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By F Tang, Ö K. Büyükuslu, M Baben, S Petersen

GTT-Technologies’ ChemApp for Python was developed to provide a powerful, easy to use interface to ChemApp for a programming language highly popular with scientists and engineers. It is used, for instance, by GTT to develop program modules such as the CALPHAD Optimiser for the FactSage™ software, by customers to move from interactive FactSage calculations to perform versatile scripting with Python, and by GTT and its partners in research projects in the area of materials informatics. Computational thermochemistry is fundamental for advancing sustainable metallurgy and creating new alloy compositions for engineering applications. Materials informatics involves handling vast amounts of data and complex workflows. GTT’s approach uses ChemApp for Python and the FactSage thermodynamic databases to design recyclable alloys from the start, incorporating a higher percentage of scraps while aiming to simplify the workflows to simulate material design steps. Challenges arise due to recycling scraps, introducing more elements for consideration. CALPHAD-based databases accurately cover materials from primary metallurgy, but additional data for minority and critical elements is crucial for precise computational modelling. GTT combines machine learning-based ab-initio databases with traditional CALPHAD databases to cover the complete chemical space with appropriate accuracy. The design of a hardfacing alloy through a high-throughput materials informatics approach is used as a demonstrator of the current possibilities.

Jun 19, 2024

By Thirumalai, K.

Although the term "spalling" has long been known, Norton l first referred to its usage for the fracture or disintegration of materials subjected to rapid temperature changes. Spalling of ceramic materials at high temperatures has received attention in the past. Removal of the char formed during ablation in re-entry of space vehicles has been referred to as mechanical spalling. The first experiments to evaluate the process of rock fragmentation by thermal spalling were conducted by Stoces using a series of gasoline burners on the quartz veins of the Zinnwald deep mines in Germany. After the development of rocket-jet burners, the principles of 'thermal spalling combined with high fluid momentum found wide practical application in rocks. The well-known jet piercing process for drilling blastholes in taconite and for jet channeling in the quarrying of granite are among the more notable of these application^.

Jan 1, 1970

By Paykan Safe

This paper reviews various process off-gas cooling options available for sulfide smelting processes. Advantages and disadvantages of each, system are discussed along with the selection criteria for a reliable and cost effective :system. Various systems are presented to demonstrate typical process parameters for smelter off-gas handling systems and to outline operating difficulties associated with each system:

Jan 1, 1998

By Christoph Miller

About 80 years ago the mining industry saw an advertisement of a machine manufacturer: ?One man ? one machine?, meaning the productivity gain by using a pneumatic rock drill instead of manual tools. Mechanization in mining had started. In the 1950's and 1960's when mechanization progressed the word could be transformed into the meaning of ?one man ? one drill rig?. During the 80's automatic functions were added to the machines. Automation started. In the 90's, the first autonomous machines were seen, transforming the advertisement from the 1920's into ?one man ? multiple machines? operated from a remote control room. Soon, the productivity gain achieved by pure automation will also be flating out meaning that the margin cost of further productivity gain will be inefficiently high. What next? In mining operations there is still a high potential of unused productivity lost by ?trivial? things like organization, logistics and operational management. Changing the focus from mechanization and automation towards optimizing the overall mining process will unleash another big potential for cost cuttings and for enhancing efficiency of production. Optimizing an overall process is a task of much higher total complexity compared to an isolated machine automation focus. And a successful process integration requires the collaboration of machine vendors, infrastructure suppliers, IT services and the mine itself. It requires a number of of important preconditions to be fulfilled: ? Integrated IT systems with seamless interfaces between all components and peripherals involved ? Real time information access in all locations ? Real time overview of all operational aspects A crucial aspect for all of these issues is a seamless communication both above and also under ground and IT interfaces which are easy and price efficient to implement. This paper highlights ways to achieve productivity gains by process optimization. It also discusses needs for industry wide activities in order to enable cost efficient performance of mine process optimization projects.

Oct 1, 2009

By A. Kontopoulos

Refractory sulfide gold ores or concentrates require an oxidation pretreatment step to yield the contained gold amenable to the subsequent leaching step. The process options for oxidation pretreatment can be broadly classified as follows: roasting, high or low pressure oxidation bacterial oxidation, chemical oxidation, each with a number of alternative suboptions. Roasting and high pressure oxidation are being applied on an industrial scale; the stage of development of the other options range from preliminary laboratory to advanced pilot plant- In this paper, the major technical, environmental and economic aspects of the above processes are being discussed. Future industrial trends will also be considered. Particular emphasis will be placed on the treatment of arsenical ores and concentrates, where safe plant operation as well as, handling and disposal of the arsenic containing products and/or effluents 'and residues is of paramount importance.

Jan 1, 1990

By James E. Hoffmann

This paper briefly reviews the conventional technologies employed for the treatment of copper refinery electrolyte bleed. The strength and weaknesses of conventional practice will be reviewed and a number of process options to address the weaknesses of present process technology will be described and evaluated. The effect of process selection upon energy consumption and the environmental aspects of process effluent control will be discussed.

Jan 1, 1997

By A. Kontopoulos

The Olympias Mine in Northern Greece is producing an extremely refractory gold-bearing arsenical pyrite concentrate, containing on the average 41 3 S, 40 3 Fe, 10-12 3 As, 25 ppm Au and 35 ppm Ag. During the process selection stage, more than a dozen alternative technologies? were considered and an in-depth analysis was prepared for the three most promising, ie roasting, pressure oxidation and biological oxidation. Detailed capital and operating cost estimates were prepared, based, where appropriate, on laboratory and pilot-plant tests. A number of criteria was used for process evaluation and selection, including capital and operating costs; environmental impact, gold' recovery, stage of development, etc. Based on the above evaluation, the Sherritt Pressure Oxidation Process was finally selected. A detailed description of the process selection stage, supported with laboratory and pilot-plant test results on many of the processes considered, will be? presented.

Jan 1, 1989

By Z. R. Llanos

This paper presents a review of industrial and experimental processes for the recovery of molybdenum, vanadium, nickel, cobalt and aluminum from spent hydrotreating or hydrodesulfurization catalysts. Numerous processes have been developed in a laboratory and pilot scale. However, worldwide, there are only four well established commercial facilities currently in operation. The installed capacity of these facilities exceeds the availability of spent catalysts and may be sufficient to assimilate future increases of spent catalysts. Despite liability risks; significant quantities of spent catalysts are still being landfilled. Changing regulations that may affect the future handling and disposal of spent catalysts are also reviewed.

Jan 1, 1995

By Xue Yang

Even though many approaches have been proposed for automated fault detection and diagnosis of Heating Ventilation and Air Conditioning (HVAC) systems, and advanced maintenance programs, such as preventive and predictive maintenance have been applied for the systems, issuing work orders for corrective maintenance is still a reality. Currently corrective maintenance still accounts for more than 55% of all maintenance programs in average facilities in the US (DoE, 2010). Indoor air related problems are especially important among corrective maintenance work orders. This paper provides details of a case study conducted to capture the workflow that HVAC mechanics follow, their rationale in diagnosis process and the information they typically refer to while responding to indoor air related corrective maintenance work orders. The general workflow for HVAC mechanics to complete such types of work orders was summarized into 5 stages, and generic information requirements recorded from the case study were synthesized. Initial findings show two main challenges in the industry for HVAC mechanics to get access to required information, which highlights the need for a systematic approach that would enable identification of such information applicable to a given context under which a work order has been generated and provide values of required information for HVAC mechanics to do sound diagnosis through integrated data repositories.

Aug 1, 2013

By E. C. Sanford

A laboratory-scale batch extraction unit and operating procedure for studying the hot-water separation of bitumen from Athabasca tar sands are described. The extractor evolved from earlier units and has been in use by Syncrude Research for the past 10 years. By using a unit such as this, it is possible to study tar sand feed quality and the effects of chemicals on the hot-water extraction process, while process variables are held constant. Data are presented to demonstrate the importance of surfactants to the process and the interrelated role of inorganic bases and surfactants.

Jan 1, 1979

By Ken-ichi Machida

"Surface modification of R-Fe-N intermetallic compounds was made to improve their magnetic property and nitrogenabsorbing ability, arid high-performance resin-bonded magnets and nitrogen storage materials were developed: Surface coating for Sm2Fe11Nx by the zinc metal produced via photodecomposition of Zn(C2Hs)2 was effective to avoid the further oxidation in the molding process of the fine powders for bonded magnets and the resulting (BH)max values were improved to -186 kJm-3. Meanwhile, R2Fe17 as the mother compounds for RzFe11Nx was highly active for decomposition of NH3 molecule and subsequent nitrogen absorption as metal nitrides. Furthermore, even inert Nz molecule was dissociated on them by impregnating Ru metal and the resulting nitrogen atoms were absorbed in the crystal lattice of R2Fe17. These results demonstrated that the nitrogen storage system was established by cycling the nitrogenation and hydrogenation of RzFe11/R2Fe11Nx materials.IntroductionProcessing for rare earth metals and intermetallic compounds requires well-controlled conditions in order to avoid the oxygen contamination involved in it due to their high reactivity, as causes the serious damage for materials such as magnets, metal hydride for hydrogen storage, and so on. Rare earth-iron intermetallic compounds, R2Fe17, provide the corresponding metal nitrides (R2Fe11Nx) by heating in N2 or a mixed gas stream ofNH3-H2 [l] and, among them, Sm2Fe11N3 has been particularly noted as one of the promising materials for high-performance permanent magnets such as bonded ones [2- 6]. Usually, the nitrogenation for Sm2Fe17 is made in Nz, but it needs the much more hard conditions of reaction pressure (-10 MPa), temperature (-550°C) and time (-72 h) than the nitrogenation in the NH3-H2 mixture [l]. In the latter case, a significant amount of nitrogen can be interstitial introduced in· the R2Fe17 crystal lattice (x=-7) under the more moderate conditions than in N2 (at 0.1 MPa and -450°C for -3 h) [3-6] and then, in a similar manner as metal hydride systems [7], the excess nitrogen in RzFe1 7Nx (x>3) is reversibly desorbed by heating at a temperature around 500°C in Ar to form the RzFe11N3 compounds. This behavior of nitrogen absorption and desorption has a close relation to the sites for nitrogen in the crystal lattices."

Jan 1, 2000

By M. M. Kim

Zn-27% Al was pressure infiltrated into a column of 20 micron diameter abrasive grade SiC particles to give billets with particle loading of 50 voli.une %. Some billets were heated to a temperature where they became semi-solid and diluted with liquid Zn-27% Al alloy to give billets with particle loadings of 12 and 16 volume %. Some of these billets were then extruded into wire with an area reduction of approximately 98%. Tensile properties of the as-cast billets were always inferior to those of the matrix alloys; however, the extruded composite samples showed at 37% improvement in ultimate tensile strength compared to their extruded conventional counterparts. The fracture surfaces of these samples are described.

Jan 1, 1990

By M. S. Badollet

"IntroductionAsbestos as received by the manufacturer of asbestos products is •in the •form of either crudes or milled fibres processed to different degrees of texture. Frequently, the manufacturer finds that l:ihe fibres as he buys them are not adaptable to his plant processes, and, therefore, it is necessary for him either to contact the mine supplying the material and request a specific texture for the :fibre or to reprocess the fibre in his own plant.When the mine or mill manager is requested to change his milling equipment to produce a special grade of fibre with a specific texture, he would like to comply. However, if he began to make special fibre grades for each customer, he would be in the position of constantly rearranging his milling technique, adding more equipment, or building a new mill. In the end, his mill would he producing hundreds of different fibre grades of varying degrees of texture, which is a difficult accomplishment if he desires to maintain any quantity of production."

Jan 1, 1950

By Dean D. Turner

Exploration geochemistry requires computer processing for quick and efficient reduction and interpretation. An easy to use microcomputer based geologic workstation fulfills this need and allows the geologist to independently process geochemical data. Functions necessary for geochemical data processing are: 1)Digitizing; 2)Communications; 3)Data base management; 4)Statistical analysis; 5)Mapping analysis; and 6)General purpose applications (ie: word processing). A geologic workstation that can perform these tasks will yield significant advantages in processing and interpreting geochemical data.

Jan 1, 1987

By Yuechang Wang

A new method of manufacturing the wavy-tilt-dam(WTD) mechanical seal has been mentioned. In this method, the special equipment is designed to provide a predetermined force to external and inner circular surface of the ring. After milling the end face of the seal by grinding miller and releasing the preload, the wavy-tilt-dam can be done on the seal surface. In this paper, a prediction model is built up to investigate the relationship between the predetermined force and the deformation on the surface of the ring by using ANSYS software. A WTD ring is manufactured by this method which approves that the prediction model is in accord with the real process and this manufacturing method of the WTD mechanical seal is a proper choice.

Jul 31, 2018

By H. Rush Spedden

A process has been developed and piloted to reject copper, lead, iron, phosphorus, bismuth, antimony, elemental sulfur, and insol from molybdenite concentrate without decomposing the contained molybdenite and rhenium. The impure concentrate is first heated with concentrated sulfuric acid at 260 to 290°C for 1 hour. This bake not only oxidizes the contaminating sulfides, but also activates the concentrate for later rejection of insol by flotation. Two stages of leaching follow the sulfation step. The first is an acidified water leach which extracts the oxidized copper, iron, and phosphorous; the second leach rejects the lead, bismuth, and antimony into a warm concentrated solution of sodium chloride. Final upgrading is achieved by conventional froth flotation. The chemistry of the process as well as results obtained from its implementation in a 5,000 lb/day pilot plant are presented.

Jan 1, 1971

By J. S. Lewis

Beneficiation and physical and chemical processing of non-terrestrial materials borrow strongly from terrestrial experience, but also involve the necessity of handling literally un-Earthly feedstocks, reagents, and environmental conditions. The present state of scientific and engineering understanding of the processing of non-terrestrial minerals, gases and hydrocarbons is reviewed with the production of rocket propellants, life-support fluids, structural metals, and refractories as the goal.

Jan 1, 1992

By Corby G. Anderson

Antimony has been utilized by mankind for thousands of years. However, due to recent environmental concerns, antimony is often considered to be an impurity element, Since antimnoy is commonly found in precious metal refractory ore bodies, extraction is essential. The Sunshine Mine in Kellogg, Idaho has recovered antimony from its precious metal tetrahedrite deposits since the 1940's. A plant was initially constructed as a primary antimony source during World War II. This facility also decreased the downstream smelting penalty for the silver copper-lead concentrate and provided an industrial commodity from a potential environmental nuisance.' This paper describes the Sunshine antimony processing- facility. Specifically, the relevant process chemistries involved in concentrate leaching, metal electrowinning, and sodium antimonate production will be discussed. In addition, ongoing areas of research to improve unit operations and treatments implemented to meet environmental' discharge requirements will be covered.

Jan 1, 1992

By Nikhil Dhawan, Veeranjaneyulu Rayapudi

This study investigates upgrading of low-grade banded hematite quartzite iron ore (Fe ~31%). Conventional beneficiation was found to be futile. The susceptibility of iron phases to microwave exposure and their selective absorption assists in the liberation of iron values. Microwave exposure of coarse particles at 540 W for 10 min yielded a concentrate with Fe 56.30% and recovery of 50.68%. Conventional carbothermic reduction at 500 °C, 60 min and 9% charcoal yielded a concentrate with Fe 57.6% and iron recovery of 68%. The presence of sufficiently bonded silica leads to an easy formation of a fayalite phase. The microwave reduction design yielded FeG of 57.6%, FeR of 47% and a yield of 24% at an optimal condition of 540 W, 8 min and 6% charcoal. It was found that a small fraction of microwave-irradiated ore-charcoal mixture melted rapidly, and pure ferrite balls were observed within 8 min. An optical micrograph of a ferrite ball reveals the retained austenite and martensite phase.

By Nikhil Dhawan, Veeranjaneyulu Rayapudi

This study investigates upgrading of low-grade banded hematite quartzite iron ore (Fe ~31%). Conventional beneficiation was found to be futile. The susceptibility of iron phases to microwave exposure and their selective absorption assists in the liberation of iron values. Microwave exposure of coarse particles at 540 W for 10 min yielded a concentrate with Fe 56.30% and recovery of 50.68%. Conventional carbothermic reduction at 500 °C, 60 min and 9% charcoal yielded a concentrate with Fe 57.6% and iron recovery of 68%. The presence of sufficiently bonded silica leads to an easy formation of a fayalite phase. The microwave reduction design yielded FeG of 57.6%, FeR of 47% and a yield of 24% at an optimal condition of 540 W, 8 min and 6% charcoal. It was found that a small fraction of microwave-irradiated ore-charcoal mixture melted rapidly, and pure ferrite balls were observed within 8 min. An optical micrograph of a ferrite ball reveals the retained austenite and martensite phase.