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By K. G. Thorne, L. J. Cabri, L. R. Fyffe, D. R. Lentz, D. Hoy

"Mineralization at the Main zone of the Clarence Stream gold deposit in southwestern New Brunswick occurs within a parallel series of quartz veins that occupy a NE-trending, steeply north-dipping, brittle-ductile shear zone related to the nearby terrane-bounding Sawyer Brook fault. This deformation zone cuts volcaniclastic sedimentary and volcanic rocks of the Silurian Waweig Formation, and is intruded by mantle-derived East Branch Brook gabbroic dikes and a number of felsic dikes. Intermittent shear-zone reactivation during local magmatic activity induced heterogeneous deformation and alteration of the country rocks and dikes. The terminal phase of shearing is associated with narrow pegmatite-aplite dikes that grade laterally into granophyric granite, and into an auriferous quartz vein. Gold, aurostibite, and gold-antimony intergrowths, predominantly with vein quartz, are associated with a low ƒO2 sulfide mineral assemblage (pyrrhotite, arsenopyrite, and berthierite) that has a sulfur isotopic signature consistent with a magmatic source. Gold saturation and deposition occurred episodically between 300° and 360°C at low activity of sulfur, predominantly in response to pressure reduction during brittle failure combined with the effects of decreasing temperature and sulfidation reactions during fluid-wall-rock interaction. Geochronological studies demonstrate that the timing of the emplacement of the pegmatite-aplite dikes and associated auriferous veins overlap with that of the Early Devonian Magaguadavic granite. Moreover, the composition of the dikes is consistent with their derivation from this granite as late fractionates. The Main zone of the Clarence Stream deposit is therefore interpreted to be intrusion-related, with the Magaguadavic granite being the ultimate source of the gold-bearing fluids. La minéralisation de la zone principale du gisement aurifère de Clarence Stream dans le sud-ouest du Nouveau Brunswick occupe une série de veines de quartz parallèles dans une zone de cisaillement fragile-ductile de direction NE et à pendage abrupt vers le nord apparentée à la faille de Sawyer Brook avoisinante qui délimite deux terranes. Cette zone de déformation recoupe les roches volcaniclastiques et volcaniques de la Formation de Waweig d’âge Silurien et est recoupée par les dykes de gabbro d’East Branch Brook, d’origine mantellique, ainsi que par divers dykes felsiques. La réactivation intermittente de la zone de cisaillement durant l’activité magmatique locale a entraîné la déformation et l’altération hétérogènes des dykes et de l’encaissant. La phase finale du cisaillement est associée à de minces dykes d’aplite-pegmatite qui passent latéralement à des granites granophyriques, puis à des veines de quartz aurifères. L’or, l’aurostibite et les intercroissances d’or et d’antimoine principalement associées aux veines de quartz sont associés à un assemblage minéral de sulfures à faible ƒO2 (pyrrhotite, arsénopyrite et berthierite) présentant une signature isotopique du souffre compatible avec une source magmatique. La saturation en or et la précipitation a eu lieu épisodiquement entre 300° et 350°C dans des conditions de faible activité de souffre, principalement en réponse à la baisse de pression durant la rupture fragile ainsi qu’aux effets de la baisse de température et aux réactions de sulfuration durant l’interaction entre le fluide et l’encaissant. Les études géochronologiques indiquent que l’âge de la mise en place des dykes de pegmatite-aplite et des veines aurifères qui leur sont associées coïncide avec le granite de Magaguadavic, d’âge Dévonien Précoce. De plus, la composition des dykes est compatible avec une origine provenant de ce granite sous la forme de phases fractionnées tardives. Le gisement principale (Main zone) de Clarence Stream est ainsi considéré comme étant associé aux intrusions, le granite de Magaguadavic étant la source ultime des fluides aurifères."

Jan 1, 2008

By Jiulong Cheng

Underground coal mining causes overburden deformation and failure, one major form of which is bed separation in the overburden. Surface subsidence can be controlled by injecting grout into the bed separations. For a long time, the grouting results of bed separation can not be validated. This is the problem in the application of this technique. This paper analyzes the conditions leading to bed separation, develops mathematical models for seismic wave fields generated before and after bed separation, and bed separations grouted with different materials, and computes the seismic wave field characteristics using the finite difference method. The results show that the existence of bed separation causes changes in the characteristics of seismic wave field, and that different grouting materials generate different seismic wave field characteristics. Intact strata, bed separation, and bed separation filled with air or water all display distinctive seismic wave field in amplitude and frequency spectra. After mining, the original location that provides strong seismic reflection wave no long exists. It is replaced by a weak and syncline-shaped reflection wave. The area, where the seam wave disappears, is larger than that of the mined area. The location, where a bed separation occurs, generates a set of reflection waves stronger than the normal one. The energy of the reflection waves varies with the materials filling the separations. Bed separations filled with air generate stronger reflection waves than those filled with water. The major frequencies for those filled with air are lower than those filled with water. Therefore, it is possible to determine the property of filling materials by analyzing and comparing the amplitude and frequency spectra of the reflection waves. Case studies of application of seismic method for exploring bed separations and grouting were analyzed. The results show that it is feasible to use seismic technique for exploring bed separations and grouting.

Jan 1, 2006

By Mu Chen, Ye-Shuang Xu, Dong-Wei Hou, Shui-Long Shen, Huai-Na Wu

"This paper presents a laboratory investigation on the mechanical behaviors of the cement-clay admixture improved by polypropylene fiber. Cement can significantly improve the clay admixture. The fiber additive also improves the strength and ductility of the improved clay. The Unconfined Compression Strength (UCS) of the polypropylene fiber-reinforced cement-clay presents an overall trend to grow with the increase of fiber length. The improved clay reached its peak strength at the fiber content of 0.5%. Then the UCS of the improved clay will slowly reverse if the fiber content continues to rise. For study of curing time, improved clay behaves better in its early strength, but an inhibition will be brought about if fibers are excessive.INTRODUCTIONGround improvement technology is essential for construction of structures in soft ground. Some traditional techniques often cost much but result in little. For instance, along the coastal region of China, soft ground is often improved by backfill with high quality sandy soil transported far away, leading to high additional haulage costs and long construction period. Reutilizing the excavated soil as backfill or subgrade after treatment, by contrast, will be more economical and effective (Hufenus et al., 2006). Many researches have been conducted to improve the compression strength of soft soil, among which, the method of mixing the soft soil with cement and fly ash is one of the most common ways (Kolias et al., 2005; Horpibulsuk et al., 2009; Porcino et al., 2012). It is known that soil resists well against compression and shear force but behaves poorly in resistance to tension. Therefore, utilizing tensile elements such as fibers and strips to improve the tensile strength will be effective because of its strength isotropy, better durability and cost effective (Haeri et al., 2000; Kaniraj and Havanagi, 2001; Consoli et al., 2010)."

Jan 1, 2015

By Mu Chen, Ye-Shuang Xu, Dong-Wei Hou, Shui-Long Shen, Huai-Na Wu

"This paper presents a laboratory investigation on the mechanical behaviors of the cement-clay admixture improved by polypropylene fiber. Cement can significantly improve the clay admixture. The fiber additive also improves the strength and ductility of the improved clay. The Unconfined Compression Strength (UCS) of the polypropylene fiber-reinforced cement-clay presents an overall trend to grow with the increase of fiber length. The improved clay reached its peak strength at the fiber content of 0.5%. Then the UCS of the improved clay will slowly reverse if the fiber content continues to rise. For study of curing time, improved clay behaves better in its early strength, but an inhibition will be brought about if fibers are excessive.INTRODUCTIONGround improvement technology is essential for construction of structures in soft ground. Some traditional techniques often cost much but result in little. For instance, along the coastal region of China, soft ground is often improved by backfill with high quality sandy soil transported far away, leading to high additional haulage costs and long construction period. Reutilizing the excavated soil as backfill or subgrade after treatment, by contrast, will be more economical and effective (Hufenus et al., 2006). Many researches have been conducted to improve the compression strength of soft soil, among which, the method of mixing the soft soil with cement and fly ash is one of the most common ways (Kolias et al., 2005; Horpibulsuk et al., 2009; Porcino et al., 2012). It is known that soil resists well against compression and shear force but behaves poorly in resistance to tension. Therefore, utilizing tensile elements such as fibers and strips to improve the tensile strength will be effective because of its strength isotropy, better durability and cost effective (Haeri et al., 2000; Kaniraj and Havanagi, 2001; Consoli et al., 2010)."

Jan 1, 2015

By Nikhil Dhawan, SHAILA MIR

The emerging problem of electronic waste has promoted the interest in exploring metal recovery from secondary sources under the umbrella of urban mining. This study presents the physical and chemical characterization of various components present in end-of-life laptops to help ascertain the sites of metallic values and develop sustainable and environment-friendly recycling. The recycling potential of a laptop is evaluated by sequential disassembly, separation, and characterization of components such as body (49.8 wt.%), printed circuit board (9.7 wt.%), hard disk drive (4.9 wt.%), and battery (12.4 wt.%). The printed circuit boards comprise metallic values, majorly copper (25 wt.%), tin (5.8 wt.%), and lead (3.1 wt.%). The precious metals (Au, Ag) with an economic advantage are abundantly present in electronic components such as integrated circuits, capacitors, resistors, and processors. Critical elements such as lithium, cobalt, and rare earth elements are detected in the discarded laptops' batteries and hard disk drives. The recycling potential representing the amount of material that can be recycled in various components, depending on the type, concentration, and purity, is determined in the range of 36–100%. On average, a unit laptop contains~ 386 g of Cu (14.45 wt. %), 49.73 g Co (1.86 wt. %), ~346 mg Ag, ~141.2 mg Au, ~650 mg of rare earth elements (Nd, Dy). This study presents a database for investigating integrated and economical recycling techniques from different components of a laptop, and an overall process flow is also proposed.

Jul 24, 2021

By S. Steinlechner, G. Schneeberger, J. Antrekowitsch

The recycling of steel mill dusts is getting more and more important. The costs and requirements of land filling are rising and companies are interested in new recycling strategies. The rising of sustaina¬bility hand in hand with the high rate of valuable metals in these residues supports new research activities on the recycling sector. Especially zinc but also iron and lead are economical factors due to the treatment of steel mill dusts. This paper gives a small overview of fundamental studies concerning the chemical and physical composition of these dusts. Furthermore aggregates for the reduction of these dusts in the liquid phase are introduced and compared. The Flash-Reactor, the TBRC-Technology (Top Blown Rotary Converter) and submerged arc furnaces and there use for melting and treatment of these dusts are in the center of interest of this paper. The final conclusion gives an overview of possibilities for reduction of filter dusts in the liquid phase.

Jan 1, 2011

By H. Möller, M. Tshibalanganda, C. Taute, A. du Plessis, M. Leary

Additive manufacturing can be used to produce complex and custom geometries, consolidating different parts into one, which in turn reduces the required number of assemblies and allows distributed manufacturing with short lead times. Defects, such as porosity and surface roughness, associated with parts manufactured by laser powder bed fusion, can severely limit industrial application. The effect these defects have on corrosion and hence long-term structural integrity must also be taken into consideration. The aim of this paper is to report on the characterization of porosity in samples produced by laser powder bed fusion, with the differences in porosity induced by changes in the process parameters. The alloy used in this investigation is AlSi10Mg, which is widely used in the aerospace and automotive industries. The sample characteristics, obtained by X-ray tomography, are reported. The design and production of additively manufactured parts can be improved when these defects are better understood.

Apr 1, 2021

By G. Song

This paper reports the anodizing voltage, gas evolution and sparking behaviors of an anodized coating formed on AZ91D in a silicate containing solution. According to their responses to an anodizing current, a four-stage anodizing mechanism is proposed. At the same time, the formed coating is characterized in terms of its microstructure, composition, thickness and corrosion performance. It was found that deposition of MgSiO3, Mg(OH)2 and MgO as well as dehydration of Mg(OH)2 are involved in the anodising process; the vigorous gas evolution accompanied by intensive sparking and the corresponding negative anodising efficiency in the later stage of the anodising process are closely associated with thermal decomposition of water due to the high temperature resulting from the intense sparking on the surface of the anodized alloy; the thickness, porosity, and composition of the anodised coating on a magnesium alloy depend on the final anodising cell voltage; and the corrosion resistance of a thick but porous coating containing more silicates appears to be more corrosion resistant than a thin but compact coating containing less silicates.

Jan 1, 2006

By S. Potgieter-Vermaak, T. T. Chiweshe, W. Purcell

Complete isolation of chromium (III) from the reference material (SARM 131), Upper Group 2 (UG2) chromite ore, and Merensky Reef mineral ore was achieved using ammonium phosphate salt as flux. Optimum pH (3.2–3.8) conditions and sample to flux ratios (1:25) were some of the factors that were critical for the complete isolation of chromium. Increasing the sample to flux ratio (1:50 excess) however resulted in the conversion of all the elements in the melt into a green solution (pH, 5.8–6.7). A different chromium compound was subsequently isolated from the green solution by allowing this solution to stand in an open vessel in a cupboard for a month during which time the pH decreased to pH 3.5–4.2. Quantitative analyses of chromium from the isolated precipitates of SARM 131, UG2 chromite ore, and Merensky Reef mineral ore indicated chromium contents of 41.87, 60.41, and 23.93% respectively which were very close to the chromium content in the original samples. Analysis of the chromium precipitates using IR indicated the presence of phosphates (1100–1200 cm−1 ) while SEM-EDX analysis showed the presence of microscopic crystalline particles with Cr, P, and O as the major elements. Further characterization of the chromium precipitates using XRD and Raman successfully identified the product as chromium (III) metaphosphate C-type (Cr(PO3)3, JCPDS no. 01-077-0672), in the isolated chromium precipitates.

By K. H. Nimerick

Froth flotation of coal is growing in importance and complexity. Some of the reasons for these changes follow. 1) A need exists for energy resource conservation. 2) Preparation plants are processing widely varying coal -- deep seam, strip and stockpiled either separately or as blends. 3) More fines are being generated because more mines are using automatic mining equipment. 4) It is more practical and economical to remove ash and sulfur at the preparation plant than during utilization.

Jan 1, 1982

By David Cocke

Study of surface and subsurface interfacial chemistry of metallic and similar systems has its enormous technological importance. Copper, for example, is a common component of many alloys and bulk amorphous systems. It is being increasingly studied today because of its use for electronic interconnect systems where processing is done below 200 ºC. Since several types of copper oxides exist, and the degree of their formation is dependent on temperature, perhaps characterization by EDS-SEM depth profiling and EIS might delineate one type of oxide from another. In this paper, we described our work on transformation of copper oxides with temperature ranging from 70 to 350 °C and their characterization by SEM, EDS, and XRD. We also showed the use of the phase angle portion of the impedance as a means to identify the predominant structure and the transition through Cu3O2 between the predominant stable CuO and Cu2O.

Jan 1, 2009

By W. Petruk, M. J. Matos

An aplite ore from Guarda in northern Portugal, containing albite, microcline and quartz and muscovite gangue was studied to identify conditions for extracting the feldspar minerals. The large amounts of quantitative mineralogical data needed to evaluate grinding behaviour were provided by automated image analysis. The images were acquired on polished surfaces by measuring back-scattered electron signals produced with a microprobe. Minerals were identified from X-ray spectra and discriminated by grey level and element-characteristic X-rays. The quantities and size distributions of the minerals were determined by measuring thin sections of unbroken ore to predict the grind required to liberate the feldspars. The ore was then ground to -1.7 mm, polished sections were prepared from sieved fractions and the quantities of mineral species and apparent total liberation were determined by analysis. The predicted and measured liberations were compared and the grinding behaviour of the ore interpreted. In an appended correction, the correct version of Equation 1 is represented and Tables 3 and 6 are revised to consider all size fractions, including those coarser than 300 micrometres, in calculating the total liberation from King's fractional liberation

Jun 18, 1905

By John W. Graydon

Incineration is an attractive alternative to the disposal of MSW in landfill sites. However, the process of incineration generates fly ash which contains significant levels of leachable heavy metals - particularly cadmium, lead, and zinc - and it is essential to manage this fly ash in an environmentally sound manner. The compositions, phases, textures, morphologies and size of fly ash particles have been studied by light microscopy, scanning electron microscopy, X-ray microanalysis, and X-ray diffraction. The detailed spatial relationships and speciation of the environmentally significant constituents have received particular emphasis. The information obtained is useful in understanding how fly ash is formed during incineration, in understanding the leaching behavior of untreated fly ash if it is disposed of in a landfill and, most importantly, in guiding the development of the best treatment strategies for fly asti to mitigate its environmental impact.

Jan 1, 1992

By O. Noirot, H. C. Owens, P. D. Rao, D. E. Walsh, J. R. Mokka

Over a period of seven years (1989-1996) the Mineral Industry Research Laboratory (MIRL) University of Alaska Fairbanks, has investigated the effects of temperature, residence time, and particle size on the degree of low-rank coal (LRC) upgrading for a non-evaporative, hydrothermal drying process, also known as hot water drying (HWD). Three Alaskan LRCs were used in this study: Usibelli coal (Seam No. 4) from the Nenana Coal Field, Little Tonzona coal from near McGrath, and Beluga coal from the Beluga-Yentna field on the west side of Cook Inlet. Replicated, factorial tests were conducted. Experimental results indicate that most of the low-rank coal upgrading via HWD occurs rapidly within the first 10-20 minutes of residence time. Thereafter, the upgrading process slows down and over 100 minutes of additional residence time are required to produce similar percentage increases in coal properties to those achieved in the first 10- 20 minutes. The properties of the hot water dried products were very sensitive to process temperature. Calorific value, carbon and oxygen contents, equilibrium moisture levels and Hardgrove gindabilities all appear to change linearly with temperature within the 275°C to 325°C range.

Feb 24, 1997

By C. Blais, G. L’Espérance

Characterization of second phase particles is important with regard to their influence on mechanical properties of materials. Analytical electron microscopy offers the possibility to achieve complete characterization of inclusions. Complete characterization of inclusions means quantitative evaluation of their chemistry and the stereological parameters. A characterization technique based on integrated microscopy and involving scanning electron microscopy, image analysis and energy dispersive X-ray spectrometry is presented. A discussion of the use of transmission electron microscopy and electron energy loss spectroscopy is also presented for the characterization of very small particles and compounds (>100 nm).

Jan 1, 1998

By E. C. L. Cardoso

Hydrocarbon polymers, as PP, made from cheap petrochemical feedstock are important in many branches of industry. However, they have an undesirable influence on the environment and cause problems due to waste deposition and utilization. Polymeric materials composites account for an estimated from 20 to 30% of total volume of solid waste disposed. Thus, there is a tendency to substitute such polymers by those ones that undergo biodegradable processes. Polypropylene (PP) is a commodity, with high melting point, high chemical resistance, low density, with a balance between physical and mechanical properties and easy processing at low cost. Nevertheless, PP shows limitations for some special applications in automotive industry and civil construction. In order to minimize this deficiency, related to rheological behavior of polymer melt, especially referring to viscosity in processing temperature, a 50% mixture with HMSPP (High melt Strength Polypropylene) was used. PP/HMSPP was blended with 10, 15, 30 and 50% of natural (sugarcane bagasse) and synthetic polymers (PHB and PLA) aiming to partially biodegradable materials. The admixtures were subjected to gamma-irradiation at 50, 100, 150 and 200 kGy and then further assessed by mechanical tests in order to evaluate their degradability.

Jan 1, 2015

By Artur R. P. Junior Sergio, Pedro A. Netto, N. Monteiro, Foluke S. de Assis, Frederico M. Margem

Synthetic fibers are being replaced gradually by natural materials such as lignocellulosic fibers. Compared to synthetic fibers, natural fibers have shown advantages in technical aspects such as environmental and economic. So there is a growing international interest in the use of those fibers. The banana fiber presents significant properties to be studied, but until now few thermal properties on banana fiber as reinforcement of polyester matrix were performed. The present work had as its objective to investigate, by photoacoustic spectroscopy and photothermal techniques the thermal properties of diffusivity, specific heat capacity and conductivity for polyester composites reinforced with banana fibers. In the polyester matrix will be added up to 30% in volume of continuous and aligned banana fibers. These values show that the incorporation of banana fibers in the polyester matrix changes its thermal properties.

Jan 1, 2015

By K. E. Waters, N. Brodusch, R. Gauvin, A. Jordens, Teng. C., H. Demers

Rare earth elements (REEs) become increasingly significant for renewable energy devices and high-technology electronic products because of their large-scale popularity and applications. In this project, a field-emission scanning electron microscope was used to characterize the composition and distribution of REEs-bearing minerals. X-ray elemental maps were acquired with a large area x-ray detector (60 and 80 mm2 collecting area) and annular detector (60 mm2 collecting area), which allow fast x-ray acquisition at high count rate. These elemental maps were transformed into phase maps, which are used to identify the composition of the mineral phases and the REEs distribution over a large area. The phase maps are an easy way to distinguish the phases with and without REEs and compare the efficiency of different REEs extraction processes. Different methods (manual and automatic) for producing phase map were studied by comparing the distribution of REEs obtained from the same area.

Jan 1, 2015

By K. E. Waters, N. Brodusch, R. Gauvin, H. Demers

"Rare earth elements are becoming increasingly in demand, due to their prevalence in both renewable energy devices and high-end electronics. The characterization of the composition, morphology and volume fraction of the various phases that have valuable rare earths in the ores are needed to find the optimal industrial process to extract the ores containing the rare earths. Rare earth-bearing minerals contain many elements with the M-and L-lines overlap, requiring a high degree of resolution, pushing the boundaries of scanning electron microscopy quantitative analysis. Enhanced microscopy at a high spatial resolution with improved x-ray quantitative analysis enables the accurate determination of the distribution of the desired rare earths in various mineral phases. INTRODUCTIONRare earth elements are becoming increasingly in demand, due to their prevalence in both renewable energy devices and high-end electronics. From batteries (lanthanum and cerium), to magnets (dysprosium and neodymium) and lighting (yttrium), the rare earth elements are crucial to the advancement of technology, and to energy saving devices (Crow, 2011). The goal of this project is to characterize the composition, morphology and volume fraction of the various phases that have valuable rare earths in the ores in order to estimate the economical VALUES (of the ores and to find the optimal industrial process to extract the ores containing the rare earths. High spatial resolution imaging and x-ray microanalysis are needed to reach this goal. In this work, the results obtained with a cold-field-emission scanning electron microscope (FE-SEM) and a silicon drift detector (SDD) energy dispersive spectrometry (EDS) detector at low accelerating voltage are compared to experimental conditions typically used with electron probe microanalysis (EPMA) instrument.With this improvement, a detailed scientific analysis of the composition of these, and other, ores will become possible with a SEM/EDS system. This will help to better understand how such ores were formed, hence assisting in finding them, and to better understand how to process them in preparation for high end industrial applications, namely through mineral processing."

Jan 1, 2012

By R. S. Krarner

Fly ash, a by-product of coal burning power plants, poses a major problem for the utility industry since most fly ash must be landfilled. These quantities may represent as much as 20% of the total material going into landfills. A major problem with fly ash utilization is that although the ash consists of useable components, ash composition can vary depending on the types of coal burned and plant operating conditions. Ash is first characterized using SEM, image analysis, and chemical methods. Processing techniques were developed to separate ash into various components including cenospheres, magnetic spheres, carbon, and clean ash. These products are again evaluated for various utilizations before being used to produce valuable products such as mullite, activated carbon, fillers in plastics, and concrete.

Jan 1, 1994