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By John B. Goddard

In-situ leaching of uranium by aqueous ammonium carbonate containing oxygen or hydrogen peroxide as oxidant results in the partial dissolution of sulfides. While some of the sulfide sulfur is oxidized to sulfate, a considerable portion is oxidized only to thiosulfate and polythionates. Polythionates poison the anion exchange resin used to extract uranium. At the Palangana operation in southeast Texas, the trithionate ion (S3062-) was found by infrared spectrometry to be the major resin poison. Treatment of ion exchange feed solutions with hydrogen peroxide only resulted in partial conversion of reduced sulfur species to sulfate, and trithionate conversion was particularly slow. Poisoning of the resin also occurred from the ammonium chloride eluant, which built up trithionate because of recycling. This was essentially eliminated by chlorinating the eluant prior to yellow cake precipitation.

Jan 1, 1984

By Gerald Stolarczyk

The Radio Imaging Method (RIM) is based upon electromagnetic (EM) wave propagation in the coal seam waveguide. The radio geophysics theory underlying RIM was developed by Hill of the national Institute for Science and Technology (Hill, 1984). Recent advances in radio geophysics instrumentation have increased operating range in the coal seam waveguide to almost 3,000 feet. This paper describes RIM longwall panel reconnaissance scans and tomography results.

Jan 1, 2006

By G. P. Halliwell, C. R. Austin

The investigation described in this paper deals with the development of high-temperature alloys of the Konel series over a considerable period of time at t,he Research Laboratories of the Westinghouse Electric and Manufacturing Co. The word ''Konel" has been coined to designate a class of alloys which are essentially nickel-cobalt-iron with other elements added, usually in small quantities. Most of these alloys contain titanium, usually about 2.5 per cent. The main consideration related to strength at high temperatures but the thermionic characteristics of the alloys was also of considerable importance. It is, however, with the mechanical properties at elevated temperatures that we are herein concerned. Much attention has also been devoted to their age-hardening characteristics. There is little need to stress the utilitarian aspect of this subject, as it has been discussed frequently. Alloys exhibiting superior properties at normal or elevated temperatures rapidly find many suitable applications. There may be some question, however, as to what constitutes a "superior alloy," or an alloy that may have good service possibilities at high temperatures. The problem is complex and various means have been employed to predict the useful life that may be expected of a material. In recent years the "creep limitJ' has been used as the best means of evaluation. Such tests necessarily are prolonged and hence collection of data is very slow. In a general survey of many alloys therefore the creep test is not desirable and recourse must be had to much shorter time tests in order more rapidly to select alloys which appear to show promise. For this reason the present survey has been made using the high-temperature tensile test and a bend test developed by Howard Scott.' In the tensile test the conditions have been standardized for all tests, so that values obtained are at least comparable, one alloy with another, although the absolute values recorded merely indicate the mechanical properties at the given temperature under a definite rate of loading.

Jan 1, 1932

By F. A. Camisani-Calzolari

The latter half of the 20th century has seen the proliferation of a series of codes to address commodity needs which were brought about by rapidly advancing technologies and the globalization of markets and consumerism. This paper addresses the specific needs and the origin of this surge and presents these codes in the context they were developed. It also compares the main codes or groups of codes and elaborates upon their strengths and weaknesses. Three main categories of codes are identified, namely: codes for reporting to international agencies, codes addressing government needs and, finally, codes for the investors and the stock market. Codes governed by international agencies usually relate to strategic commodities which have highly specialized fields of usage like nuclear power generation where international cooperation is eventually the only viable approach for both the development of technologies and their applications. Codes for reporting to governments address the necessity of each state to exploit their mineral potential profitably and to secure the preservation of wealth for future generations. Reporting to investors is experiencing a considerable popularity as of late because of globalization in mining and the growing need for outside financing of mining projects, whose capital requirements are getting out of reach for the average mid-cap mining company. All these codes have advantages and shortcomings dictated by the specific circumstances under which they were developed, therefore necessitating the definition and implementation of some kind of international standard whereby investments and the spread of information across political boundaries would be facilitated. Though none of these codes might ever become international in the true sense of the word because of significantly different legislations at national level, a step that would greatly contribute to the cross-border disclosure of information would be the reciprocal recognition of competent persons by the major mining countries, including China and Russia. It is also becoming essential that financial institutions and investors be properly advised on mining projects by reporting reserves and resources in a transparent and responsible way with the relevant public disclosures being compiled by professionals who take full responsibility for their submissions. Keywords: reporting codes, mineral resources, mineral reserves, competent person, UN Framework Classification, IAEA classification, JORC Code, SAMREC Code and CRIRSCO.

Jan 1, 2003

By experience we know about the natural event of ocean-tides. In geophysics we say that the earth-tides phenomenon is the elastico-viscous response of the earth's body to the attraction potential of moon and sun. By the fact that the tides on the planet take place in a regular periodic frequency, due to the earth rotation of 24 houres for one cycle, the rotation of the moon in about 28 days around the earth and finally to the rotation of the earth-moon combination around the sun in 365 days this phenomenon is a very important one in geophysics. The exact calculation of the acting forces is possible and the comparison of the earth's body response to these forces as well.

Jan 1, 1987

By J. W. Sterner

The Bureau of Mines conducted studies on four makes of Japanese automobiles, three 1981 and one 1982 model years, received from three manufacturers to determine if their materials composition would present problems to the current technology used to process junk automobiles for metal recovery. One of each make of automobile was hand-dismantled to determine the materials composition. In addition, two nearly identical automobiles of each make were shredded at a commercial operation where all metal products and rejects were collected for analysis to determine metal and nonmetal distribution. The average weight of the four automobiles to be dismantled, less batteries, tools, and fluids, was 1,938.3 lb. The weight was distributed as 1,472.9 lb. ferrous and 115.6 lb nonferrous metals, 275.2 lb combustibles, 72.3 lb noncombustibles, and 2.3 lb electrical components. The dismantled automobiles, less gas tanks, fluids, tools, wheels, tires, and batteries, which were all removed from the automobiles that were shredded, contained an average of 1,389.1 lb ferrous and 101.6 lb nonferrous metals, 305.7 lb nonmetals, and 2.3 lb electrical components. In comparison, materials collected from the shredded automobiles averaged 1,304 lb ferrous metals, 80 lb nonferrous metals, and 341 lb landfill materials. There were no materials used in the manufacture of the late model Japanese automobiles that should present handling or processing problems to the steelmaking or secondary metal recyclers.

Jan 1, 1984

[nder ' 1Oclific?atic>n 1 l', of Cant r Ict No. S012?U7 , the T1. S. l urc ,:i.11 of Miries ontracted tivit.l '1 -l:eudurn? Barry t1rirl ,~:>:'nci.11c:, for the 1>crfcocrnancu of a afet, Analynin Q::tc n Study to develop a plan for thc organiration nrld opera¬ion of a 'Lur('an ,`,afutj i ily ;i Cn11tur, r Before the con)y)lctic>n of the stucly, the Abiretu.l ustaldish d such a center, the WniL1, and Safety i?'\naly:-.in Cnmtor (l1S;'J:), under the dirucHan of fly, Assistant Director of JTc'"?ltl) 11111 .itut~ 1O1- 'l (.. -11: 'C'a) :_'-, ?'( )'t. 11. ~.C is 11 c' iC1cnlC:rtc:rr'd at the 1)crnv(jr Federal Center, 1)u:r',L C,r_i1f,U, rK.]

Jan 1, 1972

By Stanislaus Skowronski

OVERPOLED copper, as commonly defined, is copper which has been excessively reduced during the poling period of the refining process. Owing to its porosity, such copper is unfit for commercial purposes. The cause of this phenomenon is undoubtedly the lack of oxides in the copper, yet this does not completely explain it. Refined copper of the same "pitch" and "set" varies considerably in oxygen contents, and analyses of overpoled bars also show similar wide differences; moreover, it is possible to melt copper in crucibles so as to obtain bars that are practically free from oxygen although they show a "tough pitch" and "level set" surface. Frederick Johnson advances the following theory: The regulation of the quantity of oxygen in copper is the keynote of all copper refining. It is the presence of a Well defined proportion of oxygen in the form of cuprous oxide, forming a copper-cuprous oxide eutectic, Which enables copper to be cast free from blowholes. It seems that When oxygen is present, other gases are less soluble in molten copper; When oxygen is absent, or is present in insufficient quantity, the copper dissolves other gases, such as hydrogen and carbon monoxide, Which are insoluble in the copper when solid, and, being rejected during the process of solidification, causes internal porosity and external ridges and excrescences.1 The "level set" of Wire bars, etc., is entirely the result of a compromise between the occluded gases and cuprous oxide. With excess of the former the metal would be "overpitch" and spongy, While an excess of the latter would result in the metal being "underpitch" and brittle.2 The result of the absorption and subsequent expulsion of reducing gases, carbon monoxide and hydrogen, and the effect of this action. on the overpoling of copper are in dispute; the literature on the subject is full of contradictory statements and will continue to be so until better analytical methods have been developed. Sulphur, however, is tangible. The refiner can see it in his button sample and consequently attributes to it any trouble that may happen during the melting of the copper.

Jan 3, 1918

By Inn-Joon Park

Major problems associated predicting soil-structure interaction behavior are based on the fact that soil is neither homogeneous nor elastic and soil properties are spatially variable. There also exist significant coupling problems between the behavior of the structure and geologic media. When designing foundation or other geotechnical structures, the load transfer between the soil and structure takes place at the contact surface. This surface is called the interface. The behaviors of interface play an important role in the load-deformation response of soil-structure interaction systems. The purpose of this study is to develop improved model for simulation of saturated sand-steel pile interface behavior based on a general concept, called the disturbed state concept (DSC), which can characterize the behavior of saturated soils under dynamic loads. In this study, the Disturbed State Concept (DSC) constitutive model is calibrated and modified for steel pile-saturated sand interface and interaction by using the continuous hardening model for relative intact (Rl) state and the critical state model for the fully adjusted (FA) part in the saturated sand material. The general formulation for implementation has been developed. Then, the DSC model with modification for interface and saturated sand is implemented in finite element program based on the generalized Biot's theory. The interface tests under one-way monotonic and two-way cyclic loading and cyclic triaxial tests are executed for defining the parameters for interface and surrounding soils. Based on these parameters, steel pile-saturated sand interface and interaction are numerically simulated using the finite element program modified in this study. The DSC predictions show improved agreement with the observed results from laboratory test.

Jan 1, 2002

By Jiulong Cheng

Underground coal mining causes overburden deformation and failure, one major form of which is bed separation in the overburden. Surface subsidence can be controlled by injecting grout into the bed separations. For a long time, the grouting results of bed separation can not be validated. This is the problem in the application of this technique. This paper analyzes the conditions leading to bed separation, develops mathematical models for seismic wave fields generated before and after bed separation, and bed separations grouted with different materials, and computes the seismic wave field characteristics using the finite difference method. The results show that the existence of bed separation causes changes in the characteristics of seismic wave field, and that different grouting materials generate different seismic wave field characteristics. Intact strata, bed separation, and bed separation filled with air or water all display distinctive seismic wave field in amplitude and frequency spectra. After mining, the original location that provides strong seismic reflection wave no long exists. It is replaced by a weak and syncline-shaped reflection wave. The area, where the seam wave disappears, is larger than that of the mined area. The location, where a bed separation occurs, generates a set of reflection waves stronger than the normal one. The energy of the reflection waves varies with the materials filling the separations. Bed separations filled with air generate stronger reflection waves than those filled with water. The major frequencies for those filled with air are lower than those filled with water. Therefore, it is possible to determine the property of filling materials by analyzing and comparing the amplitude and frequency spectra of the reflection waves. Case studies of application of seismic method for exploring bed separations and grouting were analyzed. The results show that it is feasible to use seismic technique for exploring bed separations and grouting.

Jan 1, 2006

By J. Z. Cui

In this paper a statistical multi-scale method for the mechanics parameter prediction of the rock mass with random distribution of multi-scale cracks/joints is presented. First the micro-structure of the rock mass with random distribution of multi-scale cracks/joints is represented. Then the statistical second-order two-scale method for the mechanics performance predictions of the rock mass structure with random cracks/joints distribution is presented, including the statistical second-order two-scale expression on the vector-valued displacement, strain tensor and stress tensor, and the algorithm procedure of statistical multi-sale computation for the mechanics parameters. Finally some numerical results for mechanical parameters for the rock mass with random distributions of multi-scale joints/cracks by statistical multi-scale method are shown.

May 1, 2009

By J. A. Kost

The objective of Contract J0295041 was to determine if the addition of a surfactant (wetting agent) to the water used for dust control in underground coal mines results in the reduction of airborne dust. Laboratory wettability tests, including the capillary rise test, a coal dust sinking test and zeta potential measurements, were used to select a coal seam/surfactant combination for in-mine testing. Four surfactants were selected for underground testing: Surfynol 465, Aerosol MA-80, DC-13, and Dustallay. The underground tests in the Lower Kittanning seam, Indiana County, PA, involved a Wilcox Mark 20 auger mining system, equipped with spray nozzles located on the cutting augers, Conflow venturi sprays, and a spray manifold. Respirable dust samples were provided by MSA Model G personal samplers and Simslin II instantaneous dust monitor; total airborne dust samples were provided by MSA Model G samplers with UNICO filter cassettes. Based on data obtained from 24 test periods surfactants, as compared to plain water, reduced the airborne respirable dust an average of 27 percent and total airborne dust an average of 36 percent.

Jan 1, 1980

Surface Plasmon Resonance (SPR) spectroscopy, combined with cyclovoltammetry, has been successfully used to study the interactions between ethyl xanthate, heptyl xanthate, dithio-phosphate and propyl trithiocarbonate flotation collectors and a gold surface. Large, easily measurable responses have been obtained in the potential areas where the thiol collectors are known to interact with gold. The four collector types lead to differing SPR maximum values, with longer alkyl chains resulting in higher SPR responses, and the trithiocarbonate leading to the highest response values. The SPR responses differ considerably from the current density response at very anodic and cathodic potentials. There are indications that thiols might still be adsorbed at potentials as low as-300 mV (vs SHE). Keywords: flotation collectors; thiol collectors; cyclovoltammetry; surface plasmon resonance spectroscopy.

Jan 1, 2005

By S. Eck

In previous work the influence of the casting speed on the flow field and the shape of the solidification front in an industrial 0.82 x 0.25 x 0.8 m³ bronze caster had been investigated. Both numerical and experimental model represented 1:1 the real caster geometry. A comparison of the results of both numerical and experimental models for the flow during the casting process showed a good agreement in the qualitative velocity fields (flow direction and vortex formation). This work represents a parameter study of the numerical model with variations of the turbulence conditions at the inlet in order to clarify their influence on the flow field in the caster. In order to find the best boundary condition at the inlet, the numerical calculations for water have been compared with the measured flow fields in the water model. The new boundary conditions were then applied to the numerical model of the bronze casting process.

Jan 1, 2009

By P. He

Abstract This paper introduces tested results of rock-socketed pile in Nanjing, Wuhan and Chongqing. From a force- transfer model, a distribution of axial force for pile-body and inlaid resistance for rock-socketed pile was deduced. Comparing the results of test and calculation, it shows that the calculation result coincide with the test result. Keywords rock-socketed pile, load transfer, inlaid resistance, end resistance. Zusammenfassung: dieser text legt eine kuyze Einfuehyung ueber die Erfolge wissenschaftlicher Forschungsarbeit in bezug auf die Grundprinzipien der Mechanik von Belastungsuebermittlung der Einlegesteinpfeilers der Durch Benutzung von Ausgleich/Balance der inneren Kraft und Deformationskoordinierung wird das mechanische Modell der Belastungsuebermittlung des Einlegesteinpfeilers aufgestellt. Vom lebendigen Beispiel wird dia Wellenkraft des Steinpfeilera und die Verteilungskurve Einlegebfestigungskraft ausgelegt, man hat diess bereits mit der tatsaechlichen genessenen Kurve verglichen. Schluesselwoerter: Einlegesteinpfeilers, Belastungsuebermittlung, Einlegebfestigungskraft, Seitenwiderstand. Résumé - Le présent article décrit de façon succincte des résultats de la recherche sur le mécanisme du transfert de chargement du pieu d’ancrage au massif. Une modèle dynamique du transfert de chargement du pieu d’ancrage au massif est ainsi établie avec l’application des conditions de l’équilibre de contraintes internes et de coordination de la déformation. L’expérimentation sur des exemples réels a permis de mettre à jour des courbes de distribution de la force axiale du corps du pieu et de la force d’ancrage avec comparaison aux courbes effectivement mesurées in situ. Mots clés - Pieu d’ancrage au massif, Transfert de chargement, Force d’ancrage, Résistance à la pointe

Jan 1, 2003

By R. E. Wilmot

This paper is based on the experiences, over many years, of numerous authors in the South African mining industry and of the hot dip galvanizing process and its application as a corrosion protection system. The paper sets out the extensive development, financial resources and stringent operating requirements of the South African mining industry. After many years of research and operational experiences, hot dip galvanizing and, when necessary, duplex systems, have been found to meet the demanding requirements of this particular industry. The paper sets out the requirements from the standpoint of corrosion criteria and is followed with a case where the corrosion protection properties of hot dip galvanizing are demonstrated. This case history traces the early investigation of the expected corrosive conditions in a new mining operation and concludes with two follow-up visits to the mine in order to examine actual performance of the corrosion protection system after ten years in service.

Jan 1, 2007

By K. Leutwyler

The key to realistic casing stress analysis in thermal recovery installations is accurate knowledge of the temperatures involved. Much information leading to prediction of heat losses from tubing string to wellbore has been published. This .same information permits calculation of casing temperature under certain conditions. This paper reviews the basis for most of the published work, the line source solution to the diflusivity equation and examines some of its application criteria in the light of unsteady-state conditions. An alternate finite differences method is presented for correlation, and experimental data pertaining to the heat transfer mechanism in the annulus is reported. In the light of the information presented in the paper, it appears that the assumption of a line source for the tubing-wellbore system is valid even for reasonably short periods of heat flow, .such as "steam soak" operations. The empirically modified equation presented earlier matches computer derived results of the finite differences approach lor periods as short as 50 hours. Previously predicted cas ing temperatures and the associated stress levels are thus verified based on these correlative computations and the reported experimental information. Fall out from the computer output resulting in some studies of the influence of insulating cement properties on casing temperature, and experimentally studied effects of nitrogen placed in the annulus at various pressures., are described. INTRODUCTION Generally speaking, predictions of average casing temperatures have been based on an idealized model involving a centralized tubing string at uniform constant temperature radiating energy towards the casing under steady-state conditions.'. ' Heat is transferred away from the casing to the formation by unsteady-state conduction across thermal barriers consisting of cement and the mud sheath. Heat balances written on the casing permit prediction of instantaneous casing temperatures. During early periods of injection, casing temperature varies appreciably as a function of time; however, for long injection times this variation decays as heat flow from the wellbore to the formation stabilizes, and it becomes virtually negligible as conditions surrounding the wellbore become quasi-steady-state (Fig. 1). Carslaw and Jaeger -escribe a solution to the diffusivity equation for a line source (Fig. 2). A constant supply of heat is introduced into the medium from the line placed into the origin of the x-y coordinate system and parallel to the z-axis. Heat spreads outward in the infinite cylindrical solid and the temperature increase on a line going through point (x, y) parallel to the z-axis at a distance r can be predicted by: The following criterion must be considered: the Carslaw and Jaeger equation is obtained on the basis of a large

Jan 1, 1967

By Horst Peter Wölfel

The goal of biodynamic models is to simulate the vibration behaviour of the human body. In combination with experimental studies biodynamical models can be a powerful tool for the analysis of the effects of vibration exposure on health [1] and comfort. This paper gives an overview of the state of the art of biodynamic whole-body vibration models of humans, addressing both numerical models and hardware dummies. Method Two approaches are distinguished, the phenomenological and the anatomical, as illustrated in Figure 1. [ ] Phenomenological models aim to reproduce the vibration behaviour of humans with respect to particular physical quantities, chiefly the driving-point impedance at the interface to the seat, and partly with respect to other transfer functions. Discrete systems of masses, springs, and dampers with several degrees of freedom whose topology and parameters are determined by structure- and parameter identification methods are used in the sense that the functions derived from measurements are reproduced as well as possible. This paper provides an evaluation of this methodology and defines its range of application as well as its limits.

Jan 6, 2006

By C. R. Copeland

Combustion processes, comminution and materials handling can generate airborne particulates. Regulation of these particulates by the U.S. Environmental Protection Agency (U.S. EPA) is becoming progressively more stringent, and regulations will soon include ?nanoparticulates,? which are particles finer than 100 nanometers (0.1 mm). Nanoparticulates are believed to have significant negative health effects due to their high surface area and reactivity. Although it was argued that nanoparticulate concerns were only important for combustion, studies at Michigan Technological University have shown that materials handling and comminution release significant quantities of nanoparticles into the air. Laboratory studies have shown that the use of sodium metasilicate reduced airborne particles finer than 10 mm (PM10) by 86% and particles finer than 2.5 mm (PM2.5) by 80% for iron ore. Additional studies were conducted that revealed that nanoparticulate emissions were present in the types of operations conducted at pyrometallurgical facilities.

Jan 1, 2008

In mining industries, materials loading and handling costs represent a significant component of the total (capital and operation) costs. A variety of methods have been applied in surface mine equipment selection in order to select the suitable loading and haulage system with the lowest total cost. The optimal size and number of equipment calculation are very important task for mining engineering because loading and haulage equipment are major proportion of open pit mining cost. Capital and operating cost are considered in objective function with respect to interest rate, insurance and tax in non-linear form. Shovel and truck annual productivity constraint, fleet matching constraint and number of truck per shovel constraint are incorporated in this optimisation problem with continuous variables. This formulation will yield total cost minimisation per hour and good accuracy compared to previous methods.

Dec 6, 2010