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By Hidekatsu Takeuchi, Masaru Sakakibara, Shigeo Tanabe, Kenji Harada, Akihiko Suzuki, Shoji Morihana

"Deep mixing (DM) method, one of the most commonly used solidification methods, is based on the principle of solidifying soft ground. It can be classified into two categories such as Cement Deep Mixing (CDM) method and Dry Jet Mixing (DJM) method which apply hardening agent in slurry condition and in powdery condition respectively. In recent years, DM methods have undergone changes that have evolved them from the traditional method to meet the needs of the diversifying market. Among them, the Contrivance-Innovation Clay Mixing Consolidation (CI-CMC) method is a DM method which mixes a cement-type hardening agent in slurry condition mechanically with soils in situ and incorporates the innovative technique, “atomized ejection” that has been developed to allow faster installation of larger diameter columns without sacrificing quality compared with conventional methods. At this technique, the atomized hardening agent is discharged together with compressed air through a device incorporated into the mixing blade. It also has advantages of performing the works with low-displacement of the surrounding soils in consideration of environmental friendliness and with higher penetration capability against hard ground.This paper presents the technological outline of the above-mentioned CI-CMC method, focusing on the atomized-ejection technique, followed by some construction examples, applied to the self-earth-retaining wall, to the hard ground and the area adjacent to the existing structures.INTRODUCTIONAccording to the accumulation of its case histories, Deep Mixing method has been receiving the demands of its application to more challenging conditions, such as harder ground condition, and requirement of lower displacement of the surrounding ground during its operation. In addition, to match its price against the other cheaper methods and widely receive its benefit of higher quality, the cost reduction of Deep Mixing is also one of the major challenges. For the cost reduction, higher productivity and lower consumption of the material to obtain the equivalent strength and homogeneity with the conventional method are required.The Contrivance-Innovation Clay Mixing Consolidation (CI-CMC) method has been developed to meet these demands. CI-CMC incorporates the mist ejection that has been developed to achieve faster installation of larger diameter columns without sacrificing quality compared with the existing methods. Normally, we obtain cement columns of about 1.0 m in diameter by using Deep Mixing method. To increase the productivity, it is not preferable to drastically increase the penetration and withdrawal speed of the mixing blades because of the hardness of the ground and restriction by minimum number of passage of rotating blades per a certain height of the soil cement. Instead, the expansion of diameter of the columns will simply increase the productivity. The development of the new mist ejection system, as shown in Photo 1, has enabled the diameter of soil cement columns to 2.0 m on single axis while 1.6 m on double axes. Mist ejection means that the hardening agent slurry is sprayed into the ground in mist form together with compressed air thereby achieving homogeneous mixing and reducing the resistance on rotating blades."

Jan 1, 2015

By Zhan-fang Cao, Hong Zhong, Li-feng Li, Shuai Wang, Xiao-yu Cao, Guang-yi Liu, Ming-ming Wang

"In recent years, there has been an increasing focus on the hydrometallurgical processing of molybdenite, with the decline of high-grade and easily handled molybdenum minerals. In this work, a novel method of selective extraction of complex molybdenite concentrate, which is characteristic of high-grade copper ore, has been investigated. The results show that the leaching of chalcopyrite was impacted by the pH of the electrolyte when sodium carbonate and ammonium acid carbonate were added to the electrolyte. The leaching rate of molybdenum reached 99.39%, but chalcopyrite could not be leached at all in 240 min under experimental conditions of liquid-to-solid ratio 25:1, concentration of NaCl 4 mol/L, pH=9, room temperature and agitation speed 400 rpm. The grade of copper in the residue was 21.84%, with a recovery 99.93%. The technology of selective electro-oxidation leaching of molybdenum and recovery of copper from complex molybdenite concentrate is an effective separation method. The diffusion control model can be used to describe the process of leaching of molybdenum. The activation energy of the leaching reaction was found to be approximately 9.21 kJ/mol.IntroductionWorldwide, high-grade and easy-to-handle ore is decreasing, while the proportion of low-grade and complex ore is increasing. Porphyry copper ores with associated low-grade molybdenite are very abundant in China. Molybdenum is a valuable byproduct in the processing of porphyry copper deposits where the molybdenum is present in low quantities in the form of molybdenite (MoS2). In the conventional processing of copper sulfide ores by froth flotation, most of the molybdenite in the ore floats along with the copper sulfides. In this way, a bulk copper-molybdenum concentrate is produced. Afterward, the bulk coppermolybdenum concentrate is treated by differential flotation to obtain a rougher molybdenum concentrate, which requires several successive cleaning steps to produce a final molybdenum concentrate. However, it is widely recognized that flotation alone cannot economically produce a high-grade molybdenite concentrate, i.e., with less than 0.5% Cu. Therefore, in most cases, it is necessary to use a final step of chemical purification of the molybdenite concentrate to reduce the copper content to a level suitable for the market (Antonijevic and Pacovic,1992; Gerhardt et al., 2001; Fu and Zhong, 2003; Reza et al., 2006, Rafael et al., 2013)."

Jan 1, 2015

By S. Devereaux, P. Gover, S. Everett

Having real-time data of blast furnace burden profile with respect to burden height and temperature is critical to making informed decisions on blast furnace operation. Given the high temperature and gaseous environment within the blast furnace shaft, traditional instrumentation has been limited at providing the level of real-time feedback information needed to optimize blast furnace operations. Infrared thermal imagery technology provides non-contact temperature measurement across the entire burden profile, allowing for better understanding of the dynamic movement of the burden within the blast furnace shaft. This technology increases blast furnace performance by improving the decision-making process for hour by hour operations. This paper will discuss the development of incorporating infrared thermal imagery technology into the operating strategy of a lead blast furnace.

Jan 1, 2015

By F. D. Ford, Z. Dai, A. Byers

Manitoba Mining and Milling operations consist of three underground mines (Thompson T1, T3 and Birchtree), feeding the Thompson Mill. Three years ago, a collaborative effort involving Mines Exploration, Mines Project Development Group, Mill Technical Services and Vale Base Metals Technical Excellence Center was initiated to establish and verify the cause of high variability in concentrate quality and Ni recovery at the Thompson Mill. One outcome of this work was a program to systematically characterize the mineralogy and metallurgical performance of current and future orebodies feeding the mill. Mineralogy results show that high value enabling ores typically have a high pentlandite to pyrrhotite ratio and benign silicate mineralogy (mostly quartz and feldspar from sedimentary host rocks), while metallurgically challenging ores contain some combination of pyrite and/or hexagonal (non-magnetic) pyrrhotite and/or elevated quantities of talc (with associated carbonates) derived from altered ultramafic host rocks. The metallurgical performance of these two ore types has been simulated by an Excel particle flotation model, which calculates the relative floatability of particles based on the particle’s mineral composition and mineral locking determined from MLA images. The relationship between these mineral properties measured by MLA and metallurgical performance was established using 13 monthly composite samples from Thompson Mill. The model was then validated with results of laboratory flotation experiments on individual orebodies submitted for evaluation. The validated model can be used to predict plant metallurgical performance based on individual ore bodies feeding the mill. Individual orebody’s grade-recovery curves are assumed to be additive, and can be weighted in proportion to the mill feed to predict mill recovery over the same time period. The ore mixing can be done with a simple Excel spreadsheet and comes with a graphical output for easy visualization of the resulting grade-recovery curve.

Jan 1, 2015

By T. G. Carter

"Damaging seismicity associated with deep faulting in both mining and civil excavations not infrequently occurs without warning, and often before proper mitigation measures have been put into place. Severe squeezing is also a common problem for excavating through deep major faults. While both problematic conditions are difficult to predict and characterize, there is often a need at pre-feasibility and feasibility level to more reliably estimate the possible level of risk posed by such geologic structures. This paper introduces some structural geologic techniques that have potential application for both mining and civil applications for aiding forewarning of the extent of these types of problem.INTRODUCTIONEncountering adverse faulting at depth in deep excavations, whether for mining or civil purposes can create serious economic and safety impacts. For deep mines or for deep tunnel projects, measures are available for aiding prediction of the extent of possible influence that large scale faults could create, but these techniques are rarely if ever applied as part of routine site investigation programs, or even as part of risk assessment evaluations. Several well established structural geologic methods of palao-history reconstruction have potential application for aiding forewarning of the extent of these types of potential problem by allowing estimates to be made of:• controlling stress orientations that might engender reactivation movement;• principal stress magnitudes that could lead to failure initiation, and• probable mechanisms of fault deformation - brittle (bursting) or plastic (squeezing).This paper explores several structural geological and rockmass characterization techniques that have application for unravelling fault structure of importance to deep engineering projects. Their application for mining or tunnelling purposes is advocated in conjunction with conventional rockmass characterization assessment approaches using GSI, RMR and/or Q to aid early recognition and definition of potential adverse ground condition behaviour associated with intersection of significant faulting at depth."

Jan 1, 2015

By Hongyan Qu, Lihui Zheng

"Horizontal wells in coal seams, Qinshui basin, China are prone to wellbore instability problems induced by drilling, completion and production operations due to the presence of natural cleat network, anisotropy with regard to permeability, brittleness and mechanically weak property of the coal rock. The mechanism of wellbore instability in coal seams is very different from that in conventional formations, the traditional wellbore stability study methods therefore, are not proper for wellbore stability analysis in coal.In this study, the mechanism and controlling of wellbore stability of coal seams in the Qinshui basin was investigated through theoretical modeling, laboratory experiment and field operation. Firstly, a new physical model of wellbore stability for highly-cleated coalbed was proposed, considering the combined effect of mechanical mechanism and reservoir characteristics, specifically, taking the effect of reservoir pore pressure in the vicinity of the wellbore on the wellbore stability into account. Then experiments on the triaxial stress evaluation were conducted at laboratory where rock mechanical parameters such as Poisson's ratio, Young's modulus, compressive strength, tensile strength, angle of internal friction and cohesion ability were measured respectively. The in situ stress at different depths in four wells of Zheng 1-303, Zheng 1-308, Zheng 1-309, and Zheng 1-310 in the Zhengzhuang were calculated, and the collapse pressure and formation breakdown pressure were predicted through the theoretical model we developed. Finally, by comparing the maximum collapse pressure and minimum breakdown pressure of the four wells in the coal as well as in the roof and floor of the coal seams, the fluid weight window for safe drilling in each coal seams was determined, and appropriate approaches against anti-sloughing in coal seams, Qinshui basin were applied in the field operation.The wellbore stability was found not only related to the wellbore pressure, but also affected by the pressure in the reservoir through the theoretical model. The fluid weight window for safe drilling in each coal seams varies with the coefficient of wellbore stability in the model. The laboratory experiment results indicate that the roof and floor of 3 # coal in Qinshui basin has high breaking strength, high heterogeneity, and are easy to collapse and breakdown. In addition, the whole rock mineral analysis shows that 3 # coal in the Duanshi block has high clay content, resulting in the phenomenon of hydration swelling as clay encountered water, and leading to unstable coal and extreme large drilling uncertainties. Due to the effect of the unstable rock mechanical properties of the roof and floor formation on the wellbore stabilizing, drilling parameters, drilling fluid performance and BHA were optimized during the drilling process according to the formation properties, rock mechanical properties and drilling techniques in the field operation."

Jan 1, 2015

By S. Usui, Y. Shinohara, C. Tokoro, K. Horiuchi, S. Owada

Process optimization of heating and physical separation for Cobalt (Co) recycling from spent lithium ion battery (LIB) was investigated. LiCoO2 in spent LIB was transformed to LixCoO2 which was more easily decomposed than LiCoO2 by heating. Coexisting materials of aluminum and carbon, and sealed atmosphere of the LIB promoted LixCoO2 decomposition. In an atmosphere of Argon, 95 % of LixCoO2 in the spent LIB was decomposed to 76 % of Co oxide and 19 % of Co metal in 10 min at 823 K; a lower temperature than the theoretical value for LiCoO2. The Co oxide and Co metal exhibited magnetic properties and could be recovered by wet magnetic separation. Furthermore, slow heating was effective for grain growth of Co oxide and Co metal. At 2 K/min rate of heating, average grain size of Co oxide and Co metal were 239 µm and 28 µm respectively, whereas at 30 K/min they were 190 µm and 15 µm respectively. Therefore, separation efficiency for Co recovery by wet magnetic separation was increased when spent LIB was slowly heated at 2 K/min.

Jan 1, 2015

By M. Zaske, E. R. Mortensen

"As mine operators continuously look for ways to improve functionality and increase the capacity of their facilities, existing process equipment is often pushed to and past its designed limitations. As a result, equipment manufacturers are asked for economical solutions to meet redefined processing needs. Newmont Mining in Nevada was faced with such a need in its carbon-in-leach (CIL) train. In a collaborative effort between Newmont and Derrick Corp., tests were conceived to assess the viability of drop-in replacement screens using a three-dimensional screen panel. The synthetic pyramid screen panel was designed to increase flux while maintaining the existing equipment footprint. The test is the end result of an ongoing research and development project that Derrick undertook in an effort to refine and upgrade its urethane screening media. The application of this new screening media is presented for this CIL application along with future plans to implement the technology in trash, safety, carbon dewatering, carbon sizing and other scalping applications.In spring 2014, Process Machinery Associates (PMA), Derrick’s local area representative, met with Newmont to discuss the operation of the in tank screens in the CIL train at Twin Creeks, near Golconda, NV. The process was originally designed for about 12+ kt/d (13,000+ stpd) but the throughput has been steadily rising since the plant was commissioned. Newmont now requires 14.5 kt/d (16,000 stpd) to be processed. The original screens were running at their maximum capacity, and Newmont required additional screening capacity to continue the upward trend in production.Physical separation by use of screening is one of mineral processing’s oldest methods. Screening media can be prone to blinding and pegging, and the necessary support structures required for finer apertures result in smaller open areas. Therefore, more screening area generally requires larger panels and, thus, larger machines, screening media that does not blind or a combination of both.In an effort to avoid larger machines, Derrick had been working on a revolutionary threedimensional panel that would add nonblinding screen area in the same footprint of an existing machine. Alpha testing of the new screen panels began at Newmont Mill 2/5 in July of 2013. It was still occurring when PMA approached Twin Creeks about beta testing a refined machine and pyramid panel. After presenting the initial results, Twin Creeks determined that an upgraded machine and pyramid panels would be a possible solution to meet production needs. The testing of a machine eliminated the risk of capital costs to Newmont and provided Derrick the opportunity to obtain additional data."

Jan 1, 2015

By Y. Wang, S. Liu, K. Jiang

China is the world’s largest producer and consumer of non-ferrous metals. In recent years, significant progress has been made in research and commercial application of pressure leaching technology to produce some nonferrous metals. Research and development activities include a low-pressure, low-temperature leaching technology for complex copper concentrates, a hematite process to treat pressure leach solutions from zinc concentrates, and a pressure leaching - solvent extraction process for molybdenum and rhenium. Examples of commercial practices include a two-stage pressure leach technology in a zinc plant in Danxia, a direct leaching technology in a zinc plant in Zhuzhou, a high pressure acid leaching process for a nickel laterite project in RAMU, and a pressure leaching technology to treat arsenic sulfides in a plant in Guixi. The development of pressure leaching technology for the recovery of lead, vanadium, gallium, germanium, and precious metals in China will also be described in this paper.

Jan 1, 2015

"Above ground, elevated belt conveyors with span >200m between support points can cross valleys, rivers, forests and buildings with minimal footprint. The Cable Bridge Conveyor is a new type of suspension bridge based belt conveyor system that has long span between support points. It combines typical belt conveyor and the improved simple suspension bridge to form a conveyor bridge. The improved simple suspension bridge places a widened bridge deck directly on suspended cables, without the need for high truss towers. The benefits include reduced cost and increase aerodynamic stability compared to conventional suspension bridges. The Cable Bridge Conveyor’s compatibility with current belt conveyors allows the versatility in application. INTRODUCTION Belt conveyor is a ubiquitous material handling system. Conveyors can be placed directly on ground or elevated above ground by support structures. Considerations of cost, design, environment, civil work, safety and process requirements are all factors in choosing the ground based or elevated conveyors (1). The ground based conveyor has the lowest structural cost, where the conveyor is laying on an existing road. Maintenance access is easy and straight forward. Compared to the ground based conveyor, the elevated conveyor can cross existing buildings and structures, give passage to traffic beneath the conveyor, has smaller footprint, and requires less civil work to pass mountainous areas. The drawback of the elevated conveyor is higher structural cost, which can be compared with savings in civil work and other benefits. Conventional elevated conveyors are supported by rigid truss type structures, with typical span of 15m to 25m between concrete support bents or steel trestles. Triangular truss, using steel pipes instead of hot rolled steel sections, is more efficient. The typical span of triangular truss supported conveyor is around 30m to 40m, while the weight is about 10% less than conventional box truss with shorter span (2). Long span elevated structure based on suspension bridge is another step forward in increasing the distance between support bents, reaching 100m~400m and beyond. The very wide distance between support points of an elevated conveyor offers unique benefits. The conveyor can cross rivers, valleys, highways, forests and other obstacles with minimal footprint and reduced civil work. The versatility from long span conveyors makes bulk material transportation over previously impossible terrains now a feasible option."

Jan 1, 2015

By Meeok Kim, Paul Beljan, Gordon Chen

"Clinton combined sewer overflow storage (CSO) facility project developed by the Department of Water Environment Protection of Onondaga County, New York, is to improve sewer facilities and infrastructure in Syracuse, New York. The below grade facility will provide a storage of untreated stormwater during highflow periods to be treated later, thus reducing CSO discharges to Onondaga Creek.The CSO system consists of three parallel storage tunnels and two end chambers (west and east chambers) as main underground structure. The storage tunnels are about 850 ft. long, 55 ft. wide, 24 ft tall and located 20 ft deep below grade. The chambers, include above access and operation structure, are about 40 to 55 ft. deep and approximately 60 to 100 ft. wide.Kiewit Infrastructure and Weidlinger Associates Inc. developed an alternative approach for the tunnels to meet the facility completion schedule, strict design guide lines and quality control as an environmental and water tight concrete structure for the project. The original design anticipated use of a TBM machine to bore three parallel tunnels between two previously constructed chambers.The alternative design used a three barrel culvert cast-in-place structure in a cut and cover excavation supported by a soil bentonite wall. The SOE along the jet grouted bottom seal provided a ground water cut off as well.The SOE system is specially designed to enhance the quality of culvert CIP structure construction by providing enough space for a full height construction. Also it further reduces the construction time by having the less squarefootage of jet grout installation. The design of tunnel systems is accomplished effectively through the utilization of soil structure interaction using a finite element methodIntroductionTo avoid construction of an additional treatment plant to handle increases in combined sewage flows, the Department of Water Environment Protection of Onondaga opted to construct the Clinton combined sewer overflow storage (CSO) facility.The Clinton CSO facility provides an environmental friendly mitigation method for combined sewer overflows on Onondaga lake which is located in northwest of Syracuse."

Jan 1, 2015

By Partha Sircar

"For Berth 22 modifications at the Port of Oakland, nearly 600 octagonal 24-inch ‘diameter’ precast-prestressed concrete piles were driven, some piles over 160 feet long. Prior to production pile driving, an indicator/test pile program was performed, which included extensive use of dynamic load testing with (Pile Driving Analyzer (PDA) & CAPWAP analyses. The indicator test-pile program resulted in requiring significantly longer piles than the original design based on subsurface borings. The cause of this discrepancy is investigated in light of the available geotechnical information, soil mechanics principles and standard techniques for pile capacity computations. Several interesting phenomena emerged. These include relatively low resistances offered by crushed rockfill than would conventionally be assumed, non-homogeneity of an apparently uniform formation and the effects of jetting on pile side friction. Also revealing was the significant increase in capacity between 1 and 3 weeks of driving for long piles in clay. Recommendations were developed for pile capacity for future use as “lessons learned”.IntroductionThe foundation for the replaced Berth 22 structure at the Port of Oakland in California involved driving approximately 570, 24-inch octagonal precast prestressed concrete piles. A plan and a section for the pile locations are presented in Figure 1.The ultimate loads on the piles used in the design are presented in Table 1 – the loads are quite heavy.The foundation design was followed by an extensive Indicator Pile Program. The contractors (Manson Construction Co. of Richmond, California) opted to use a Delmag D62-02 diesel hammer (Rated Maximum Energy – 165 kip-feet). Per the project specifications, the same hammer was used for both indicator and production pile driving. The production piles of appropriate lengths were ordered based on thr results of the Indicator Pile Program. A number of interesting results were found from the Indicator Program, which is discussed in this paper."

Jan 1, 2015

By S. Pastor, S. Hahn

"As the concept of autonomous haulage systems (AHS) moves from prototypes to production-ready applications, the operating performance of the haul road will become critical to the overall success of autonomy in mining. Deterioration in road performance will require remediation, human intervention and significant, albeit temporary, changes to operating procedures, to accommodate road maintenance. With autonomous trucks comes the opportunity to reduce road formation and operating width. This will, therefore, generate potentially significant reductions in stripping ratios and improvements to mine economics, but only if the design of the road, and its associated deterioration rate, is predictable and manageable, based on the materials used to construct the road and the maintenance interventions to be carried out on the road.This article presents the assessment of a digital photogrammetric approach to the characterization of a mine haul road surfacing, or wearing course material. Design and maintenance parameters for these roads are currently determined partly from physical particle size distribution (PSD) assessments of ‘in-road’ material. However, this approach does not accommodate the need, nor leverage the benefits from, AHS. The digital imaging approach is assessed in this article, using two standard digital analysis software tools, together with in-service mine haul road wearing course samples and images that are analyzed to determine the applicability and reliability of the approach to deliver a real-time assessment of haul road surfacing conditions and thus to identify the road maintenance interventions required to address deterioration.Enhancements in mine road design, construction and management for the past 20 or more years has largely been focused on short-term tactical needs. These improvements have not been matched by advances in the fundamental technologies that underpin mine road design and management and, although the quality of mine roads have probably"

Jan 1, 2015

By Liwen Hu, Jianxun Song, Hongmin Zhu, Qiuyu Wang, Shuqiang Jiao

The subchloride titanium was prepared by sponge titanium and titanium tetrachloride in the CaCl2 at 1173 K. The species were detected are mainly titanium dichloride, and the average valent in the melt are 2.05. The accurate equilibrium constants were obtained for the reaction 3Ti2+ = 2Ti3++Ti after the accurate activities of titanium chloride were evaluated with emf method, and the observed deviations from ideal behavior are discussed.

Jan 1, 2015

By Runsheng Xu, Haiyang Wang, Pengcheng Zhang, Tengfei Song

Semi coke, a byproduct in the chemical industry, is a new fuel for blast furnace injection in China. In this study, semi coke and bitumite were milled into different size, ranged from 0.147mm to under 0.074mm. The content of volatile matter and ash, which affect the combustibility of semi coke, were measured using muffle furnace. The mixture, in which the proportion of coal in different sizes changed, was blend by semi coke and bitumite with different size. Activation energy calculation and the comprehensive combustion characteristic index of all kinds of blends was also discussed. The result obtained by Thermogravimetry –Derivative Thermogravimetry curves indicates that the smaller the size of mixture is, the lower for the characteristic temperature, and the better for its combustibility, Semi coke can be a substitute for anthracite in blast furnace injection.

Jan 1, 2015

By Cui Wang, Qian Li, Kexin Jiao, Haibin Zuo, Jianliang Zhang

Abstract：A rational cooling water system is the assurance for long campaign life of blast furnace．In the paper, the heat transfer of different furnace period and different furnace condition based on the water quality characteristics were analysed, and the reason of the heat flux over the normal from the hydrodynamics was analysed. The results showed that, the vapour-film and scale existence significantly influenced the hearth heat transfer, which accelerated the brick lining erosion. The water dynamic characteristics of the parallel inner pipe or among the pipes were the main reason for the abnormal heat flux and film boiling. As to the reasonable cooling water flow, the gas film and the scale should be controlled and the energy saving should be considered.

Jan 1, 2015

By Virgil Optasanu, Yvon Lacroute, Eric Lesniewska, Tony Montessin, Pauline Vitry, Eric Bourillot, Cédric Plassard

A general challenge in metallic components is the need for materials research to improve the service lifetime of the structural tanks or tubes subjected to harsh environments or the storage medium for the products. One major problem is the formation of lightest chemical elements bubbles or different chemical association, which can have a significant impact on the mechanical properties and structural stability of materials. The high migration mobility of these light chemical elements in solids presents a challenge for experimental characterization. Here, we present work relating to an original non-destructive, with high spatial resolution, tomographic technique based on Scanning Microwave Microscopy (SMM), which is used to visualize in-depth chemical composition of solid solution of a light chemical element in a metal. The experiments showed the capacity of SMM to detect volume. Measurements realized at different frequencies give access to a tomographic study of the sample.

Jan 1, 2015

By Qian Li, Li-chen Hou, Yong-bin Yang, Tao Jiang, Jian-jun Hu, Bing Xu

Extraction of gold from refractory gold concentrates usually requires an oxidation step to remove arsenides、sulphides and carbonaceous matter. In this investigation, the gold concentrates were two-stage roasted under different atmospheres and temperatures. Results indicated that at the first stage, under neutral atmosphere, the removal rate of arsenic increases as the temperature rises. Under the oxidizing atmosphere, with the increase of temperature, arsenic content in the residued calcine increases, in addition, the volatilization of arsenic is also affected by the oxidation of carbon that generated CO, which is advantageous to the decomposition of arsenate decomposition. At the second stage of roasting, it is the higher temperature and stronger oxidizing atmosphere, the faster sulfur and carbon oxidated rate is, but at the same time, the calcine appears the phenomenon of consolidation because of the phase of silicate compounds generate.

Jan 1, 2015

By Shuqiang Guo, Xionggang Lu, Yuyang Bian, Weizhong Ding, Lan Jiang, Kai Tang, Changyuan Lu

For recovery of rare earth elements from the NdFeB based permanent magnet scraps, a high temperature process was used. Permanent magnets scraps were firstly oxidized in air. The optimal oxidation conditions under air are at temperature of 700oC holding for 30min. After the oxidation process, the oxides were reduced by graphite crucible at 1500oC under Ar atmosphere. By this way, the rare earth elements were recovered in the form of oxides, and Fe was separated to the metal phase. Boron distributed in both the rare earth oxides (REO) containing slag and the metal phase. In order to reduce the boron contents in the rare earth oxides, the carbon saturated iron bath and NdFeB added carbon saturated iron bath were used to refine the slag. By this process, the rare earth oxides with a comparatively high purity of 98.2% were gotten.

Jan 1, 2015

By Patrick M. Eduafo, Brajendra Mishra, Mark L. Strauss

Direct acid leaching of rare earth metals (REMs) from waste lamp phosphors is non-selective, leading to co-dissolution of impurities mainly calcium, phosphorus, silicon, iron and zinc. Calcining the phosphor powder at different temperatures followed by leaching with HCl isn’t efficient for the extraction of all the chief rare earths especially cerium (Ce), lanthanum (La) and terbium (Tb). Therefore, multi-stage leaching operations are required for the separation of the REMs in phosphor dust. This paper will outline a new process for extracting Ce, La, Tb, Eu and Y from waste fluorescent lamps using a three-stage leaching and separation process. A flowsheet has been developed which shows this process is selective and efficient.

Jan 1, 2015