Search Documents

By Peter Claus

In the last years, supported gold catalysts with particle sizes smaller than 10 nm have attracted a lot of attention. While gold bulk metal is rather inert in chemical reactions and, thus, is of low interest for catalysis, highly dispersed gold particles supported on oxides as TiO2 or ZrO2 show surprisingly high activities in some reactions important for the chemical industry. The oxidation of carbon monoxide at low temperatures is mainly used as model reaction to study the unusual properties of gold catalysts [1]. On the other hand, to evaluate the catalytic potential of gold, other chemical reactions which allow to control also the selectivity have to be considered. The selective hydrogenation of ???-unsaturated aldehydes to allylic alcohols is of both commercial relevance (e.g. in fine chemical and pharmaceutical intermediate production) and specific scientific interest [2]. Note that thermodynamics favors hydrogenation of the C=C over the C=O group (stronger negative free reaction enthalpy of 35 kJ/mol), and for kinetic reasons the C=C bond is more reactive than the C=O group. Thus, in the presence of most of the conventional hydrogenation catalysts, based on Pt, Rh or Pd, -unsaturated aldehydes such as acrolein and crotonaldehyde are hydrogenated predominantly to the saturated aldehydes and only to a minor extent to unsaturated alcohols. Therefore, it is desirable to find catalysts which are able to control the intramolecular selectivity by hydrogenation preferentially the C=O group while keeping the olefinic double bond intact (Fig. 1).

Oct 1, 2003

By L. D. Smith

Net Present Value Impact of Discount Rate The Discounted Cash Flow (DCF) method of valuations is universally used and accepted. The main criticism of the method is that it does not recognize the value of projects long life projects. This can be seen in the preceding graph where the present value of cash flows in later years are small for discount rates over about 10%. This graph covers a project that has a 25 year operating life. It is clear from the low height of the NPV bars at 10% and 15% in the last years of the project that an additional 25 years would add almost no value to total project NPV. As an example of this effect, an colleague undertook the evaluation of a pulp and paper project. The plant could be justified, but it was not possible to justify planting the trees as they took too long to grow and so had not appreciable NPV. The plant had to purchase wood to feed the plant.

May 1, 2013

By Max J. Spendlove

The Federal Bureau of Mines has been a leader in resource recovery research since it was founded in 1910. Until the early 19601s, most of the projects were concerned primarily with the task of extending and improving conventional technology oriented to secondary metals and minerals upgrading and processing for marketable products of highest value. By the mid-1960's with the passage of the Solid Waste Disposal Act of 1965, all resource recovery research programs were increased in scope and intensity as an effort to solve the growing number of environmental problems and the rapid depletion of domestic energy and mineral resources. Many new materials were investigated including urban refuse, manufacturing, industrial wastes, and stockyard wastes. The objective was to promote maximum recycling as the most practical answer to problems of waste disposal, pollution control, and the short supply of minerals and energy. The new research projects ranged from the conversion of animal manure and other organics to oil, to the recovery of precious and common metals from demolished aircraft and electronic scrap. This profile includes brief descriptions of many selected research projects that typify, the total spectrum of Bureau of Mines research in the important field of resource recovery.

Jan 1, 1977

By Bertram Price

Libby, Montana is the site of a large vermiculite deposit that was mined between 1920 and 1990 to extract vermiculite for commercial applications such as insulation, gardening products, and construction materials. The Libby vermiculite deposit also contains amphibole minerals including tremolite, actinolite, richterite, and winchite. Historically, Libby mine workers experienced high exposures to amphibole structures, and, as a group, have experienced the health consequences of those occupational exposures. It has been suggested that Libby residents also have been and continue to be exposed to amphibole structures released during the vermiculite mining operations and therefore are at increased risk for disease. The Agency for Toxic Substance and Disease Registry (ATSDR) conducted two epidemiological-type studies of residents living in Libby and the surrounding areas to assess these risks. The Environmental Protection Agency (EPA) collected and analyzed exposure data in Libby and used those data to project risks of asbestos-associated disease for Libby residents. The EPA has placed the Libby Asbestos Site, which includes the mine and the town of Libby, on its National Priority List of hazardous waste sites in need of clean up. This article presents a review of the exposure studies conducted in Libby and an analysis of health risks based on the data collected in those studies. Libby mine workers have experienced elevated levels of asbestos-associated disease as a consequence of their occupational exposures to amphibole structures. Libby residents? exposures typically are substantially lower than mine workers? historical exposures, and the health risk projections for residents are, accordingly, substantially lower. © 2007 Published by Elsevier Inc. Keywords: Libby; Montana; Vermiculite; Amphibole minerals; Asbestos; Asbestos-associated disease

Jan 1, 2007

By Turcotte. Yves-Laurent

Notre conférencier, Monsieur Yves L. Turcotte, Vice-président et Directeur général chez Promaintech Novaxa est diplômé en génie industriel de l?Université du Québec à Trois-Rivières et détient une maîtrise en gestion de projets de l?Université du Québec à Montréal. Il est une véritable sommité canadienne dans le domaine de l?amélioration de la performance des organisations. Provenant d'entreprises manufacturières et de services, il possède plus de 20 ans d?expérience en tant que développeur de technologies, conseiller et formateur auprès d?entreprises. Il a à son actif la réalisation de mandats dans plus de 400 entreprises. Il est reconnu pour sa grande capacité d?analyse et pour trouver des solutions novatrices et profitables aux problèmes des organisations les plus complexes. Aujourd'hui, il dirige Promaintech Novaxa, une division de DMR, qui a célébré son dixième anniversaire en 2006. Cette organisation ayant des places d?affaires dans la région de Montréal, Québec et Vancouver compte plus de 50 professionnels et a une carte de visite dans 16 pays. Les axes d?intervention sont le Management, la Productivité, la Fiabilité, l?Innovation et l?Amélioration Continue.

Feb 1, 2008

By W. E. Falck, A. Usubiaga, J. Spangenberg, P. Schepelmann, S. Šolar, D. Wittmer, F. Blanchard

The extraction and processing of mineral resources may be accompanied by environmental impacts. In spite of technological advancements, the enormous increase in production volumes within the last decades has induced sizeable environmental impacts along the life-cycle of products. Beside environmental impacts, social issues associated with mining need to be considered to ensure the social acceptability of mining activities. The project EO-MINERS aims at deploying Earth Observation (EO) tools to inform best practices in mining and to thus assist the global mineral resources industries in their transition to sustainable development. In order to facilitate the handling of complex sets of information requirements from a wide variety of stakeholders, a set of indicators was developed that will inform the process of EO tool and services development. The project strives to enable stakeholders outside the industry to meaningfully participate in decision-finding processes on mining-related issues by developing and providing EO products and services that fit the information requirements. The project has identified a wide range of such information requirements by stakeholders that could be potentially provided by EO tools. The applicability of the EO tools on the local level is tested on three mining sites.

Jan 1, 2011

By Rafael C. Castro, Geoffrey Hughes, Fredrick (Rick) Vincent, Philip H. Albert

Seven pairs of drop and ventilation shafts, between two and nine feet in diameter, will convey combined sewer flow to a 230-foot-deep, 26-foot diameter storage tunnel. This paper will present case histories for each site. Discussion will include functional requirements, program and site access constraints, structural design, geology, the variety of excavation and lining construction methods used, and lessons learned. Noteworthy observations include the importance of assuring competent ground sup-port at the soil-bedrock interface and of achieving tight verticality tolerance using both top-down and raise bore excavation methods.

Jan 1, 2007

By J. S. Fox

"Pyroclastic rocks are useful guides to volcanic centers due to the tendency of their fragments to increase in size and volume toward the source vent. The felsic rocks of these centers can be the prime hosts of base metal deposits in the Precambrian Shield; their sub-volcanic equivalents are often the focus of porphyry copper mineralization in the Cordillera. Quantitative mapping of pyroclastic rocks has not yet developed into a routine prospecting tool in Canada, however, possibly due to the cumbersome nature of existing manual techniques and their limitation to structurally simple terrains.A rapid pyroclastic mapping method has been developed whereby the field geologist acquires only a down-plunge outcrop photograph, a record of the fragmental deformation ellipsoid and a record of some descriptive features from each station. Mean fragment size and volume percent are obtained later in the laboratory from a photo-enlargement: by means of a digital analyzer. A computer program uses the strain parameters to 'undeform' the field measurements and obtains genetic information from the descriptive data. Results can be superimposed on a geologic map, with values for each station being represented by a dot of a specified diameter corresponding to the size or volume percentile range to which the value belongs.Control traverses were run over the pyroclastic rocks surrounding the Anderson Lake mine and the Flin Flon South main shaft in northern Manitoba. In both locations, the mapping has delineated regular increasing trends in mean size and volume per cent toward the head frame."

Jan 1, 1977

By Michel Aubertin

Les digues de retenue de résidus miniers devraient être conçues de façon à supporter les charges les plus défavorables qui puissent être anticipées. Les nombreux incidents survenus au cours des dernières années à travers le monde montrent toutefois que la stabilité de ces ouvrages reste encore problématique. Les cas de rupture les plus courants sont reliés aux glissements le long des pentes, à la liquéfaction des rejets, au débordement des bassins, ainsi qu?à l'érosion régressive et de surface. Après avoir rappelé la nature et l?importance des certains incidents récents, l?origine de ces problèmes est brièvement présentée. On aborde ensuite le lien entre les critères à adopter pour la conception des ouvrages et les risques associés à leur rupture. De nouvelles avenues pour aider à contrôler certains problèmes sont enfin discutées, en mettant l?emphase sur la codisposition des roches stériles dans le parc à résidus miniers.

Nov 1, 2002

By J. Drelich, C. L. White, Ch. Zhou, W. M. Cross, E. T. Zellers, E. M. Nadorny

A laser-based particle deposition (LBPD) technique has recently been developed at Michigan Technological University for patterning mesostructures made of nanoparticles and their clusters. The LBPD technique makes use of laser induced optical forces to transport and pattern nanoparticles on a variety of conductive and non-conductive substrates from nanoparticle-in-liquid suspension. A weakly focused laser beam is used to confine and propel particles along the laser beam. Confinement is accomplished by forces due to optical field gradients that act on polarizable particles and tend to move them to axis of the laser beam. The force propelling the particles along the direction of the laser beam arise from momentum conservation of photons scattered from the particles. In this paper, this novel LBPD technology is briefly reviewed, and several examples of patterning are presented. The size and morphology of mesostrips produced from gold and polystyrene nanoparticles, under a range of deposition conditions, have been characterized by optical microscopy, atomic force microscopy, and scanning electron microscopy. The results presented here demonstrate that gold and polystyrene nanoparticles deposited by LBPD can form clusters of particles. When deposited at an appropriate rate, such clusters can form multilayer mesostrips of high particle density. One goal of research on such systems is to fabricate arrays of parallel lines made up of colloidal particles having a range of surface functionalities. Such arrays have potential for application as novel microsensors for environmental sensors.

Jan 1, 2003

By P Mesquita, A Nolan

Using a scientific-principled definition of global socio-ecological sustainability can be a useful basis for planning precious and base metal mining projects. The mining industry faces key challenges of; viability of the minerals industry; the control, use and management of land; national and local socio-economic development; environmental management; materials stewardship; and access to information. Using a framework for strategic sustainable development to assess the current reality of mine project development has resulted in identifying areas of strength and opportunities for improvement between current best practices and a desired vision of sustainability constrained by science based principles. These gaps indicate opportunities to strengthen current strategies, tools, and actions with a deeper understanding of socio-ecologic systems and a first-order, principled definition of sustainability, enabling success in moving towards achieving a sustainable society, ie sustainability. Evaluation of mine project development and their impacts on ecological and social systems using a systems perspective which recognises the underlying principles of operation, delays, feedback loops and response to change highlight specific opportunities to create value for social, economic and ecologic systems. Envisioning this future for mining projects within a sustainable society can be done by evaluating their development and operations guided by the sustainability principles. Performance indicators play a key role in measuring progress towards achieving sustainability goals yet it is necessary to consider whether indicators capture the whole systems perspective. Connected to this broader view, indicators can contribute much value to the mining industryÆs sustainability journey. This paper examines how current processes for mining projects can be developed using a whole systems perspective and measured using holistically designed performance indicators.

Jan 1, 2009

By Larry Rayburn

In the spring of 1999, construction commenced on the new Steelers Football Stadium in downtown Pittsburgh, Pennsylvania. Richard Goettle, Inc. (RGI) was the successful bidder to install the specified augercast piles for the foundation package. Description - Pittsburgh Steelers Stadium The new stadium will house the Pittsburgh Steelers Professional Football Team. It is widely believed that if a team is provided with a modern playing facility, that a winning season will ensue (Not always the case). The new stadium location is on the north side of Pittsburgh on the Ohio River, and just downstream of the confluence of the Monongahela and Allegheny Rivers. The site is west of existing Three Rivers Stadium. The Three Rivers Stadium was built during the late sixties and housed both the Pirates Baseball and Steelers Football Teams. The Public Auditorium Authority elected to replace this outdated stadium with two new stadiums, one for each professional team. The landmark stadium was imploded in February of 2001.

Jan 1, 2001

By M. D. Lackey

The "Art" of Big Hole Drilling has been in a continual state of evolution at the Nevada Test Site since the start of underground testing in 1961. Emplacement holes for nuclear devices are still being drilled by the rotary drilling process, but almost all the hardware and systems have undergone many changes during the intervening years. The current design of bits, cutters, and other big hole drilling hardware results from contributions of manufacturers and Test Site personnel. The dual string, air lift, reverse circulation system was developed at the Test Site. Necessity was really the Mother of this invention, but this circulation system is worthy of consideration under almost any condition. Drill rigs for Big Hole drilling are usually adaptations of large Oil Well drill rigs with minor modifications required to handle the big bits and drilling assemblies. Steel remains the favorite shaft lining material, but a lot of thought is being given to concrete linings, especially precast concrete.

Jan 1, 1983

By D C. McPhail, S L. Rogers, J Brugger

Using iron- and sulfur-oxidising bacteria to catalyse the breakdown of sulfides that host the gold is an important biological method for the pretreatment of refractory gold ores. Following this biological treatment a combination of chemical and physical methods are used for leaching (such as the cyanide process) and concentration (such as carbon-in-pulp or electrowinning) of gold. Although these methods are well accepted by industry, they harbour limitations in the processing of low-grade refractory ores, and regulatory agency/public acceptance of cyanide use. Thus, it is beneficial to industry to develop environmentally friendly, cost-efficient leaching and concentration techniques that are based on micro-organisms. This may soon be possible by adapting the results of recent regolith geoscience research, which has shown that micro- organisms are capable of driving a biogeochemical cycle of gold dispersion, transport and reconcentration in the supergene environment. The indigenous microbiota in biologically active soil microcosms from a number of Australian sites are capable of solubilising up to 80 wt per cent of the gold contained in these materials during 50 days of incubation. Studies using molecular microbial techniques have shown that a metallophilic bacterium, Ralstonia metallidurans, is present in biofilms on gold grains from a number of Australian sites. R metallidurans is capable of actively accumulating gold from solution, suggesting that the bacterium may contribute to the formation of secondary gold grains and nuggets. Identifying the biochemical and physiological pathways that lead to the dispersion and accumulation of gold in regolith, and quantifying the reaction kinetics of these processes may thus lead to the development of industrial bio-processing capacities for gold-containing ores.

Jan 1, 2007

By Lukasz Maciag, Ryszard Andrzej Kotlinski, Ryszard Krzysztof Borówka, Dominik Zawadzki

Concentration and composition of rare earth elements (REE) and major elements in the sediment samples from the IOM H11 Fe-Mn nodule deposit, eastern part of the Clarion-Clipperton nodule field (located between the Clarion-Clipperton Fracture Zone - CCFZ; tropical Pacific), have been studied. We show the controls on REE concentrations and described vertical/horizontal variability of selected metals in pelagic sediments from the CCFZ. According to Kato et al. (2011), who analyzed 2000 seafloor sediment samples at 78 sites of the Pacific Ocean, deep-sea mud shows high concentrations (2230 ppm maximum) of ?REY and could be potential resource of these elements in the future. However, our work does not fully confirm that sediments in the IOM H11 are significantly enriched in REE.

Sep 1, 2014

By D. R. Zuchelli

In order for MSHA to require the use of a noise control, the control must be proven ?technologically feasible?. Technologically feasible controls must reduce a miner?s noise overexposure to the permissible exposure level (PEL) or achieve at least a 3 dBA reduction in the miner?s noise exposure. The miner?s total noise exposure should be examined from an occupational viewpoint and not solely on a machine or equipment basis. This examination requires a field evaluation of the occupation as opposed to an equipment test conducted in a laboratory. The operator of a Hilti TE MD20 LS electro-pneumatic drill realized a full shift noise exposure (TWA8) reduction exceeding 8 dBA as compared to when operating a Gardner Denver S83F pneumatic jackleg drill while installing an equal number of drill holes into the Idaho Springs Gneiss rock formation. However, the Hilti drill?s penetration rate was only 27% of that of the jackleg drill. Although the Hilti drill was proven to be technologically feasible as a noise control, its slower penetration rate would require its economic feasibility to be evaluated on a case-by-case basis.

Jan 1, 2011

By R. E. Tremoureux

This paper describing the methods and costs of quarrying limestone at Sloan, Nev., is one of a series of similar papers being prepared for and published by the Bureau of Mines on this industry in the United States. These papers are designed to disseminate information regarding the methods used. The cost tabulations represent local operating expenditures only and not total production costs. It is recognized that publication of total production costs might in many instances cause embarrassment to individual producers as well as to the industry as a whole. On the other hand, operating costs are essential to the technical discussion and study of the methods Employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. The quarrying operations at Sloan are interesting not only from a technical viewpoint and because of the magnitude of the deposit, but also because the quarry is located in a desert region far removed from the centers of population where lime is used. The quarry and plant are in Clark County, Nev., 20 miles west of Las Vegas, which is the nearest town to the site of the Boulder Canyon Dam. Sloan is on the main line of the Union Pacific Railroad connecting Salt Lke City and Los Angeles. The latter city is 280 miles from Sloan and it is the shipping, point for all supplies.

Jan 1, 1932

By Bujtor G. J, McMahon D. W

This guide to the understanding of ore reserve estimation is the revised version of a report with a similar title circulated within the CRA Limited (CRA) group of companies in mid-1980. It is the principal result to date of an Ore Reserve Study commissioned by CRA in late 1977.This guide to the understanding of ore reserve estimationis the revised version of a report with a similar titlecirculated within the CRA Limited (CRA) group ofcompanies in mid-1980. It is the principal result to dateof an Ore Reserve Study commissioned by CRA in late1977.The study was prompted by two ore reserve situations.The Zinc Corporation and New Broken Hill Consolidated,Broken Hill, had reached the point of havingto find a replacement 'for their traditional ore reserveprocedure and Mary Kathleen had to admit publicly thatore reserve predictions would not be realized. Thesewere not however the only problems to be looked at. Asmentioned more fully later, other ore reserve situationswere known, or were met during the study, in copper,gold and nickel as well, where poor realization: expectationratios had ranged from embarrassing to disastrous.These made it clear that ore reserve estimation had to belooked at afresh.The fresh look has resulted in a broadening of theconcept of ore reserve estimation from its traditionalpurely computational basis to an approach embracingall the many things that can affect expectation andrealization as essential factors. Hence this guiderepresents a gathering together of what has been learnedand what should be known to all those concerned withore reserves in any of its diverse aspects.The study has been marked"by a number of changesof thinking. At first the aspects that appeared to requireattention were two; recognition that an ore reserve statementwas an estimate, not a precise calculation; and asearch for im improved estimation procedure adapted tolow grade ores with narrow economic margins. Threeyears later the view was that the need was to incorporateinto ore reserve estimation all relevant aspects of theproposed mining operation from choice of a samplingmethod to sales contract specifications.This study is thought to be unique in being frankabout weaknesses in ore reserve estimation and intreating failures not as natural disasters (like drought orflood, which have to be endured) but as potentiallyavoidable. It has led to three principal conclusions.

Jan 1, 1982

By Yves Bellemare

Entre 1983 et 1997, l'exploitation de la pierre de taille au Québec a été marquée par l'émergence et la consolidation de plusieurs nouvelles variétés de granit, provenant exclusivement ou presque de la Province de Grenville. Le Québec demeure toujours le principal expéditeur canadien de granit dimensionnel, avec des expéditions annuelles représentant près de quatre-vingt-dix pour cent des expéditions totales canadiennes de granit brut et transformé. La production annuelle de granit brut oscille, depuis 1994, autour de cent mille tonnes métriques. Cette production a plus que doublé de 63 000 à 140 000 tonnes métriques entre 1981 et 1990, mais elle a connu une chute importante en 1991 (67 000 tonnes métriques); cependant depuis 1994, elle est en forte progression (Ménard, 1998). En 1983, le granit dimensionnel était extrait de plus de vingt-cinq carrières, dont les trois quarts se localisaient dans la Province géologique de Grenville. Comparativement, en 1997, le Québec comptait trente-sept carrières actives, dont trente-cinq dans le Grenville (Gaudreau et al., 1998). Cette concentration des carrières dans la Province de Grenville s'explique par la demande accrue de nouveaux produits au fil des ans et par le potentiel élevé de découvertes de nouvelles variétés dans cette Province géologique. L'accessibilité au territoire, toujours plus grande, a facilité la mise en production de carrières favorisant la diversification des produits. Le ministère des Ressources naturelles du Québec (MRNQ) a consacré depuis 1980, beaucoup d'efforts dans la recherche de nouveaux gisements et de nouvelles variétés. En plus des programmes de subvention destinés aux prospecteurs ou aux compagnies, le ministère a réalisé des campagnes d'inventaire de pierre de taille, de pierre concassée et de pierre d'enrochement pour en connaître le potentiel géologique et à orienter les recherches futures (Nantel, 1983; Nantel et Martignole, 1991; Bellemare, 1995a, b, c, d, e, f, 1997, 1998a and b; Bellemare et Petryk, 1996a, b, c and d). Cette étude donne un aperçu des différentes variétés de pierres extraites dans la Province de Grenville entre 1983 et 1997, les situe dans leur contexte géologique et en localise les principales régions productrices. Elle est une suite à l'article publiée par Nantel (1984).

Jan 1, 2001

By Greg Barnes

Agenda ? The Mining Stock Life Cycle ? Current Environment ? Valuation ? Golds ? Valuation ? Base Metals ? Case Study ? Quebrada Blanca Hypogene Commodity Investment Cycle ? Macro-Economic Indicators ? LME Inventories ? watch the trend; rising inventories ? bad for prices, declining inventories good for prices ? OECD Leading Indicators ? PMIs ? Purchasing Manager Indices ? Industrial Production ? more important for metals consumption than GDP ? Housing Starts ? US, Europe ? Auto Sales ? All things China ? metal imports/exports; SHFE inventories; SRB stockpiling ? Seasonality ? it does play a role ? What is Chris Dutton (TDSI Quantitative Analyst) saying?

May 1, 2010