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By S Lehane, S Pearce

The characterisation and assessment of waste rock has been the subject of considerable research, and many guidance documents have been published both internationally and within Australia. While these documents provide detailed information on how to characterise waste rock, there is not a great amount of detail on how to determine the optimal waste management options from an operational viewpoint. For example, typical questions that a mine operator would seek answers to include: What placement method should be used (eg end tipping versus paddock dumping)? What is an optimal tip head height for waste placement in a storage facility? How should sulfide grade control be carried out?Defining the contributing factors to waste management and waste material placement and assessing the contribution of each variable directs these assessments towards a semi-qualitative and quantitative methodology. Quantitative methodologies show an increase in the confidence of these assessments by providing logical, measureable assessments.As part of a strategic assessment for waste management at an active mine site, a detailed risk-based investigation of the influence of variables common to waste placement was completed. These variables included placement method, placement height, sulfur grade and material conditioning (eg compaction) on the associated risks of waste material storage. The assessed risks include temperature assessments (potential for thermal take-off as a result of spontaneous combustion), toxic gas production and flow and acid production potential. Applying a numerical modelling approach to the assessment of the different waste material placement strategies allows for the variation in risk to be graphically presented and communicated through risk matrices and histograms.CITATION:Pearce, S and Lehane, S, 2015. Quantitative risk assessment tools to assist with waste management and placement guidelines, in Proceedings Tailings and Mine Waste Management for the 21st Century, pp 353–364 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By T. T. Chen

Raw anode slimes consisting primarily of PbSO4, AgCuSe, Cu3Se2, Cu2-x Se, Cu2O, CuSO4.5H2O, Sn arsenate and Sb-Bi-As oxide are batch-leached with electrolyte-O2 to dissolve Cu. During this process, Cu2O and CuSO4.5H2O are solubilized and the Cu in the selenides is leached with the formation of Ag2Se and Se. A small amount of Cu remains in the Ag2Se, Sn arsenate and Sb-Bi-As oxide. The decopperized slimes are repulped in Na2CO3 solution to convert most of the PbSO4 to NaPb2(CO3)2(OH). The Sn arsenate and Sb-Bi-As oxide partly react, but the Ag2Se is not significantly affected by the Na2CO3 solution. The NaPb2(CO3)2(OH) intermediate phase is dissolved in acetic acid to leave a final product consisting of Ag2Se, Se, Sn arsenate and Sb-Bi-As oxide, together with small amounts of PbSO4, NaPb2(CO3)2(OH) and various gangue constituents.

Jan 1, 1993

By R. G. Bradburn

The events which led to computer control of the grinding circuit at Brenda Mines are described, beginning with mill operating philosophy. High production rates are encouraged so that, despite severe upstream disturbances, a manual control method to meet this philosophy had developed. Unfortunately, due to the time interval between manual control adjustments, losses in production resulted. An analog control method was devised and, although superior to manual control in some situations, was found to suffer from several practical limitations. The data logging capabilities of a control computer seemed warranted. Circuit test- work combined with an analysis of operating data showed that (1) metallurgical personnel, at times could increase production rates by as much as 10 percent over that achieved by grinding operators, (2) the chosen data base required an increase of 2 percent or more to be statistically significant and (3) for a 2 percent increase there would be a significant rate of return of investment in a computer installation, Consequently one grinding circuit was fully instrumented, and a rented control computer was installed by Brenda personnel. Prior to installation, Brenda metallurgical and instrumentation personnel were trained in the use of the computer. An experimental program was devised with short and long term objectives. The short term objective was to develop a practical control strategy which would yield immediate production improvement. This goal has been met as described in this paper. Statistically significant increases in excess of 2 percent have been established. Work is being completed for the permanent installation of computer control on all four grinding circuits at the present time. Long term objectives are (1) off line analysis of the circuit using mathematical models of process units, (2) on line experiments to study alternative contol tactics, and (3) possible expansion of computer facilities to the crushing plant.

Jan 1, 1976

By Leo Gentile, David Selhorst

The $528 million Toledo Waterways Initiative (TWI) was implemented by the City of Toledo in 2002 and completed in August 2020. Toledo is one of many US cities required to implement a Long-Term Control Plan (LTCP) but one of few to have completed its plan. TWI consists of three storage and conveyance tunnels, four below grade storage basins ranging from 4 to 36 million gallons (MG), miles of sewer separation and interceptor improvements, green infrastructure and other appurtenant structures to dramatically reduce combined sewer overflows to the Maumee River, Ottawa River and Swan Creek. All three rivers flow into Lake Erie. The City’s 180-year history as a Midwest shipping, manufacturing and transportation hub provided design engineers and contractors no shortage of unknown underground challenges to complete the projects. The City will begin its 5-year Post-Construction Compliance Monitoring in 2021 to satisfy the final LTCP requirement. A program overview and experience from tunnel and underground basin construction in urban areas with buried active and legacy infrastructure will be discussed.

Jun 13, 2021

By Michael S. Moats, Scott C. Campin, J. Brent Hiskey

"Electrochemical techniques are a valuable means of analyzing the passivation of commercial copper anodes. Electrochemical impedance spectroscopy (EIS) provides information concerning transport and reaction phenomena occurring at an electrode surface. Commercial. copper anodes of varying compositions have been examined using EIS. Experiments were conducted in a flat cell with an electrolyte of 40 gil Cu2 + and 160 gil H2S04 maintained at 65 DC. Impedance spectra were obtained at the potentials characteristic of the open circuit voltage and passive region for each anode. The spectra of the passivating films exhibited a flattened resistive/capacitive loop at middle to high frequencies and an inductive loop at low frequencies. An equivalent· circuit utilizing an inductor-resistor series in parallel with the double layer capacitance and charge transfer resistance was adequate in modeling the impedance data. The influence of anodes impurities on the components of the equivalent circuit is discussed and correlated with a hi-layer passivation model.IntroductionPassivation of copper anodes during industrial electrorefining has received considerable attention in the past few decades. Great strides have been made in understanding the roles of anode impurities [1-25], electrolysis parameters [20,26], and electrolyte chemistries [20,26]. Even so, passivation still occurs even in the most modem of refineries. The exact cause of passivation is not fully understood. It is known that the anode surface becomes covered by a passivating film. This film has been proposed to be CuS04'&5H20, Cu20, or mixed oxides. The localized concentrations of Ft, Cu+, and Cu2+ ions determines which phase is more favorable. The presence of these ions is controlled by the reaction kinetics and diffusion of species through the slimes layer.Reaction kinetics between Cu, Cu +, and Cu2+ are based on the dissolution mechanism of copper. There exists four different models to describe the dissolution of pure copper. The classical model of Mattsson and Bockris [27] involves two single electron transfers with the cuprous-cupric reaction being the rate detennining step. More recently, Wong, Collier, and MacFarlane [28] used ac impedance to elucidate a more complex mechanism involving the affect of pH and anions. Their findings indicate that the formation of cuprous ions in solution, Cu(I)so~ is favored over Cu(1I) ions adsorbed to the electrode surface in the presence of sulfate and as pH increases from pH 1 to pH 5."

Jan 1, 1997

By J B. Pateiro-Fernßndez, M Fuchsschwanz, G Deissmann, S Ahmad

Quang Ninh province is the most significant coal producing region in the north of Vietnam. The Nui Beo Coal Company (NBCC) operates open pit mines in Quang Ninh province and the waste overburden produced is dumped as sidehill fill in the Chinh Bac waste dump site. In the past, no special consideration has been given to the environmental impacts during the dumping operations. The mine waste is transported in trucks from the mine site to the dumping site and the loading, hauling and dumping operations are the main sources of dust emission. Rain events, especially during the rainy season, cause the generation of contaminated surface water as well as seepage of water through the dump at a number of locations. The existence of cracks at the top of the dump can pose serious stability problems with heavy rain events leading to failure of slopes which can potentially disturb vast areas of land currently used for agricultural purposes and human settlement. For sustainable development at the Chinh Bac waste dump site in the future, apart from the social and economic considerations to be assessed, there is an absolute necessity for environmental protection measures to be in place both during and after the dumping of the mine waste overburden. Research Association Mining and Environment in Vietnam (RAME) is working to develop and implement concepts for the mitigation of environmental problems emerging from dust, contaminated water and lacking slope stability to ensure successful rehabilitation of the coal mine waste dumps in the north of Vietnam. Within the framework of RAME, the Institute of Mining Engineering I (RWTH Aachen University) is managing and working to develop the stabilisation concepts for the solid mine waste dump in collaboration with the Chair of Geotechnical Engineering (RWTH Aachen University), Brenk Systemplanung and the Vietnamese group of companies VINACOMIN (Vietnam National Coal-Mineral Industries Group). The most economical and environmentally sound operations, as well as locally adaptable environmental protection measures, are essential for the sustainable development of the dumping operations at Chinh Bac dump. This paper describes the dump site and the sustainable development possibilities with an emphasis on the environmental protection and stability problems at the Chinh Bac waste dump.

Jan 1, 2009

By L. Bryson, J. H. W. M. Brits, K. Voogt

"The Anglo American Platinum’s Rustenburg Base Metals Refinery (RBMR) has the world’s first full deposit nickel plating tankhouse. Impurities in the nickel electrolyte can induce stresses in the electrowon nickel deposits that could lead to delamination of the deposit. Identifying the impurities that contribute to increasing internal stresses in the nickel deposit is key to successful operation and automation of the tankhouse. Impurities were introduced in the plant electrolyte and the effects on the full-scale nickel deposits evaluated. The impurity-adjusted electrolyte solutions were also analyzed using commercially available bench-scale methods to determine the induced stress. A correlation between impurity-induced deposit stress and full-scale delamination was developed. A direct correlation can now be made between feed quality, i.e. impurity concentrations, and degree of delamination in the plant. This methodology has the potential to rapidly predict the effect of new reagents, upstream process upset conditions and synergistic interactions between impurities on deposit stress and delamination of nickel deposits.INTRODUCTION Nickel electrowinning in sulphate media was first pioneered by Outokumpu in its Harjavalta refinery in 1960 (Saarinen and Seilo, 1985). The original process was very manual with starter sheets plated onto “acid resistant” steel for 36 hours and then manually stripped and cut into sheets which could be inserted into the main production cells for a further 4–5 days. The starter sheet stripping and manufacture process was later automated. The same technology was subsequently implemented on a number of plants around the world. Anglo American Platinum’s Base Metal Refinery (BMR) began nickel electrowinning in the early 1980’s. The recent expansion of Anglo American Platinum’s Base Metals Refinery necessitated the construction of a new nickel tankhouse to achieve two primary objectives. The first to increase the capacity to 32 400 tpa nickel and the second to reduce employee occupational exposure to nickel aerosols. The new tankhouse has been commissioned and is in the process of ramp-up; more details are given by Hagemann et al. (2016). Fundamental to lowering employee exposure to aerosols was automating both harvesting and final handling of cathode. In order to accomplish this a bold move was taken to plate up to 10 days on permanent titanium blanks which are harvested by automatic crane and automatically stripped. The original development work for the plating nickel on titanium blanks over a ten day cycle is given by Bryson et al. (2006)."

Jan 1, 2017

By David Burgess

The paper describes experiments at the Somerset Mine, Colorado, under a cooperative agreement between U.S. Steel and the U.S. Bureau of Mines. A test was made of the tube bundle method of mine air sampling which was developed for European longwall mines; some 300,000 running feet of tubing provided continuous monitoring at 39 locations. Carbon monoxide concentrations were obtained with standard deviations of less than 1 ppm and oxygen concentrations with standard deviations of less than 0.20 percent. A base level of CO index (ppm CO evolved/pct 02 removed)) was determined to be 0-20 through most of the passageways of the mine. However, in one working section where the coal was initially hot (about 180°F within a pillar) the CO index was demonstrably higher, >20 trending upward to about 60 when smoke appeared and the section was sealed. The data are discussed in terms of laboratory experiments on CO evolution from coals.

Jan 1, 1975

By S. V. Ulianov, A. Y. Senchenko, E. M. Kurchevskaya

"A process sample of old copper-containing tailings (-2.0+0 mm) from an iron-ore plant was tested in TOMS institute in order to develop a process for copper concentrate production. The study of tailings material composition indicated that -0.2+0 mm fraction was efficient and contained 97.26% of copper. Copper is predominantly concentrated in chalcopyrite which is present both in free form and in intergrowth with ore and rock-forming minerals. Study of chalcopyrite using an optical microscope and Qemscan SEM determined that the most grains surface was covered with oxide films. Additionally, a lot of grains had micropores on their surfaces that indicated a partial mineral leaching. The oxide films did not make it possible to float copper minerals from head material. It was recommended to apply an attrition operation to restore chalcopyrite floatability. In order to increase selectivity a regrinding stage for a primary copper concentrate was introduced to obtain P80 26 um. Taking these recommendations into account a flotation flowsheet was developed to process the old Cu-containing tailings. The flowsheet allowed us to obtain a concentrate with 23.5% Cu content at 71.5% recovery.INTRODUCTIONStudy of material composition is an important prerequisite for development of a minerals processing technology. Mineralogical study contributes to search for an efficient technology to recover valuables and for prospective methods of minerals processing.The use of such up-to-date analysis methods and equipment as Qemscan and Mineral-C7 allows one to determine minerals size, liberation degree, and mineral associations. Mineralogical data can reveal reasons for hard processing of minerals prior to development of the process.The advanced process mineralogical methods used to study Cu-bearing pond tailings indicated several factors that influenced development of the process. The first one is a barren size fraction which is to be removed from the process in order to considerably reduce the costs connected with grinding. The second is the presence of films on chalcopyrite surface; in this context, a preliminary attrition of the material was recommended. The third factor is finely disseminated Cu minerals in sulphide and in the rock, which predetermined selection of particle size for flotation. All these data led to significant decrease in time required to develop the process technology. The developed process flowsheet based on the obtained mineralogical data is present in Figure 1."

Jan 1, 2016

By P. Mundell, R. Torbin

"There are many physical and operational obstacles in pipelines that make the passage of inspection robots impossible including:•,Small radius bends•,Low operating pressure•,Plug valves•,Large changes in pipe size•,No permanent access to the pipeline.The inspection of unpiggable pipelines requires the marriage of a highly agile robotic platform with NDE sensor technology operating as an integrated system. Foster-Miller and GE/PII are developing a robot that is essentially a battery powered, train-like platform. Both front and rear tractors propel the train in either the downstream or upstream direction. Like a train, the platform includes additional ""cars"" to carry the required payloads. The cars are used for various purposes including the NDE sensor module(s), the power supply, and data acquisition/storage components. The robot is designed with a slender aspect ratio and the ability to change shape as required by the physical obstacle presenting itself. The MFL sensor module must also morph itself through the physical obstacles, and thus, will require some level of segmentation. The segmented MFL magnetizers and transformable sensor module represent a major advance in the science of sensor technology and pipeline inspection."

Jan 1, 2005

By Finlayson E, Hilyard D, Francis G

Papua New Guinea's mainland is dominated by a foreland thrust belt, which can be divided into two zones. The "body" zone is floored by Palaeozoic granites and metamorphics of the Fly Platform (Tasman Orogen). Underlying the "tail" zone is Papuan Plateau, rifted from the Tasman Orogen during Coral Sea spreading, and believed to underlie the Papuan Peninsula and Papuan Islands region (D'Entrecasteaux, Woodlark, Misima, Sudest, and Rossel Islands). Thrusting began in the Miocene and continues today in the crust below the "body" zone. The youngest known thrusted rocks in the "tail" zone are Pliocene in age. Recognition of foreland thrusting has major implications for petroleum prospectivity of the Papuan and North New Guinea Basins, mineral exploration prospectivity, and geological terrane identification in PNG.

Jan 1, 1987

By Liane J. Terrill

A 9O) ft (275 meter) section of a highly fractured beam of halite was mined from the roof of a supported thirteen year old drift at the Waste Isolation Pilot Plant (WIPP). The operation was conducted with a continuous miner and allowed the unique opportunity to collect spatial information on roof beam geology and to observe ground support conditions during the mining advance. Photographs and fracture maps of the mining face document the progress of the operation and the deteriorated condition of the strata. This case study details the drift's excavation and support sequences. the geomechanical response, and the conditions found in the exposed roof beam.

Jan 1, 1997

By Raffaella Granata, Daniele Vanni

"This paper presents the drilling and grouting program performed at two abandoned landfills located into former calcarenite rock quarries in Manfredonia, Italy. Tests performed after the abandonment of the landfills detected leachate infiltration into the groundwater, which required the implementation of a remedial program. In order to seal the rock fissures and create an impervious basin at the base of the two landfills, sub-horizontal boreholes were drilled and grouted into the rock under the waste deposits. At the same time, sub-vertical boreholes were drilled and grouted along the perimeter, to laterally confine the landfills. Finally, the landfills were properly capped with an HDPE membrane, geogrid, geotextile and topsoil. The methodology implemented to create a watertight barrier under the two landfills was innovative and cost-effective. Moreover, the drilling and grouting minimized the environmental impact of the remedial work, since the waste remained in their original location and were not affected by the remedial process.IntroductionThe two landfills, “Pariti-1 RSU” and “Conte di Troia”, are located approximately 6 km (4 miles) southwest of Manfredonia, a small town close to Foggia, Italy (Fig. 1). These landfills are located into two rock quarries, formerly used for the extraction of calcarenite (i.e., a weak calcareous sandstone, in tuff facies), and were abandoned in the early 90s. The two landfills cover a total area of about 45,000 m2 (11.2 acres), and mainly include urban solid waste with a depth of up to 25 m (82 ft). The main characteristics of the two waste landfills are listed in Table 1."

Jan 1, 2016

By Basil C. Maine

"Dado el aumento de la carga eléctrica y la escasez de agua encontrada en la mina Cerro de Pasco Corporation, se vio necesaria la reducción de consumo tanto para la empresa como para los que compran dicha energía, viéndose afectada las subestaciones que alimentan las siguientes propiedades de la C. de P.; la Mina de Goyllarisquizga, mina y concentradora de Cerro, mina y concentradora de Morococha, concentradorade Mahr Túnel, mina San Cristóbal, y mina y concentradora de Casapalca, así como las municipalidades de las mismas, entre otros. Por tal motivo, el objetivo del presente texto busca incrementar la capacidad de las plantas generadoras existentes a través de varios proyectos como la estimulación de lluvias, desviación del rio Colorado, el dragrado del canal de Upamayo, la elevación del lago Junín. Para el programa de refinamiento de zinc, se autorizó la construcción del proyecto hidroeléctrico de Paucartambo con una capacidad de 65 mil K, obteniéndose las siguientes características: la carretera de acceso, represa de desviación, la bocatoma, desarenador, cámara de carga, túnel principal, cámara de equilibrio, válvula de mariposa, funicular paralelo, casa de fuerza, tres turbinas de impulsión, generadores, subestación. Por último, se instaló el sistema de corriente de alta frecuencia que ayudará a las comunicaciones, telemediciones, control de relays de sobrecarga, así como permitirá que las subestaciones entre Carhuamayo y la Oroya controlen la energía usada en los distintos puntos centrales del sistema. "

Jul 20, 1956

By W. W. Agey

Under terms of cooperative agreements, the Federal Bureau of Mines Inter-mountain Experiment Station assisted the General Services Administration (GSA) in operating the manganese-ore purchasing depots at Deming. N. Mex., and Wenden, Ariz. A resident metallurgist stationed at the depots directed sampling of the ore lots for assaying, took samples for amenability testing, calculated acceptances for payments to shippers, and served as technical adviser to the depot manager. The Intermountain Experiment Station at Salt Lake City, Utah, tested the amenability of the ores to determine how much of the manganese could be recovered in concentrates assaying a minimum of 40 percent manganese (Mn) and containing a maximum of 16 percent iron (Fe), 15 percent silica (Si02) plus alumina (AI203), 0.3 percent phosphorus (P), and I percent copper (Cu) plus lead (Pb) plus zinc (Zn). All chemical analyses of the ores and test products were done at Salt Lake City. In all, 567 ore lots submitted to the Deming depot were tested by flotation to determine their amenability to concentration into specification-grade material; 421 lots were amenable, and 146 were unamenable, primarily because of high copper content or excessive silica or iron in the flotation concentrate. Chemical analyses totaling 42,700 were made on the ores submitted to the Deming depot and on the products of the amenability-test program.

Jan 1, 1959

By D Brett

The Paper presents the authors thoughts on how the mining industry should be improving the education of site personnel so they can provide a greater level of effective control of tailings dam safety including empowerment to develop their own documentation, monitoring and surveillance systems and to better liaise with specialist external technical staff or consultants.

Jul 1, 2021

By Oscar E. Harder

THE TERM "physical metallurgy' is used in the title of this lecture in preference to "metallography ?because the former has a broader meaning with most audiences, some people thinking of the latter as being limited to work with the microscope. This distinction, how- ever, has not been held by the out- standing workers in the field of metallography, such as the late Professor Sauveur. In the broadest sense metallography is essentially the same as physical metallurgy. The American Society for Testing Materials has adopted-the following definition: "Metallography is that branch of science which relates to the constitution and structure, and their relation to the properties of metals and alloys." This definition might be improved by adding after "properties" -"and their industrial and scientific uses." Metallography has also been defined as the science of metals and alloys. Physical metallurgy is to be distinguished from process metallurgy in that the latter relates particularly to the production of metals from the ores.

Jan 1, 1940

Some 15 years ago, Dr. Adolf Schmidt, director of the Magnetic Observatory in Potsdam, Germany, developed an instrument, which was a modification of Lloyds balance, for the measurement of the vertical component of the earth's magnetism in the field. There was a keen demand for this because (1) it was desirable to have a field instrument that would measure the component of the earth's magnetism which stands in the closest and simplest relation to the configuration of the subterranean magnetic formations-the vertical component; (2) it was desirable to have an instrument that was not only more sensitive but also more reliable than the existing vertical magnetometers (the dip needle, for instance). The application of the magnetometer in oil geology demanded such an instrument, because the magnetic disturbances produced by most types of magnetic formations associated with the occurrence of oil (salt domes, faults, anticlines with crystalline core, etc.) are too small to be detected with the ordinary dip needle. The writer can prove, by some investigations recently made for the U. S. Bureau of Mines, that these instruments may be used also to very great advantage in mining, because they are capable of measuring anomalies which are as great as twice the normal strength of the earth's magnetic field. Even for such anomalies, the field balance is more advantageous than the dip needle. First, the instrument rests on a firm support and can be adjusted in the proper azimuth, which insures measurement of the vertical intensity only, without a part of the horizontal intensity, which is very important for the interpretation. The readings give the vertical intensity in linear terms and not as a function of an angle; and the field balance is insensitive to temperature when used with scale values that are adequate for the determination of large anomalies. In another phase of mining, the gold placer work, the field balance has also shown excellent results for which the dip needle is not adequate. What has been said about the dip needle holds also, though to a lesser extent, for two other types of vertical variometers recently used, the Tiberg balance and the Thomson-Thalen magnetometer.

Jan 1, 1929

The Iron Prince orebody occurs within the Lower Middleback Jaspilite Horizon of the Middleback Group and consists of hematite within host rocks of jaspilites and schists. The ore was probably the product of leaching of silica from jaspilites and replacement by iron, concentrations occurring in suitable structural traps. The narrowness and the presence of extensive dolerite amphibolite dykes within the orebody make it essential to operate a grade control programme in advance of the faces. Information from drilling is drawn up on bench plans, step plans and impurity overlays, and these serve both in day to day production planning and in long term planning. Mining is done selectively by open-pit methods and blending conducted by keeping at least three faces of different grades of ore open at any one time. No stock piles of ore are kept for blending, but contact ore, contaminated ore and enriched material are dumped for later beneficiation.

Jan 1, 1971

By P. D. Frost, H. A. Robinson, J. R. Doig, M. W. Mote

The mechanism of hardening in heat-treatable zirconium alloys was foUNd to be analogous to that for titanium alloys. Zirconium containing a relatively large addition of a ß -stabilizing element such as molybdenum or columbium can be hardened by the following transformation: Lean alloys, having insufficient alloy content to retain ß at room temperature are hardened by the following transformation: Application of these findings in Zr-Mo-Sn and Zr-Nb-Sn alloys produced strengths as high as 190,000 psi with reasonable ductility. PRIOR research on zirconium alloys has been concerned with development of greater strengths and creep resistance by solid-solution hardening or by dispersion hardening. Although solution and aging heat treatments had been applied earlier to zirconium alloys, quenching frequently produced low ductility. The possibility that the ß-to-w transformation, discovered earlier in titanium alloys,' might also occur in zirconium alloys and cause low ductility was considered, and, indeed, was found as predicted2 to be the case. In the earliest experiments, the heat-treatment response of titanium, too, was disappointing. However, by avoiding the formation of the embrittling w phase, it became practical to obtain room-temperature strengths higher than 180,000 psi, with elongation values of 10 pct.3 Based on the present concept of titanium heat treatment, the principal requirement for a heat-treatable zirconium alloy is that it contains a certain minimum amount of one or more ß -stabilizing elements. Only molybdenum, columbium, and tantalum, when present in sufficient amounts, are known to stabilize ß zirconium to room temperature during rapid cooling from the ß field. Tantalum was undesirable because of its high thermal-neutron cross section. Aluminum and tin are effective a stabilizers, but aluminum has been shown to seriously decrease the corrosion resistance of simple zirconium alloys in hot water. Therefore, for the present study, tin was used as the stabilizer addition. The alloys selected for this evaluation are presented in Table 1 along with their analyses and ß-transus temperatures. The analyses indicated that intended compositions were usually realized. EXPERIMENTAL PROCEDURES All of the alloys were melted from sponge zirconium and fabricated to sheet for heat treatment

Jan 1, 1960