerais."

Jan 1, 2016

By P. E. Cavanagh

FOR THE PAST seven years Mr. W. Simpson, Chief Mechanical Inspector for the Nova Scotia Department of Mines, has carried out exhaustive field trials of non-destructive inspection equipment in the coal mines of that Province. This work has demonstrated the usefulness of a number of types of non-destructive inspection when used for periodic inspection of hoisting and haulage equipment in the coal mines of Nova Scotia. As a result, the Dominion Coal Company has instituted a programme of regular preventive maintenance inspection ?by a special staff of qualified and trained men. The purpose of this present paper is to describe how non-destructive testing techniques are used on ropes, axles, couplings, and other hoisting and haulage equipment, how these methods are being used in other industries, and the expected benefits from intelligent and properly organized use of these techniques in the coal mining industry.

Jan 1, 1956

By A. Boehm

"For recycling LD slag into the steel making process, the phosphorous containing calcium silcate phases have to be removed from iron oxide phases. One possible technical solution could be magnetic separation in a wide range of susceptibilities from ferromagnetic to paramagnetic. To check the feasibility of magnetic separation the distribution of the magnetic susceptibility in size classes as well as the liberation of the phosphorous containing phase were evaluated by a new method combining two dimensional physical property analysis with QEMSCAN analysis. The particle size classes of energy controlled comminution products were subdivided into fractions of defined magnetic susceptibility using a hand magnet of well known field properties (pick up method). On the one hand the susceptibility classes were wet assayed on the other hand analyzed by QEMSCAN followed by data evaluation using iDiscover 5.3.1(FEI), which was adapted to the data structure of two physical properties (size and magnetic mass susceptibility). The results allow the comparison of mass based (3D) cumulative distribution of grades from the wet assays with the area based (2D) distribution from QEMSCAN analysis, in order to control a systematic (size dependent) stereological error for this special type of material. As the physical separation property forms a crucial parameter the results from the liberation analysis by QEMSCAN can be interpreted more profound with respect to an expectable separation result. Once the various mineral compositions of the particles are assigned to the physical properties the Henry Reinhardt chart serves to predict the best possible separation result and thus the feasibility of a separation technique.INTRODUCTIONThe two Austrian steel plants operated by voestalpine AG produce about 650,000 t (voestalpine 2014) of LD slag in the course of steel production from pig iron according to the basic oxygen process blowing oxygen in the converter by an oxygen lance. The process is also known as the Linz Donawitz (LD) steelmaking process. By the addition of lime (CaO), carbon, phosphorus, silica, manganese and sulfur, which are present in the molten pig iron, shall be oxidized and bound in the slag either as oxide or silicate phases, or leave the slag in the gaseous phase (CO). The average chemical composition of the investigated LD slag is given in table 1."

Jan 1, 2016

By Daniel Cluff

Frozen backfill for mining operations in permafrost must be delivered in such a state so as not to thermally impose on the host rock surrounding the filled stope. The placement process, the material strength demand, and the freezing time delay are the parameters that control the applicability of the method. A two-year research program was carried out in the field and using a laboratory-scale apparatus, designed to simulate a pour of frozen backfill, to study the mixing, thermal properties and segregation. The frozen rock and tailings must be at a below zero temperature and get fully wetted so the surfaces cause adherence of the particles to one another and enhance the solidification of the poured backfill. The results provided a recipe and a process for mix design for open stoping operations in cold regions. The testing evaluated the sensitivity of the test parameters that included the amount of water added in the mix, the temperare of water, the rockfill/tailings ratio, and the temperature of solid constituents.The paper presents the result of this environmentally friendly, innovative technology. The distribution of the materials and the mixing process are instrumental in achieving the properties required for open stoping applications.

Oct 1, 2010