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By A. Boehm

"For recycling LD slag into the steel making process, the phosphorous containing calcium silcate phases have to be removed from iron oxide phases. One possible technical solution could be magnetic separation in a wide range of susceptibilities from ferromagnetic to paramagnetic. To check the feasibility of magnetic separation the distribution of the magnetic susceptibility in size classes as well as the liberation of the phosphorous containing phase were evaluated by a new method combining two dimensional physical property analysis with QEMSCAN analysis. The particle size classes of energy controlled comminution products were subdivided into fractions of defined magnetic susceptibility using a hand magnet of well known field properties (pick up method). On the one hand the susceptibility classes were wet assayed on the other hand analyzed by QEMSCAN followed by data evaluation using iDiscover 5.3.1(FEI), which was adapted to the data structure of two physical properties (size and magnetic mass susceptibility). The results allow the comparison of mass based (3D) cumulative distribution of grades from the wet assays with the area based (2D) distribution from QEMSCAN analysis, in order to control a systematic (size dependent) stereological error for this special type of material. As the physical separation property forms a crucial parameter the results from the liberation analysis by QEMSCAN can be interpreted more profound with respect to an expectable separation result. Once the various mineral compositions of the particles are assigned to the physical properties the Henry Reinhardt chart serves to predict the best possible separation result and thus the feasibility of a separation technique.INTRODUCTIONThe two Austrian steel plants operated by voestalpine AG produce about 650,000 t (voestalpine 2014) of LD slag in the course of steel production from pig iron according to the basic oxygen process blowing oxygen in the converter by an oxygen lance. The process is also known as the Linz Donawitz (LD) steelmaking process. By the addition of lime (CaO), carbon, phosphorus, silica, manganese and sulfur, which are present in the molten pig iron, shall be oxidized and bound in the slag either as oxide or silicate phases, or leave the slag in the gaseous phase (CO). The average chemical composition of the investigated LD slag is given in table 1."

Jan 1, 2016

By F. Chiesa, Jeremy Carignan, B. Duchesne, D. Levasseur

"Aluminium A206 (AlCu4) is one of the strongest aluminium casting alloys with tensile properties approaching those of ferritic ductile iron. If the specification on the silicon content (< 0.05%) is easy to achieve during alloy ingot production, it is not the case in a foundry, where returns are used which are not perfectly cleaned from the silicate containing molding sand (Olivine). In alloy A206, the Si content is controlled in order to avoid the formation of a low melting point intermetallic phase (such as phase Q Al5Cu2Si6Mg2); these phases will melt during the solutionizing heat treatment to which alloy A206 must be subjected to develop its outstanding mechanical properties. This incipient melting may deteriorate the mechanical properties of Alloy A206 if the solutionizing treatment is applied at the standard temperature of 530°C.In the present study, a lower temperature solutionizing (520°C) was applied to a high Si content 206 alloy in order to reduce or eliminate the possible incipient melting. This was carried out on a complex shape industrial casting weighing 14 kg (31 lb) and 560x410x250 mm (22x16x10”) in size poured in aluminum 206 with a high silicon content (0.22% vs 0.05% max for alloy A206). Twenty ASTM E8 subsize tensile specimens were excised from two locations in the casting in order to compare the tensile properties for the two solutionizing temperature used (530 and 520°C). Optical and SEM microscopy allowed to investigate the causes of the differences in the properties observed between the 2 zones of the casting studied for 3 different heat treatments. INTRODUCTIONIn spite of their “textbook” outstanding mechanical properties (Up to twice the strength and elongation of the widely used A356 alloy), aluminum-copper alloys of the 2xx series are seldom used because of their propensity for hot tearing [Li, 2011], the segregation of copper [Cho, 2003], and their sensitivity to stress corrosion cracking [Jean, 2009, p. 113)]. Also, because of their wide freezing range and high thermal conductivity, a wide mushy zone makes feeding difficult, unless strong temperature gradients are created by liberal use of chills and risers in the critical zones of the part. Because they are prone to hot tearing, grain refining of Al-Cu alloys is particularly important, titanium playing a major role in the process [Sigworth, 2003]; grain refining has also been shown to be beneficial to fatigue strength [Jean, 2009, p. 103]. The practical basis of foundry practices pertaining to these alloys is outlined in an AFS webinar [Weiss, 2014]."

Jan 1, 2016

By John R. Goode

"This paper reviews options for the separation of a mixture of rare earth elements (REE) into its component elements. Earlier separations used selective chemistry such as double salt precipitation and reductive/oxidative processes – methods that still have a place in the industry. Fractional crystallization was developed for more complete separations of adjacent REE. The latter method was replaced by ion exchange (IX), which was in turn replaced by solvent extraction (SX). Two main SX chemistries are in use, solvation and cation exchangers, with several variants (mixed solvents, ionic liquids, etc.) now under investigation. SX plant configurations have evolved including advanced techniques like “hyperlinking”, novel saponification methods, and alternative stripping techniques. The classic mixer-settler is the most commonly employed device although centrifugal contactors have been pilot-tested. Non-dispersive SX options including microfluidic devices and membrane-assisted SX techniques are being developed and could revolutionize the SX option. Other REE separation techniques now being studied include Molecular Recognition Technology (MRT), Free Flow Electrophoresis (FFE), newer IX systems, and electrolytic processes. Additionally, the classical crystallization and selective precipitation methods and newer bacteria-mediated processes, chloride volatilization, high performance liquid chromatography, and magnetic separation systems have been studied. This paper reviews the options and concludes that conventional SX is the technology of choice but viable alternatives could be demonstrated and acceptable within a couple of years.INTRODUCTIONThe chemical properties of the individual REE are very similar which is why REE minerals and ore deposits almost invariably contain a mixture of all fifteen REE, i.e., La to Lu plus Y. That said, the distribution of REE in a given deposit is frequently dominated by the light REE (LREE, i.e., La to Nd). Examples include the Bayan Obo, Mianning, Lynas Mt. Weld, and Molycorp Mountain Pass deposits where heavy REE (HREE – Sm to Lu and Y) typically account for well under 5% of the REE content. The LREE operations produce some HREE but the main sources of these important elements are the ionic clay deposits of Southern China. Importantly, all of the REE recovery operations referenced above, except for cerianite-bearing ionic clay deposits, initially produce a mixed REE precipitate or calcine with a REE distribution similar to that in the ore (Goode, 2016). However, the consumers of the REE, the manufacturers of magnets, phosphors, catalysts, optical glass, etc., require separated products with purities generally ranging from 99% to as high as 99.9999% depending on the element in question and the end use. Hence there is a need to separate the individual REE one from the other. This paper is intended to review the options."

Jan 1, 2016

By Baochun Wang, Hongli Jia, Zhaolian Wang, Fengliang Liu

"Promote and apply a new beneficiation technology and equipment effectively processing the refractory and medium-fine grained weak-magnetic minerals. HUATE® Forced-oil Cooling Vertical Ring WHIMS adopts the transformer oil cooling technology to cool excitation coils, solving the easily generated scaling problem resulting from water cooling, thereby to eliminate the demineralized water system. With <25 temperature ?raise, its magnetic field is stable. Wrapped by outer magnetic armor, it can generate a background intensity 1360kA/m. It effects very well in 1) wet preseparating the weak-magnetic coarse grains, like hematite, manganese ore, ilmenite, and purifying the concentrate; 2) removing the ferrous impurities and purifying the non-metallic minerals, like quartz, feldspar, kaolin; 3) enriching and recovering tailings from non-ferrous metals, like copper, lead, cobalt, molybdenum, thereby to greatly improve the mine resource utilization. It has applied 14 relative patents in China, and the invention patent in 56 countries, like Russia, USA, Australia, via PCT international organization. HUATE® WHIMS has been applied and accepted in more than 100 mines in and out of China. Compared with water cooling vertical ring WHIMS, it’s energy-saving and water-saving, and avoiding generating the scale. While compared with JONES WHIMS under the same separation indexes, it’s featured of more space-effective, lighter, lower costs, higher gradient, higher efficiency, larger processing capacity and wider grain application scope. Greatly promoting development of mineral processing technologies, HUATE® WHIMS is the equipment to reduce costs and improve efficiency urgently needed by the mine enterprises now.INTRODUCTIONAt present, influenced by the price and production factors, the international market demand for the grade of iron ores is increasing continuously. Restricted by the ore occurrence state, the beneficiation technology level and product economic value, every year the stope strips the stockpiling and discards hundreds of millions of tons of waste rocks containing iron, especially the weak magnetic hematite and limonite with <20% Fe%. The utilization technological bottleneck of these waste rocks makes their concentration ratio as high as 5-6, which leads to the huge wastes of energy, materials and beneficiation reagents and the increase of production costs. The effective solution is to improve the selected Fe% of the waste rocks like hematite. With the successful application of HPGR technologies in Chinese large iron mines, the mill feeding size has been reduced to 6-0 mm or 3-0 mm from the original 15-0 mm in the crushing system with 3 stages of crushing and 1 stage of closed circuit. This creates the conditions for the wet separation and recovery. While for the medium-fine grained weak-magnetic minerals, it lacks of the effective separation and recovery equipment in the world, which’s badly in need of R&D of the medium-fine grained high gradient wet strong magnetic preseparation equipment."

Jan 1, 2016

By M. Bunch

"THE SUPER CYCLE IS GONE The utopia of the rising sales volume, for mining companies from 2002-2011, was entirely due to rising production volume and prices. The Australian mining sector experienced an 18 percent annual growth rate in revenues, and 11 percent growth in prices. (1) However, EBIT remained flat during the same time period. In addition, Australian mines saw a 7 percent annual decline in both labor and capital productivity. (2) Mines in the U.S. and Canada produced similar results, whereas the world-wide mining industry has seen a productivity drop of 40% since 2001. (3) The decade “Bull Run” of rising prices was trashed by companies that chased low-quality assets while increasing debt on their balance sheet. It seemed everyone believed the “super cycle” would last forever, while completely ignoring the history of cycle downturns. Worldwide mining operations are as much as 28 percent less productive today than a decade ago, according to new McKinsey research. The results from McKinsey’s new MineLens Productivity Index (MPI), which adjusts for declining ore grades and mine cost inflation, show that the pronounced decline in productivity is evident across different commodities and is seen in most mining players and geographies. (4) McKinsey sees three important areas of focus to address the root causes of productivity decline. 1) Embed effective management operating systems at mines 2) Prioritized operational excellence and capabilities development 3) Focus on innovation Reality has now settled back in and companies are struggling to make ends meet. The basic management staple of controlling costs and improving the production/productivity that was lost in the excitement is now back in play. Traditional cost-cutting approaches, such as across-the-board spending cuts, layoffs, and hiring freezes are only short-term initiatives and will not permanently improve a company’s cost structure or improve long- term competitiveness. This can only be accomplished by engaging front-line employees and empowering them to make necessary improvements in their daily work. It is time for leaders to lead and develop cultures of continuous improvement within their organizations in order to sustain their mining project to the end of mine life. Successful operating managers require two different skill sets of Leadership and Management; knowing how to lead people in their organization and how to manage the work they do."

Jan 1, 2016

By T. Thriveni, Ji Whan Ahn

"The current advanced technologies for the manufacture of light weight metals processing significantly increasing and attributes to the safety, performance, recyclability and economy. Still lack of technologies developed for light weight metals processing waste utilization and application. Environmentally friendly methods need to develop for better understanding the processing waste utilization. Alumina and aluminium processing creates a wide range of waste products, the most significant being is red mud. Bauxite residue is a high volume hazardous waste and nearly 3 billion tons have been dumped worldwide. Approximately, 120 Million tons/yr of red mud being produced without any environmental sustainable solution. Currently the most significant technology is waste utilization. The bauxite residue is suitable for road base construction, golf bunker sand, back fill and, general fill. Sustainable recycling technologies are necessary for the bauxite residue utilization for the recovery of rare earth elements and cement materials. Carbonation or CO2 sequestration of carbon dioxide is a method pioneered for the bauxite residue is modified to reduce alkalinity. The carbonation of alkaline material is an inexpensive and safe process that leads to the formation of thermodynamically stable products. The use of the carbonation can be an advantageous solution for environmental climate change and sustainability problems in the new century.INTRODUCTIONIn 2014, bauxite consumption was estimated to be 9.6 million tons, nearly all of which was imported, worth an estimated 269 million dollars. More than 95% of the bauxite was converted to alumina, and the remaining 5% went to non-metallurgical products, such as abrasives, chemicals, proppants, and refractories. Global aluminum demand is growing steadily spurred by growth in India and China (RBCAluminum Market Outlook, 2013) (Figure 1). Aluminum consumption is expected to rise 5% annually through the end of the decade, reaching 67 million tons per year by 2020. Global bauxite production decreased by 17% from that of 2013, principally owing to lower production in Indonesia. In response to a Government ban on exporting bauxite and other unprocessed mineral ores that took effect on January 12, 2014, bauxite mines throughout Indonesia shut down and production decreased from 55.7 million tons in 2013 to an estimated 500,000 tons in 2014. The ban was part of a mining law that was instituted in 2009 to increase development of downstream processing facilities in Indonesia."

Jan 1, 2016

By G. Simard, D. Boudeville, A. Leclerc, A. Boivin

"The objective of this work is to study the various parameters that affect the overflow clarity of gravity settlers used in the precipitation circuit of alumina hydrate from the Bayer process. A mathematical model incorporating the size distribution of the feed suspension (Multi Size Group model), its diphasic nature (Schiller Naumann model) and the presence of turbulence (Shear Stress Transport model) has been solved numerically using ANSYS-CFX software. Preliminary results indicate that the overflow clarity is mainly controlled by lateral diffusion of fine particles (~20µm) from the exit of the feed well and by their upward transport from the sediment bed interface. Also the turbulence pattern in the settling zone seems to play a significant role in this vertical transportation. The validity of the model has been verified by comparing the measured solid concentrations from a pilot classifier with the calculated ones. This model could provide mineral processing plant operators and designers with a tool to optimize the configuration of classifiers with respect to the overflow clarity.INTRODUCTIONProblemIn the Bayer process, alumina hydrate precipitation from the saturated liquor is initiated in settler by adding crystallization seeds. Most of the precipitated alumina settles to the bottom of the tank while the liquor and the remaining alumina rise to the top, where they are removed at the overflow. Ideally the overflow clarity, which depends on the operational mode of the classifier, should be controlled within targeted limits."

Jan 1, 2016

By Eugene Barsky

"At present, theoretical concepts of gravitational separation processes are mainly limited by the study of the interaction between a flow and a solitary particle. Then the main conclusions of this analysis are applied to a mass process. However, this analysis is absolutely insufficient, because some elementary phenomena such as the ingress of coarse particles into the fine product output and vice versa cannot be interpreted from its standpoint. It is also impossible to predict the results of the classification of a material with a specific granulometric composition on a specific apparatus on its basis.In the present paper, an extended model of the process is suggested. The model is based on the behavior of all the particles of a specific narrow size class, and not on that of an individual particle. Similarity criteria of the process, which were empirically derived previously, are obtained from the analysis of this model.INTRODUCTIONIn case of gravitational separation, a part of solid phase moves, as a rule, vertically upwards with the flow, while another part settles against the flow. This flow is extremely complicated and chaotic due to various random factors. Among these factors are mass interactions of particles with each other and with the apparatus walls, non-uniform character of concentration and velocity fields, turbulent vortices and local fluctuations, real particles shape difference from spherical one, etc.Particles rotation results in a transverse force (Magnus' effect). At the motion of a non-rotating particle in a non-uniform velocity field, a transverse force also arises (Saffman's effect).A great number of publications have been devoted to the account for all these factors in two-phase flows in recent decades. Very complicated models have been developed, but the problem has not been completely solved as yet [1, 3].At the same time, simplified models of the behavior of a solitary particle in a flow are being developed. Despite their schematic nature, such models often prove to be useful for establishing general laws of the process and its similarity criteria [1]."

Jan 1, 2016

By Christopher R. Harris

"Considerations are presented for developing and implementing self-hardening slurry mix designs to be utilized in barrier seepage walls. Slag-cement-cement-bentonite (SCCB) slurries are the primary focus, with some comparisons referenced to the more traditional Portland-based cement-bentonite (CB) slurries. Field and laboratory mixing methods are reviewed, including 1) single sack – single mixer method; 2) bentonite slurry mixer – cementitious addition mixer method; 3) bentonite mixer – grout mixer – CB blending mixer method. Major phenomena associated with the dynamics of barrier wall excavation, such as loss of water from the in-trench slurry and consolidation of in-trench slurry are discussed. Other topics touched upon include sand content effects, fluidizers utilized, and chemical contaminants. The role of higher bentonite to water ratio is reviewed, with demonstration of improvement of filtration properties, and an increase of water retention of the final consolidated product.IntroductionSelf-hardening slurry has been utilized to construct barrier seepage walls for many decades. This is essentially a single-step slurry excavation and backfill process whereby the trench-supporting fluid gains strength over a short period during installation and maintains or develops low hydraulic conductivity. The resulting curing slurry becomes the actual barrier wall as the resultant cement-augmented clay slurry now fulfills the dual purpose of both temporary trench stabilization and final cured-in-place product. This eliminates the requirement and expense of subsequent backfill/slurry displacement operations required in traditional barrier wall installations.Self-hardening slurries have been fabricated using a number of various clays, most commonly sodium bentonite, calcium bentonite, attapulgite, and sepiolite. Perhaps due to plentiful high quality sodium bentonite deposits found domestically, the proven excavation stabilization properties imparted from sodium bentonite slurries, sodium bentonites are typically specified for formulating self-hardening slurries in the US. Cementitious materials utilized most commonly are Portland cement and slag (ground blast furnace slag or GBFS). For the purposes of this discussion, self-hardening slurry having a cementitious of Portland will be referred to as CB. Those having cementitious material of GBFS replacing Portland (partially or wholly) will be referred to as SCCB."

Jan 1, 2016

By Chu E. Ho, Alfredas Daugiala, Nicola Ebanks

"The construction of an ancillary structure for the new Second Avenue Subway Line in Manhattan, New York City involved a deep excavation in highly variable rock conditions adjacent to a fragile masonry building. The maximum difference between the lowest and highest rock elevations was about 30 feet, which posed a problem for the installation of secant piles that formed the supporting retaining wall for the excavation. At certain areas, the rock levels were higher than the top of the invert slab of the ancillary structure. To avoid disturbance to the adjacent fragile building, the secant piles were fully cased for drilling through the overburden soils and the rock sockets were formed using non-vibratory technique. This paper discusses the design and installation details of the secant pile wall and the contingency measures that were considered to mitigate the highly variable rock conditions. Monitoring of the adjacent fragile building showed that impact of pile installation were controlled within tolerable limits and safety of the building was not compromised.INTRODUCTIONThe 96th Street Station forms part of the newly constructed Second Avenue Subway Line on the East side of Manhattan Island, New York City (Figure 1). During construction of this station, several deep excavations were carried out adjacent to existing fragile buildings (Arksman et al. 2012, Grigson et al. 2016). These fragile buildings were typically four to five stories high, with a single rubble wall basement supported on timber piles or seated directly on the fill. The timber piles were often found to be in a poor condition and connections to the footings were compromised due to rotting of the timber within the zone of water table fluctuation. Several of these fragile buildings had to be strengthened and underpinned to improve the stability of the structures prior to commencement of excavation for the new subway station box (Trabold et al. 2012, Ho and Pena-Iguaran, 2013). The situation was most challenging at Ancillary Buildings 1 and 2 located at 93rd and 97th Street respectively, where secant pile walls were located merely 2 feet away from the adjacent property line, due to architectural space constraints. While mitigation of excavation induced ground movements can be controlled by the adoption of a stiff excavation support system, a more concerning factor was the uncertainty associated with the impact of the secant pile wall installation on the stability of the existing fragile buildings. This was particularly difficult at Ancillary 1 where the secant piles encountered highly variable rock levels that intruded into the excavation space. The following sections discuss the design and installation of the secant pile wall and contingency measures that were considered at Ancillary 1."

Jan 1, 2016

By G. Meschke

"This paper reports on computational and experimental research, performed at the Collaborative Research Center “Interaction Models for Mechanized Tunneling” at Ruhr-University Bochum, Germany. Research covers a broad spectrum of topics relevant for mechanized tunneling in soft soil conditions. This includes advances exploration methods and models for the characterization of the in-situ ground conditions, the interaction of the face support and the tail gap grouting with the porous soil, multi-scale models for the design of fiber reinforced segmental linings with enhanced robustness, computational methods for the numerical simulation of the tunnel advancement, the soil excavation and the material transport in the pressure chamber, logistics processes and risk analysis in urban tunneling.INTRODUCTIONMechanized Tunneling has proven itself as an economical and flexible construction method that continues to undergo a dynamic evolution process. Shield diameters continue to increase, and the application range of tunnel boring machines is being extended to an ever-increasing variety of geotechnical conditions. In order to maintain economic viability and to ensure an environmentally friendly construction process, realistic and reliable numerical models are required in order to make informed decisions during planning and construction. To provide a reliable numerical prognosis, it is necessary to accurately assess and understand the interactions between the components involved in mechanized tunneling with the surrounding site, the ground, and any pre-existing structures. Heterogeneous geological conditions and often only approximated ground parameters create, in contrast to other engineering projects, special demands. This necessitates new insights to new problems that can only be effectively solved through truly interdisciplinary research. To address these challenges, the German Research Foundation (DFG) has established the Collaborative Research Center “Interaction Models for Mechanized Tunneling” (SFB 837) at the Ruhr-University in Bochum in 2010. Collaborative Research Centers are interdisciplinary scientific research groups in which cooperative research is conducted under the umbrella of a central research theme. With a research budget of ca. 10 Million Euros for the second 4-year funding period, and a research team composed of 13 project leaders along with approximately 35 scientific assistants the SFB 837 is currently one of the largest research groups conducting fundamental research in tunneling related topics worldwide.RESEARCH TOPICSThe research topics of the SFB 837 encompass a number of relevant planning and construction related aspects in mechanized tunneling (Figure 1). These research themes are each supported by computational models and laboratory investigations and are all included in an SFB overarching Tunnel Information Model (TIM). Interaction groups integrate and combine the results of different submodels through prototypical cause-and-effect relationships, and through the analysis of the Wehrhahn metro line (WHL) project in Düsseldorf, which has been adopted as the reference project for the SFB 837."

Jan 1, 2016

By Guiqing Zhang, Liansheng Xiao, Zuoying Cao, Li Zeng

A new process of direct solvent extraction of nickel from sulfuric acid leach solutions of low grade and complicated nickel resources using a novel extractant HBL110 was proposed. The basic performance of new organic system was investigated and the continuous pilot plant and the industrial test were conducted. The results indicated that the extractant of HBL110 can be used to directly extract nickel selectively over iron, aluminum, manganese, magnesium, calcium and chromium from sulfuric acid leach solutions. The loaded organic solution can be easily stripped using dilute H2SO4 solutions. Both kinetics of extraction and stripping of nickel were fast. The continuous pilot plant test with the sulfuric acid leach solution of laterite containing 6.22g/L Ni2+, 14.1g/L Fe3+, 0.73g/L Fe2+, 33.9g/L Mg2+, 1.58g/L Al3+, 0.495g/L Ca2+, 0.97g/L Mn2+ and 0.5g/L Cr3+ as feed in mixer-settlers showed that the process had run stably with 98% recovery of nickel. The concentration of nickel in strip liquors reached as high as 50 g/L while the removals of Fe3+, Fe2+, Mg2+, Al3+, Ca2+, Mn2+ and Cr3+ were 98.5%, 91.5%, 99.95%, 99.8%, 99.1%, 98.6% and 99.5%, respectively. The industrial test with the sulfuric acid leach solution of electroplating sludge containing 11.5g/L Ni2+, 2.68g/L Fe3+, 7.54g/L Cr3+, 0.61g/L Mg2+, 2.09g/L Al3+, 0.68g/L Ca2+, 0.022g/L Mn2+ and 0.154g/L SiO2 as feed in mixer-settlers also showed that the process had operated successfully with 99.5% recovery of nickel. The concentration of nickel in strip liquors reached 42.7 g/L while the removals of Fe3+, Cr3+, Mg2+, Al3+, Ca2+, Mn2+ and SiO2 were 99.2%, 99.77%, 99.73%, 99.56%, 99.57%, 98.51% and 98.75%, respectively. The new process exhibited big advantages of short flow sheet, high recovery of nickel, high removal of impurities, low chemical reagent consumption and low cost. Application of this process in industry is expected to make important impact on the extraction of nickel from sulfuric acid leach solutions and to deliver good environmental and economical benefits.

Jan 1, 2016

By Petrus Christiaan Pistorius, Farzin Fatollahi-Fard

The production of synthetic rutile—a common starting material for most titanium production processes—from iron-rich titanium minerals such as pseudorutile and ilmenite is described. The process for “upgrading” the mineral to synthetic rutile is by carbothermal reduction of the mineral while immersed in a molten salt at high temperature, followed by magnetic separation of the reduced iron. A variety of factors are also investigated, such as particle size of the mineral, the type of mineral, and the molten salt used. The solubility of iron(III) oxide in different molten salts is also experimentally determined.

Jan 1, 2016

By Peter Sylvén, Darwin Morales

Despite being crucial for the smelting process, furnace tapping using oxygen lances has not been considered an operation that brings value. Therefore, these important tools have not seen a significant change in over 100 years. Problems related to the use of oxygen lances include: • Inaccurate tool: causing damages shortening the life of the taphole refractories. • Safety: extended exposure to the operator in an unsafe area of the furnace. • Cost: high oxygen consumption & high lance consumption. • Time consuming and frustrating to connect one lance to another. This paper will suggest a very good solution; new concept thermal lances. We will show how these provide an outstanding performance for a more efficient, faster and cost-effective furnace tapping operation. These new lances are very accurate tools that enable the operator to perform a more controlled operation; resulting in longer taphole life, fewer repairs and less down-time.

Jan 1, 2016

By Mike Johnson, Niels Verbaan, David Dreisinger

The Search Minerals Foxtrot project in Labrador is a surface deposit enriched in the highly sought after heavy rare earth elements. Early metallurgical work investigated beneficiation of the rare earth content of the Foxtrot resource using flotation, gravity separation and magnetic separation. The concentrate was then processed by acid baking and water leaching to produce a REE leachate for purification and recovery. The Search Minerals Direct Extraction Process was developed through bypassing the beneficiation process and directly acid treating a coarse crushed ore material prior to water leaching. The result is a simple, low risk technical process for direct recovery. Concurrently, the treatment of the water leach solution was modified to produce a high grade (98.9% total rare earth oxide) product for refining.

Jan 1, 2016

By Peng ZANG, Qihang Liu

Experimental work was conducted to determine the relationships of coal char conversion with temperature and heat absorption. The results show that at an earlier stage of the coke forming process, lump coal would absorb large amounts of heat but the increase of high temperature strength of lump coal was not significant. Contrarily, the lump coal’s high temperature strength was greatly improved at later stage of coke forming process. A number of residual coal was found in most tuyere coke samples illustrating that the lump coals added in the melter gasifier were not completely transformed into coke when they arrived at the tuyere region. The results indicate that the improvement of lump coal’s high temperature performance is limited in the melting gasifier by the low coke forming rate which could become the core factor of fines generation of lump coal in the melting gasifier.

Jan 1, 2016

By Pan Gu, Zhen Zhang, Jiang Diao, Bing Xie, Hongyi Li

Furnace refractories are in most cases chemically incompatible with smelter slag, which leads to a steady erosion in their thickness over time. Once too thin, refractory walls become mechanically unstable and catastrophic failure can result. Historically, external shell cooling was applied to generate a freeze lining of slag and thus prevent refractory erosion. Many modern high intensity smelting furnaces instead maintain their physical integrity by the use of internally cooled wall panels, plates or finger coolers. An initial refractory lining is often installed inside of the coolers, such that the furnace originally operates with a temperature (insulated) rather than a heat flux (freeze lined) boundary condition. This paper examines the change in slag-wall heat transfer coefficient and slag superheat as a function of process intensity. The implications of the changes in heat transfer on residual brick thickness are explored using analytical modelling.

Jan 1, 2016

By Huanmei Yuan, Yuanyuan Wang, Hao Bai

Composite phase change materials are widely used in energy-saving and energy efficient process. Nano-encapsulated phase change materials are especially significant for making advanced working fluid applicable to waste heat recovery or storage. In this study, silica-coated stearic acid (SA) Nano composite phase change materials were prepared from tetraethyl orthosilicate (TEOS) and stearic acid (SA) via sol-gel process. The materials were investigated by Field emission scanning electron microscopy (FE-SEM), Transmission electron microscope (TEM), Fourier transform infrared spectroscopy(FT-IR) and Differential scanning calorimeter (DSC).The FE-SEM and TEM results show that monodisperse microspheres with stable core– shell structure were formed and SA was encapsulated in the silicon dioxide shell. The FT-IR results show that there were no chemical reaction between silicon dioxide and SA, which is the chemical property of the composite material, is stable. The DSC results show that the composite phase change material has favorable heat capacity.

Jan 1, 2016

By Minting Li, Hailong Yang, ChangWei, Cunxiong Li, Gang Fan, Xingbin Li, ZhiganDeng

The filtration problems on acid leaching sludge of high silicon zinc ore have been paid extensive attention in zinc hydrometallurgy. It was found that soluble silica can be effectively converted into silica precipitate with good settling, filtration and washing properties, and the filtration rate can be in excess of 800 L/m2 · h under certain leaching conditions. According to investigating on the filtration rate, viscosity and concentration of silica of leaching sludge or liquor, the filtering temperature can tremendously improve the filtration property of pulp. At the same time, the experimental data indicated that the viscosity of leaching liquor was the key factor influencing filtration property of leaching sludge.

Jan 1, 2016

By Bo Liang, Hongmin Zhu, Kai Huang, Shafiq Alam

A new approach of recovering platinum and palladium from electronic wastes by hydrochloric acid leaching followed by selective adsorption on low-cost and environmentally benign biomass sorbent prepared from easily available agriculture waste is suggested. The obtained adsorbents were prepared by a combination of chemical modification and hydrothermal carbonization process with (NH4)2C2O4. It was found that the maximum adsorption capacity of hydrothermal carbonized garlic peel for Pt( ) and Pd( ) was 1.64 and 0.42 mol/kg respectively. The Langmuir adsorption isotherm was applied to describe the adsorption process. Kinetics of the Pt( ) and Pd( ) ions adsorption was found to follow pseudo-second-order rate equation. The adsorbents were examined by scanning electron microscope (SEM), and Fourier transform infrared spectroscopy (FT-IR). Based on the characterization results, a possible mechanism of Pt( ) and Pd( ) ions adsorption with the hydrothermal carbonized garlic peel was proposed. This study provides a promising adsorbent with efficient adsorption property for platinum and palladium recovery from the leach solution of electronic wastes.

Jan 1, 2016