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By R. Adams

Zirconium is the 20th most abundant element in the Earth?s crust and it most often occurs in the form of silicate (as zircon), less often in the oxide form (as baddeleyite or caldesite). Historically, the world?s production of zircon was entirely derived from mining and processing beach sands or heavy mineral sands that were being exploited primarily for their titanium content, i.e., to generate TiO2 feedstocks that would be used for making titanium pigments and, to a lesser extent, titanium metal. Zircon was then regarded as a byproduct, with the sharply fluctuating prices typical of a commodity where the supply is essentially involuntary and not truly responsive to market demand. However, in recent years, zircon has shown considerable mining investment appeal in its own right. Projects have been planned ? and some have already come to fruition ? based mainly on the zircon potential of the deposit. Booming Chinese demand for zircon to meet the requirements of the ceramic and zirconium chemical sectors has been a major factor causing zircon prices (f.o.b. Australia) to surge from US$674/t ($611/st) at [ ] the end of 2005 to beyond US$2,400/t ($2,177/st) by the end of 2011.

Jan 1, 2012

By Will H. Coghill

[The supply of gravel spar and of acid spar is not well balanced. Gravel spar -- 85 per cent flourspar, 5 per cent silica -- gluts the market, whereas acid spar -- 98 per cent fluorspar, 1 per cent silica -- is somewhat scarce. Hence it is desirable to convert some of the gravel spar into acid spar. Knowledge of this condition prompted the Franklin. Fluorsrar Co. at Paducah. Ky., to enter into cooperation with the U. S. Bureau of Mines and the Missouri School of Mines and Metallurgy to improve the methods of fluorspar, milling so that morn acid spar would be available. The fluorspar company detailed Mr. Omar Greeman for the work. During the course of the investigation, while Mr. Greeman was also doing work for a master's degree in the School of Mines? an extensive study was made of gravity concentration of fluorspar ores. Decrepitation by heat treatment was also given a laboratory try-out. A part of tie time was spent on flotation; these notes relate only to the flotation. The results of one of the flotation runs is appended. The test was made in a 500-gram mechanical-agitation machine. The sample was ground to 100-mesh in a pebble mill.]

Jan 1, 1928

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) measurements on solutions and isolated powders provide direct evidence for the involvement of Cr(V) species in the reduction of Cr(VI) by NAD(P)H. ESR analysis of an isolated Cr(V)NAD( P)H solid yields 6 11 = 1.9831 and 6.i. = 1.9772, indicating that the unpaired electron occupies the d22 orbital of the Cr(V) ion, with square-pyramidal geometry. Addition of hydrogen peroxide (H2 0 2 ) to the N AD(P)HCr( VI) reaction mixtures suppresses the Cr(V) species and generates hydroxyl (""OH) radicals. The ""OH radicals were detected via ESR spin trapping, employing 5,5-dimethyl-1-pyrroline-N-oxide and a-(4-pyridyl-1- oxide)-N-tert-butylnitrone as spin traps. The dependence of Cr(V) and ""OH radical formation on the H20 2 and Cr(VI) concentrations indicates that the Cr(V) species react with H20 2 to generate the ""OH radicals. Similar results were obtained by using various diols (arabinose, cellobiose, FAD, fructose, glyceraldehyde, ribose, and tartaric acid), a-hydroxycarboxylic acids, and glutathione. Investigations with superoxide dismutase showed no significant participation of 02 in the generation of OH radicals. These results thus indicate that the Cr(V) complexes, produced in the reduction of Cr(VI) by cellular reductants, react with H20 2 to generate ""OH radicals, which might be the initiators of the primary events in the Cr(VI) cytotoxicity.In this paper we report an electron spin resonance (ESR)3 spectroscopic detection of Cr(V) species in the reduction of potassium dichromate, henceforth called Cr(VI), by NAD(P)H and other diols. Also reported here is the detection of the hydroxyl (""OH) radical in the reaction between hydrogen peroxide (H2O 2) and a variety of Cr(V) complexes. This work was undertaken because while the reduction of Cr(VI) to lower oxidation states has been suggested as a key step m the mechanism of Cr(VI) toxicity, mutagenicity, and DNA alteration, the details are not yet clear (1-5).Earlier studies on the mechanism of Cr(VI) reduction in cellular systems include those on the reduction of chromate by microsomes (6-8), rat liver DT-diaphorase (9), and aldehyde oxidase (10). All these studies imply that Cr(VI) can be reduced to Cr(Ill) by cellular constituents. Regarding the mechanism of Cr(Vl) carcinogenicity, Jennette postulated that Cr(V) is the ultimate carcinogenic form of chromium compounds (8). This conclusion has led to many further investigations of the formation of Cr(V) in the reduction of Cr(VI) under biologically relevant conditions (11-33). More recently, however, Kawanishi and co-workers (34) have investigated the mechanism of DNA cleavage induced by Cr(VI) in the presence of H20 2 and have argued that it is not Cr(V) itself that is carcinogenic, but it is the reactive oxygenated species (02, 10 2 , ""OH) (produced by the decomposition of the Crv(02) ¾ - ion) that cause the DNA alteration."

Jan 1, 1990

As part of a continuing program of evaluating the Nation's crude-oil resource, this report presents information pertaining to resource, primary reserve, and potential waterflood reserve for 3,209 selected reservoirs contained in 24 oil-producing States, as of January 1, 1968. To that date the selected reservoirs had not been subjected to pressure-maintenance or secondary-recovery operations. These reservoirs also met the following parameters: (1) a minimum of five oil-producing wells on January 1, 1968, (2) a minimum of 50 acres areal extent, (3) a minimum of 50,000 bbl of oil ultimate primary recovery, and (4) the principal reservoir energy was other than active water encroachment. The selected 3,209 reservoirs produced 527 million bbl of oil in 1967, about 17 pct of U.S, total production. Primary oil reserve was 4,983 million stb; in addition, there was 6,043 million stb of potential water- flood oil reserve. Oil resource in the selected reservoirs was 59,547 million stb. A brief history and outlook of waterflooding are presented for each State. Depth and producing rate statistics and geologic distributions of production, resource, reserve, and potential waterflood reserve for the selected reservoirs are presented by States in the appendix. Also included in the appendix are description, history, and technique modifications of waterflooding, and a preliminary cost estimate of a closed-system water-injection project.

Jan 1, 1970

The panic bars (and associated linkages and electrical circuitry) that are defined in this document are a machine operator-actuated control for the emergency deenergization of the tram motors on self-propelled, electric and diesel face equipment; including haulage equipment such as shuttle cars. There are nine basic types of panic bars (and several variations) that are recommended in this document, but all of the panic bars arc characteristically of the 'fire door" type that is frequently encountered on outside exit doors of many public, and some commercial buildings. It is also the intent of the following panic bar designs that, when emergency brakes arc added to the face equipment machinery for which they arty required, that they be designed and hooked up so that actuation of the panic bar will result in automatic application of the emergency brakes (immediately following the deenergization of the tram motors). The following panic bar design requirements are a restatement of the proposed requirements defined in the Federal Register, requirements cited in "Guidelines for the Design and Installation of Devices for Deenergization of Self-Propelled Electric Face Equipment/Automatic Emergency Brakes" by C. E. Lester and J. D. Greenhalgh of MESA, and Bendix recommendations that were formulated as a result of discussions with personnel at the various machine manufacturers and underground coal mines that we surveyed, discussions with G. I. Judy (our consultant), etc:

Jan 1, 1974

By Andreas Bienz

The safety of persons from accidental explosions and fires during manufacture, storage, transport etc. of explosives, pyrotechnics, propellants, firework and ammunition is most commonly assessed according to prescriptive rule-based approach: Safety is given when all requirements which are listed in numerous regulations and directives (such as e.g. safety distances, limited quantities, protective installations etc.) are complied with. Such a deterministic prescriptive rule-based approach is quite easy to apply but has got disadvantages, however: The actual state of safety in a specific case is not explicitly and quantitatively expressed, and it is not distinguished between the endangered individuals and the whole group. As a result, the effects of the safety measures cannot be measured. This is why uneconomical and in the worst case useless safety precautions cannot be avoided. In addition, waivers are difficult to negotiate, meaningful and sound arguments for pro and con being lacking.

Jan 1, 2007

By P. M. Y. Waye, R. Yewen

"As mines utilize more automation in mining operations to improve efficiency and safety, a corresponding increasing demand is placed on the transport of information. Some of the recent technological advances in underground telecommunications are described for various data, voice and video applications. In particular, two new innovative underground communication systems are described, one with highspeed data at 30 Mbps and the other for minewide evacuation and safety applications.The high-speed data system incorporates state-of-the-art data networking technologies and the existing leaky-cable, narrow-band radio channels. The new system provides over the same basic infrastructure — the highspeed data network at 30 Mbps TCP/IP Ethernet with 100 Base-T interconnection, plus 32 narrow-band radio channels.The second system is a system for minewide evacuation with “through-the-earth” communication infrastructure. Emergency situations can be communicated to and from all the miners within seconds through a central control location. The technology involved does not require leaky cable or any other similar transmission media installation. Many applications are possible, including warning miners of emergency situations, mine rescue operation to communicate with trapped miners, and regular reporting from miners working alone."

Jan 1, 2002

By Arthur Dubé

An account is given of the developments brought about in the last fifteen years by metallurgical research in the field of heat treatment of steels. The practical aspects of these developments are especially emphasized. Methods of representation of the phase-change during austenitizing and sub-critical transformation of austenite are described and the importance of time-temperature-transformation charts for the planning of heat treatment cycles is shown. Special copies such as retained austenite and internal stresses developed on quenching are also discussed in some detail. Due to the interest shown currently in these problems, it has been thought advisable to describe briefly the underlying principles and present some of the results already available.

Jan 1, 1945

By Russell L. Cook

Stringent environmental regulations, which have limited the use of sludge ponds, coupled with the economic incentive to clean more 'coal or to add fine coal cleaning additions to existing preparation plants have increased the use of static thickeners in preparation plants. The Lamella Gravity Settler, sometimes de signated Lamella Thickener, is a shallow depth sedimentation device which has been applied in a variety of industrial process and wastewater control projects in place of the conventional raked thickeners. This paper presents the theory and design of the La-mella Thickener, as well as describing the operating results from several full scale installations in a variety of Appalachian preparation plants.

Jan 1, 1977

By D Capstick, M B. Ebell

This paper describes the test work, process design, commissioning and operation of a processing system at the Ergo gold operation that improves the extraction efficiency from gold tailings material. The improvement in recovery is derived from the separation of the gold contained within the sulfides of the tailings material and a dedicated process stream to recover that gold.The sulfides are separated by means of a flotation circuit and that resulting concentrate is subjected to a regrind of below 20 ¦m to enable a greater liberation of the gold. The ultra-fine material is then subjected to a dedicated leach circuit to recover the now exposed gold particles.The case study is an example of the challenges of introducing new technology and methodologies to a well-established operation and thereby attaining improved efficiencies and tangible business benefits.CITATION:Ebell, M B and Capstick, D, 2013. Improving extraction efficiency from Witwatersrand gold tailings using flotation and ultra-fine grinding of concentrates, in Proceedings World Gold 2013 , pp 301-306 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By Ryan Weaver, Travis Coleman

The drilled shafts that support transmission lines and substations have been increasingly subject to testing to assess the integrity of placed concrete. Cross-hole Sonic Logging (CSL) has been used, but large diameter shafts with challenging site access are generally more favorable to Thermal Integrity Profiling (TIP) testing. TIP testing assesses the shafts based on measurements of the concrete temperature during curing. The TIP results provide assessment of integrity both within and outside the cage, along with information about the alignment of the cage and concrete cover. This data has allowed shafts with imperfect results to be subject to more detailed structural evaluations. However, it may not be well understood how to use this additional information by designers and engineers. The purpose of this paper is to present TIP results of transmission line foundations, both with and without issues with integrity, including cage shifting, minimal concrete cover, or soil inclusions. The intent is to provide general guidelines of the issues that merit additional investigation and those that should be recognized as inconsistencies inherent to underground construction. BACKGROUND This paper is intended to discuss some of the drilled shaft evaluations made when TIP testing is performed. The authors of this paper were recently involved with a transmission line project that was designed and constructed for a Confidential Utility Client located in the Midwest United States. The project was delivered as an Engineering, Procurement, and Construction (EPC) contract with the electrical line construction company as the prime contractor. The contractor then subcontracted several parts of the work which included engineering for transmission line and foundation design, foundation construction, and third-party testing intended to evaluate the concrete homogeneity and integrity of the place concrete in the deep foundations. The testing method selected was Thermal Integrity Profiling Method B, which uses thermal sensors embedded in the concrete. The TIP testing was administered by Mr. Travis Coleman with GRL Engineers, Inc. Mr. Ryan Weaver with Burns & McDonnell served as the owner’s engineer and technical consultant for the utility and was responsible for reviewing submitted TIP reports and providing recommendations to the utility on their acceptance, and if there were any issues that would warrant further discussion and analysis.

Jan 1, 2019

By K. K. Kelley

The entropy values at 298.1° K. for the elements and inorganic compounds, on which sufficient data were available for calculation in 1931, were discussed in a previous publication (96).3 Since that time the specific beats at low' temperatures of many more inorganic substances have been determined, and considerable advances have been made in the realms of spectroscopy applicable to the determination of thermodynamic properties. Moreover, a critical study of the existing vapor-pressure data made by the author (98) furnishes entropy of vaporization results suitable for obtaining approximate values of the entropies of a number of gases from the entropies of the solids or liquids. Consequently, it appears worth while at the present time to supplement the former publication, giving the new values now obtainable and making such revision in the older values as the data warrant. The methods of calculating entropies were discussed in previous publications (96, 98) and will not be repeated here. ENTROPIES AT 298.1° K. FOR INORGANIC SUBSTANCES In the following pages, the same arrangement is followed as in the previous publication (96). All entropy values are expressed in 15° gram-calories per degree Kelvin per gram-formula mass of substance. The figures given for gases do not include the effect of nuclear spin, as is nearly universally customary at present. The estimates of accuracy in the case of the values obtained from heat-capacity data apply only to the existing measurements and to the necessary extrapolations as they are made. It is assumed usually that the substances are in such an energy condition at the lowest temperatures reached in the specific-heat measurements that the usual normal type of extrapolation may be made. No allowance is made for error in this assumption. The recent work on Gd2SO4. 8H2O and FeC13 illustrates the difficulties that may arise in obtaining the entropies of some paramagnetic substances. Also the data and calculations for such substances as CO, H20, and N20 show that the correct entropy is not obtained in all cases by indiscriminate application of the usual

Jan 1, 1936

By P. O. Sandvik, George Erdosh

"AbstractThe Cargill phosphate deposit, located 32 kilometers southwest of Kapuskasing, Ontario, was discovered by the Resource Development Group of International Minerals & Chemical Corporation in 1975 and has been evaluated through an extensive program of 190 drill holes, numerous chemical analyses, metallurgical tests, and engineering and economic studies.The Cargill alkalic complex, comprising principally car-bonatite and pyroxenite-amphibolite rocks, was intruded in to the rift system of the Kapuskasing High during late Precambrian time about 1,800 million year s ago, near the intersection of northeast- and northwest- trending faults. The Cargill complex is one of at least ten known alkalic complexes in or close to the Kapuskasing magnetic-gravity-high system and is expressed by an elongated, northeast- oriented, three-part magnetic anomaly 7.2 kilometers long by 2.8 kilometers wide . Weathering and leaching under assumed temperate to cool, moist climatic conditions , and controlled by faulting, shearing and/or initial petrographic variations within the carbonatite , developed a small, locally confined karst system in the car bonatite rocks and resulted in a thick enriched leached carbonatite zone, capped by troughs and sinks, filled with a residuum of apatite, goethite, clay and other minerals stable in the near -surface, oxidizing environment. Overburden is 5 to 165 meters thick."

Jan 1, 1977

By R. V. Ramani, R. Bhaskar

"The National Academy of Sciences (1) recognized the importance of studying the spatial and temporal characteristics of respirable coal mine dust atmospheres. In this paper, the progress to date of a research project on dust transportation and deposition in mine airways is presented. A mathematical model is proposed for studying the transport of dust. A source representative of dust generation in underground coal mining is defined. The influence and applicability of surface roughness, dispersivities, coagulation and reentrainment to vine dust flow arc examined. A convective-diffusion model is proposed for the transport and deposition of dust in mine airways. Using the model, the spatial and temporal characteristics can be evaluated in terms of dust concentrations in the mine atmospheres.INTRODUCTIONThe prediction of the behavior of fine particles Is Important in many fields of science and engi¬neering including physics, chemistry, mining, mineral processing, and atmospheric science. In mining from the health point of view, fine coal dust is associated with the appearance of pneumoconiosis in miners exposed to the dust. Also, in addition to being a nuisance factor obscuring visibility and general mobility of miners, it can lead to sudden catastrophic incidences of explosions. This paper outlines the progress to date of a research project on dust transportation and deposition in mine airways. A mathematical model is proposed for studying the transport of dust for the various mechanisms. The dust dispersion is defined in terms of a dispersion term determined from experimental data by Skubunov (23). Coagulation is considered as one of the mechanisms that can lead to changes in the particle size distribution. Reentrainment as a possible secondary source of dust was examined during model development but was not included in the final model."

Jan 1, 1988

By Eric Zahl

Researchers at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health, Spokane, WA, have collaborated with three Western longwall coal mines in an ongoing effort to develop technologies that will aid in providing safe and stable working areas. The goal of the research described here is to develop a stress monitoring system that will provide immediate information to mine managers for making daily safety decisions as areas of poor ground are mined through. Initial work has focused on answering preliminary questions regarding the reliability and use of stress change patterns. Research is concentrated on monitoring horizontal stress because horizontal stress is transmitted over long distances through stiff strata, thus allowing an extended length of entry to be monitored. This paper presents an explanation of the concept, key results from field tests at two mine sites, and a proposed process for imple¬menting a monitoring system. System design layouts, instrument use, data collection and interpretation methods, and processes to present findings to mine staff are described. Additional validation and correlation with actual failure mechanisms are required before this approach can be recommended at ongoing operations. How¬ever, initial results indicate that this approach shows promise in mines prone to bumps and roof falls associated with large stress changes. In particular, analyses of measured changes in horizontal stresses appear useful.

Jan 1, 2002

By C. W. Goodale

TOMBSTONE, a name not exactly full of cheerful suggestion, has a great record as a mineral producer and a colorful history as a frontier mining camp. The only practical route to Tombstone in the early 80's was by way of San Francisco and Los Angeles. The Southern Pacific was building across Arizona, and a sleeper was attached to a construction and freight train at Los Angeles, and was trailed slowly across the Colorado Desert to Benson in the San Pedro Valley. Thence one staged 26 miles to Tombstone, which is located near the foot of a range of hills at an altitude of about 4500 ft.

Jan 1, 1925

By John J. Simmons

Federal and state regulations, in an effort to reduce acid rain, are becoming increasing more stringent regarding sulfur content of fossil fuels. Whereas coal from Illinois and Ohio contains between 1.5 and 37. sulfur, Wyoming has billions of tons of coal reserves containing less than O.5/% sulfur. However, much of Wyoming's coal is high in moisture, 25-30%, and low in energy, 8,200 to 8,900 BTU, vs. 10,500+ BTU for Illinois and Ohio Basin coals. Wyoming currently ships in excess of 130 million tons of coal to utilities as distant as Michigan, Wisconsin, Minnesota, Iowa, Nebraska, Louisiana, Oklahoma, and Texas. With freight charges ranging from $12.00-$20.00/ton, more than $1.5 billion a year is spent to transport water. A test shipment of more than 50,000 tons of Wyoming coal has recently been made from Mobil's Cabello Rojo Mine, south of Gillette, by Burlington Northern to the Robert's Bank British Columbia coal terminal for transloading and shipment to Taiwan Power Company. This coal assayed approximately 8,400 BTU/lb. and 277. moisture. Carbontec Energy Corporation feels the future availability of dried coal containing 11,000+ BTU could substantially enhance the potential export as well as the domestic market for Wyoming coal. Large and small utilities, along with industrial furnaces require tens of millions of tons of Wyoming, West Virginia, and other Eastern The federal government is encouraging the expenditure of hundreds of million of dollars by utilities to retrofit their boilers to allow them to burn higher sulfur coal. This program, if carried to completion, would cost many tens of billions of dollars, with the net result being high power costs sustained by the utilities. These costs will be passed on and paid for by the American consumer. A sensible alternative would be the burning of low sulfur coal by the utilities, without costly capital and operating expenditures. Carbontec Energy feels the successful operation of a Carbondry Coal Drying Plant in Wyoming will be the forerunner to other similar and larger operations in the State. CARBONTEC RESEARCH The activities of Carbontec's personnel to develop a viable process to dry sub-bituminous and lignite coal goes back some 14 years; in fact, for some of us it goes back to 1962 when we were involved in a program under which lignite coal from Truax Trayer's Velva mine was placed in low sulfur coal, which are burned alone or blended with high sulfur, Midwestern coal. Carbontec believes that a high BTU. reasonably priced, shippable coal fuel produced in Wyoming and delivered at costs competitive with Eastern low sulfur coal, could offer substantial benefits to Wyoming coal producers, utility customers, and to the State of Wyoming.

Jan 1, 1989

By P. Cheung, J. Gulyas, R. Clary

Over the past 50 years, the use of autoclaves in the metallurgical industry has evolved from final metal recovery (hydrogen reduction) and purification (sulphide precipitate oxidation) to treating whole ores and concentrates. Recent process developments, such as the use of autoclaves for laterite leaching, have necessitated higher temperature and pressure operations, which in turn have seen marked advancements in technology and manufacturing capabilities to keep in step with process demands. This paper will discuss the advances in technology in terms of design, materials and construction of autoclaves and liners, typical dip tube design and geometric layout. This paper will also address specific auxiliary equipment, such as acid and steam injection systems, and components, such as agitator seal systems.

Jan 1, 2004

By P Ritchie, E H. Briese, N A. Currey

Kidston Gold Mines, located in semi-arid North Queensland, Australia is currently in its closure phase. Highly innovative and comprehensive rehabilitation strategies were employed at the site, including the direct revegetation of the surface of the tailings storage; the construction of a tailings sediment entrapment pond; the construction of a spillway to drain large rainfall events from the surface of the tailings; the construction of store/release covers over the tops of the waste rock dumps; the sheeting with oxide waste rock of the waste rock dump slopes; the partial back-filling of the initial Wises Hill Pit with waste rock and thickened tailings produced from the subsequent Eldridge Pit; the partial flooding of Eldridge Pit following the end of mining; and the construction of wetland systems to treat contaminated tailings and waste rock dump seepage. These closure strategies involved the careful consideration of water management. Specific water management issues included understanding the water balance of the tailings dam; the operation of the tailings dam sediment entrapment pond and spillway; understanding the water balance of the store/release waste rock dump covers; the importance and sustainability of vegetation on the tailings, store/release waste rock dump covers, and on the sheeted waste rock dump slopes; the level and quality of water in the partially flooded Eldridge Pit; and the treatment of contaminated seepage in the constructed wetlands. The seasonal and highly variable rainfall experienced in this semi-arid climate posed a number of challenges for the management of water on the site post-closure. The paper details these challenges and highlights how they were resolved over the period leading up to and following the end of mining.

Jan 1, 2003

By C. Patrick

Annually, the U.S. coal industry generates and must dispose of over 200 million tons of coal refuse, expanding a major environmental problem. The purpose of this research was to investigate the feasibility of utilizing coal refuse as an aggregate in concrete. This paper reports on findings of the initial phases of a project to determine the viability of replacing traditional concrete blocks, used for under-ground ventilation stoppings, with refuse blocks. Refuse was collected from three active preparation plants in Eastern Kentucky and used as the primary aggregate for concrete cylinders. The refuse fell within ranges normally observed for size consist, moisture, and ash. Stress-strain analyses yielded compressive strengths of the refuse cylinders from 59% to 77% of the control group strengths. Low variability within groups while significant differences between groups were found. On-going determination of effects of weathering on the refuse cylinders is being conducted and will be completed in early 1995. The research results are favorable for the future direction of the overall project objectives.

Jan 1, 1995