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By R. L. Bruening, N. E. Izatt, S. R. Izatt

"Rare earth elements (REE) are essential and unique components of many high-technology products without which functioning of modern society would be greatly impaired. Commercial deposits of REE are limited to a few geographical locations. Largely untapped sources of REE are available in endof- life (EOL) magnets, rechargeable batteries, and electronics. Presently, < 1% of REE in EOL wastes is recycled. Conversion of EOL wastes to liquid streams allows use of IBC’s Molecular Recognition Technology (MRT) process to selectively recover, separate, and purify target REE and associated metals at g/L to mg/L or lower concentration levels. The MRT process together with its applications to separations of REE and associated metals in recycling as well as in mining are described. Economic and environmental advantages of MRT are presented. INTRODUCTIONRare earth elements (REE) include the lanthanide series (La-Lu), Y, and Sc. These elements are not rare, but concentrated minable deposits are scarce (Cordier 2012; Haxel, Hedrick, & Orris, 2002). Over 95 % of the world’s supply of REE is controlled by China (Hanson, 2011a) where they are mined, processed, and the pure elements incorporated into a growing number of consumer and military products. The consumer products are marketed worldwide. Since REE are vitally important in consumer and military products, this situation has caused other nations to scramble to develop the capability to produce their own supply (Cordier, 2012).In the U. S., Molycorp has reopened the Mountain Pass REE mine in California and production has begun (Goldenberg, 2010). Development of a reliable internal source of REE is of high national priority in the U.S. (Hanson, 2011b; Hess, 2012: “Obama Announces”, 2012). These elements have in recent decades been incorporated into new consumer and military products that are essential to our economy and defense. These products range from wind turbines, high performance magnets, hybrid car rechargeable batteries, energy efficient lighting electronics, flat screen televisions, and smart phones to advanced weapons systems (Haxel et al., 2002; Levkowitz & Beauchamp-Mustafaga, 2010)."

Jan 1, 2012

By Sungdon Kim, Chuljoo Kim, Joonsoo Kim, Hosung Yoon

"This study was performed to establish the optimum leaching condition through the experiments for the oxidized roasting followed by leaching of fluorocarbonate rare earth mineral (bastnasite) using sulfuric acid, and to establish the optimum condition for the recovery of cerium by ion- sieve method from the leached solution of bastnasite. The optimum conditions for the sulfuric acid leaching by the oxidizing roasting of bastnasite concentrates are that the roasting temperature is 550 -600 °C, the roasting time is 2 hrs, the concentration of sulfuric acid is 6N, the leaching temperature is S0°C and the leaching time is 3 hrs. At this time, the leaching yield of total rare earth oxides in the leaching of bastnasite concentrates is about 91%. When cerium is recovered by ion-sieve method from the solution obtained by the sulfuric acid leaching of the roasted bastnasite, the optimum conditions are that the TREO(total rare earth oxide) of leached solution is below 70 g/l, the flow rate of leached solution is 9.6 ml/min and the ratio of height to diameter of resin packed in column is above 9. In these conditions, the recovery of cerium of yield 85% and purity 96% is possible.IntroductionThe rare earths are generally called to Lanthanides, which are totally 17 elements including Scandium of atomic number 21 and Yttrium of atomic number 39 in addition to 1 S elements from Lanthanum of atomic number 57 to Lutetium of atomic number 71. Since the separation to each element is very difficult because of their similar chemical properties, the rare earths were used as the mixed rare earths and the mischmetal without separating to each element. However, the high purity rare earths are recently produced commercially to each element so that they are used as the materials for high tech. industry such as electric and electronic materials, catalysts, optical materials, special alloy and 8Uperconductive materials, and their consumption is rapidly increasing. Therefore, the purpose of this study is firstly to prepare leached solution by using the series of process of the oxidation-roasting and leaching by sulfuric acid. Next, second purpose is the separation and recovery of cerium by ion-sieve method."

Jan 1, 1998

By J. Kang

Supercritical fluid extraction (SFE) has became an attractive alternative technology to be a new process to recover metal, of which can be substitute the existing Leaching/Solvent extraction processes. Solvent extraction of metallic ions is a technically important and also well-established process that is used in the chemical and hydrometallurgical industries.1 Solvent extraction techniques use the chelation of metallic ions dissolved in liquid solution with organic ligands. Conventional solvent-extraction technique needs large amount of organic solvents and often creates environmental problems.2 More environment-friendly technology is needed nowadays, and there have been increasing attentions to extract metal ions by SFE. CO2 becomes one of the most notable alternative organic solvents due to its nonflammable, nontoxic, nonpolluting, and relatively inexpensive properties with its moderate critical point (73.8 bar, 31.06 °C). Many works have been reported in metal extraction under the supercritical CO2 (scCO2) solvent.3-5 In this study, to recover cobalt from wastes especially from spent lithium ion battery scrap, we selected two ligands ? Cyanex 272 and DEA (diethylamine) for the metal extraction in scCO2. Cyanex 272 is a commercially available extractant along with its series, Cyanex 301 and Cyanex 302. Smart and coauthors measured the metal extracting abilities of these three extractants, and found that Cyanex 301 and Cyanex 302 extracted metal ions much better than Cyanex 272 in the scCO2 solvent.10 The pH of water contacted with high pressure CO2 (70-200 bar, 25-70 oC) is about 2.8-2.95 based on the calculation and the measurement.6-7 Cyanex 272 is known to be less effective as a metal extractant in this low pH environment compared with other Cyanex series. However, when DEA is added to metal extraction reaction with Cyanex-272, DEA works as a strong base to Cyanex 272 converting Cyanex 272 to a deprotonated form (Figure 1), which results in an easy formation of metal complex and the enhanced extraction rate of metal ion.8 Therefore, the purpose of this paper is the metal extraction from spent lithium ion battery waste using scCO2 with Cyanex 272 and DEA.

Jan 1, 2010

By Katsutoshi Inoue

The sulfuric acid leaching of spent hydrodesulfurization catalysts yields an acidic solution rich in rare metals such as molybdenum, vanadium, cobalt, and nickel in addition to aluminum. For the purpose of separating and recovering the rare metals from the solution, basic solvent extraction characteristics of the metals involved with commercially available acidic organophosphorus reagents like TR-83, PC-88A, PIA-8 and CYANEX 272 as well as aliphatic alpha-hydroxyoxime LIX 63 from sulfuric acid media were investigated in the present work. It was demonstrated that CYANEX 272, PIA-8 and LIX 63 possessed excellent selectivity for molybdenum and vanadium over the other metals at comparatively low pH. Further, recovery of molybdenum and vanadium from the total leach liquor by the selected extractants was discussed. Additionally, in order to achieve preferential separation and recovery of cobalt and nickel over an appreciable amount of aluminum from the raffinate obtained after recovering molybdenum and vanadium, a systematic investigation was conducted on synergistic extraction behaviors of the mixed solvents of LIX 63 in combination with a series of acidic extractants such as CYANEX 272, PIA-8, PC-88A, D2EHPA, TR-83 and OPEHPA for cobalt, nickel and aluminum. It was elucidated that all of these mixtures could exhibit a good synergistic effect for extraction of cobalt and nickel, and that the lower the pKa of the acidic extractants, the greater the synergism. Contrarily, the extraction of aluminum, was considerably suppressed by LIX 63. Effective extraction of cobalt and nickel away from aluminum was accomplished from the sulfate solution at low pH (1.0 - 2.5) with the mixtures. In particular, the mixtures consisting of LIX 63 and CYANEX 272 or PIA-8 appeared to be the most feasible and economic from an industrial point of view, yielding acceptable separation efficiency for cobalt and nickel over aluminum and .a low acidity requirement for stripping cobalt and nickel as well as negligible degradation of LIX 63. Aluminum can be readily recovered as sulfate salt from the raffinate obtained after recovering molybdenum, vanadium, cobalt and nickel as outlined above by conventional crystallization method.

Jan 1, 1995

By Zhenzhong Bian, Ruiyang Zhang, Xiaofeng Zhong, Zhangxuan Ning, Yuanping Zhang, Jie Lu, Airan Zhang

This study addressed the separation and recovery of vanadium(IV), iron, and titanium from synthetic and real leach solutions of vanadium-bearing titanomagnetite using extractant P204 (di-(2-ethylhexyl) phosphate) and P507 (2-ethylhexyl hydrogen- 2-ethylhexyl phosphonate). Based on the speciation analysis of vanadium in sulfuric acid medium, the single-stage extraction efficiency of vanadium, iron, and titanium was 94.21%, 3.45%, and 5.32%, respectively, under the optimal extraction condition of P204-P507 concentration of 15% (v/v), P204 to P507 ratio of 3:1 (v/v), TBP (Tributyl phosphate) concentration of 5%, sulfonated kerosene concentration of 80%, initial pH of 1.8, contact time of 8 min, and phase ratio (O/A) of 2:1. By confirming the predictions of the McCabe-Thiele diagram, a five-stage countercurrent extraction was carried out and the desirable extraction efficiency for vanadium reached 98.13%. The maximum co-extraction coefficient and distribution ratio of vanadium were 2.58 and 26.23, respectively. The stripping efficiencies and concentrations of a vanadium-rich solution by three stages of countercurrent experiments with 20 vol.% sulfuric acid reached 99.14% and 0.58 g/L, respectively, while almost all of the titanium remained in the organic phase. The mechanism of synergistic extraction between hydrogen ions of P–O–H and VO2+ in acidic conditions was confirmed by ATR-FTIR spectroscopy and molecular structure derivation. Besides, the separated impurity ions ( Fe2+) after oxidation, precipitation, and roasting process form a qualified iron oxide pigment with a total iron content of 97.2%.

Apr 25, 2023

By CHENGLONG XU, HAORAN LI, YALI FENG, JINRONG JU, Shunliang Liu

With the depletion of mineral resources and the growing demand for metal resources from industrial development, the recovery of metal resources from secondary resources has attracted increased attention. Among all secondary resources, spent catalyst is one of the most important as it contains valuable metals such as vanadium, nickel, molybdenum, cobalt, and aluminum. Compared with the extraction of metals from minerals, the recovery of valuable metals from spent catalysts has the advantages of a simple process, a short production cycle, lower investment cost, and less environmental impact.

Apr 1, 2023

By CHENGLONG XU, HAORAN LI, YALI FENG, JINRONG JU, Shunliang Liu

In order to realize the resource utilization of spent hydrodesulfurization catalyst, a solvent extraction-oxalic acid precipitation process is studied in this paper for efficiently recovering vanadium, nickel, and aluminum from the acid leaching solution of spent hydrodesulfurization catalyst. The process conditions for extracting vanadium with Cyanex 272 and precipitating nickel using oxalic acid as a precipitation agent were explored in detail. The results show that vanadium (IV) in the sulfuric acid medium containing nickel and aluminum was efficiently and selectively extracted by Cyanex 272. After three-stage countercurrent extraction, the extraction efficiency of vanadium was 99.76%, and the co-extraction efficiencies of nickel and aluminum were only 2.47% and 1.87%, respectively. Thermodynamic calculation shows that the extraction of vanadium (IV) from the sulfuric acid medium with Cyanex 272 is an endothermic reaction. The innovative method of oxalic acid precipitation was used to recover nickel from the raffinate, achieving selective extraction of nickel from the solution containing a high concentration of aluminum. The precipitation efficiency of nickel was 98.58%, while that of aluminum was only 0.75% under optimal conditions. The proposed flowsheet for the separation of vanadium, nickel, and aluminum from acid leaching solution may provide a new idea for the comprehensive recovery of valuable metals from spent hydrodesulfurization catalyst.

Nov 30, 2022

By A. Iizuka

This study was aimed at separating and recovering arsenic, antimony, and tin from refining byproducts generated in a nonferrous smelter. The target byproduct was a silicate slag containing the above elements. The silicate structure of the slag was destroyed by alkali roasting, which then enabled leaching of arsenic, antimony and tin in solution effectively. Arsenic was selectively leached out by hot water after alkali roasting of the slag, while remained antimony and tin in the residue were leached out by a hot hydrochloric acid solution. However, when the solid-liquid ratio in the leaching solution was increased, hydrous gelatinous silica (gel-like silica) was formed during the hydrochloric acid treatment and filtration became difficult. Therefore, high temperature and high pressure leaching was attempted to improve the filterability of the silica leaching residue. In the high temperature and high pressure treatment, the hydrous gel-like silica was transformed into easily filterable aggregated silica, and thus, filtration became easy. By investigating the neutralization and sulfurization treatment for the obtained hydrochloric acid leachate (second leachate), it was possible to separate antimony and tin. INTRODUCTION This study aims to separate arsenic and recover valuable metals such as antimony and tin from refining byproducts generated in a nonferrous smelter. The target smelting byproduct is antimony-containing slag in this study. In many cases, alkali roasting was adopted as pretreatment for extraction and recovering valuable metals from smelting residues and wastes (Rao, 2006). For antimony-containing slag in this study, one effective method for separating arsenic is to convert arsenic to sodium arsenate (Na3AsO4) by roasting with a sodium compound and then to remove arsenic by hot water leaching. In addition, by alkali roasting, the silicate structure of the slag is destroyed, and effectively alkalizing tin and antimony is accomplished. Then, precipitating and recovering tin and antimony leached into the acid solution are considered possible by sulfurization and neutralization treatments. In this research, we conducted basic studies on the following. 1) Destruction of silicate structure in slag by alkali roasting and leachability of arsenic. 2) Conversion of hydrous gelatinous silica to aggregated silica by hydrochloric acid treatment of residues after arsenic leaching under high temperature and high pressure, as well as leachability of antimony and tin. 3) Separation and recovery of antimony and tin by sulfurization and neutralization treatments of hydrochloric acid leachate. These topics of investigation can support to consider the separation and recovery process of arsenic, antimony, and tin from antimony containing slag.

Jan 1, 2019

Sanes are utilized to make molds for metal castings in the foundry industry. Approximately a half ton of sand is disposed of for each ton of metal cast in this country. The purpose of this investigation was to study and develop a process to separate chromite sand and silica sand from reclaimed sands for a steel foundry. Physical separations were utilized to yield silica and chromite sands with desirable molding properties. Several different separation methods, including electrostatic, magnetic, and various gravitational approaches were examined. Experimental results are presented. A method was developed to separate chromite sand from silica sand after mechanical or thermal reclamation. The reclaimed sands are passed through a rare earth magnetic separator to separate chromite sand and magnetic impurities from non-magnetic silica sand. Chromite sand can be recovered from magnetic silica sand or magnetic impurities very effectively using a wet concentrating table. The applicabilities of the separation methods are discussed.

Jan 1, 1995

By Junji Shibata

Heavier rare earth, which is contained in a small amount in ores such as bastnesite and monazite, has been accumulated as a heavier rare earth residue without doing separation and purification due to the lack of suitable methods. The heavier rare earth residue includes seven rare earth elements such as Tb, Dy, Ho, Y, Er, Tm and Yb. Separation and recovery process of Dy, Y, Tm and Yb from leached solution of the heavier rare earth residue was investigated by using a column method with solvent impregnated resin. The solvent impregnated resin was prepared by impregnation of organophosphorous extractant whose trade name is PC-88A into a macro porous resin, Amberlite XAD-7. It was almost impossible to separate them in simple adosorption and elution steps. However, we attained to individually separate Dy, Y, Tm and Yb from the leached solution first by changing eluent concentration gradually from pH2 to 0.02kmol/m3 HC1 in the elution step, and secondly by using a development column and changing eluerit concentration in the elution step. The separation process flow was proposed for a heavier rare earth residue by using the solvent impregnated resin method.

Jan 1, 1998

By Martha Gellner, Lutz Wuschke, Hans-Georg Jackel, Urs A. Peuker

"Electric vehicles are an alternative to the existing combustion engine driven cars. According to the EU Battery Directive a substantial recycling rate of at least 50 wt.-% has to be met for aged batteries since 2006. Existing recycling techniques are based on energy intensive pyro- and hydrometallurgical process, which are not able to recover all components. Aluminum and lithium for instance are slagged. The EU-Project “ABattReLife” investigated possibilities for a mechanical processing in order to create a sustainable process and a closed material loop from grave to cradle. After a sufficient liberation of the Li-ion batteries, components like the doped carbon black fraction (mainly lamination of electrode foils), the separator foil and the housing material can comparatively easily be separated from the other components by screening and air sifting. The remaining mixture consists of anode and cathode foils which have a similar free-settling ratio and are more difficult to separate from each other. A second comminution and compaction step modifies the particle size and shape as well as the degree of delamination. These changes influence the density of the electrode foils in order to improve the separation efficiency. Yield and purity of the generated metal concentrates were parameters to show if the separation was successful. The specific energy consumption for the different methods of processing was estimated in order to benchmark the cost-benefit ratio for each one.The studies have been accomplished with a zig zag sifter (model TUBAF), a hammer mill (model HM 340 Jehmlich) and with a Petkus-Sifter. Finally a process flow sheet was developed for a Li-ion battery recycling plant in pilot scale."

Jan 1, 2016

By Soner Top

In this study, a process to separate manganese and iron from manganiferous iron ores by reductive acid leaching followed by magnetic separation was conceived and experimentally tested. In the leaching process, sulfuric acid was used as lixiviant and oxalic acid was used as reductant. The experimental results showed that the manganese and iron separation was optimum when the concentration of the sulfuric acid and oxalic acid were 0.75 M and 30 g/L, respectively, at a temperature of 80 °C, a solid/ liquid ratio of 67 g/L, stirring speed of 400 rpm, and leaching duration of 60 min. Under this condition, 90.49% and 6.78% of Mn and Fe were dissolved, respectively, from the ore sample with a size fraction of − 106 μm. It was determined that the leaching of manganese from the ores was a second-order reaction with an activation energy (Ea) of 53.38 kJ/mol. The leaching residues obtained under the optimum condition were subjected to high-intensity wet magnetic separation tests to recover the remaining iron content. This separation process produced a concentrate containing 56.20% Fe and 1.79% Mn with iron and manganese recoveries of 56.83% and 66.73%, respectively. A magnetic separation test from an unleached ore sample was also carried out as a benchmark. To the best of our knowledge, this is the first time that a magnetic separation process was used to a residue obtained from reductive acid leaching of manganiferous iron ores to recover iron.

By Soner Top

In this study, a process to separate manganese and iron from manganiferous iron ores by reductive acid leaching followed by magnetic separation was conceived and experimentally tested. In the leaching process, sulfuric acid was used as lixiviant and oxalic acid was used as reductant. The experimental results showed that the manganese and iron separation was optimum when the concentration of the sulfuric acid and oxalic acid were 0.75 M and 30 g/L, respectively, at a temperature of 80 °C, a solid/ liquid ratio of 67 g/L, stirring speed of 400 rpm, and leaching duration of 60 min. Under this condition, 90.49% and 6.78% of Mn and Fe were dissolved, respectively, from the ore sample with a size fraction of − 106 μm. It was determined that the leaching of manganese from the ores was a second-order reaction with an activation energy (Ea) of 53.38 kJ/mol. The leaching residues obtained under the optimum condition were subjected to high-intensity wet magnetic separation tests to recover the remaining iron content. This separation process produced a concentrate containing 56.20% Fe and 1.79% Mn with iron and manganese recoveries of 56.83% and 66.73%, respectively. A magnetic separation test from an unleached ore sample was also carried out as a benchmark. To the best of our knowledge, this is the first time that a magnetic separation process was used to a residue obtained from reductive acid leaching of manganiferous iron ores to recover iron.

In the screening process, used to prepare particles for many applications, shape is known to have a significant effect. The degree of flakiness of construction aggregates has been considered particularly important. The objective of this research was to find values of operating parameters that optimize the separation of flaky from non-flaky particles by slotted screens. Thus an investigation was conducted to experimentally determine the influence of the particle size and thickness on the screening process. The Response surface method was employed for modelling and analysis of the data. Experiments employing a central composite design were performed on a pilot-scale, rectangular-aperture, vibrating screen to examine the effects of the screening variables the mass recovery of flaky and non-flaky particles to the oversize product. The SAS statistics package was used to fit a second-order model to each response and to analyze the fitted surface to determine the optimum levels. The optimization associated with a dual response system was then considered. The results of this study should provide a basis for optimizing screening conditions to obtain maximum recovery of non-flaky particles to the screen oversize while minimizing the recovery of flaky particles, which should be of interest to the aggregate industries.

Jan 1, 1999

By M. Abdollahy

Solvent extraction of gallium from Bayer solution of Jajarm Alumina plant was investigated us-ing Kelex100 as extractant. Taguchi experimental design method was used in order to optimize the separation factor of Ga and Al. Optimum conditions were obtained as follows: Temperatuer: 65°C, volume ratio of aqueous phase to organic phase: 3.0:1.0, process time: 60min and organic phase containing 15vol.% Kelex100, 5vol.% isodecanol in kerosene. In this conditions, 74% gallium and 0.3% aluminum was extracted and separation factor was obtained 828.63.

Jan 1, 2014

By P. Romm

The German Kupferschiefer (copper shale) mining history reaches back over 800 years with its last active mines being shut down in 1990. Increasing metal demands and potential thread of future supply shortages led to the initiation of new exploration programs including feasibility studies for the Spremberg deposit as well as Federal Ministry of Education and Research (BMBF) funded research investigations of Kupferschiefer Waste Dump treatment in the Mansfelder region. This article describes the sensor based sorting results of coarse Kupferschiefer via Near Infrared (NIR) Sorting, being conducted by the department of mineral processing (AMR) in Aachen, Germany. It provides information about the necessity of presorting of the different ore types prior to flotation and puts the NIR Sorting results into context with conventional Kupferschiefer processing. Keywords: NIR sorting, kupferschiefer, sensor based sorting, preconcentration

Sep 1, 2012

By Weng Fu

In this study, Resin-in-Pulp (RIP) technology is used to separate Pb from a chalcopyrite slurry. Solvent-impregnated resin, Lewatit® VP OC 1026, which contains di(2-ethylhexyl) phosphoric acid (D2EHPA) in a macroporous polystyrene matrix was used, as the functional group exhibits selectivity for Pb over Cu. Adsorption pH, kinetics, as well as resin and CuSO4 concentrations were investigated. The results show that the kinetics of Pb and Cu loading are fast, reaching the adsorption equilibrium within 30 min. The equilibrium pH of 2 was chosen as optimum for operation in order to achieve a high Pb extraction rate and extent as well as selectivity for Pb over Cu. High Cu(II) concentration in solution results in Pb(II) requiring a larger amount of resin for the same degree of extraction. Regeneration and reuse tests show that the loss of adsorption capacity happens in the 1st and 2nd cycles and then the adsorption capacity stabilises for the 3rd cycle.

By Elsa Agante

Recycling of solid wastes, a common practice nowadays, requires the separation of the different materials in order to increase the products added value. The separation of one plastic from mixtures of different types of plastics is not easy due to their similar physical properties, but different techniques are available, from automatic sorting systems based on optical sensors to techniques adapted from mineral processing, namely gravity, froth flotation and electrostatic processes. In the last decade, many researchers have addressed the separation?s problem of different polymers, like Polyethylene Terephthalate (PET) and Polyvinyl Chloride (PVC), two polymers commonly used in packaging which have similar density. One proposed technique is the classical froth flotation performed in agitated cells. Froth flotation is a versatile and relatively cheap process widely used in mineral separation. It is based on the different behaviour of particles in the presence of an inter-phase air-water, which depends on the materials surfaces properties. Froth flotation can be affected by some variables such as impeller speed and air flow rate. Agitated cells, when used with low density materials, like plastics, can produce overstated turbulence that prevents the adhesion and collection of particles in the froths. In this case, separation is favoured by column flotation smoother hydrodynamics. This paper proposes the separation of PET from PVC by column flotation. The experimental work was carried out in a column of 9cm diameter and 1m high. The effects of some operating conditions, such as depressor and frother concentration, air flow rate and feed grain size on products grade and recovery were evaluated and the best flotation conditions for the separation of these plastics were established.

Jan 1, 2006

By Xi-Shan Li, Qian Li, Yong-bin Yang, Tao Jiang, Jie Ge

Compared with other pretreatments of sulfur & arsenic-bearing gold, double-layered pellet roasting has an advantage that sulfur dioxide and arsenic trioxide volatilizing from this refractory gold ores can be solidified into the coating without emission during the roasting. However, the separation of coating from roasted double-layered pellet should be focused on in the novel pretreatment. Based on the difference of physicochemical characteristics between roasted solidified coating and pellet core, several separation methods including grinding, drop impact and water quenching method had been systematically studied in this paper. The results showed that magnetic and gravity concentration could not obtain a satisfactory separation effect. The optimum separation rate of grinding was only 38.94% at grind time 12min, but it increased to 85.05% by drop impact under drop height 0.75m, drop times 20 and impact angle 45°, and that of water quenching taking advantage of slaking reaction of lime could approach 75.32%.

Jan 1, 2015

By Hao Deng, Hongmin Zhu, Jichao Li, Kai Huang

"Silicon and silicon carbide mixing micropowders obtained from the saw cutting industry of polycrystalline silicon ingot is separated by a simple sequential sedimentation. The Zeta potentials of the powders in the aqueous suspension are adjusted by varying the pHs with dilute acid or alkaline reagents. The dispersion and aggregation content of the microparticles is significantly influenced by pHs, and so their settlement velocity in the same hydraulic conditions are quite different, and silicon powders tend to suspend in the upper section of the suspension for its finer size and smaller density under the stronger Zeta potential repulsion force. The original content of the cutting powders with 30%wt silicon are separated into the Si-rich and SiC-rich powder respectively, and 62%wt Si-rich powder can be obtained after 4 times of sedimentation under pH = 8.0, showing the great potential for Si and SiC powder separation and recovery in a cost-effective way.IntroductionWith the fast development of photovoltaic (PV) technology these years, the market demand for the solar-grade high pure silicon material significantly increased, making the silicon recycling and recovery from the wire sawing slurry profitable and attractive[1]. Waste silicon slurry was produced in the multi-wire sawing process of a silicon ingot by using an ethylene glycol-based solution and silicon carbide abrasives as the slicing system. During this slicing process, about 30% of the silicon ingot will become the waste as the fine particles suspended in the slurry, which mainly consists of silicon kerf-loss particles, SiC fragmental particles, tiny iron fragments from the worn sawing wire and ethylene glycol-based solution [2]. The separation of above individual component is usually easy except for Si and SiC fine particles for their quite similar properties. So the biggest challenge for the effective recovery and recycling of silicon particles from the wire sawing slurry actually lies in the mutual separation of silicon and silicon carbide particles."

Jan 1, 2012