Search Documents

"Hematite pellets were electro-deoxidized to iron in molten sodium hydroxide to produce iron containing about 10-wt % oxygen. The anodic reaction was the evolution of oxygen on an inert nickel anode. Before the electrochemical reaction, there is a reaction between sodium hydroxide and ferric oxide to form sodium ferrite and, in order to compensate for the reduction in sodium oxide content, 1 wt % sodium oxide is added to the melt. In a laboratory cell, the cell voltage was 1.7 V with a current density of 5000 A m-2, a current efficiency of 90% and an energy consumption of 2.8 kWh kg-1.Introduction The iron and steel industry contributes about 2.3 bn tonnes/annum of the carbon dioxide to the atmosphere, which is about 10% of the total, and some believe that, in order to prevent a catastrophic rise in the earth’s temperature, carbon dioxide emissions must be reduced by 50% come 2050. However, by 2050, it is likely that the iron and steel industry would have grown significantly so that the production may have risen to 2 or 3 bn tonnes/year so in order to meet the 50 % reduction on today’s figure, the carbon dioxide may have to be reduced to 25% or less, which is a very demanding requirement. There are probably three ways of reducing the carbon dioxide output:1. By capture and sequestration, but this may be technically very demanding.2. Reduction using hydrogen in place of carbon."

Jan 1, 2009

By W. H. Hannay

Introduction The subject matter of this paper will be treated under two heads: (1) experimental work and the development of the purification system, and (2) the operation of the commercial plant. During 1927-28, a two-ton slag-retreating plant was in operation at the smelter for experimental purposes. Details of this operation and of the commercial plant are presented in a paper by G. E. Murray, read before the Annual General Meeting of the Institute in April, 1933 (1). A point which has considerable bearing on the subject of the present paper, and which was not emphasized by Mr. Murray, is the concentration of volatile impurities in the zinc oxide fume produced. The result of the operation of the slag fuming furnace is largely to confine in a closed circuit all the minor constituents of the Sullivan concentrates, both lead and zinc. They pass into the feed of the zinc fuming furnace, with the result that all impurities which volatilize-such as arsenic, antimony, tin, fluorine, etc.-report in the zinc oxide product. The accompanying condensed flow-sheet (Figure 1) will illustrate this. The only outlet for impurities which is not shown is the small tonnage which passes the Cottrell plants. The flow-sheet would indicate the possibility of building up a prohibitive concentration of cathodic impurities in the oxide leaching plant feed. However, after three years' continuous operation this has not occurred. Should this condition arise at some future date, discard of some tonnage of blast furnace slag is indicated. In Mr. Murray's paper, the much greater flexibility of blast furnace operation, due to the slag fuming furnace, is stressed, particularly as to the lead content of the slag. The requirements of our lead refinery call for a bullion containing about 0.70 percent antimony.

Jan 1, 1934

By M. Olper, M. Maccagni

"The crude zinc oxides (CZO) produced in any thennal process dealing with EAF dust also contain lead, cadmium, and a considerable amount of halides (chlorides and fluorides). The high halide contents make these crude zinc oxides less and less attractive, both technically and economically, and a further refining procedure is nece'ssary to meet the zinc and zinc oxide market requirements.Hydrometallurgical techniques commercially used to dehalogenate the crude zinc oxides are not effective enough to upgrade the crude zinc oxides to the required specification for their direct use in the traditional sulphuric electrolysis by primary zinc producers.The EZINEX® PROCESS has solved the problem of the halides contained in the crude zinc oxides. This process is the only proven technology electrowinning zinc from a chloridebased electrolyte in a conventional cell house. This paper discusses the process economics taking the data from feasibility studies of different size commercial plants."

Jan 1, 2000

By P. A. Treasure

The EMEW® cell has been developed to overcome a number of inherent limitations in conventional electrowinning technology, particularly the high cost and restricted process windows characteristic of conventional hardware. The technology has been widely demonstrated to achieve high performance for various metals under chemical conditions well outside the limits required for efficient operation of conventional cells. This process flexibility offers significant opportunities for cost savings. in recovery of zinc from primary and secondary sources. The EMEW® technology is now available on a fully engineered basis, as a versatile commercial alternative to conventional electrowinning hardware. Application of the EMEW® cell for recovery of secondary zinc material offers significant advantages to the recycling industry. For example, a selective caustic leach can be used where there are high levels of iron or other contaminants in the target material. The reagent requirement is minimal as most of the caustic is regenerated in the bell and zinc dust that may be required for electrolyte purification is produced in the cell. A high purity zinc powder or cathode is produced in the cell. In the case of acidic zinc electrolytes, the cell is capable of operating over a much wider range of operating conditions than a conventional cell.

Jan 1, 2000

J. L. McK. YARDLEY,* Pittsburgh, Pa. (written dlscussion ?) .-It is interesting to observe how closely Mr. Hansen agrees with other investigators to the effect that the art of electrolytic zinc has left the realm of mystery. In his introduction, lie has said practically what Thomas French said in his paper "The Future of Electrolytic Zinc. "1 The successful electrolysis of zinc from sulphate solutions has not been an easy matter, and it is only within recent years that the difficult problem of depositing high-grade zinc has been satisfactorily: accomplished on a commercial basis. The principal requisite is. that the electrolyte shall be quite free from certain impurities. The methods by which freedom from these impurities is assured are now very well understood, and with experienced superintendents there is little difficulty in obtaining a high efficiency in that part of the process. When certain underlying principles are recognized, the difficulty encountered in dealing with the filtration of the acid and slimy solutions also largely disappears, although it has been a very serious one to the uninitiated. In the dissolving of the zinc from the roasted ore, there is nothing which any competent chemical' engineer cannot undertake, and any other operations connected with the electrolytic process are either of little or no difficulty, or are common to the retort process. Mr. Hansen also agrees with R. G. Hall's statement in " Some Economic Factors in the Production of Electrolytic Zinc:"2

Jan 10, 1918

By Nagy El-Kaddah

"One of the emerging technologies for the production of ultra-clean metals is electromagnetic filtration. The theory and the mechanism of electromagnetic separation of inclusions from molten metal are briefly reviewed along with basic electromagnetic separation systems. This paper focuses on inclusion removal in the induced current separators, with specific reference to a new separator developed at the University of Alabama. A simple analytical model is presented for the analysis of particle separation in such a system. The role of the applied magnetic field on inclusion removal will be discussed. It is shown that particle velocity increases exponentially with increasing magnetic field strength. At moderate field strengths, the velocity of 50 to 100 u. inclusions· are an order of magnitude larger than those achieved by buoyancy. The separator developed at the University of Alabama is described together with experimental results of laboratory and large scale experiments on purification of molten aluminum. These results demonstrate the capability of the system for producing super-clean metals.IntroductionThe nature of extraction, refining and processing of metals is such that oxides and other non-metallic particles will always be present. This is due to the highly reactive nature of metals with oxygen and other non-metallic elements. The presence of these type inclusions in metals, even in minute amounts, can seriously flaw the reliability and performance of the final product. They not only reduce the strength and the stiffness of the metal/1/, they are the reason behind many of manufacturing defects such as porosity in castings, surface and internal cracks in continuously cast ingots and rolled products, etc., which act to cause premature failure of manufactured parts. In fact, for critical applications such as turbine blades, there is virtually no tolerance for inclusions above ten microns in size /2/. Therefore, removal of inclusions from the liquid metal is an essential processing step.The demand for cleaner metals has brought major changes in the technology and practice of metal refining and casting. Inclusion removal from the melt is currently achieved by passing the melt through a series of melt treatment systems, including induction stirring furnaces, argon-stirred ladle, and ceramic foam and deep-bed filters /3,4/. These systems are generally capable of removing all inclusion particles above 50 microns in diameter, which meets current cleanliness requirements for most applications. However, they may not be able to meet the projected cleanliness levels for critical applications due to kinetic and operational limitations of these systems in removing smaller particles /5/."

Jan 1, 1996

By Nagy El-Kaddah

One of the emerging technologies for the production of ultra-clean metals is electromagnetic filtration. The theory and the mechanism of electromagnetic separation of inclusions from molten metal are briefly reviewed along with basic electromagnetic separation systems. This paper focuses on inclusion removal in the induced current separators, with specific reference to a new separator developed at the University of Alabama. A simple analytical model is presented for the analysis of particle separation in such a system. The role of the applied magnetic field on inclusion removal will be discussed. It is shown that particle velocity increases exponentially with increasing magnetic field strength. At moderate field strengths, the velocity of 50 to 100µ inclusions are an order of magnitude larger than those achieved by buoyancy. The separator developed at the University of Alabama is described together with experimental results of laboratory and large scale experiments on purification of molten aluminum. These results demonstrate ?the capability of the system for producing super-clean metals.

Jan 1, 1996

To provide a method for locating trapped miners promptly and accurately. The Approach: Develop a wireless emergency system that is intrinsically safe, compact, easy to operate, reliable, sturdy, and economical. How It Works: A (one transmitter has been developed under Bureau of Mines contracts. The transmitter weighs only a few ounces, is powered by a cap lamp battery, arid can be carried on the miner's belt. A compact loop antenna, which could either be carried by the miner or strategically located in the mine, is used to generate a magnetic field that is sensed by a mobile receiver on the surface. When needed, the antenna is deployed to form a single loop. In mines where the overburden is less than 600 feet, a loop of No. 19 wire approximately 30 feet in circumference is normally adequate. This antenna weighs less than one half pound. In deeper mines, a heavier wire and bigger loop is required; a No. 10 wire deployed around a pillar has been used.

Jan 1, 1974

By Lorant B. Geller

Sixteen miners died tragically at the Paymaster gold mine at Timmins, Ontario in February, 1945, when a badly corroded hoist rope broke. The investigation of the Royal Commission that followed arrived at a number of recommendations (Investigations, 1947) aimed at avoiding future disasters of this kind. One consequence was the development, and legislated use in Canada, several decades ago, of powerful electromagnetic (EM) instruments for the nondestructive testing of mine shaft wire ropes. The authors have been involved for many years in the design, production, and testing of EM instruments (Geller and Udd, 1990 and 1992, Geller and Kitzinger, 1991, Geller et al., 1993). Since the mid-1990s particular attention was paid to the design and operational results obtained from the computer- controlled portable MagnographJ II wire rope tester (Geller et al., 1995 and 1998). In the present article the authors summarize further hardware- and software-related developments of this instrument. Further, an account is given of the results obtained from the most recent design known as the PermaScanJ testing system. This is also a computerized dual-function system. In it, however, the sensor head is designed primarily, if not solely, for permanent installation and for remotely controlled operation. This represents a basic departure from traditional designs, which were intended for ad hoc temporary installations. The remotecontrolled instrument described in this paper has now been in operational use for more than 4 years.

May 1, 2003

By Vadim J. Jabotinski

Electron beam processing is potentially very attractive for the high temperature treatment of hazardous materials. The very high power efficiency of the electron beam energy source (80- 90% of the power from the electric power line is converted to useable energy) is one of the positive features of this technique. This paper will consider advanced electron beam concepts for solid, liquid, and gaseous waste treatment such as stabilization of radioactive solid and liquid hazardous streams. Fundamental aspects and applications including an analysis of the economic potential of electron beam processing of waste treatment will be presented.

Jan 1, 2000

"Mechanical alloying (MA) synthesizing technology and thennohydrogen processing (THP) were utilized to produce nanocrystalline Ti-MMC's reinforced by TiB intermetallic compound by using TiH2-B powder mixtures. Powders MA'ed up to 8 hours were examined by X-ray diffraction and SEM study. All MA'ed powders afterwards were HIP'ed at 700, 800 and 950EC for 1 hour. Detailed XRD, SEM and TEM study of the samples were carried out to determine the structure and micrography of the Ti-TiB MMC material processed by MA+THP approach followed by HIP'ing at high temperatures.IntroductionThe fiber reinforced titanium base composites [1,2] which possess a great resistance to high temperature have been investigated. In these studies fibers of C and SiC were used as reinforcing materials. However, these fibers react with Ti-matrix at elevated temperature resulting in product formation at the interface between the matrix and the fiber. Because of the chemical reactions, strength of the product MMC material diminishes.In conventional techniques of whisker reinforced composite material production, the mixtures of matrix metal powders and dispersed fibers are consolidated by hot pressing, HIP and/or hot extrusion. These techniques, however, have some shortcomings. Hard and brittle fibers could be broken during mixing cycle of the processing. Consolidation techniques could also be the cause for fiber breakdown. Attaining of the uniform dispersion of fibers into the metal matrix is not an easy process. The chemical reactions at elevated temperature exposures in the interface between the matrix material and fiber reinforcement cause product formations leading to poor mechanical properties."

Jan 1, 1998

The information age has arrived. In every aspect of life, at the end of the second millennium, computers and information technology have made significant inroads. In mining there has been huge growth in the use of digitally controlled systems. From resource evaluation to mine planning to daily operations, information is being acquired, analysed, modeled and presented, using state-of-the-art information technology. Explosives, too, have moved into the information age. Computer controlled trucks and manufacturing plants have been developed and are now a regular feature on many mine benches. The next challenge for the explosives industry as a whole is to integrate blast initiation with information technology. The benefits are there, both to the supplier and to the end-user. Much has been written in the past about the potential for blast improvement but there are other significant advantages to a digital initiation system. These include security from unauthorised use, stock control and minimisation, reliability through testability and ease of use to name a few. So why is it taking so long? Surely the complexity of an electronic initiation system is far less than that of mobile phones that have been around for a long time. The answer, it seems, lies in the level of new technologies that need to be developed. There are enormous technological hurdles to be overcome in order to put into the market a cost-effective, reliable, user-friendly electronic initiation system. The most significant of these are:Safely and reliably initiating an explosive from an electronic device powered by a small capacitor. Prior to the development of electronic detonators primary initiation of explosives was by shock tube spit or by passing large currents and voltages down a pair of wires. Electronic detonators do not have that luxury. For example the energy stored in a æBeethovenÆ exploder is more than 500 times greater than that available to an electronic detonator. Communicating to a multitude of devices over very long cables installed by miners in harsh conditions. The deployment of an electronic detonator system has been likened to building a large telephone exchange in the rain and getting it to work perfectly first time! New communications protocols needed to be developed and tested. Wiring and connection systems have to be designed to survive the mining environment. In spite of these technological hurdles most of the major explosives manufacturers have persisted with electronic initiation systems and we are now, in 1999, starting to see the results of these multi-million dollar efforts. At SMI we are often asked many questions about this technology. The remainder of this paper seeks to answer those most often asked. As with any business linked to information technology todayÆs breaking news is tomorrowÆs archive and we expect the rate of development and understanding to accelerate as these technologies become accepted by the global mining industry.

Jan 1, 1999

By Steve Brace

Electronic detonators have been commercially available to the mining industry worldwide for over ten years. It is estimated that total cumulative global sales will have reached 25 million units by the time of the Conference in February 2004. This is below 0.2% of all detonator types sold during this period. Perhaps 20 million will have been used underground in South African gold, diamond and platinum mines. These will have been produced by South African companies, in South Africa for South African customers. Here efforts have met with greater success and in 2003 fully 5 million, or 3% of local detonators sold, could be of an electronic type. However, it is estimated that about US$7.00 (R50.00) has been expended on R & D, manufacturing facilities and marketing, for each unit so far sold. Large sums of money continue to be spent. Despite the apparent success in South Africa, is it justified? Electronic initiation systems have not produced significant technical benefits to the end-user underground nor corporate profits to the supplier. Some doubt they ever will (even from the large surface operations where the price per unit is much higher). A conclusion might be that they have failed. In 1998 Smit and Pistorius wrote a paper titled “Implications of the Dominant Design in Electronic Initiation Systems in the South African Mining Industry”. This ISEE paper seeks to summarise and review the conclusions of the earlier work. These were: that a dominant design had not yet emerged; the type of connector and the way in which detonators are connected and programmed would be a strong determinant influencing the development of a “winning” product; technical aspects rarely solely determine which becomes the dominant design (marketing, social and economic factors often have a strong influence); electronic initiation systems were an emerging technology for the underground gold mining industry in South Africa and because it was under severe cost pressure the mines would look to them to raise productivity and hence profits; finally, as a dominant design begins to emerge, one could expect a number of players to exit from the industry.

Jan 1, 2004

By Joshua Hoffman, William Chad Wedding, Braden Lusk

The emergence of electronic detonators as viable products for use in production mine blasting has enabled mining professionals to rethink the traditional blast design methodologies that pertain to timing. In many ways, electronic detonators can allow great advances in productivity, cost effectiveness, fragmentation, and safety. There are a number of commercially available systems that enable users to program delay times, usually in one-millisecond intervals, according to design decisions. While manufacturers have performed internal studies pertaining to the accuracy of these systems, an independent study quantifying the accuracy of the systems has not been completed to date. The mining industry is in the business of production and any quality control endeavors to independently confirm the accuracy studies performed by the manufacturers would only detract from their bottom lines. Furthermore, limited information is available concerning the accuracy of modern pyrotechnic delay based detonators. In 1985, the Bureau of mines completed a study of three manufacturers’ electric millisecond delay detonators (Bajpayee, 1985). This was the most recent extensive independent study performed on detonators, which unitized pyrotechnic delays, from numerous manufacturers. Advances in the manufacturing process for pyrotechnic delays may have increased the accuracy of detonators using these technologies in recent years. It is commonly accepted that electronic detonators are more accurate than both shock tube type non-electric as well as electric detonators, but the relative accuracy was not objectively and adequately quantified.

Jan 1, 2011

By Laurent Airaud

For around ten years, electronic detonators are available for those who want to use advanced methods and to apply theories promoted by engineers and professors to reduce blast concerns or improve fragmentation and dilution. Furthermore, decision makers can verify the use of electronic detonators to drive down mining costs. Engineers and more specifically blasters are the actual users and have to be convinced of the easiness of electronic detonators. This paper deals with electronic detonators and the notion of easiness. Common feelings about the notion of easiness are discussed. Then, examples of new technologies like, automobile, photography or Information Technology are discussed to observe how they progressed throughout time with new features and sales volume. For the specific explosive initiation industry, each step of the life of an electronic detonator is dealt with concerning the easiness and a table is used to quantify this notion.

Jan 1, 2004

By Tuan Nguyen, Dirk Hummel, Ruilin Yang

In a tunnelling site in Japan, it was found that detonators failed to initiate with their shells and primary explosive intact. Their capacitors, however, were discharged due to some damage on the application-specific integrated circuits (ASICs). These detonators are distinctly different from other commonly observed failures, where the shells are rather crashed due to excessive dynamic pressure received from neighbouring blastholes which fired earlier. Such incident has not been reported elsewhere. Detonator failures during a blast are deemed not safe and can cause disruption on the project productivity. It is therefore desirable to understand the origin of such event. Various measurements were conducted to diagnose the problem, but the root cause had yet to be identified. This paper applies a discovery from a 60-year-prior-laboratory experiment and formulates a theory that could explain the observed detonator failure and predicts the measurements and observations.

Feb 6, 2023

By C. Zuniga, S. Combrinck, C. Peters

Agnico Eagle Gold have partnered with Enaex Australia at their Fosterville gold mine to leverage a combination of drill and blast technologies to optimise underground development mining. The mine is the first site globally to collaboratively develop and trial Enaex SWIFT electronic development detonators, which utilise a novel approach to the user interface, simplifying implementation and enabling the benefits of electronic initiation without the complexity of a conventional system. This has been combined with the use of a Sandvik 422i smart jumbo, and the Enaex underground emulsion charging unit with the capability to tailor the delivery of explosives as required and report on a hole-by-hole basis. The combination of these technologies enables full engineering oversight of the development cycle, in turn enabling optimisation of this process in a historically conservative application. The methodology for leveraging these technologies is to bore a controlled and defined blast pattern through using a smart jumbo, load the blast holes utilising lace loading to deliver a desired quantity of ammonium nitrate emulsion per hole, with the ability to reduce chargeweight for perimeter control, and utilising Enaex SWIFT electronic detonators with flexible template type pre-defined delays to initiate the blast holes. Subsequent to firing and excavation the performance of the blast in fragmentation, advance efficiency, and overbreak and underbreak is measured and reviewed. This is then used to optimise the development cycle and apply to other parts of the mine.

Feb 6, 2023

By Fred D. Rosi

Introduction There is probably no field in which materials research has played a greater role than that of electronics. However, to trace present and future patterns of materials research in electronics is not an easy assignment, since this industry has a high degree of dynamism in its growth, and is busily engaged today in the scientific improbabilities of only recent yesterdays. On the other hand, this task seems especially appropriate since electronics is a truly frontier industry - one whose place in American industries has advanced from 50th prior to World War II to 6th in 1967, with sales of more than $22 billion. And this growth has been associated with the equally rapid progress of science and technology over the period - in particular with the emergence of materials science as a vital force in underscoring this progress. For several reasons this parallel growth is not too surprising. First, by its very definition electronics is a science that essentially deals with the nature, behavior, detection, generation, control and utilization of electrons in solids or at their surfaces. Second, in the electronics industry, systems are made of an integration of components, and these components with their interconnections are made of materials. Thus, the basic building blocks of systems are materials; and it has been largely the advances in materials research and technology that have led to new and improved devices and systems. It follows, therefore, that the broadening of the frontiers in electronics through the exploration of new territories is tantamount to scientific discovery and materials innovation to a degree found in no other major industrial activity. But to put this in the proper perspective of present and future materials trends, it would be appropriate first to survey historically the progress in electronics by pointing out major scientific discoveries and associated materials research patterns that have led directly to its tremendous growth. Then from this base we can consider recent trends in materials research that could form the basis for future progress in the electronics industry. In my review I shall examine the areas most familiar to me, so I must acknowledge at the outset that this survey is not all-inclusive.

Jan 1, 1971

By V. V. Satya Prasad, A. Sambasiva Rao

Electroslag melting technologies have recently been developed for recycling light scrap of valuable metals and alloys such as superalloys and oxygen free high conductivity (OFHC) copper at Defence Metallurgical Research Laboratory (DMRL), Hyderabad. Conventionally, electroslag melting processes use consumable electrodes. Because of the difficulty in compaction of scrap into a consumable electrode of satisfactory quality, non-consumable electrodes such as graphite and water-cooled copper have been designed. Electroslag remelting using a water-cooled non-consumable electrode was developed to melt scrap of a nickel base superalloy. Sound ingots with smooth surface finish and properties comparable to vacuum melted superalloys could. be obtained from scrap using this process. A modified electroslag crucible melting process using graphite crucible and graphite electrode was developed for recycling OFHC copper scrap. Copper ingots with less than 10 ppm oxygen and electrical conductivity"" 100% IACS could be produced. The same process was also utilized to produce copper-based alloys such as copper-chromium and copper-titanium starting from copper scrap.

Jan 1, 2000

By F. Fraas

ELECTROSTATIC methods are used to separate and concentrate or purify granular particles derived from ores or various synthetic and agricultural products. Compared with other separation methods that require many technological refinements, the electrostatic attraction of fibers, grass, and seeds to charged surfaces clan be accomplished under the most primitive circumstances, and the early development of this method of beneficiation seemed very promising. Precise application of the method to provide high selectivity, however, is a complex procedure, and interest in this method declined. During this period Mr. O. C. Ralston initiated a Bureau of Mines research program oil electrostatic separation. It is the purpose of thins publication to describe the development of the electrostatic method of particle separation from the early beginning to the present resurgence of interest. Most of the information for this description bas been derived from references, a few of which were not available for thorough review. Much information has been drawn from the investitions of the Bureau. Acknowledgments Mr. O. C. Ralston, former Chief metallurgist of the Bureau of Mines, began the research program on the subject and did research on the mils literature. Both Mr. Ralston and Mr. H. B. Johnson, former president of the Huff Electrostatic Separator Co., furnished patent references. A critical review by Mr. F. D. Lamb, Research director, and Mr. M. J. Spendlove, Supervisory metallurgist, Bureau of Mines, College Park Metallurgy Research Center, lifts been of much value in preparing this report.

Jan 1, 1962