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By K. C. Corin, M. Tadie, R. M. Manenzhe

The near depletion of high-grade ores, among other factors, has necessitated the consideration of alternative PGM sources. Various factors in the metallurgical processing of ores result in valuable minerals being lost to the tailings, and hence, PGM tailings are a possible alternative PGM source. However, as the value residing in PGM tailings remains unquantified and uncharacterised, there is a challenge in knowing the recoverable fraction of value contained in PGM wastes. This paper outlines the in-situ techniques of oxygen uptake and EDTA extraction for their possible use for determining the recoverable value in PGM tailings. Both methods have shown efficiency in determining the weathering of sulphide minerals and sulphide-bearing ores. Keywords: PGM tailings, tailing retreatment, oxidation, oxygen decay, EDTA

Jan 1, 2020

By I. Y. Motovilov, S. A. Telkov, M. B. Barmenshinova, Z. S. Abisheva

As a rule, removing waste rock at the beginning of the process improves the conditions for the flotation of minerals, and also reduces the operating costs of crushing, grinding and flotation. Lead-zinc ores in the Shalkiya deposit of the Republic of Kazakhstan are classified as difficult for enrichment, but taking into account their significant reserves, they are one of the main potential ores for the production of lead and zinc. Under industrial conditions, for processing ores of the Shalkiya deposit, a selective flotation concentration scheme with the production of lead and zinc concentrates is recommended. However, according to the recommended scheme, it is not possible to obtain high-quality concentrates of lead and zinc, with high metal recovery. The paper presents the results of studies of preliminary gravitational enrichment of lead-zinc ore in the Shalkiya deposit. Based on the fractional analysis for the particle size range of -40+8 mm, Henri- Reingard enrichment curves were constructed, separation density (2730 kg /m3) was established to isolate the light fraction with the lowest possible lead and zinc content, and gravity enrichment indices (0.7-0.71) were determined. It was found out that when using gravitational enrichment of the original large-sized ore in the Shalkiya deposit, tails are released at the beginning of the technological process with a yield of up to 20% with the extraction of silica up to 30%, calcite up to 11% and carbonaceous matter up to 12%. As a result of the studies, it was found that the beneficiation of crushed lump ore could be conducted in heavy suspensions. One of the positive aspects of the use of gravitational enrichment is the reduction of energy costs for grinding the heavy fraction, which was experimentally proved in this article. Keywords: Lead-zinc ores, Shalkiya deposit, fractional analysis, gravitational enrichment, floating fraction, sunken fraction, separation density

Jan 1, 2020

By Yuriy V. Gulyaev, Galina V. Sedelnikova, Valeriy D. Lunin, Valentin A. Chanturiya, Igor J. Bunin

"Probable mechanisms of disintegration of mineral particles in gold-containing sulphides and benefication products exposed to high-power electromagnetic pulses are discussed. Experimental data are presented to confirm the formation of breakdown channels and selective disintegration of mineral complexes as a result of pulse irradiation, which makes for efficient access of lixiviant solutions to precious metal grains and enhanced precious metal recovery into lixivia during leaching. Experiments with different gold-containing products revealed a synergetic effect of high-power electromagnetic pulses with widely varying parameters and moisture in mineral pores on breaking-up and gold extraction processes for various resistant goldcontaining mineral products.Several series of tests performed in IPKON RAS, IRE RAS and TsNIGRI yielded an absolute gain in precious metal recovery, up to 30-80 % for gold and 20-47 % for silver, with resultant gold recovery as high as 90 %. An essentially new, environmentally safe and energy-saving breaking-up technology has been developed for resistant gold-containing products. This new method would shorten the way from raw minerals to final products and help significantly reduce the cost of these products as it obviates the necessity for using the expensive procedures of energy-intensive and environmentally hazardous oxidative roasting and autoclave breaking-up for ore concentrates."

Jan 1, 2003

By K Haga, G Danha, A Shibayama, L L. Godirilwe

The hydrometallurgical separation and enrichment processes provide an effective way to selectively recover metals from relatively dilute multicomponent sulfuric acid leach solutions. The multicomponent leach solution utilised in this study contained 0.3 g/L Cu, 0.34 g/L Ni, 0.13 g/L Co, and 2.96 g/L Fe, which was obtained after high-pressure oxidative acid leaching (HPOAL) of the copper-nickel smelter slag. The solvent extraction (SX), precipitation, and xanthate complexation processes were employed to recover and upgrade Cu, Ni, and Co from the leach solution. Batch SX tests were carried out using a countercurrent two-stage mixer settler extraction column, and LIX 984N (10 per cent v/v) as a copper extractant. Fundamental parameters influencing the extraction process such as pH, mixing speed, H2SO4 concentration, and organic/aqueous (O/A) phase ratio were investigated. For copper enrichment in solution, a combination of two extraction stages and two stripping stages were employed. Copper was successively separated from Fe, Ni, and Co under optimised extraction conditions (pH 2, 400 rev/min, O/A 0.25, and 20 min contacting) and stripping conditions (175 g/L H2SO4, 400 rev/min, O/A 4, and 20 min contacting). About 97 per cent of copper was extracted with low co-extraction of Fe, Ni, and Co of about 5.90 per cent, 1.47 per cent, and 2.53 per cent, correspondingly. A final Cu-rich solution containing 23 g/L Cu was obtained with a very low Fe concentration of 0.05 g/L. Additionally, for iron removal from the Ni/Co raffinate solution, more than 99 per cent of iron was precipitated at pH 4 by the addition of a calcium carbonate (CaCO3) suspension, with low co-precipitation of nickel and cobalt of around 3.68 per cent and 2.27 per cent, respectively. Furthermore, about 83.6 per cent of nickel and 99.4 per cent cobalt were co-precipitated from the solution by potassium amyl xanthate (PAX) solution at pH 6. The Ni and Co xanthate complexes were thermally decomposed and recovered as cobalt oxide (CoO) and nickel sulfide (NiS) solids.

Aug 24, 2022

By M Hilden, G Forbes, Z Ye, M Yahyaei, F Reyes, V Jokovic

Soft sensors offer several practical advantages for the process control of comminution circuits by combining multiple conventional sensors and other data sources with real-time analysis using mechanistic, phenomenological or machine learning models. While there has been a growth in the use of machine learning techniques for developing soft sensors in minerals processing applications, this paper describes advantages and challenges of using soft sensor models developed on the basis of process knowledge. Recent experience with three new soft sensor technologies developed by the authors are discussed. The Mill Filling Inference Tool which has been implemented at several mine sites, compares SAG mill load cell and power draw measurements with outputs of a semi-mechanistic power model to estimate the mill ball and total filling in real time. The progressive wear of the mill liners is modelled, allowing the model to correct the load mass due to the mass loss automatically and to estimate the charge trajectory. This information enables the mill to be operated more confidently near its limits. A coarse-ore stockpile soft sensor as been recently developed using a 3D cellular automata-based model to track ore size throughout the pile, and estimating the live capacity and size at each stockpile feeder to the primary mills. Finally, a hydrocyclone soft sensor is being developed to monitor performance using available hydrocyclone models to estimate the size and flow balance around the cyclone in real time. The model-based soft-sensor approach aims to synthesise and analyse existing data and provide operators and engineers with process- and model-relevant information that can facilitate making better process decisions. Maintenance data has proven useful for model development as it allows soft sensors to automatically adjust and compensate for the effect of progressive wear, for example for mill liners, thus helping the models to maintain calibration throughout the equipment life.

Aug 24, 2022

By P C. J Blackney, I M. Glacken

Spotted Quoll is a massive sulfide nickel deposit located in the Forrestania greenstone belt in the Archaean Yilgarn block in Western Australia. Discovered in October 2007, mining has progressed from open pit to underground and currently uses longhole open stoping with paste fill as the primary stoping method. Immediately prior to 2019, the Mineral Resource estimate (MRE) was defined by a single grade domain of nickel greater than or equal to 0.8 per cent, irrespective of the host lithology, a legacy of the original ore wireframe being built using explicit methods. While a number of obvious structural offsets were honoured in this nickel grade domain, only one modelled fault was used to undertake domaining of arsenic. From 2019 onwards, implicit modelling in Leapfrog Geo™ was used to construct a mine-scale geological model, which triggered the definition of a high-grade core of massive/matrix nickel sulfides surrounded by a low-grade halo of stringer/disseminated nickel sulfides in the surrounding rock. As part of the evolution of the geological model and with the aid of Seequent Central™ to allow collaboration between site-based mine geologists, Perth-based resource geologists and Melbourne-based consultants, a detailed review of the structural mapping was carried out as additional information from underground development became available. This allowed numerous faults and shears to be identified – particularly in the lower half of the mine. These were used to define further structural domains and to refine the understanding of the nickel and arsenic grade distributions in the mineralised envelope. The increased definition to the domains provided by the geological model resulted in a significant improvement in the accuracy of the Mineral Resource estimate, as measured by reconciliation using voids of the mined stopes determined from the cavity monitoring survey (CMS).

Mar 22, 2022

By L Clarkson, D Williams, P Redcliffe, F van der Wal

This research presents a snapshot and insight into the trends, patterns, and common considerations identified in the current standing of real-time tailings dam monitoring practice. Based primarily on information derived from concurrent research by the author (in form of a Catalogue of Real-time Instrumentation and Monitoring Techniques for Tailings Dams), challenges and opportunities when transitioning to a real-time monitoring system are discussed. Learnings and key considerations between different monitoring approaches are explored, including themes of limitations and advantages that were observed consistently through global supplier feedback.

Jul 1, 2021

By D Reid

Many of the relevant engineering behaviours of tailings are controlled to a large degree by the density of the material. For example, loose tailings are prone to brittle strength loss, while dense tailings are dilative (i.e. gain strength) at large shear strains. The critical state framework has been successfully developed over the past few decades to assess whether in situ conditions are contractive or dilative, and estimate relevant engineering parameters on that basis. Tailings comprising primarily silt-sized particles, when subaqueously deposited, often form a particularly loose state compared to subaerially deposited material of similar index properties. Such subaqueous deposition occurs in the decant pond area, where the tailings typically pluviate in quiescent conditions within a pond of standing water. Silt tailings deposited in such a manner have been observed to be extremely loose in a number of TSF investigations. Of particular concern, the deposited material in such cases appear to be significantly looser than can be reproduced in the laboratory - even using moist tamping, the sample preparation method which can usually produce the loosest samples possible in laboratory conditions. While the loose density of subaqueously deposited silt tailings is clear, in a well-managed upstream-raised TSF the decant pond is usually small and far from the perimeter embankments, however there are a number of examples where the engineering performance of such materials becomes relevant – for example, when historical deposition practices were poor, resulting in subaqueous deposition near the perimeter embankment. This paper outlines the geotechnical characterisation of a number of such subaqueously-deposited zones, compares the in situ state to that achievable in the laboratory, and discusses options for assessing the expected engineering performance of such materials when comparable laboratory tests are unavailable.

Jul 1, 2021

By Gino Vogt

In mechanized tunnelling operations performance, consumption and safety are main factors for jobsites. One of the most important components effecting these factors, especially in slurry TBM operations, are Slurry Treatment Plants (STPs). Inadequate/ suboptimally dimensioned and designed STPs create bottlenecks for tunnelling operation and jeopardize time schedules and performance. Inefficiently planned STPs could drastically increase consumption figures such as electrical power, bentonite, water and polymers, etc. Inaccurately selected and treated suspension properties can cause a high-risk potential for the whole job. This paper debates the relevant key parameters for STPs from start to finish of a project and its results in influencing factors from the manufacturer´s point of view.

Jun 13, 2021

By Armin W. Stuedlein, Jim Zammataro, Bernie Hertlein, Daniel Belardo, Qiang Li, Antonio Marinucci

"An experimental program focusing on four drilled shafts was conducted to determine the effect of high strength steel reinforcement bars on lateral resistance, steel casing on axial and lateral resistance, and steel casing without internal reinforcement on lateral resistance. Thermal Integrity Profiling (TIP) Thermal Wires and crosshole sonic logging (CSL) access tubes were installed in each shaft, and thereafter the corresponding non-destructive testing (NDT) was performed on each shaft to assess the integrity of the shafts and to compare the results from the different NDT methods. The results of the CSL tests using scored PVC tubes are compared against those conducted in 73/56 fully-threaded steel hollow bars, whereby the results indicated that the threaded bars served as a good host for performing the CSL tests. The data from the TIP Thermal Wires is compared against the results from the CSL tests for each of the four shafts, and the similarities and discrepancies between the two methods are discussed. This paper will serve as a reference to those interpreting the measurements and data obtained by performing nondestructive integrity tests on drilled foundations.INTRODUCTIONNon-destructive tests (NDTs) embody a set of critical tools for the evaluation of the integrity of constructed deep foundations, particularly for cast-in-place foundation elements. Construction defects may require the rejection of the foundation element by the owner’s representative, resulting in costly repairs or replacements and delays to the project schedule. The use and appropriate interpretation of the results from the NDTs provide the information required when evaluating the integrity of these constructed elements. A cooperative research program was conducted to assess the effects of various construction variables on the axial and lateral performance of drilled shaft foundations, which provided an opportunity to compare the established Crosshole Sonic Logging (CSL) test method to the newer Thermal Integrity Profiling (TIP) Thermal Wire method. This paper presents an overview of the experimental program performed at the geotechnical test site at Oregon State University (OSU), details of the CSL and TIP installation and testing methods, and the results of the NDTs on the constructed drilled shafts. Because one of the shafts was constructed with fully-threaded longitudinal steel hollow bars, this experimental program also allowed the assessment of the use of the hollow bars as access tubes for the CSL tests. Both the CSL and TIP test methods indicated that the shafts were of good quality and free from defects or anomalies; the data obtained using the TIP method also provided an estimate of the as-constructed shaft diameter and the reinforcement cage alignment, which will prove helpful when back-calculating axial and lateral load transfer during future loading tests."

Jan 1, 2016

By I. Kaabachi, F. Meunier, N. Morales

In open pit mining, ore and waste are hauled outside of the excavation area by trucks that move along a system of ramps. The design of these ramps must be carefully addressed because they have to comply with geomechanical constraints to ensure the stability of the pit walls, provide access to the different levels and phases, but also maximise the value of the extracted ore and reduce the extraction of waste. Because an optimisation approach able to deal with the design of the full ramp system seems to be out of reach at the moment, this paper addresses the problem of designing one ramp providing access to a single pushback, which has been determined beforehand. The optimisation objective is therefore to find a ramp that gives access to one given potential volume, while minimising its impact on the economic value of the volume. Two versions of the problem are formalised. One version allows the extraction of ore and waste only if this extraction is necessary for the ramp system. This version somehow minimises the intrinsic value of the ramp system. In the second version, it is possible to extract more than is needed by the ramp system. For instance, this takes into account the possibility of attaining ore on the wall opposite to the ramp as soon as the ramp reaches its level. In the setting mentioned above, the contribution of this work is three-fold. First, the computational complexity of the two different versions of the problem is presented and discussed; in particular, they are shown to be NP-hard. Second, compact integer programs modelling these two versions are proposed. Third, an efficient GRASP algorithm able to cope with the large instances of the problem is proposed. To assess the proposed approaches, the models and algorithms are applied to real instances with an off-the-shelf solver, illustrating and discussing their potential and relevance for the two versions of the problem. They are also compared with other approaches from the literature in terms of value and resulting designs.

Sep 1, 2021

By I. O. Flores, A. Anani, H. Li

Current technological advancement has increased the exploitation of deeper ore bodies using underground methods. In certain cases, the mineral deposit starts near the surface and continues deep within the earth's crust. Such deposits are best mined with both underground and surface methods. Two main techniques are used to determine the optimal transition depth from surface to underground - a disintegrated approach and an integrated approach. Both methods have limitations in their use to determine the optimal transition depth. The objective of this research is to investigate the conditions in which an integrated approach to the transition depth problem is superior to a disintegrated approach. Three binary integer linear programming models are developed for this purpose: a surface and underground model for the disintegrated instance and an integrated model. A case study is performed to validate the models, with a comparative sensitivity analysis to obtain operational insights.

Sep 1, 2021

By D. Harrington

We Americans pride ourselves that ours is the greatest, most advanced and most civilized nation in the world, yet statistics indicate that apparently we have little appreciation for the lives and limbs of the people whose efforts give us whatever greatness we possess. The latest available statistics indicate that the annual accident death rate per 100,000 of population is nearly 80 or far higher than that of any other country in the world except Chile; is more than double the rate in Hungary, Netherlands, Ireland, Belgium, Denmark, Italy, Germany, Norway, Sweden, and Finland; is nearly double that of England, Wales, the Union of South Africa, New Zealand, Japan, Australia, and Scotland; and is 25 to 40 percent greater than Switzerland, France and Canada. To make matters worse, from the viewpoint of mining; the latest available statistics give mining by all adds the worst accident rate of the major industrial occupations in the United States, the accident severity rate for mining in 1935 being listed by the National Safety Council as 10.14, the next highest rate being 4.52 for construction, and the average rate for 30 main industries being 1.58. IMPROVEMENT IN SAFETY RECORDS Offsetting to a slight extent this rather dark picture is the fact that starting about 1930 the mine-accident rate in both coal and metal mining began to fall, reaching an all-time "low" in metal mining in 1932 and in coal mining in 1933. It now appears probable that the year 1936 has again lowered the accident rate in coal mining and this, together with the fact that the years 1933, 1934, 193 5, and 1936 all set much lover accident rates in coal mining than ware achieved for any similar previous period, gives hope that the trend is definitely in the right direction, though from the above figures mine-accident severity has a long, tedious road to travel before it becomes as low as the severity rate of all other major industries in the United States.

Jan 1, 1937

By Anthony Lucas

THE discovery of oil in 1901 on the Spindletop dome, Texas, inaugurated a new industry on the Gulf Coast, an industry which has grown with the discovery of successive fields, until today it engages the services of thousands of workers and employs enormous capital. New fields are being discovered from time to time and doubtless some still remain to be found, though of late years discoveries have become more infrequent. Nowadays several hundred dry holes are drilled each year in a fruitless and blind effort to discover new fields, for as yet geologic science has developed no effectual method of locating the coastal oil deposits in advance of drilling. Moreover, despite the occasional discovery of new fields, the total production of the Gulf Coast is today no greater than it was in 1906, for the added production of the new fields has been offset by the rapid decline and more or less complete exhaustion of some of the older ones. Careful geologic work within the fields has in some cases increased the production temporarily, but has developed no really new supplies. The Gulf Coast oil industry seems to have passed its period of greatest expansion and to be declining at a fairly steady rate, and this condition is naturally viewed with alarm by the more farsighted operators. In my opinion, the time has come for the adoption of radical and aggressive methods of prospecting, and a fraction of the money wasted yearly in drilling shallow wells in hopeless locations might well be devoted to this purpose. Many facts lead me to believe that all the salt-dome oil has had a common origin; that it has migrated up from considerable

Jan 7, 1918

By Jerry L. Smith

Industry on a whole has not been very receptive to government prodding to implement waste minimization programs. Waste minimization has the appearance of substantial benefits, however, there are underlying difficulties and suspicions that need to be addressed before industry will support pollution prevention initiatives. They can be summarized as follows: - Human behavior resists change, uncertainty, and unknowns. - New waste minimization techniques are difficult to find and research. - Calculating the true cost of present waste practices as well as new techniques being considered is difficult and time consuming. - Getting a consensus opinion of all the individuals affected on the course or technique to be employed in a pollution prevention program. New software products have addressed many of the problems associated with implementing pollution prevention programs: They contain research on a large number of pollution prevention techniques and case studies; they generally are accessed by EPA ID number, chemical name, or synonym; and some programs have the option to print a comprehensive written user-specific pollution prevention program.

Jan 1, 1994

By A. R. Bell

Rio Algom Limited are currently undergoing a major expansion of their mining operations in the Elliot Lake area. To date this has involved the increase of output at the Quirke Mine from 4080 to 6350 tonnes per mill day (4500 to 7000 tons), the rehabilitation of the Panel Mine to produce at the rate of 2990 tonnes per mill day (3300 tons) by 1980, and the rehabilitation of the Stanleigh Mine to produce 4540 tonnes per mill day (5000 tons) by 1984. In addition, the planning for the rehabilitation of the Milliken Mine to produce 4990 tonnes per mill day (5500 tons) is now underway. This major expansion is taking place at a time of increasing awareness of occupational health matters and has involved very high capital expenditures and detailed planning related to the ventilation system to endeavour the provision of an acceptable environment. The paper discusses the ventilation systems, established and proposed, and relates them to historical and current data on mine air contaminants.

Jan 1, 1980

By John Ward Smith

Aragonite, co-occurring with calcite and dolomite as matrix minerals, has been discovered in Mahogany zone oil shales of Colorado's Eocene Green River Formation, posing puzzles on the geochemical patterns of their separate origins, reasons for their simultaneous existence, and their interrelation. The presence of aragonite is demonstrated by X-ray diffraction. Amounts of aragonite and dolomite are significantly and inversely related, but the calcite quantity is essentially independent of either aragonite or dolomite quantity. A geochemical pattern outlining the deposition conditions that created the Green River Formation oil shale is postulated from characteristics of the oil shale. The development of the three separate carbonates--aragonite, calcite, and dolomite--the inverse relationship between aragonite and dolomite, and the independence of amounts of calcite and the other two carbonates are shown to be natural consequences of this oil-shale genesis pattern.

Jan 1, 1973

By Michael G. Mayer

Since its invention in 1859 various designs of lead batteries have evolved to meet commercial needs for traction applications and standby power. In recent years major developments have taken place in lead alloys and the chemistry and mechanical design of industrial lead batteries. These are reviewed in relation to their commercial application together with the new type of maintenance free gas re-combination lead-acid batteries which are opening so many new markets for lead.

Jan 1, 1990

Adolph Greiner, Seraing, Belgium:—I have nothing special to add to Professor Hubert's paper except to say that there are some little things that it would be well to have corrected when the paper comes to be published. In dealing with the thermal efficiency of the engine, you will find that the 29.84 per cent. was a very high one. Professor Hubert has forgotten those engines built under the Cockerill type, but he has referred to them in Appendix 11. At our works at Cockerill we have built 63 engines, giving 63,000 h.p., and the other companies who have received licenses have built 113 engines, making 103,000 h.p., and aggregating 176 engines and 166,000 h.p. Eight years ago I had the pleasure of giving to the Institute the results obtained up to that time. Since then a good many engines have been constructed. In 1898 I thought a blast-furnace producing 100 tons of pig iron would allow 3,000 h.p. Professor Witz and Professor Hubert show that with the same production of pig the new engines take 3,800 h.p. out of the gas. At present at Cockerill we make 700 to 800 tons of pig iron per day, and we hope to have 26,000 h.p. in a few years. At present we have only half of that in gas-engines, but we hope to have in five or six years all the gas out of these furnaces to the number of 25,000 or 26,000 h.p. Tom WEstGarth, Middlesbrough, England :—My contribution is not a paper in the ordinary sense of the word, because I am sure you will agree with me that what I have written is only supplementary to the other two papers. The notes are schedules of the larger-size gas-engines built by British engine-makers, of 500 h.p. and upwards. If you look at the schedules you will find that in England gas-engines have become quite ordinary motors for a good many purposes. It was at first thought that gas-engines were troublesome, and ill-

Jan 1, 1907

By Jorge Madias

A Aceros Arequipa é a maior siderúrgica do Peru. A empresa opera uma planta em Pisco, com uma aciaria para 850.000 t anuais de aço líquido, e uma capacidade de laminação de 1.250.000 t anuais de produtos longos. Um projeto de integração vertical incluindo coqueria non-recovery, sinterização e alto-forno foi considerado. Como parte do projeto, um forno piloto de coqueificação foi instalado, com o intuito de testar carvões próprios e importados e obter a máxima participação de carvão local nas misturas. Foram testados sez carvões peruanos e antracito. Os carvões importados escolhidos foram três da Colômbia e quatro dos Estados Unidos. Levando em conta as baixas propriedades dos carvões próprios, foi introduzida a estampagem da carga. A máxima participação dos carvões locais, mantendo a qualidade requerida, foi obtida com 80% de carvão peruano, e 20% de um carvão columbiano. Pode-se usar até 10% de antracito, junto a 60% de carvão peruano e 30% de carvão colombiano.

Oct 30, 2017