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By Cui Wang, Bing Dai, Haibin Zuo, Jianliang Zhang

The damage mechanism of ductile cast iron cooling stave applied to No.4 blast furnace of Guofeng steel was analyzed through damage investigation in details, the damage causes: hightemperature gas flow erosion, wear of burden, high-temperature ablation, carburizing damage, improper operation on blast furnace, etc. were given out both in macroscopic and microscopic views. It can be obtained from metallographic diagrams that the diameter of graphite nodules increases, the number per unit area reduces, and roundness declines, successively, from cold to hot surface, which are not conducive to stave longevity. In summary, the material for staves manufacture should be better in comprehensive mechanical properties to prolong the service life, thus making blast furnace long campaign.

Jan 1, 2015

By Kexin Jiao, Huichang Song, Zhijia Zhang, Jianliang Zhang, Zhengjian Liu

A clear understanding of iron carburization reaction occurring between molten iron and carbonaceous materials is of great importance in blast furnace, and it is one of the hot spots that ironmaking workers pay close attention to. Although carburization rates between iron and coke have been studied, the factors directly controlling it have not been clearly identified. This study focused on the kinetics analysis of iron carburization reaction. Sulfur content was determined as having positive influence on graphite carburizing reaction rate in the range of 0.02% - 0.06%. The values of apparent activation energy calculated by the experiment are consistent with the existing literature, which in turn proved the reliability of the experimental data.

Jan 1, 2015

By Honglei Zhang, Yue Wang, Guotao Xu, Li Liu

The influence of rich oxygen atmosphere on the properties and structure of castables used in the hot wind pipe of blast furnaces was analyzed. Results show that the cold compressive strength of castables is affected by the change of rich oxygen volume in the wind pipe, the bulk density decreases and apparent porosity of castables increases with the addition of rich oxygen in wind pipe. With the addition of rich oxygen, the velocity of heat transfer increase and result of the steel shell become over hot out of safe limit at the thin lining in hot wind pipe.

Jan 1, 2015

By Jun Miao, Kang Liu, Jilai Xue, Jun Zhu

CO2 emissions must be reduced by at least 50 % by 2050, and hence the technical solutions to capture and convert CO2 into value–added products should be considered. A Cobalt(III) Schiff base complex (Salen–Co(III)) has been investigated as a catalyst for synthesis of cyclic carbonate from CO2 and epichlorohydrin(ECH) with tetrabutylammonium bromide (TBAB) as co–catalyst. To recover Salen–Co(III) for the next cycling operation, it was immobilized onto zeolite 13X through excessive impregnation method. The immobilized catalyst was characterized using XRD, SEM, BET and ICP–AES techniques. Catalytic tests showed that yield of cyclic carbonate reached 90 % using 0.5 mol % Salen–Co(III) at ambient conditions. The immobilized Salen–Co(III) exhibited better catalytic activity than the homogenous one when used at the first cycle, but the yield decreased by some 20 % after five cycles.

Jan 1, 2015

By E. C. L. Cardoso

Hydrocarbon polymers, as PP, made from cheap petrochemical feedstock are important in many branches of industry. However, they have an undesirable influence on the environment and cause problems due to waste deposition and utilization. Polymeric materials composites account for an estimated from 20 to 30% of total volume of solid waste disposed. Thus, there is a tendency to substitute such polymers by those ones that undergo biodegradable processes. Polypropylene (PP) is a commodity, with high melting point, high chemical resistance, low density, with a balance between physical and mechanical properties and easy processing at low cost. Nevertheless, PP shows limitations for some special applications in automotive industry and civil construction. In order to minimize this deficiency, related to rheological behavior of polymer melt, especially referring to viscosity in processing temperature, a 50% mixture with HMSPP (High melt Strength Polypropylene) was used. PP/HMSPP was blended with 10, 15, 30 and 50% of natural (sugarcane bagasse) and synthetic polymers (PHB and PLA) aiming to partially biodegradable materials. The admixtures were subjected to gamma-irradiation at 50, 100, 150 and 200 kGy and then further assessed by mechanical tests in order to evaluate their degradability.

Jan 1, 2015

By Chunyang Guan, Jilai Xue, Zengjie Wang, Qiaochu Liu

Molten salts electrolysis method to prepare Al-RE alloys has attracted increasing attention recently. CaCl2 and Na3AlF6 were the most often used melts for this purpose. In this work, Al-Sc alloys prepared by electrolytic deposition process in both CaCl2 and Na3AlF6 melts were investigated, respectively. It was found that Sc distributes almost uniformly and Sc contents increase with increasing current intensity in both melts. Current efficiency was measured for comparison among various current densities applied. The alloy products were analyzed using XRD and SEM, where the formation behaviors of Al-Sc intermetallics were investigated in details. The experimental and theoretical results demonstrate that Al3Sc and Al0.968Sc0.032 are the major precipitates in the Al-Sc alloys prepared by molten electrolysis. The results are useful for selection and optimization of the molten salts compositions and the parameters of electrolysis operation.

Jan 1, 2015

By Shengli Wu, Jinming Zhu, Wei Huang, Xinliang Liu

The sinter of high basicity would interact with lump ores or acid pellets in the cohesive zone of blast furnace due to the difference of chemical composition and micro structures. The results of this work showed that the softening-melting properties of lump ores and acid pellet would be obviously improved by the high temperature interaction. However, the high temperature interaction index (INI) would be influenced by many factors, such as chemical composition, porosity, interaction interface and so on. The INI between sinter and porous limonite lump ore (L-2) was much higher than that of dense hematite lump ore (L-1) and acid pellet (P-1). In addition, though the softening and melting properties of L-2 were poorest in respective iron ores, the softening and melting properties of integrated burden B (consist of sinter and L-2) were not worse than other integrated burdens due to the strong high temperature interaction.

Jan 1, 2015

By Jianguo Yin, Wenqiang Yang, Xiaoli Yuan, Juan An, Wentang Xia

Low grade iron ore with phosphorus (LGIOWP), a raw and wasted industrial solid material was used as an adsorbent to remove Pb(II) from wastewater. The effects of initial pH value, adsorptive time, initial Pb(II) concentration, adsorptive temperature and LGIOWP dosage on the Pb(II) removal efficiency were studied. The results show that the Pb(II) removal efficiencies exceed 99.4% and Pb(II) concentrations are less than 0.30 mg/L under the conditions of pH value 7.0, adsorptive temperature 50 oC, adsorptive time 30 min, initial Pb(II) concentration 100 mg/L, particle size <0.25 mm, adsorbent dosage 5 g/L and stirring speed 260 r/min. After Pb(II) removal reaction, the Pb(II) concentrations of wastewater completely accord with the requirement of national discharge standards of pollutants from lead and zinc industries (GB 25466-2010) (TPb= 0.5 mg/L) in China. Therefore, it can be concluded that LGIOWP is a new low-cost adsorbent which is suitable for the adsorption of Pb(II) from wastewater.

Jan 1, 2015

By Peng Lv, Shiqian Liu, Bin Xu, Qian Li, Yongbin Yang, Tao Jiang

The treatment process of a low-grade refractory gold ore containing sulfide minerals and carbonaceous matters was studied in this work. The gold extraction of this ore by all-sliming cyanidation was only 11.75%. Hence, a pretreatment was necessary. In this paper, a flotation-preoxidation-cyanide leaching process was developed. The concentrate from the flotation procedure was processed using different preoxidation methods. A concentrate containing 34.08g/t of gold with the gold recovery ratio of 81.20% was obtained by flotation. After roasting, microwave heating or alkaline pressure oxidation, the gold cyanidation ratio reached 82.37%, 81.26% and 71.09% respectively. Roasting was an effective, reliable and mature technique to oxidize sulfide minerals and carbonaceous matters. Roasting and microwave heating both produced dangerous environmental pollutants while alkaline pressure oxidation was eco-friendly.

Jan 1, 2015

By Shadia J. Ikhmayies

CdSxTe1-x and CdS1-yTey solid solutions are usually formed in the interfacial region in the CdS/CdT thin film solar cells during the deposition of the CdTe layer and/or the processing steps of the device. It is well known that CdCl2 heat treatment encourages the formation of the CdSxTe1-x alloy which improves the solar cell performance. In this work, indium doped CdS1- yTey thin films are produced by first producing CdS:In thin films by the spray pyrolysis (SP) technique on glass substrates, then annealing the films in nitrogen atmosphere in the presence of elemental tellurium. The films are characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and transmittance measurements. The transmittance is used to deduce the optical parameters such as; the extinction coefficient, refractive index, besides to the real and imaginary parts of the dielectric constant. The dispersion parameters such as Eo (single-oscillator energy) and Ed (dispersive energy) of the deposited films are also estimated and discussed.

Jan 1, 2015

By Yuan She, Qihang Liu, Keng Wu, Hailiang Ren

By observing different coal char’s microstructures and microscopic morphologies during the coking process, the characteristics of COREX coal char’s microstructure and properties were analyzed. MCRI and MCSR were used to respectively describe the reactivity and the strength after reaction of coal char, with those of BF’s coke for reference, and then the physical meaning of MCRI and MCSR were given. MCRI and MCSR were determined by the composition of coal char. For the two kinds of COREX coal, the formula to forecast the hot performance of coal char was set up by making a multiple linear regression between the hot performance and microstructure of the coal char at 1100℃, and the predictive values of coal char’s hot performance at 600℃, 800℃ and 1000℃ coincided well with the measured values.

Jan 1, 2015

By Shengli Wu, Juan Zhu, Wei Huang, Xinliang Liu, Kaiping Du, Kaifa Zhang

Based on the furnace burden of high content of Al2O3, the process of softening and melting and the characteristic of primary slag were studied with the increase of MgO content in the sinter and adding some MgO into the pellet. The results showed that the content of MgO in the primary slag increased with the increase of MgO in the sinter and pellet. Meanwhile, the permeability of the furnace burden was improved because of low viscosity of high MgO primary slag. Compared with the increase of MgO content in the sinter, the increase of MgO content in the pellet can improved the softening and melting characteristic of the comprehensive furnace burden more effectively. More Mg-bearing pellet should be chosen in the comprehensive furnace burden for the purpose of improvement the fluidity of primary slag and the permeability of the furnace burden in the burden of high Al2O3 content.

Jan 1, 2015

By Lu Lin, Yanping Bao, Xiang Li, Linzhu Wang, Xiaobai Yan

The results showed the microinclusions were mainly Al2O3 and sulfide inclusions from tapping to the beginning of LF refining. Al2O3 inclusions were modificated into calcium aluminates after calcium treatment. Lots of spherical calcium aluminates composite inclusions containing MgO, TiO2 and MnS were found after soft blowing and during tundish metallurgy and left in the slab which caused the defects of beam plates. Pure Al2O3 inclusions were observed again after soft blowing 8min. Average sulfur content in inclusions decreased because of the high desulfurization ability of refining slag. Average Ca/Al ratio value in inclusions increased during LF refinging because of the reduction of CaO in slag by carbon and it increased obviously during the process of soft blowing 8min because of the dissolusion of calcium wire.

Jan 1, 2015

By Jing Zhan, Gui Li, Wei-feng Li, Li-Hua Jiang, Chuan-fu Zhang, Jian-yang Hwang

Thermodynamics analysis for processing the charge with lead concentrate and lead sulfate-containing materials in bottom blowing smelting furnace was conducted. The results show that the technology of large-scale processing PbSO4- containing materials with PbS concentrate in bottom blowing furnace under the condition of using high-iron slag type, batch heat supplement, high temperature and rich oxygen is thermodynamically feasible. The exploration test and industrial experiment confirm the results. When S content in mixed ore is 16~17% with coke foam content of about 5%, the lead paste amount can be increased up to 40%.

Jan 1, 2015

By C. S. Todd, R. L. McNearny, S. Dun, P. Clark, P. W. Conrad, X. Liu, J. Q. Wu, H. Rhee, W. J. Elliot

Soil erosion is strongly related to soil hydraulic properties. Understanding how surface coal mining affects these properties is therefore important in developing effective management practices to control erosion during reclamation. To determine the impact of mining activities on soil hydraulic properties, soils from undisturbed areas, areas of roughly graded mine spoil, areas with replaced topsoil before seeding, and revegetated areas at the Rosebud Mine in Eastern Montana were evaluated. Field and laboratory studies were conducted to determine the soil hydraulic properties of the four representative areas, including particle-size distribution, organic matter content and saturated hydraulic conductivity. Using this data, Water Erosion Prediction Project (WEPP) simulations and risk analyses were performed to investigate mining’s effects on changes in soil erosion potential. Significant differences were seen in the hydraulic properties of the soils in the representative areas due to the mining and reclamation practices at the mine. The WEPP simulations show that the potential for soil erosion increases as a result of mining activities disturbing the soil. The simulations also indicate that the erosion potential may return to pre-mining levels over time with effective revegetation practices.

Jan 1, 2015

By E. Siami-Irdemoosa, S. R. Dindarloo

Ease of excavation or rippability, also called diggability or excavatibility, is a critical decision-making parameter in the selection of both the overburden removal method and the required equipment in surface mining and geotechnical engineering projects. The most widely used method of estimating rippability is rock mass classification. Although there are different classification schemes in the literature, all of them have the two major limitations of sharp transitions at class boundaries and subjective uncertainties in decision making. In this study, the decision trees method was employed as a classification tool for estimating ground rippability, using the four rock mass parameters of weathering degree, uniaxial compressive strength, joint spacing and bedding spacing. The results were compared with those of the widely used method of diggability index rating (DIR) and a fuzzy-based DIR. The problem of subjective uncertainty was resolved in the proposed decision trees method, as the tree rules were derived automatically from the training data sets. Compared with fuzzy-DIR, a decision tree classifier is simpler, needs less computational time and is more appreciable by industry practitioners. Nevertheless, the proposed method is not flawless and, similar to both the conventional and fuzzy DIR methods, yielded poor estimations in particular instances. The limitations of the three methods are discussed.

Jan 1, 2015

By Y. Luo

Highwall mining, which is a relatively new mining method, is a preferred and often the only feasible method for extracting coal reserve left by surface mining operations in areas with steep terrain and in closely spaced thin coal seams. Though its safety record is comparable to that of surface mining, failures of mine structures in highwall mines, especially the highwall, have occurred. Methods for the systematic designing of highwall mines to meet the safety and operational challenges are still evolving. This paper presents the results of research into improving the existing design methods and developing new ones for highwall mining operations. The design methodology is aimed at ensuring structural stability of the highwall, roof, web and barrier pillars and preventing subsidence. It takes into consideration the major ground control challenges of soft and layered mine roofs, and interactions from mining closely spaced coal seams. An optimization design process applying a pressure arch concept can be incorporated to improve the recovery rate of coal reserve. A computer program based on the design methodology was developed.

Jan 1, 2015

By Gregg Davidson, Lonnie Jacobs, Brett Zernich, Alan Howard, Robert Pintabona

All Rights Reserved. Printed in the United States of America. Information contained in this work has been obtained by SME, Inc. from sources believed to be reliable. However, neither SME nor its authors guarantee the accuracy or completeness of any information published herein, and neither SME nor its authors shall be responsible for any errors, omissions, or damages arising out of use of this information. This work is published with the understanding that SME and its authors are supplying information but are not attempting to render engineering or other professional services. If such services are required, the assistance of an appropriate professional should be sought. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, or otherwise, without the prior written permission of the publisher. Any statement or views presented here are those of the authors and are not necessarily those of SME. The mention of trade names for commercial products does not imply the approval or endorsement of SME.

Dec 1, 2014

By R Dimitrakopoulos, R Senécal

This paper presents a metaheuristic solution to the optimisation of open pit long-term production scheduling with a stockpile and geological uncertainty. The optimisation formulation is a two-stage stochastic integer programming (SIP) model that determines the optimal mining sequence that maximises the total discounted cash flow, while penalising for high deviations from production targets. A parallel implementation of Tabu Search is proposed to accelerate the solution of the SIP formulation and take full advantage of multicore computer processing. Different variants of the proposed algorithm are applied to a case study to assess the performance of the parallel approach. The proposed algorithm and variants are benchmarked using linear relaxation of the complete problem to determine robustness and provide a better overview of the related performance. The results show a net improvement over the sequential solution, and the new proposal seems to be promising when working with a large-scale data set.CITATION:Senécal, R and Dimitrakopoulos, R, 2014. Parallel implementation of a Tabu search procedure for stochastic mine scheduling, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014 , pp 405–414 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By E Lima, D Gregory, C Faria, A Lapworth

Open pit mine enterprises are complex systems that depend on multiple parameters such as mineral grade distribution, geotechnical characteristics, economic conditions and engineering requirements, all of which vary in time and space with a different degree of uncertainty. The unpredictable nature of these inputs imposes a risk to mine owners and shareholders which in the worst case can lead to highly undesirable financial outcomes.Desktop studies commonly examine a set of scenarios based on adjusting variables such as commodity prices, mining costs, processing costs, and metal recoveries to understand their relative impact on the economics of a project. It is less common to systematically explore and simulate hundreds of alternative physical designs to understand and compare the financial risk associated with one or more mining projects.This paper presents a risk assessment tool set and methodology that uses web based cloud computing to enable multiple simulations of mine designs to be rapidly and efficiently executed. The methodology includes generating random sets of prices and costs values within their respective probability distributions. Pit designs are then created to maximise the profit for each set of input variables. Various approaches to analysing the results are discussed. Use of the same high performance computing environment for understanding the financial risk associated with the variability of the underlying geological resource model is also discussed, with provided examples using case studies from two of the major mineral producers.CITATION:Lima, E, Gregory, D, Lapworth, A and Faria, C, 2014. Simulating extraction shapes to understand financial risk using high performance computing, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014 , pp 351–360 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014