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By I. Gombköto

To sustain the growth of industrial production necessitates the increasing of the amount of processed mined raw and secondary materials. As a side effect of raw material production, the amount of tailings material, - coming from mineral processing operations ? increases as well. Using wet technology, these tailing materials are generally transported and stored with the water used for previous operations. This habit could lead to dangerous situations. Enough to remember the disasters had happened to the last decade, safe tailings operations need to remove as much water from the solid as possible. Environmental, technical and economical needs should meet, therefore using a technology combining these specific needs could be necessary. Paste technology was introduced generally into tailings operations at the last ten years, as an answer to the call of the above mentioned challenges, however there are still many questions to answer within the frame of using it. The Institute of Raw Materials Processing and Environmental Process Engineering of the University of Miskolc has been dealing with mechanical process engineering, especially by the support of the EU project TAILSAFE Contract nº EVG1-CT-2002-0066 and the NKFP 3A/068/2004 Hungarian fund extensive research has been carried out about paste technology. Different test methods and materials were applied. Tested tailings materials were as follows: different fly ashes from coal power plants from Pécs ? Hungary, Gyöngyös ? Hungary, Neyvil ? India, different Croatian ashes, hazardous waste incineration plant ashes from Dorog ? Hungary, different kind of sands from Hungary, fine glass sand from Fehérvárcsúrgó ? Hungary, flotation ore processing tailing from Gyöngyösoroszi ? Hungary. Different additives, as gypsum, bentonite and cement were tested as well. The applied test methods were as follows: physical material testing (laser sizer, piknometer, different microscopes), X-ray diffraction analysis, settling columns, the three measuring pipes tube viscometer (16~27 mm pipe diameter), a hydraulic test loop with different pumps (40~53 mm pipe diameter, 0.2~4 m/s average slurry velocity range, 0%~52 % volumetric concentration range), rotational viscometer, Cassagrande yield locus tester and the slump cone test. This paper summarizes and systematizes the results of the aforementioned research as well as reports about the developed paste pipe transport design method based on the fine suspension ? coarse mixture model. The paper also reports about a systematic experimental series with different materials to establish criteria when high concentration suspensions behave like paste.

Jan 1, 2014

By Imre Gombköto, Zoltán Pap, Ákos Debreczeni, Sándor Nagy

Eddy current separators have become generally used in waste recycling industry during the last decade. There are many papers dealing with separation processes on eddy current separators, and also many article describes particle trajectory and different particle features affecting particle trajectory. These data are used in modeling as well. Within the frame of R&D project called ‚Fundamental research into the exploitation of the economic development potentials of critical raw materials in international co-operation - CriticEl?, authors are aimed for using Eddy Current Separator (ECS) as a mechanical separation step of high value critical elements recovery of selected WEEE’s like display panels, PCB’s. ECS, equipped with 305 mm wide belt, and a concentric magnetic rotor is used for experiments targeted development of methodology for determining separability of different particles on ECS. The subject of our work was to investigate the behavior of model particles with different shape, conductivity (aluminum and copper), orientation and size in order to separate Al and Cu according to the results of many experiments were carried out in this field. However it looks like that throwing distance of one particle is only possible to describe by a certain distribution for even the same particle within the frame of the same conditions. Sample mean and standard deviation are depending on some of the particle feature and acting forces. The paper is going to draft the first results on the relationship between distribution of throwing distance and particle properties.

Jan 1, 2014

By Chao Li, Kym Runge, Saeed Farrokhpay, Dee Bradshaw

"It is well known that froth phase has a controlling influence on the overall flotation performance. Froth recovery is expected to be affected by froth transportation behaviour. The latter has been represented by different volume balance and energy balance based models. In froth transportation models based on a volume balance, the froth phase is divided into different zones. The total froth residence time is the sum of the time spent in each zone and is dependent on the cell geometry, bubble burst rate and the position that bubbles enter into the froth phase. Alternatively, the froth transportation model based on an energy balance treats the froth phase as a block. In this model, froth height above the concentrate lip is being predicted by minimising the energy of the system which is dependent on the froth geometry, froth stability and froth rheology. The froth height can be used to calculate the froth efficiency of delivering mineralized bubbles from the pulp to the concentrate lip. This paper critically analyses the current models of froth transportation in flotation, and examines the limitations of these models. The importance of froth rheology, which is the resistance to the froth flow towards the discharging weir, in determining froth transportation, is also highlighted."

Jan 1, 2014

By Z. C. Zhen

Basing on character of fine ores, and employing all the advantage of dissolved-air flotation, the study within the dissertation put forth the methods of superfine metal mineral flotation with dissolved-air flotation equipment, and constructed a full set of laboratory flotation system. Experiments both in water and in slurry were respectively carried out by means of this flotation equipment. Further study was also fulfilled on mechanism of air-dissolved released devices, and the key components of system including ejector, releaser and saturator were designed. Optimizing devices parameters were chosen by taking ideal performance of the devices into consideration, according to orthogonal experiments and tests on bubbles factors, those performance factors were called air release rate, air release efficiency. The results with some minerals are better than JJF flotation machine with 30 litres bulk. The Dissolved-air Flotation(DAF) machine shows great potentiality in treating super-fine metal mineral concentration. The research indicates the Dissolved-air Flotation(DAF) system has superiority over mechanical flotation machine in fine flotation. Air-dissolved released bubbles appear on the surface of hydrophobic minerals in priority, solving collision probability less in the tradition fine mineral separation, such that the metallurgy technology of fine metallic minerals are improved. The exploratory research is a foundation for industrial pilot, commercial test and equipment maturity in the future.

Jan 1, 2014

By M. Gonzalez Fernandez

"If the final goal of metallurgy is the extraction of metals from a given ore, everyone knows that this achievement relies on many separation steps involving much more than a biphasic material made of metal and gangue. Nevertheless, still today, most of the design and follow-up of industrial processes only consider metal grades; in best case metal grades per size class. Working with such heterogeneous material, made of several minerals, with different grain size and texture, implies to consider finer ore models to be able to predict the behavior of material and the subsequent operation performances. Analytical tools are now available to provide such relevant and accurate data which are applied in geometallurgy. To achieve a true geometallurgical approach for process design, but also for optimization, accurate process simulation absolutely needs to combine these fine ore models with the corresponding unit operation models. Based on generic, but configurable, criteria of description and a hierarchical approach, the material modelling tool embedded in the USIM PAC process simulator provides the necessary flexibility to describe any type of ore with almost no limit in the level of details and associated physical properties that can be met in the mining industry. The simulation engine and the mathematical models of unit operations are designed to manage such a diversity of material modelling. The paper present various ore models and some of their applications in flowsheet simulation. It proves the interest of this detailed and advanced approach to accurately predict plant performances. INTRODUCTION Process simulation used for process design and optimization requires accurate unit operation modeling. During the last decades, main efforts of the different teams developing software simulators have been dedicated to those models for comminution and physical separations such as flotation or gravity concentration (Kojovic et al., 2012, Soni and Yoon, 2014). In most case, the ore is modelled with a size distribution and metal or mineral grades. A water phase is considered for wet processes. The association of unit operations and such material models generally allows, after some parameters adjustment, to achieve good agreement between experimental and simulated data. The use of the obtained simulator to test alternative configuration of circuits or settings of equipment devices can be accurate enough as far as the ore processed is close to the ore used for simulator adjustment. However, when the ore gets very different grades, coming from different mineral proportions or grain sizes, the simulation results can be of poor accuracy. Because any physical separations such as gravity, magnetic or flotation, do not sort metal and gangue but particles, made of minerals, containing metals, the only way to be accurate enough for allowing extrapolations, is to model particles. The phase model tools embedded in the USIM PAC process simulator gives this possibility. However, as such level of details are not always available for analyses, the tool has been designed with a high level of flexibility, to adapt the model to the available data. In this paper, the principles of this conceptual modelling tool are presented, and some application cases illustrate the material model flexibility and its interest."

Jan 1, 2018

By E. Alldén Öberg

In 2004, LKAB decided to start a basic engineering study in expanding its existing production lines at the Malmberget mine site. It was expected that some of the production lines would become bottlenecks with reference to capacity. In this study, the sorting plant is examined and the results show that several unit operations will be limiting under current operating conditions. An additional purpose with the study was to investigate how replacement of some machines would influence performance and if production plans for the coming years might be achieved. Steady-state simulations using the software Modsim? were extensively used to study process performance for different operating conditions, such as iron content and size distribution in run-of-mine ore. Model parameters were derived from pilot plant data and when possible from ex-isting circuits. A complication for the simulations was the lack of relevant data and therefore some of the initial results were only indicative. The result shows that installation of new screens would give a much better operation, but also new crushers would be an improvement. This, since they can be run with full crusher chamber and tighter CSS. During 2007, most of the proposed remedies were implemented and the result is that the bottle-necks are gone, and the grades and material balances are even better than what was envisioned from the simulations.

Jan 1, 2014

As a kind of collector, Xanthates are generally used to make sulfide minerals hydrophobic in flotation process. Xanthate adsorption on a galena surface has been widely studied experimentally. In this paper, DFT methods were employed to investigate the local adsorption interactions about the collectors,such as ethyl xanthate (CH3CH2OCS2?, EO) and ethyl trithiocarbonate (CH3CH2SCS2?, ES), absorbing on two different PbS clusters. From the results, it can be easily found that, on the edge or at the apex, both collectors, with two S atoms bidentate coordinating on the clusters, have surprising interaction energies, while on the surface, its interaction is relatively weak in the form of monodentate ligand. NBO analysis results reveal that there is at least a covalence bond with sulfur atom about 10% and lead atom about 90% when the absorbed lead is on the lattice edge or at apex, but, if the absorbed lead is on the lattice surface, no covalence band would be found. Meanwhile, the S-Pb bond, formed by the absorbed Xanthate and galena lattice, seems to have much more covalence characteristic than that formed in the PbS lattice inner. Furthermore, those data also imply that the difference of the collecting effect between the EO and the ES may be not notable, because of the similar distance and the interaction energy for the same interaction mode.

Jan 1, 2014

By Kyle P. Flynn, Frank J. Hrach, James D. Bittner

ST Equipment & Technology, LLC (STET) has developed a processing system based on tribo-electrostatic belt separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. In contrast to other electrostatic separation processes that are typically limited to particles greater than 75µm in size, the triboelectric belt separator is ideally suited for separation of very fine (<1µm) to moderately coarse (300µm) particles with very high throughput. The high efficiency multi-stage separation through internal charging/recharging and recycle results in far superior separations that can be achieved with a conventional single-stage free-fall tribo-electrostatic separator. The triboelectric belt separator technology has been used to separate a wide range of materials including mixtures of glassy aluminosilicates/carbon, calcite/quartz, talc/magnesite, and barite/quartz. An economic comparison of using the tribo-electrostatic belt separation versus conventional flotation for barite / quartz separation illustrates the advantages of dry processing for minerals.

Jan 1, 2014

By Ljudmil S. Grigorov, Eric Forssberg, Hanumantha Rao Kota, Robert J. Pugh, Lidia B. Alexandrova

"We have used the microscopic thin balance developed by Scheludko at al. (1970) technique to study the stability and interactions within the thin film between the silica surface and air bubble with (i) a long chain C10 amine and (ii) a cationic/anionic surfactant systems consisting of mixtures of a long straight C10 chain amine with long straight chain C8, C10 and C12 sulfonates. It was found that the mixed surfactants caused lower contact angles, lower rates of the thin aqueous film rupture and longer film lifetime, compared to the pure amine system.This behavior was explained by the initial strong adsorption of positively charged interfacial complexes from the mixed surfactant system at the air/solution interface followed by adsorption at the silica interface. It was also shown that the chain length compatibility between the anionic and cationic surfactants controls the strength of the interfacial complex, determining an inhibition in the thin film rupture and dewetting of the film. The rupture mechanism was explained by an earlier established heterocoagulation mechanism between the positively charged air/solution interface and the solution/silica interface which remained negatively charged. The formation of the interfacial complex at the air/solution interface was confirmed by using surface tension data."

Jan 1, 2003

By Cuim R., M. L. Li

Fankou Lead-Zinc Mine produced pyrite concentrate (P.C.) from the zinc tailings by rougher and scavenger flotation before 2010, with the averaged S grade of 40.54% at recovery of 79.34% ( to the feed of S circuit). On the one hand, the economic value of P.C. increases with its purity, on the other hand, when the S grade of P.C. feed to sulfuric acid manufacturer is over 47%, the pyrite cinder can reach a high Fe grade of 62% which can be directly sold as iron concentrate. On this background, engineers in Fankou Mine set the P.C. with S grade of 47% as target. The direct way to reach that goal was to clean the rougher P.C.. Lots of cleaning flotation tests were conducted and the compromised strategy was to produce two ranks P.C. with the S grade of 47% and 38% at the recovery of 44.20% and 36.17%, respectively. The dual-product flowsheet was successfully industrialized in 2010. In order to further improve the quality of P.C., gravity separation was introduced into the flowsheet. The numerical simulation and separation tests were performed to evaluate the beneficiation and classification performance of hydrocyclone as it treated the rougher P.C.. It was shown that the underflow of hydrocyclone could addressed the S grade of 47%, and the finer size overflow could also be enriched to P.C. with S grade of 47% by flotation, due to the contained pyrite with well liberation. That is to say, with the ingenious addition of hydrocyclone to treat the rough P.C., single P.C. with S grade of 47% could be achieved. The new flotation-gravity separation flowsheet was commissioned to produce the high quality P.C. at the end of 2013. The averaged S grade is 47.20% at recovery of 82.26% in 2014. The two steps flowsheet improvement maximizes the enterprise benefits and leads to simple utilization of Fe in pyrite in downstream industry.

Jan 1, 2018

By A. P. Liu

Semi-industrial test on fine products of Meishan dressing plant was carried out with type RP80/25 high pressure roller mill produced by Homburg Corporation of Germany, and the influences of such factors as energy consumption, water containing, throughput and circulating load on rolling effect were investigated. Closed circuit experiment result showed that Meishan iron ore could be suitable for powder grinding with high pressure roller mill, and energy consumption of the operation was declined by 25%~30%, which was favorable for energy-saving, increasing production efficiency and improving grinding effects. According to above experimental results, this paper put forward the technical proposal of application of high pressure roller mill in Meishan, and pointed out some technical problems which needed to be settled urgently in technology disposal.

Jan 1, 2014

By U. S. Chattopadhyay

The estimated requirement of the nation by the year 2020 is approx. 80 Mt of steel and more than 0.2 million MW installed capacity of the electricity, thereby increasing the consumption of the coking and non-coking coal, which is expected to be in tune of about 75 Mt & 500 Mt respectively. One of the major deleterious factors in achieving the goal is the deteriorating quality of the feed coal used in both steel and power industries. Indian coking coals, in general, are typified by high ash, high inert (both organic and inorganic), low rank, low reactive macerals content, heterogeneous petrographic make-up, inferior coking properties and poor amenability to washing, thereby necessitating suitable washing measure. Coke-based steel industries in India require washed coking coal containing ash % varying between 17-19. The situation demands taking on immediate challenges to fill up the gap between the requirements and supply of coking coal. This paper reviews the R&D attempts in this laboratory and throws light on the key measures as long-term solution to the problem. Search for alternative source of coking coal, like LVC coal and their judicious preparation technology. The low volatile coking coal (LVCC) constitutes about 50% of the total coking coal reserves in India. These coals are characterized by high raw coal ash content (37 to 40%) and very difficult washability potential. If these coals are treated in the existing washeries, which are generally 2 or 3-product systems, the cost of clean coal is high as the byproduct sale value is low. It has been proposed to produce a new type of by product, which enjoys high demand and good coking properties.

Sep 1, 2012

By A. J. Ren

The ore, dealt with in this paper, is a certain rutile in Shanxi province, China. A trunk flowsheet with gravity concentration is used, and the TiO2 grade of rutile concentrate is about 90%, but the TiO2 recovery is less than 50%. In order to increase the rutile recovery, the laboratory test, using the truck flowsheet with flotation, is carried out. The flowsheet is that firstly floatable gangue is re-moved by flotation; secondly rutile is recovered by flotation; and thirdly impurity is separated by LIMS, HIMS, gravity concentration and flotation from the rutile concentrate. In rutile flotation, BK423, a phosphonic acid, is used as rutile collector, and Na2SiF6 is used as silicates depressant. The experimental result shows that the recovery of rutile concentrate is improved obviously, and the recovery of ultimate rutile concentrate is 68.01% TiO2 and 84.88% rutile. The TiO2 grade of first concentrate is 95.98%, and the TiO2 recovery is 45.60%. The TiO2 grade of second concentrate is 80.53%, and the recovery is 22.41%. Furthermore, magnetite and ilmenite are recovered in the flowsheet.

Jan 1, 2014

By R. Kobialka

In the article results of experiments over jaws? linings in jaw crushers with different shaping of working surface were presented. Following sets of jaws were under investigation: immobile plain jaw and moving jaw with grooving surface. Grooving jaws have groves with circular, triangular and trapezoid cross section. In order to evaluate efficiency of comminution both the grain composition of product and the content of irregular grains were determined, as well as the size of crushing forces and process efficiency were measured. For the combination: plain jaw with grooved one, a good results were obtained as regards the grain composition of product and the content of irregular grains. Crushing forces were higher at crushing with mixed types of jaws (the one plain, the second grooved), in comparison to crushing with using both grooved jaws. Efficiency of the process was definitely higher for mixed jaws.

Jan 1, 2014

By Yang Zhao, Tao Xiu-xiang, Chen Song-jiang

"China is rich in low-rank coals that account for 45.68% of existing coal reserves in China. The clean and efficient utilization of low rank coals is of great significance for ensuring the effective energy supply and promoting economic development and environmental protection. In order to solve the difficult problem in flotation of low rank coal, it has become the focus of research in the related field that oily bubbles instead of air bubbles are taken as a carrier in flotation to improve the attachment efficiency and recovery of low rank coal. In this paper, low rank coal slime collected from Shendong mining area was used as the experimental material, and it focused on the characteristics of oily-bubble flotation process of low rank coal. Additionally, difference in conventional flotation and oily-bubble flotation was discussed. The induction time between air bubbles, oily-bubbles and fine low rank coal particles was measured. The results indicated that the induction time between oily-bubbles and coal particles was obviously lower than that of air bubbles. By comparing the foam height of air and oily bubbles, it was found that the amount of oily bubbles is less than air bubbles, causing relative low flotation rate of oily-bubble flotation at initial stage. Besides, the maximum foam height and half-life of air bubbles and oily-bubbles were measured respectively. The results showed that the stability of oily-bubbles was higher than that of air bubbles, which is benefit for the enrichment of concentrates. The clean coal water recovery of oily-bubble flotation is lower than that of air bubble flotation, which indicated oily-bubble flotation is lower in water entrainment. INTRODUCTION China is the largest energy consumer in the world, accounting for 23% of global energy consumption in 2016 and 27% of global energy consumption growth. Whereas coal is taken as the major primary energy source and its share of China’s primary energy consumption is 62% in 2016, in which the low rank coals, such as lignite, long-flame coal, weakly caking coal, and non-caking coal, accounted for about 50% of total coal production capacity (China’s energy market in 2016, BP). Moreover, the exploitation and utilization of low rank coals and other coals that are difficult to float have been an important strategy for China’s sustainable development of the coal industry (Liu et al., 2014). However, the combustion of low-quality coals leads to a serious environmental pollution. In addition, the deterioration in geological conditions of coal resources, and the increasing improvement in the mechanization for mining significantly caused the increased amount of fine coal."

Jan 1, 2018

By H. Z. Liu

An extra-refractory gold ore in China belongs to Carlin Type Gold Ore which is not only submicroscopic but also rich in arsenic and organic carbon. They have been proved that its floatability is not good enough and the gold in the ore could not be leached almost if it was not pretreated. The tests for the ore were carried out in accordance with flotation-concentrate preoxidation-cyanidation(or CIL) processes in order to exploit the mine. Two new depressants were discovered in the flotation tests and improved concentrate grades from about 20g/t to 32~50g/t. The methods of the concentrate preoxidation tests were alkaline atmospheric oxidation, acidic atmospheric oxidation, acidic pressure oxidation, roasting oxidation?biooxidation. The cyanidation tests after the concentrate preoxidation have proved the gold extraction of the pressure oxidation to be the highest(92.5%) and that of roasting secondary(89.3%). After fuller techno-economic comparison, it is suggested that the flotation-pressure oxidation or roasting-CIL process should be the most optimal for treating the ore. The gold recoveries of the ore were 83% for the pressure oxidation and 80% for the roasting respectively.

Jan 1, 2014

By Dezhou Wei, Cong Han, Shuling Gao, Wengang Liu, Yanbai Shen

The recycling schemes of copper mineral to a copper raw ore produced in China is investigated in this paper, of which is aimed at copper concentrate‘s grade is over 26.00% and recovery is over 90.00%. The primary copper mineral the raw ore is chalcopyrite and the main gangue minerals are quartz, orthoclase, albite, clinochlore and phlogopite. There are four useful metal elements contained in the copper raw ore, which are Cu, Pb, Zn, Au and Ag, and the grade of each is 3.75%, 0.01%, 0.11%, 0.31 and 483.5 g/t. Two floating recycling schemes and its corresponding flotation reagent system were determined. The results show that calcium oxide, sodium carbonate and sodium sulphide were used as regulators, sodium n-butylxanthate was used as collector and terpenic oil was used as frother in two floating recycling schemes are effective. The open-circuit test’s results show that the copper mineral contained in raw ore can be effective collected, and both concentrates gotten through two schemes are up to grade.

Jan 1, 2014

By M. J. Lottering

Gold deposits in South Africa are invariably associated with uranium bearing minerals. Although it is low grade uranium by international standards, averaging around 0.3 kg U3O8 per ton of ore, recovery of uranium as a by-product improves the overall economics of gold extraction. Moreover, the current high uranium prices as well as increased demand due to renewed interest in nuclear power provide significant incentives for dedicated uranium production. An understanding of the uranium leaching response to changes in operating conditions is an important first step to-wards optimisation of uranium recoveries. In South African acid leaching plants, uranium dissolutions higher than 90% are difficult to achieve, and the chemical origin of this limit is not clear. To study leaching behaviour, an important consideration is the mineralogical characteristics of the ores. Typically, a diagnostic leaching approach can be followed. In this paper, a mineralogy-leachability explanation is presented to rationalise the difficulty in exceeding 90% dissolution from low grade uranium ores on the basis of a simple diagnostic leaching method. It was found that brannerite was the main reason for the existence of a dissolution limit in Witwatersrand ore and that chemical liberation was more effective to increase end dissolution compared to physical liberation. The findings from these investigations will form guidelines for developing economically viable flow sheets for improved uranium recovery, at least in a South African (Witwatersrand) context.

Jan 1, 2014

By Yang Xiao, Zhang Yimin, Bao Shenxu, Liu Chun

Stone coal is a unique vanadium-bearing resource in China. Many techniques, such as salt roasting-water leaching, blank roasting-acid leaching, direct acid leaching etc. have been developed for vanadium extraction from stone coal. The vanadium leaching rate can reach 74.9% for stone coal from Jiangxi, but only about 27% of vanadium is leached for Hubei ore by applying salt roasting-water leaching technique. This paper investigats the vanadium occurrence in stone coal by microscope observation and electron probe, and compares the minerals components of stone coal from Jiangxi and Hubei. Although most vanadium exist as an isomorphism by replacing Al(III) from dioctahedral structure in mica group minerals in stone coal from two regions, the free vanadium is remarkably abundant in Jiangxi stone coal than in Hubei stone coal, which results the fact that vandium is relatively readily extracted from former. Moreover, the content of calcite in Hubei stone coal is much higher than that in Jiangxi stone coal. Calcium can react with V2O5 to form water insoluble calcium vanadates during roasting and this may be the reasone why the water leaching rate of vanadium is low for Hubei ore. Acid leaching is more beneficial to the vanadium leaching but other extra methods, such as adding aid-leaching agent and/or increasing acid concentration is need for the ore where vanadium is embeded firmly. This study can effectively guide the selection of vanadium extraction techniques for stone coal from different regions.

Jan 1, 2014

By P. Gao, J. W. Yu

"Magnetizing roasting-magnetic separation is an important route for the beneficiation of refractory iron ores. In this investigation, a pilot-scale fluidized magnetizing roasting reactor was introduced and used to study the effects of roasting temperature and the flow rates of reducing gas CO and fluidizing gas N2, on the magnetizing roasting performance of an Anshan-type carbonate-bearing fine iron ore. The results showed that the hematite was almost reduced to magnetite by a gas mixture of 4 m3/h CO and 1 m3/h N2 at a roasting temperature of 540 °C. Under the optimized conditions, a high-grade magnetic concentrate assaying 66.1 wt.% Fe with a recovery rate of 91.2% was achieved from an Anshan-type carbonate-bearing fine iron ore assaying 42.0 wt.% Fe. The XRD, VSM, and optical microscopy analyses revealed that the siderite was successfully converted to magnetite by roasting. Some coarse hematite particles were difficult to reduce to magnetite completely; however, these generated magnetite particles with a fine hematite core could also be effectively recovered by magnetic separation after liberation from gangue minerals due to their strong magnetism. INTRODUCTION Magnetizing roasting followed by low-intensity magnetic separation has been considered as an effective solution, both technologically and economically, when upgrading refractory iron ores (Zhang et al., 2012; Peng et al., 2012; Li and Zhu, 2012). According to the type of roasting reactor, the magnetization roasting can be divided into shaft furnace roasting, rotary kiln roasting, and fluidized bed roasting (Zhu and Li, 2014).Shaft furnace magnetization roasting system is mainly composed of heating and reduction processes. The hematite ore is first heated to 700~800 °C in the heating zone, then falls into reduction zone where the weakly magnetic hematite is reduced to magnetite by coke oven gas at 550~600 °C (Yan et al., 2012). However, several years of engineering practices indicate that the shaft furnace can only process the hematite ores with a granularity of 15 ~75 mm, and the shaft furnace roasting is also characterized by heterogeneity of roasted product. Hence, the shaft furnace magnetization roasting technology is gradually replaced by high-gradient magnetic separation with the development of high-gradient magnetic separator. The rotary kiln generally handles the hematite ores with a grain size of less than 30 mm (Zhu and Li, 2014), however the formation of clinker ring in the rotary kiln will affect the yield of iron resource. In the fluidized bed furnace, the hematite ore is shaken up by an upward current of gas which maintains the individual particles in suspension (Yu et al., 2018). The precise adjustment of the gas velocity to the particle size and the specific weight of the hematite ore, make it possible to generate a floating mixture of gas and solids which behaves almost like a liquid (Yu et al., 2017a). The process is reported to have the following advantages over the other roasting techniques: ease of control due to absence of moving parts within the reactor, homogeneity of roasted products, ability to handle fine particles, and high efficiency of heat transfer and mass transfer (Li et al., 2015; Yu et al., 2017b). However, the simultaneous heating and reductive magnetization of hematite ore occur at the same place in the conventional fluidized bed reactor. Therefore, the reductive atmosphere, as well as the safety and stability of anti-explosion are hard to be controlled. Besides, the roasting temperature for conventional fluidized bed furnace is usually up to 950~1150 °C (Liu et al., 2017). Thus, the formation of clinker ring caused by high temperature will affect the operating efficiency."

Jan 1, 2018