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By S. L. Gay

The conventional mass-balance equations used as constraints can lead to flow estimate values of zero even though the flow estimates should be some positive number. This is because many of the constraint equations are satisfied if the flow rates are zero. The way to overcome the problem is to use a slightly different form of the equations. For example, rather than use the conservation of flow of solids as a constraint it is better to use the constraint that the percentage of solids going into a unit equals the percentage of solids coming out of the unit. Examples are given using mineral processing data sets from Mount Isa, Queensland, and Red Dog, Alaska

Jun 21, 1905

By A. J. Davidson

A Cu-conducting solid electrolyte was used to develop the sensor. Instead of measuring the potential across the electrolyte from the reference material to the Cu-containing phase, a potential was applied and the stable current measured. This gave reasonable readings for copper-tin alloys, which agreed with the theoretical calculations, but was less satisfactory in the case of mattes because the surface area of electrolyte presented to the matte phase varied from sensor to sensor. To overcome this problem the potential was applied, the current was measured and then reversed and remeasured and the ratio of the currents was calculated. The current ratio is shown to be independent of the resistance of the electrolyte and the surface area of the electrolyte offered to the melt, but strongly dependent on the activity of the copper

Jun 21, 1905

By F. C. Gennari, D. M. Pasquevich

With the gradual exhaustion of natural rutile, there has been extensive research into its synthesising from lower-grade titanium minerals. The removal of Fe from pseudobrookite (Fe2TiO5) by chlorination was studied, using both isothermal and non-isothermal thermogravimetric measurements. Correlation of the results obtained from element distribution maps, scanning electron microscopy, energy-dispersive X-ray analysis and phases detected by X-ray diffraction in the chlorinated samples showed clearly two associated processes. First, the pseudobrookite particles reacted with chlorine and iron was removed selectively as FeCl3(g), leaving a solid residue rich in the TiO2 phases anatile and rutile, separated from an inner layer of unreacted pseudobrookite by a distinct interphase boundary. Second, chlorine allowed TiCl4(g) to form in the reaction bed, where it removed iron from the Fe2O3 crystals as FeCl3(g) and substituted Ti through a pseudomorphic reaction

Jun 21, 1905

By R. G. Kidel, S. C. Doming

The project has shown that it is feasible for a junior company to reopen a narrow vein-style gold mine and successfully take it into production. An intimate understanding of the mineralisation and a flexible approach to mining are crucial, as are stringent cost control and efforts to keep overheads low. The project has confirmed the geological complexity of the Main Lodes, which consist of highly sheared quartz-sulphide infill in strongly sericitised granodiorite. The existence of discrete high-grade zones within the Hangingwall Lodes has also been confirmed. Broad low-grade zones continue to be recognised and require the local application of bulk longhole mining methods. The initial mine plan called for predominantly longhole stoping, but adverse ground conditions have meant that a switch to air-leg mining has produced higher run-of-mine grades. The excess capacity at the processing plant can best be used by batch processing, with its reduced maintenance requirements

Jun 21, 1905

By R Adamian, F. T. Da Silva, D. H. Gameiro

Schytill and Geldart diagrams were developed for the TiO2-C-Cl2 system at 1 073 and 1 273 K, so as to define the hypothetical relations between particle sizes and chlorine velocity for simultaneous fluidisation of mixtures of anatase concentrate and charcoal for carbochlorination. It was concluded that the operating limits on chlorine gas velocity will be controlled by the behaviour of the reducing agent, mainly because of its lower density. An increase in temperature from 1 073 to 1 273 K will have only a small influence on the fluid-dynamic behaviour of the mixture. For bubble fluidisation, the maximum sizes 0.413-0.478 mm for anatase and 0.529-0.611 mm for charcoal will be adequate. When the particle size distribution is large, fluidisation will be feasible only if conducted in two stages, otherwise the residence time of the small particles in the reactor will be very short. New diagrams will be needed for the gaseous chlorides in the second stage

Jun 21, 1905

By D. Bitzios, A. Gracia, V. Meggiolaro, J. D. Baker

Synthesis report on a project carried out under the EC-funded BRITE-EURAM programme. A large deposit in Spain and several smaller ones in Greece and Sweden were investigated. Beneficiation testwork, including the development of an innovative wet circuit, was undertaken in Italy. The Spanish Ilustracion deposit lies occurs in thin, white layers throughout a zone 35-40 m thick and 1.5 km long, in laminated calcsilicates. Total resources of more than 100 000 000 t include proven open-pittable reserves of 4 500 000 t averaging 35% wollastonite. The beneficiated product is suitable for various applications, including ceramics. The Swedish and Greek marble-hosted skarn deposits include Albatross, with 2 500 000 t of reserves at 30% wollastonite, and Panorama, with reserves estimated at more than 700 000 t

Jun 21, 1905

By A. R. Naderian

Laboratory strength and deformation testing of freshly blasted sandstone and claystone overburden from Jeebropilly colliery in Queensland and in-situ plate-bearing tests on four backfills of different ages showed that the bearing capacity of backfill is a function mainly of compaction, not of age. The modulus or stiffness of the backfill is significantly increased by previous loading, in some cases up to threefold. Backfill material experiences some compaction through the passage of mining vehicles, likely to provide a bearing capacity that will support normal construction activities; the limited testing performed suggested that completed backfills are capable of supporting loads of up to 200 kN/m2 while sustaining displacements acceptable for a wide range of residential and industrial uses, but may be susceptible to collapse settlements due to saturation in the long term

Jun 19, 1905

By M. Lombardero, J. Garcia-Guinea, J. Taboada, B. W. Roberts

The structural, textural and mineralogical properties of the slate formations of NW Spain make it the most important district in the world for quarrying roofing slates. Over the past 10 years the introduction of new methods has increased yields from 2 to 13%. The main factors affecting quality are quartz grain size less than 75 micrometres, homogeneity of slaty cleavage and S0-S1 intersection angle, very low metamorphic grade, absence of secondary foliation, beds 10-12 m thick and low content of oxidisable Fe sulphides. The two main controls on fissility are lithology and deformation accompanied by metamorphism. The minimum natural block size should be 0.6 m3 but this volume can be reduced for modern cutting tools such as diamond wire, chain and circular saws. Structural analysis is crucial in exploration and quarrying, as shown by the prospecting methodology applied at Dominio de Truchas in central Spain and the computer analysis of rock mass discontinuities at Casaio quarry

Jun 19, 1905

By M. Foguenne, A. van Lierde, P. Henry

Leaching experiments were carried out on a spent catalyst sample with a honeycomb structure, containing 47.5% Ti, 5.8% Mo, 2.7% Si, 2 035 ppm As, 52 ppm Pb and 8.8 ppm Hg. More than 93% of the Mo and As was removed by direct alkaline leaching after grinding to 80% -36 micrometres. The residue contained 0.3% Mo and 60 ppm As. To obtain a TiO2 matrix with 30 ppm As, acid leaching at controlled pH with 90 kg/t Al scrap was followed by oxidising alkaline leaching. Treatment of the direct alkaline leach solution or of the mixed solutions from the two-stage process involved two successive operations: purification by neutralisation with Al(OH)3 addition to raise the Al concentration to 4 g/l, and ion exchange on Amberlite IRA 94 S resin. Whatever the type of solution treated, elution with 200 g/l NH4OH solution gave an eluate of very high purity containing 164 g/l Mo, less than 70 mg/l V and less than 2 mg/l As

Jun 19, 1905

1994 estimates for Porgera are probable and proven reserves of 58 200 000 t of ore grading 5 g/t Au. Gold mineralisation is related to an intrusive complex emplaced at shallow levels in poorly consolidated sedimentary rocks. The complex is located in a zone of fold-and-thrust deformation, whose formation may have been initiated shortly before emplacement and continues locally today. Abundant primary magnetite in the complex gives an intense, 5 km wide aeromagnetic anomaly. The deposit formed during two main stages of mineralisation, the first related to early magmatic-hydrothermal activity and the second representing later epithermal overprinting centred on the Roamane fault. Hydrothermal alteration followed closely on emplacement indicating a close genetic relationship between magmatism and mineralisation. Both stages of hydrothermal activity post-date and overprint early propylitic alteration. Several factors have acted in unison or sequentially to concentrate metals at the deposit, including an extensional or trans-tensional tectonic setting within an arc or collisional environment, the exsolution of a magmatic hydrothermal fluid prior to sulphur saturation in the melt, the development of the hydrothermal system into one favourable for transporting gold, the action of late-stage faulting in focusing epithermal fluid flow, and the role of dissolved gases in promoting fluid phase separation and high-grade ore deposition

Jun 19, 1905

By T. M. Williams, P. M. Green

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The sediment geochemistry of streams draining Southern Uplands and Lake District turbidites was compared with lithogeochemical data for the source greywackes, using stratigraphically defined catchments. Several systematic trends in element abundance variation between source and stream sediment can probably be applied more widely to interpretation of drainage geochemistry. Pb and Zr increase markedly from source rock to sediment, by adsorption on clay and zircon grain concentration. Variation of feldspar-related elements Rb, Sr, K and Ba appears to be controlled by source grain size and compositional maturity. Ni shows surprisingly little change and Fe and Co are only slightly raised. Cr is particularly useful, with variations superimposed in anomalously high regional levels. Abrupt changes in Cr distribution in stream sediment coincide with stratigraphical boundaries, allowing drainage data to be used as a surrogate for whole-rock values

Jun 19, 1905

By L. Villa, O. Suarez, D. Arias, L. G. Corretge

The deposit comprises two vertical, lenticular bodies emplaced in the allochthonous block of a Variscan thrust. Epigenetic mineralisation occurs as replacement of carbonated volcaniclastic rocks of Cambro-Ordovician age. The dominant sulphide minerals are sphalerite and galena with minor chalcopyrite; the main non-metallic mineral is quartz and there is hydrothermal silicification, chloritisation and sericitisation. Sulphur isotope values for sphalerite and galena are heavy and reflect the fundamental relationship between delta-34S in ZnS and in PbS, suggesting isotopic equilibrium. Four sphalerite-galena pairs yield temperatures between 163 and 218 degrees C, in good agreement with the 187-207 degrees C estimated by the Ga/Ge-sphalerite geothermometer. The ore sulphide was leached by the hydrothermal solution from diagenetic pyrite in the host rocks and disseminated sphalerite and galena in Cambrian carbonates

Jun 19, 1905

By R. Sweennen, A. Vervoort, J. Caers

A case study is presented of the mechanical behaviour of fractures in the Westphalian A and B siliciclastic succession of mud-, silt- and sandstones with intercalating coal layers in the Campine basin of northeast Belgium. Mining ceased in the area in 1992 and a pilot well was drilled to assess the feasibility of methane extraction by hydraulic fracturing. Work was carried out to study the influence of types of cement fill in fractures on the shear behaviour of the rocks by comparison with that of the coal seams. X-ray computerised tomography was used for visual appraisal and selection of jointed rocks before destructive shear testing was carried out. Two major type of veins were found to be present, one cemented with carbonate and the other with kaolinite or kaolinite/carbonate. Uniaxial compressive strength and shear tests showed that differentiation of the two types of veins was vital in evaluating the strength of the sandstones, as cementing of the fractures by rigid carbonate minerals can reinstate the strength of the rock masses to that of the intact material. Kaolinite was more susceptible to plastic deformation than carbonates

Jun 19, 1905

By J. H. Morris, G. M. Steed

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Oxygen isotope analysis indicates that quartz, carbonates and muscovite could all have formed in near-isotopic equilibrium with the mildly saline H2O-CO2 ore fluid at 330 degrees C. Calculated values for O, C and S in the ore fluids imply derivation from a deep, homogeneous source region and are consistent with formation either as a direct or an indirect result of igneous processes. Values for delta-O18 plot a little outside the accepted magmatic range, but have almost certainly been modified by exchange reactions with wall rocks. These reactions were also the most likely cause of deposition of the ore constituents. The chemical and isotopic character of the fluid was similar to that in many Archaean and later mesothermal auriferous vein systems, especially the Mother Lode region of California. If the Southern Uplands-Longford Down accretionary complex conceals an Ordovician arc, the tectonic setting was also broadly comparable

Jun 19, 1905

By A. D. Mukherjee, H. N. Bhattacharya

Middle Proterozoic sulphide ore mineralisation occurs in isolated blocks of the NE-SW trending Delhi fold belt composed of Delhi Supergroup rocks. The Ajari-Basantgarh-Pipela belt forms part of the longest, widest and westernmost tectonic unit of the Delhi fold belt and consists of amphibolites, metapelites, quartzites and carbonates. The metapelite lenses and associated amphibolites host pyritic copper mineralisation. Mineralisation takes the form of sheet-like bodies consisting of ore lenses of various sizes interlayered with host or associated rocks. Massive, banded and disseminated varieties of ore are found. Pyrite is dominant with subordinate chalcopyrite and sphalerite. Pyrrhotite, galena, cubanite, mackinawite, marcasite and freibergite constitute the minor minerals. The characteristic features of the ores suggest a possible correlation with Besshi-type deposits, and the closely associated amphibolites are interpreted as low-K tholeiites of a fore-arc setting

Jun 19, 1905

By M. T. Styles, E. Condliffe, R. C. Leake, R. J. Chapman, D. J. Bland

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Quantitative point analysis and microchemical mapping identified 52 different types of mineral in inclusions, usually ranging in size from 5 to less than 1 micrometre, inherited from source bedrock. A combination of grain chemistry, heterogeneity and inclusions provides a grain signature reflecting the type and history of source mineralisation. Several grains from an alluvial site are needed, to allow for bedrock variation and the presence of inclusions in only 10-20% of grains. A total of 1 530 grains obtained from 30 localities in Scotland were of ten types, two of them minor variants. Two types in the Highlands may be related to centres of Caledonian igneous activity, but the most widespread is likely to have been of deep-seated origin and structurally controlled. Gold in the Ochil Hills is probably from a source associated with Devonian andesitic activity. In the Southern Uplands, grain types reflect two separate episodes of mesothermal lode gold mineralisation and relationships with Permian red beds/mafic volcanics and with Tertiary dykes

Jun 19, 1905

By A. M. Tunstall

Aspects of blast vibrations, damage mechanisms and the influence of rock quality on damage severity are reviewed and results presented from a monitoring programme in which the rock mass rating for six tunnels was determined. The peak particle velocity induced in the tunnels during open-pit blasting was measured and the tunnels were inspected visually for fresh damage after each blast. The results suggest that the quality of rock in which an excavation is situated has an influence on the level of ground vibration to which it can be subjected without sustaining damage. This means that the use of a single limiting value of peak particle velocity, as in the blast damage criteria for residential structures, is not ideal and may result in damage to excavations in poorer-quality rock masses

Jun 19, 1905

By A. J. Beer, A. Wetherelt

Paper presented at the UK minerals industry conference held in Leeds, UK, 3-5 April 1995. Camborne School of Mines has developed a simple, cost-effective light-sectioning method that has been used successfully in tunnels and small stopes. Light sectioning provides an almost visual examination of the stope's excavated profile. An illuminated section of walls, roof and floor is recorded photographically. Overbreak and underbreak can then be easily quantified by reference to the designed shape. The prototype rig is described. Use of a fish-eye lens to capture a greater field of view is discussed. Calibration was achieved by comparison with images made with a conventional wide-angle lens with nominal distortion. The system is reliable under a range of operating conditions including dust, heat and humidity. It is also simple and easy to use, does not require skilled personnel and is low cost

Jun 18, 1905

By W. Petruk, M. J. Matos

An aplite ore from Guarda in northern Portugal, containing albite, microcline and quartz and muscovite gangue was studied to identify conditions for extracting the feldspar minerals. The large amounts of quantitative mineralogical data needed to evaluate grinding behaviour were provided by automated image analysis. The images were acquired on polished surfaces by measuring back-scattered electron signals produced with a microprobe. Minerals were identified from X-ray spectra and discriminated by grey level and element-characteristic X-rays. The quantities and size distributions of the minerals were determined by measuring thin sections of unbroken ore to predict the grind required to liberate the feldspars. The ore was then ground to -1.7 mm, polished sections were prepared from sieved fractions and the quantities of mineral species and apparent total liberation were determined by analysis. The predicted and measured liberations were compared and the grinding behaviour of the ore interpreted. In an appended correction, the correct version of Equation 1 is represented and Tables 3 and 6 are revised to consider all size fractions, including those coarser than 300 micrometres, in calculating the total liberation from King's fractional liberation

Jun 18, 1905

The first part describes a model (the C model) based on the motion of the grinding charge. The charge is treated as a continuum, which allows analytical solutions to the equations that are developed. The C model is equally applicable to ball-, semi-autogenous and autogenous mills and contains a description of the power draw of both the cylindrical section and the cone-ends. Differences between the power draw of grate- and overflow-discharge mills are described from consideration of the different shapes and compositions of their charges. A large database of industrial mill data is used to demonstrate the accuracy of the model. Part 2 describes a simpler, empirical model (the E model) whose performance is based on that of the C model. The same database was used to assess the predictive capabilities of the E model. The model was shown to be only slightly less accurate than the C model despite its much simpler structure

Jun 18, 1905