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By S Basu, S L. A Gowravaram

CaF2 has been a common constituent in a wide variety of welding fluxes, including those used for submerged arc welding (SAW). The widespread use of CaF2 stems from its role in lowering the liquidus temperature as well as the viscosity of the molten slag that covers the weld pool. However, the harmful effect of fluoride evaporation from molten flux, on the environment as well as the health of the users is becoming increasingly evident over the years. This has led to increasing attention towards reducing the CaF2 concentration in the fluxes. The fluoride-free formulations face the challenging requirement to maintain the thermo-physical properties (viscosity, liquidus temperature etc) like those observed in fluoride-containing fluxes. In the present work, three fluxes with compositions in the CaO-MnO-SiO2-Al2O3 system have been identified as promising alternatives to the CaF2-rich fluxes. However, the thermo-physical properties of any such flux need to be comparable to CaF2-based commercial SAW fluxes before it can be adopted for regular use. The single hot thermocouple technique (SHTT) has been used by several researchers in the past as a tool for observing the melting and solidification characteristics of fluxes. This device has been developed in the present work and is used to characterise the melting behaviour of the fluxes. The measured solidus and liquidus temperatures from SHTT were compared with the results from differential thermal analysis (DTA) and simulations using the FactSage™ software for a comprehensive understanding. In spite of having a slight deviation in the measured values from the multiple techniques, the results obtained from these multiple methods show that the selected compositions could be potential CaF2 free alternative welding fluxes.

Jun 19, 2024

By Palmer DJ

Mercury is introduced into EZ's electroly tic zinc/sulphuric acid plant complex at Risdon, Tasmania, in zinc sulphide concentrate. Mercury is volatilised during the roasting operation and then distributed in the sulphuric acid plant effluents and product acid. Following an investigation of the factors determining the mercury distribution, a plan was formulated to-provide an environmentally accep- table degree of mercury containment at Risdon. This paper discusses details of the various control measures investigated and out- lines the reasons for selecting the particular procedures finally adopted for the Risdon plant.

Jan 1, 1980

By P Revell, G Wilkie, P Walters, L Keeney, F Faramarzi

Grade Engineering® is a value-driven strategy aiming to maximise benefits by exploiting intrinsic grade variability of ore deposits. It utilises a multitude of separation techniques to remove low grade material before being introduced to post-blast size reduction processes, i.e. crushing and grinding. At an operational scale, Grade Engineering® techniques can be implemented at the drill-and-blast stage, to control the degree of fragmentation in accordance with the spatial distribution of valuable minerals across an ore domain through differential blasting. It can also exploit intrinsic textural and breakage characteristics of a given ore type to reject uneconomical barren material at coarse sizes, which is known as Natural Deportment. Grade Engineering® can also be employed in the deliver stage of the mining value chain through sensor-based bulk and particle sorting. Each strategy is therefore highly dependent on the responsiveness of an orebody to available techniques. That is, the extent to which Grade Engineering® drivers would be capable of unlocking potential values of currently un-amenable orebodies depends on how detailed the heterogeneous nature of ore domains can be described. This paper considers exploring possible linkages between deportment characteristics of an ore and its competence when broken in a range of energy inputs at a particlebased level. Accordingly, potential opportunity may lie in exploring whether the intensity of input energy (or degree of fineness) can be used as a lever to improve or ‘unlock’ ore amenability to Grade Engineering® techniques. Implications from such a detailed approach offers new opportunities to enhance Grade Engineering® gains through engineering ore competence variability.

Nov 10, 2020

By R A. Pax

Electrostatic separation is a core requirement for the beneficiation of mineral sands suites to provide valuable product. Although the basis of electrostatic separation has been understood for some time, the details required to be able to calculate the metallurgical performance of a separator has not previously been achieved from a mechanistic perspective. Empirical models have had some success but require extensive test work. Traditionally, performance of an electrostatic separator is determined by careful experimental work using the target mineral suite. Although electrostatic separation was invented at the end of the 19th century, very little modification of the basic equipment occurred until relatively recently, with the addition of a plate electrode to aid separation. Previously, the author has presented results, calculated using finite element modelling (FEM), of the electric fields present in an electrostatic separator in various configurations. This paper will present some new mathematical modelling work, which uses the FEM determined electric field configurations but also incorporates some fundamental physical processes that provide insight as to the limitations and opportunities for this important separation technique.

Oct 5, 2011

By M A. Harrington-Baker, J M. Trudnowski

Sulfate-reducing bacteria (SRB) have the ability to immobilise dissolved metals by precipitating them as sulfides, provided that a favourable biochemical environment is created. Such an environment includes the presence of sulfate, anaerobic conditions and the availability of organic carbon. If such conditions are engineered within a reactive barrier or field-bioreactor, most metals can be effectively removed. To demonstrate this concept, three passive SRB field-bioreactors were constructed in 1998 at an abandoned mine site in the vicinity of Butte, Montana, USA to treat acid mine drainage with characteristic elevated concentration of metals and low pH. Performance of the field-bioreactors, using aqueous samples, was monitored over 32 months until the project was terminated, field-bioreactors were decommissioned and solid matrix sampling of the reactive matter was performed. The most important analytical results are presented in this paper together with conclusions regarding the appropriateness of the field-bioreactors construction features. Only Zn, Cu, and Cd were being removed as sulfides due to SRB activities. Changes in concentrations of other metals (Fe, Mn, Al, As), which do not necessarily precipitate as sulfide, seemed to be affected by SRB only in an indirect manner by responding to increased pH caused by SRB activity. An innovative cellular containment system used for placing organic matter worked very well in preventing settling of the organic matter and ensuring uniform flow of AMD throughout the entire cross-section of the organic carbon with no preferential flow paths This demonstration was funded by the US EPA and was jointly administered by the EPA and the US DOE under DOE contract number DE-AC22-96EW96405. The project was implemented by MSE Technology Applications, Inc, Butte, Montana, USA.

Jan 1, 2003

By C Li, K McDonald an, T Nicholson, C Brown

The relative reactivities of chars prepared from different coal samples at temperatures in the range 500 to 1150¦C were determined by measuring the rates of metallisation of a standard ilmenite concentrate. The results have been interpreted in relation to different measured physical and chemical properties of the chars. Char reactivities were found to correlate with the maximum specific surface area (SSA) of the chars, obtained from plots of SSA versus temperature. Weathering of coal samples gave higher reactivities which correlated with higher SSAs. Experiments using recycled chars showed that the high internal SSAs developed during earlier reduction reactions provide no benefit in terms of increased metallisations. The important role of char hydrogen contents in controlling low temperature metallisation rates was demonstrated. Chars prepared from different rank coals had the same hydrogen content when prepared at the same temperature. Ilmenite metallisation rates had a linear dependence on the hydrogen content of the chars. Large differences in the slopes of the metallisation versus H2 content curves for different chars were interpreted in terms of SSA variations and catalysis of the gas reactions by dispersed metallic iron particles in the chars. A simple test based on magnetic separation of the char was shown to give an indication of enhanced reactivity due to contained metallic iron.

Jan 1, 2001

By H S. Smit, P Lotz

Gold mining companies who are signatories of the International Cyanide Management Code (visit www.cyanidecode.org for further information) are required to measure WAD cyanide on-line and destroy WAD cyanide in excess of specified limits. Weak acid dissociable (WAD) cyanide refers to those cyanide species liberated at a moderate pH of 4.5 such as HCN(aq) and CN-, and the majority of Zn, Cd, Cu, Ni and Ag complexes with low dissociation constants. It is potentially toxic to humans and animals. Recognising and in response to the gold mining industryÆs need for an on-line WAD cyanide measurement device, Mintek recently developed the WAD Cynoprobe. The WAD cyanide analysis technique is based on the use of a ligand exchange reagent that liberates WAD cyanide from metal-cyano complexes. The ligand exchange reaction is represented by the following chemical equation: Metal(CN)X + yLigand <-> Metal(Ligand)y + xCN- The plant filtrate is treated with a ligand exchange reagent, to liberate WAD cyanide, before measuring the free cyanide concentration via amperometry. The instrument proved to be accurate and reliable in the laboratory as well as under industrial gold plant conditions during various trials. It has gained wide-spread commercial acceptance both locally and internationally. However, itÆs recent exposure to complex ore types have called for refinements to the analysis technique. It has been further developed to improve its precision and accuracy and to remove reagent and thiosulfate interferences. Its compatibility with the most commonly used destruction oxidants has also recently been investigated. The WAD Cynoprobe may be configured to measure both free and WAD cyanide concentration. Its fast analysis time, approximately 5 min, makes it suitable for use in the control and optimisation of the cyanide destruction and recovery process. Proper oxidant dosage control and monitoring of effluent concentration levels will ultimately result in less cyanide and post-destruction salts discharged into the environment.

Jan 1, 2008

By M I. Pownceby, N A. S Webster, A J. Studer, I C. Madsen, J A. Kimpton, M J. Fisher-White, L Lu

In situ synchrotron X-ray and in situ neutron diffraction-based experimentation have been implemented to characterise the formation of the complex calcium ferrite iron ore sinter bonding phases silico-ferrite of calcium and aluminium (SFCA) and SFCA-I. Experiments were carried out using fine-grained (<20 ¦m) sinter mixtures containing ~77 wt per cent Fe2O3, 14 wt per cent CaO, 3.5 wt per cent SiO2 and 5 wt per cent Al2O3, with diffraction data collected during heating until 1300 - 1350¦C, which was enough to ensure complete melting of the SFCA phases. In the case of the in situ synchrotron experimentation, results showed that altering the nature of the starting sinter mixture (ie substitution of goethite for hematite; substitution of an amorphous Al2O3-based mineral for gibbsite) did not have a significant effect on the thermal stability range of the SFCA phases. It did, however, have a profound effect on the formation and rate of consumption of the calcium-rich ferrite phases C2F and CF, and on the formation mechanisms of SFCA and SFCA-I. The in situ neutron diffraction experimentation is the first described in the context of iron ore sintering, and the observation of both SFCA-I and SFCA formation in the in situ diffraction data represents the first step in achieving the goal of charactering iron ore sinter phase formation in large volumes of industrial sinter starting materials with a wide range of particle sizes (up to 6.3 mm).CITATION:Webster, N A S, Pownceby, M I, Madsen, I C, Studer, A J, Lu, L, Manuel, J R, Kimpton, J A and Fisher-White, M J, 2013. In situ x-ray and neutron diffraction studies of silico-ferrite of calcium and aluminium iron ore sinter phase formation, in Proceedings Iron Ore 2013 , pp 487-494 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By K Saito, M Hasegawa

Removing sulfur and phosphorus from molten iron can be expressed by the following reactions, respectively. [S]Fe + (O2-)slag = (S2-)slag + [O]Fe [P]Fe + (3/2) (O2-)slag + (5/2) (FeO)slag = (PO43-)slag + (5/2) Fe(liquid) These equations indicate that desulfurisation and dephosphorisation have opposite oxygen potential conditions. If a small amount of desulfurisation slag not removed is carried over to dephosphorisation process, the reaction of sulfur mentioned above proceeds toward left hand resulting in increasing sulfur content in molten iron. For better understanding of such re-sulfurisation reaction in hot metal pre-treatments, the present study aimed at evaluating the effect of iron oxide on the sulfur distribution ratio between slag and hot metal. To measure sulfide capacities and FeO activities simultaneously at temperatures below the melting point of pure iron, CaO-SiO2-FeO and CaO-Al2O3-FeO ternary molten slags were brought into equilibria with copper-iron-sulfur liquid alloys, and the equilibrium oxygen partial pressures were determined with an electrochemical technique involving the stabilised zirconia solid electrolyte. The experimental results showed that the sulfide capacity increased with an increase in FeO content, and this trend was consistent with the fact that FeO was basic. Although the addition of FeO raised the FeO activity and oxygen potential, the calculated value for sulfur distribution ratio between slag and hot metal increased with increasing FeO content.

Jun 19, 2024

The Southern 'B' lode orebody at the New Broken Hill Consolidated Limited (NBHC) mine, Broken Hill, is a continuation of the zinc-rich orebody that was first mined in NBHC in the 1940's. Preliminary diamond drilling in the early 1960's resulted in sufficient information to delineate the southern extension of the presently mined 'B' lode orebody, In 1966 the sinking of a 7.3 metre diameter circular shaft (No. 3 Airway) was commenced to improve the ventilation of the southern extremities of existing workings and to provide a base to further explore and develop the orebody extension. Development on four levels was started in the early 1970'.s to link the existing workings with the new shaft. Three possible mining methods - sublevel open stoping, loader cut and fill with ramp access and sublevel caving - were investigated and the decision was made to mine the orebody by transverse sublevel longhole stopes and pillars with trackless equipment and ramp access between the major working levels.

Jan 1, 1977

By N L. Turner, D J. Robinson, A J. McFarlane, N M. Chapman, L L. Kuhar, R L. Meakin, R Martin

A number of geometallurgical tests have been developed within the AMIRA P843A Geometallurgical Mapping and Mine Modelling (GeMIII) project, an interdisciplinary collaborative research project involving four research groups and over 20 global mineral companies. Researchers at the Commonwealth Scientific and Industrial Research Organisation (CSIRO) have been focusing on the development of predictive hydrometallurgical indices for the GeMIII project via rapid, small-scale, cost-effective tests and protocols for comparative ranking of attributes relevant to leach performance. One of the focus areas has been the development of a leaching scheme for determination of the mineralogical deportment of copper in a large number of samples for geometallurgical applications.Various leaching schemes have been used over the last 20 years to identify the mineralogical deportment of copper. Typically, weak sulfuric acid and cyanide are used to target copper oxides and æsecondaryÆ copper sulfide minerals, covellite, chalcocite and bornite, respectively. Residual copper is assigned to chalcopyrite and/or bornite. Adaptations of this scheme have included the use of a weak organic acid to target oxides or ferric sulfate to target secondary copper sulfides. Testing of the weak acid/cyanide scheme in the GeMIII project using head and residue QEMSCAN mineralogical data analysed with a statistically reliable comparison method indicated that the inferred mineralogical deportment from various leaches could differ markedly from the theoretical or assumed value. Based on this initial work, test development and leach tests on samples from multiple sites has resulted in the development of a scheme to target copper oxides, chalcocite, covellite, bornite and chalcopyrite. This paper presents results from leach tests conducted on a large sample suite from two pits in a Cu-Au ore deposit with results calibrated using mineral liberation analyser (MLA) mineralogical analysis. This study has assisted in the development of a protocol for determining the mineralogical deportment of copper in a large number of samples for geometallurgical applications.CITATION:Kuhar, L L, McFarlane, A J, Chapman, N M, Meakin, R L, Martin, R, Turner, N L and Robinson, D J, 2013. Calibration and testing of a geometallurgical leaching protocol for determining copper mineralogical deportment, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 177-186 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By M Xu and, P F. Wells, A N. Kerr, Y Shields

Triethylene tetramine (TETA) has been used in combination with sodium sulfite (sulfite) for pyrrhotite depression at Clarabelle Mill since 1998. This combination has been highly successful at reducing pyrrhotite levels in the bulk (Ni/Cu) concentrate. Although highly effective, the roles of TETA and sulfite are not well understood. Treating bulk samples of the circuit feeds through the miniplant enabled the effects of circuit configuration on the performance of the pyrrhotite rejection circuits at Clarabelle to be determined. Reasons for the different performance of the non-magnetic pyrrhotite rejection circuit in the miniplant were investigated and tested in the laboratory. The effect of different grinding environments in the laboratory was examined to better understand the depressing mechanisms of TETA/sulfite. Modification of the grinding chemistry improved the selectivity of pentlandite over pyrrhotite in the presence of TETA/sulfite at current plant dosages.

Jan 1, 2005

By R Shrimali, P Rajmeny, L Shekhawat, A Joshi

Rampura Agucha open pit mine has successfully been excavated to a depth of 320 m, incorporating multistage working. The key to success is the implementation of presplitting as control blast measures at every stage of mining, including intermediate cut backs, in addition to the final wall. The major challenges encountered in establishing presplitting in the hang wall as compared to the footwall of the mine are:reversely dipping foliation, ie dipping into the hang wall itselfstriking obliquely at an angle of 20–30° with regards to the general strike of the pit wallthe presence of numerous geological planes of weaknesses like major faults, slips, etc.Control blast parameters like hole inclination, spacing and stand-off with buffer row were chosen initially from the literature survey and were subsequently fine-tuned by field trials to the mine geo-mining conditions of the hang wall. Electronic initiation used for trim blasts along with double presplitting in fault-affected zones helped in getting better presplit performance and resultant stability of the hang wall.CITATION:Rajmeny, P, Shrimali, R, Shekhawat, L and Joshi, A, 2015. Establishing the design parameters of a control blast for long-term stability of the hang wall at Rampura Agucha Mine, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 437–446 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By I Cameron

Simulation is increasingly being used to analyse mineral processing operations and explore efficiency options. Engineers that use simulation are rightly concerned with the quality and applicability of the underlying models. However, many of these models have a significant empirical component, and the best structure for this component may not be apparent. There is an opportunity to improve the quality and application range of these models by exploring potential structures for this empirical element. One approach to this problem is the use of structural optimisation, which is a formalisation of the model development process. This method searches through a family or hyper-structure of candidate models for a model that is optimal with respect to some measure of model quality. This method has been applied to the modelling of an industrial flotation circuit. The result was a model that was a significant improvement over a number of standard models reported in the literature. Structural optimisation provides a method to compare potential models in a systematic and efficient way, and hence to improve the structure of process models.

Jan 1, 1998

By Anievas JB, Sevillano AC

This paper describes the acquisition, exploration, development, initial operation and subsequent financing of the Bulawan mine by means of a listing on the Toronto Stock Exchange of a subsidiary of the parent company, Philex Mining Corporation.Located on the island of Negros in the Philippines the property is unique on at least two counts: it is a disseminated gold deposit that occurs in a region of predominantly porphyry copper mineralisation; and it is a gold deposit that is mined by a bulk method of extraction (front and block cave) instead of the normal selective mining methods.

Jan 1, 1997

By S Hapugoda, H Han, L Lu

Charcoal produced from Syzygium Zeylanicum trees was widely used in ancient Sri Lankan iron smelting practices. Charcoal made from Syzygium Zeylanicum tree trunks, branches and leaves were analysed by optical mineralogy and SEM and found to contain unusually high concentrations of calcium oxalate (CaC2O4.H2O – CaOx) crystals in plant cells. Partial and full reduction tests of a high-P Brockman ore were conducted at several temperatures with coke and coke doped with CaOx and CaCO3. It was observed that CaOx promoted reduction and generated comparatively more metallic iron in reduced samples. Furthermore, CaOx encouraged phosphorous partition into slag phases than into the metallic iron, suggesting CaOx can a potential alternative fluxing material to calcium carbonate for treating high-P iron ores in ironmaking processes.

Sep 18, 2023

By B J. Monaghan, R J. Longbottom, S Prabowo, D Del Puerto, B Maisuria, C W. Bumby

The use of hydrogen as a reducing agent can substantially reduce carbon dioxide (CO2) emissions from the ironmaking process. Iron ore fines can be reduced in a fluidised bed (FB) using hydrogen (H2) at high temperatures (>800°C), although several studies have reported the sticking of particles which causes the bed to defluidise, effectively shutting down the process. Here, we report results from the reduction of New Zealand (NZ) titanomagnetite (TTM) ironsands in a small-scale laboratory FB (100 g) at temperatures between 800–1000°C using H2 flow rates up to 5 standard L/min. No sticking phenomena are observed under any of these conditions, which is attributed to the formation of a stable titanium-bearing oxide layer on each particle’s exterior, preventing iron-iron contact at the particle surfaces. Pre-oxidised NZ TTM ironsands have also been studied and shown not to stick. Interestingly, at lower reaction temperatures the reduction kinetics for pre-oxidised ironsands is faster than for as-received ironsands. This increased kinetic rate can be attributed to the preoxidation stage inducing micro-fractures that create a void for the hydrogen to diffuse into the inner regions of the particle. In addition, oxidation of TTM appears to segregate the particle into two distinct phases, a high Aluminium-Magnesium (Al-Mg) phase and a high Titanium (Ti) phase. The findings are important as increasing the operating temperature of the FB reactor results in a faster reaction rate and higher gas utilisation, making the process more economically attractive. Furthermore, oxidation of NZ TTM ironsands results in a faster reduction rate at lower temperatures (800°C– 900°C) opening the opportunity to reduce the reaction temperature which might be beneficial in a final commercial-scale process.

Sep 18, 2023

By Whiteman P. C, Stacey G. S, Hunter G. D

Processing of lead-zinc and copper ores by Mount Isa Mines Limited produces large quantit- ies of concentrator tailings waste which is pumped as a slurry to special dams where the solids are allowed to settle and dry out. These areas are unattractive and show no signs of encroachment by plant life even though the surfaces of some dams have remained undisturbed for more than a decade. During 1970 Mount Isa Mines Limited commenced a long term research program in conjunction with the Department of Agriculture, University of Queensland to deter- mine possible methods of establishing a plant cover on this material. Research has defined the major factors limiting plant growth in the tailings medium. Modification of the edaphic conditions through fertilizer inputs, particularly of phosphorus and nitrogen, and alteration of "soil" physical properties by incorporation of mulching mater- ials, provided conditions which allowed plant growth. The outstanding "soil" amendment treatment was incorporation of fly ash, a waste product of the company's coal fired power stations. A range of crop and pasture species have been selected which have grown well with adequate irrigation under the amended conditions in the field. Further research is assessing a range of native plant species and agronomic techniques to provide a stable plant cover on the tailings dams.

Jan 1, 1974

By Magne L, Barria J, Castro O, Menacho J, Gonzalez GD

An extensive experimental campaign was developed in a continuous 6 x 2' (D x L) pilot scale SAG mill. The effect of the feed flow rate, feed solids concentration, ball filling fraction and feed size distribution, over the mill performance was investigated. The residence time distribution (RTD) for the fine material was measured in every test, in order to detect changes in the mixing characteristics of the mill under different operating conditions. Based on phenomenological considerations a state model of the SAG mill was developed, which independently incorporates mechanisms such as: grinding, mass transport and classification in the grate discharge. These can be parametrised using information and optimisation software. This comminution model extends the compensation condition, which is a conventional hypothesis for ball milling, to the semi-autogenous mill grinding. The mathematical analysis of this hypothesis, applied to SAG mills, allow the reduction of the number of parameters in the model, using the relationship Ki = (1-bii)Si, where b and S have the conventional meaning. Therefore, the distribution fracture matrix bij and the specific fracture rate SIE are grouped in just a single diagonal matrix Ki.

Jan 1, 1993

By H S. Mitri, A Sainoki

Destress blasting techniques have been widely employed in underground mines for the purpose of preconditioning highly stressed rock mass. Appropriate applications of the technique successfully contribute to increasing mine safety (eg mitigating the risks for rock bursts). This paper presents a simulation technique to estimate the extent of damage zones induced by destress blasting. A 3D numerical model with a single blasthole is constructed with FLAC3D code, whereby static analysis is carried out in which horizontal and vertical stresses are applied to the model in order to simulate stress conditions in a deep underground mine. Afterwards, dynamic analysis is performed whilst applying time-varying blast pressure along the blasthole. The blast pressure profile takes into consideration an instantaneous increase and gradual decrease in blast pressure as well as the propagation of detonation along the blasthole. In this paper, constitutive models allowing for shear and tensile strengths of rock mass that are dependent upon strain rate are newly implemented into FLAC3D code with C++ programming language, whereby blast-induced damage is assessed by the extent of tensile and shear failure zones. The results obtained from the dynamic analysis show significant decrease in the extent of yielding zones induced by destress blasting with increasing the magnitude of in situ stress. They indicate that considering in situ stress state is indispensable in order to propose proper blast design for each level in underground mines. Based on these results, the relationship between the extent of the damage zone and depth at which destress blasting is performed is established. Furthermore, stress dissipation induced by destress blasting is examined with static analyses, in which the modulus of elasticity is decreased according to a rock fragmentation factor, a, only for the area where tensile and shear failures takes place during the dynamic analyses. A model parametrical study with respect to a is undertaken. The relationship between the rock fragmentation factor and the stress dissipation in the yielding zones is developed from the parametrical study. The developed relationship can be useful when destress blasting is designed for massive rock masses.CITATION:Sainoki, A and Mitri, H S, 2015. Simulation of damage zones induced by destress blasting, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 245–256 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015