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By C. R. Wohrman

A melt of pure electrolytic iron with about 0.4 per cent. sulfur and 7 per cent. manganese was prepared in connection with a study of inclusions in iron. The alloy darkened rapidly when etched with a 10 per cent, alcoholic solution of nitric acid, and microscopic examination revealed the presence of a semimartensitic, semi-Widmanstättian structure (Figs. 1 and 2) closely resembling the structures found by Benedicks in his artificially prepared "meteoric iron."' The structures found by Benedicks were readily explained by the presence in his alloy of the two well-known iron-nickel solid solutions, taenite and kamacite, and of their eutectoid (?) aggregate, plessite. By analogy, one would infer the existence of similar phases in the iron-manganese alloy just described, such an inference being strengthened by the similarity displayed in many ways by nickel and manganese in their effects on iron. Iron-manganese Alloys are Regarded as Homogeneous Heterogeneity of iron-manganese alloys has not been recognized heretofore, judging from the data of standard metallographic books and those of original papers. In fact, iron and manganese are quite generally regarded as completely miscible in the solid state. Dr. Rosenhain,2 for example, writes: Alloys of group (a), of which those of gold-silver, iron-manganese, and copper-nickel are examples, when allowed to crystallize sufficiently slowly to attain their condition of final equilibrium, present a microstructure exactly similar to that of a pure metal—the homogeneous character of the molten solution is in that case so completely maintained that the microscope cannot detect the presence of any second constituent. Guillet and Portevin3 refer to the iron-manganese system as an example of the "case of metals completely miscible in the solid state."

By R. Khanna, K. Hyun Ko, A. J. Berkovich, J. Hook

"The co-pyrolysis of synthetic polymer polyethylene terephthalate (PET) and agricultural wastes (naturally occurring polymer-macadamia nut shell) was investigated in the temperature range 473K to 1273K using a horizontal furnace with an aim to understand their thermal degradation under isothermal conditions. In-depth characterization of pyrolysis residues was carried out using x-ray diffraction (XRD) and solid state nuclear magnetic resonance (NMR) for carbon structure, and through determination of the concentration of unpaired electrons using electron paramagnetic resonance (EPR). In previous studies, it has been found that PET thermally decomposes ~ 650K-700K, releasing (~80 wt % of initial weight) gaseous products due to random chain scission. In the case of macadamia nut shell, three types of byproduct can be obtained from pyrolysis: char, tar and gaseous products. In the co-pyrolysis of macadamia nut shell with PET in 50-50 wt% ratio, total product weight ratio could be modified with the addition of PET acting as a hydrogen source. This is because a recombination of thermal cracking products of cellulose could be suppressed by hydrogen from PET, which will later lead to an enhancement of tar formation. In addition, pyrolysis around 673K is sufficient for bond cleavage to occur in cellulose and lignin leading to the formation of negatively charged activated carbon with high surface area, providing bonding sites for volatiles evolving from PET. Therefore the co-pyrolysis may be able to enhance the product yield (tar/char/solid carbon residue) along with a reduction in the release of gaseous products. During the co-pyrolysis, temperature was found to have a significant influence on the kinetics of thermal degradation and solid residual by-products after co-pyrolysis.INTRODUCTIONPlastics are being used worldwide in a wide range of applications in the modern society; their usage has resulted in increasingly a massive waste problem. The production of most synthetic plastics requires hydrocarbons that are produced from petrochemicals derived from fossil oil and natural gas, a non-renewable source (Speight 2011). Currently, plastic manufacture utilizes ~4% of world oil and gas production, and it is expected to drive further increases in petroleum demand by 1-2% due to their large volume of manufacture (Hopewell, Dvorak et al. 2009). Landfilling and incineration of plastic waste are the two main routes to plastic waste management (Encinar and González 2008). In Australia, only 10% of waste plastics were recycled in 2006 (White and Hyde 2011). This means that large amount of fossil fuels from plastics has either been simply burned for energy recovery or buried in the ground. There is an urgent need for developing alternative avenues for recycling waste plastics. Our group at UNSW has carried out extensive research on the recycling of waste polymers as carbon resource in steelmaking including slag foaming and carbon dissolution from waste plastics into liquid steel at 1600°C; the effect of basic plastic characteristics such as chemical composition, structure, bonding network etc. was examined (Sahajwalla, Rahman et al. 2009)"

Jan 1, 2012

By George Schmitt, Ted Dowey, Grant Millener, Sean McAndrew, Eric Jordan

The Rondout-West Branch Bypass Tunnel is being built to bypass a substantial leak in New York City’s primary water supply tunnel. The 13,500 foot long tunnel travels 600 feet under the Hudson River through the same troubled geology and high pressure water inflows that the original tunnel did in the 1940s. A Robbins TBM traversed this geology and built gasketed segments. Nine thousand two hundred feet of 16 foot diameter interliner was installed and backfilled within the segments. Finally, reinforced cast in place lining was placed. This paper addresses the challenges and the multi-tasking approach the contractor utilized.

Jun 13, 2021

By Thomas Konstantis, Spyridon Konstantis, Panagiotis Spyridis

"Tunneling and Underground works are unequivocally subject to a diversity of inherent uncertainties associated with the geotechnical, hydro-geological and environmental regime that surrounds them. On many occasions, these uncertainties can provoke loss events of considerable consequences. The present contribution elaborates on losses that the insurance market has suffered in the recent years, following a construction failure event. These losses are being considered and analysed on a quantitative basis through evaluation of cost related data, with explicit discretization of the applied construction methodology and of the subsequent developed failure type since both of which are considered of major importance. Given the identified persistence and regularity of some loss-contributing factors, recommendations are provided on the basis of a proactive risk engineering management approach that are envisaged to reinforce the understanding of project risks and alleviate the incurred insurance cost. 1 INTRODUCTION The underground construction sector has always been a very challenging area for all involved parties, including the insurance market. Main reason for that remains the uniqueness of the uncertainties sources and the subsequent inherent risks that the tunneling and underground projects are exposed to. In many instances, these risks materialize, leading to loss events with substantially high impact on reinstatement cost and incurred delays, which depending among others on the insurance coverage will have to be bared by the Insurance market. In the recent decades and as the tunneling industry boomed and expanded with many major and significant projects undertaken around the world, the insurance market was faced with additional challenges. Increased competition during tender coupled with the scale and complexity of the projects and politically driven decision making exerted pressure on the project timelines, completion dates and budget. The pressure for on-time or even early project completion- to avoid liquidated damages or achieve bonus payments, respectively- along with cost reduction efforts and the incentive for innovative failure events. That, in turn, put additional pressure on the Insurance market which had experienced a significant amount of losses with substantial cost. One of the triggered mitigation actions was the introduction of the Code of Practice for Risk Management of Tunnel Works (ITIG, 2006 & 2012; MunichRe 2006, Wannick, 2007, Spencer, 2008, Adeyemo, 2011)."

Jan 1, 2016

By D. G. Kuehn

Mass spectrographic studies have been conducted on the positive ions and neutral species of glow discharges containing 1.0 pct S02 and 1.0 pct CO in helium. Measurements were conducted for gas pressures from 3.5 to 10.1 torr using both dc and 60-Hz ac excitation. The ion species that were observed included S+, SO+, SO+, 0+, O2+, C+, CO+, and CO2+ with lesser amounts of SO3+, (CO)2+, SCO+, and (SO?CO)+ or CS+2. Interpretation of the functional dependence of the various ionic and neutral species on pressure and applied power showed that CO reacted with the SO formed in the discharges to produce CO2 and sulfur. Deposition of elemental sulfur was observed in the plasma container.

Jan 1, 1973

An Integrated Geology-Mine-Plant and Eco-Efficiency Simulator for Anglo Platinum's Evaluation and Operational Improvement Initiatives

Sep 13, 2010

By P R. Lock

The Silver Swan nickel mine is located at the Black Swan Nickel Project, 53 km north east of Kalgoorlie, Western Australia. The Silver Swan orebody is a massive sulphide nickel deposit dipping 70¦ east with an average in situ grade of 14 per cent. Mining of the massive orebody is by Mechanised Ramp Cut and Fill (MRCF). A mining recovery of 98 per cent and minimising dilution are primary goals in extracting the high-grade ore. Placing a distinguishable marker bed (working platform) on rock fill was identified as a key method to achieving these goals. Gravel from a pit located onsite was considered the most suitable material for the marker beds. Research undertaken to design the marker beds using the gravel revealed conventional methods used in mining would not suffice, but that road stabilisation methods could be a viable alternative. Trials used a road recycler to mix cement and gravel in situ and several test beds were constructed on the surface to determine the final design. The trials attempted to replicate a marker bedÆs life cycle of construction and placement and mucking of ore from the marker bed. Testing the marker bed for strength for use as a working platform was completed using a Clegg Hammer; good correlation to a Clegg Impact Value and the compressive strength of the stabilised gravel was found. This paper describes the use of a road stabilisation machine, tests conducted, monitoring and marker bed design and discusses underground placement of the marker bed and its performance.

Jan 1, 1998

By D. Harrington

Correct ventilation of underground workings whether in coal or in metal mines consists in establishing such control of air currents that the miners may work in safety, with maximum comfort and efficiency, and without impairment of health; also in controlling the air flow so that the mine workings may at ordinary times be kept reasonably free of harmful gases or dusts, and so that in time of emergency, as when a fire or an explosion occurs, there may with minimum delay be maintained as much or as little air flow as is desired throughout the mine in its entirety or in certain parts of the mine. Control of air flow is the essential point of any mine ventilating system, and is obtained only by the installation of mechanically operated fans, and other ventilating devices such as doors; overcasts, regulators, etc. Every mine, large or small, coal or metal, should from the outset be equipped with a fan. Much has been written about natural ventilation, and many claims have been made that in specific mines or parts of mines there is sufficient natural air flow. As a matter of fact, there are actually very few if any mines, coal or metal, where natural ventilation creates atmospheres anything like adequately safe or healthful for underground workers even at ordinary times or under ordinary. conditions; and at the time of a fire or an explosion mines depending upon natural ventilation are practically helpless, and are decidedly dangerous for the unfortunates forced to be in them either at the time of the disaster or afterwards when trying to handle conditions arising from the emergency.

Jan 1, 1929

By Jaime Newell

Actualmente la química de los iones ha adquirido una importancia preponderante en sus aplicaciones industriales, de forma que el presente artículo revisa las definiciones de la ionización y sus aplicaciones en la industria minera Las moléculas de gran número de compuestos en solución, están formadas por partículas mucho más pequeñas que se denominan iones. Cuando algún compuesto es disuelto en agua, sus iones se mueven libremente tomando parte en la reacción química. Aquellos iones que muestran carga eléctrica positiva se llaman cationes y los de carga negativa, aniones. Solo aquellos materiales que dejan sus iones en solución, están sujetos al proceso del intercambio iónico. El factor de que muchos compuestos son ionizables en agua u otro solvente, es la llave del intercambio iónico. El proceo de intercamio iónico se origina cuando el cambio se hace entre cationes se llama intercambio catiónico y cuando se realiza entre aniones, intecambio aniónico.

Jan 1, 1959

By Richard M. Tinlin

Some of the practices of the mining industry that may place an undesirable stress on the groundwater environment are coming under increasing scrutiny from legislators and regulatory agencies. Among these practices are mine dewatering, the use of tailings ponds, land rehabilitation, and technological innovations such as in situ leaching of waste clumps and ore deposits. Pernichele, noting that 24 states have enacted legislation controlling to varying degrees the environmental effects of mining, has emphasized the importance of assessing the potential for damage to groundwater when evaluating, planning, and designing mining projects. 1 Illinois has enacted legislation requiring anyone opening, operating or abandoning a mine site to obtain a permit from the Illinois EPA. The law is one of the first to require regular monitoring and reporting to a control agency. Legislation has also been recently enacted at the national level that will have a significant impact on the mining industry; e. g., the Federal Water Pollution Control Act Amendments of 1972 (Public Law 92-500). The stated objective of this Act is to restore and maintain the chemical, physical and biological integrity of the nation's waters. Specifically, according to Sec. 102(a), the Administrator of the U.S. Environmental Protection Agency (EPA) is required to prepare or develop comprehensive programs for preventing, reducing or eliminating the pollution of the navigable waters and groundwaters and improving the sanitary condition of surface and underground waters. The definition of the terms "pollution" and "pollutant" is of particular significance to those who must comply with PL 92-500. The definitions are quite broad and include most of the adverse water quality effects of man's activities. As defined in Sec. 502(19), "pollution means the man-made or man-induced alteration of the chemical, physical, biological and radiological integrity of water." Within the Act, the list of pollutants includes dredged spoil, solid waste, incineration residue, chemical wastes, radioaetive materials, heat, wrecked or discarded equipment, rock, sand, cellar dirt, and industrial waste discharged into water.

Jan 1, 1973

By C. A. Y. Shephard, H. L. Brusset

Pressure maintenance by water flooding in the Pembina Field made consideration of wet crude dehydration and disposal of the produced water mandatory. Crude dehydration, the treatment and disposal of produced water, as well as the sale of gas and crude oil were expected to be handled more efficiently at one central point than at several conventional batteries. This plan was effected by routing the produced fluids to the central station by way of several well testing batteries referred to as satellites. To realize the full efficiency inherent in such consolidation the entire system was made self-regulating. Programming ensures the testing and proper routing of all products to their destination. Forty producing wells have been self-operated during the winter 1959 -1960 with gratifying results.

Jan 1, 1960

By J. Borlée, J. P. Birat

"ULCOS is a large European program launched by a consortium of 48 partners led by arcelor and a core group of steel producers, which was started in 2004 with the support of the European Commission (RFCS and 6FP programs) to search for breakthrough process routes that could, in the future, when fully developed, demonstrate the potential of large cuts in CO2 emissions for the production of steel from iron ore.The timescale for commercial implementation is the post-Kyoto period, i.e. 15 to 20 years from today.The present paper presents the progress made in the first 2 years of this 5 year program.Several concepts are being investigated in parallel: re-engineering of the blast furnace to incorporate CCS in the core of the process, smelting reduction with CCS capabilities, massive use of natural with more CO2-lean technologies than today, hydrogen steelmaking and electrolysis of iron ore. Biomass also offers very attractive perspectives, while raising major challenges.None of these new steelmaking routes are ""no regret"", which means that the European Steel Industry has already incorporated extensive energy saving steps in its present process technology and is working as close to thermodynamics limits as is cinematically and economically feasible, and that decreasing GHG emissions further means introducing breakthrough technologies that add significant costs to the operation of the Steel Mills.They will also require much research and development before they can be proven and implemented commercially.IntroductionThe ULCOS program (Ultra Low CO2 Steelmaking) is a large research program of the European Steel Industry and its industrial and research partners launched in September 2004 to investigate steelmaking technologies that have the potential of reducing the CO2 emission of the Industry by a large amount, typically in the order of 50%. It is supported in the European Community by the 6th Framework and the RFCS programs through 3 complementary European projects [1,2].The present paper summarizes the work carried out in the phase 1 of ULCOS and in framing the program of phase 2."

Jan 1, 2008

By D. E. Munson

The Waste Isolation Pilot Plant (WIPP) Project was established in 1975 by the Department of Energy (DOE) under Public Law 193 to develop the necessary technology for safe disposal of radioactive wastes from the defense programs of the U.S. The technology development involves extensive theoretical, numerical, and laboratory programs, as well as construction of the WIPP facility in southeastern New Mexico for in situ testing and waste storage demonstration. If after the demonstration, the facility is found to comply with regulations of the Environmental Protection Agency, then the facility will become a repository for Transuranic (TRU) waste. The underground portion of the facility is 655 m beneath the ground surface in massive natural salt deposits of the Salado formation, as shown in Figure 1.

Jan 1, 1991

By R Kjar

Globally, it is anticipated that the mineral sands industry will enter a period of short supply. Demand for both titanium dioxide and zircon is forecast to continue increasing, with new projects needed to come on-stream to fill the supply gap. Victoria is well placed under this scenario as a source due to the high quality of its mineral assemblage, its excellent resource grade and the globally significant size of its mineral sands resources.Australia’s mineral sands rich Murray Basin remains under-developed, especially at its extensive Victorian margins. Development to date has not progressed adequately for the reasons of technology difficulty, history of competition with other jurisdictions and the absence of a platform that requires development as a consideration for security of tenure. Victoria’s mineral sands potential is not just about the Murray Basin, in addition, there have been discoveries in the Gippsland Basin and prospective sites in the Gippsland Basin remain under-explored. Key problems included the lack of available ground for potential developers and the intellectual property of solutions to technological problems associated with the fine grained mineral deposits belonging to a previous developer (with patents now expired).As such, the timing is right to re-visit the potential of the Murray Basin as a site for long-term development with high returns based on current and predicted prices.In order to understand why Victoria’s earth resources in general, and mineral sands in particular, remain under-explored and undeveloped, the Department of Primary Industries initiated an internal review of its role in encouraging and supporting investment in the earth resources sector.As a result, the Victorian Government has committed to taking action to encourage effective ground turnover and acknowledges that a new focus on engagement with industry is needed to bring new investment to the State. The revision of the Mineral Resources (Sustainable Development) Act 1990 provides an opportunity for the government to better align its legislative processes with industry project lifecycles and facilitate access to valuable resources that currently remain undeveloped.Victoria has a track record in assisting projects reach development stage. Iluka currently has two operations in the State in addition to its mineral separation plant that is capable of processing HMC from its South Australian operations. Iluka is expected to ramp up its Murray Basin Stage 2 operations with the WRP mine scheduled to come on line in early 2012. Meanwhile, Astron is actively seeking partners for its Donald Mineral Sands project. The project is becoming increasingly attractive given the recent price hike in zircon; Astron has access to an estimated five to 6 Mt of zircon in its Donald WIM 250 deposit.Given its substantial and valuable mineral sands endowments, the State of Victoria should sensibly be the centre of future investment in project development. However, as previously mentioned this is currently not the case. The Government is therefore committed to implementing new measures that protect security of tenure but ensure that genuine companies can access endowments where they have a clear intent to work those resources.

Oct 5, 2011

By M Fitzgerald

Fimiston Open Pit is operated by Kalgoorlie Consolidated Gold Mines (KCGM) as a joint venture between Barrick Gold and Newmont Mining. Over 110 years of underground mining resulted in the development of nearly 3500 km of underground workings including backfilled and open stopes up to half a million tonnes in size. These voids significantly complicate blasting processes at KCGM, influencing blast movement direction and magnitude. Blast movement monitoring to improve mine reconciliations was identified as an improvement project in the business plan for the geology team in 2008. Following successful trials in 2008 to 2009, blast monitoring and translation of ore blocks were implemented as a permanent grade control program from late 2009 and is now part of the Management Operating System (MOS) of the mine. This paper presents a summary of results from the Blast Movement Monitoring (BMM®) data collected to date. Ore blocks at KCGM are translated primarily using BMM® data. This data is obtained from the BMM® system which measures the movement of a radio transmitter installed in a blast pattern from a preblast position to a post-blast position. The application of the data collected by the BMM® tends to be both mine site and blast specific. At KCGM, an average distance obtained from the BMM® data within a given shot is the primary method used for translation. In the case that BMM® data is unavailable, a theoretical movement vector established from Orica Shotplus with distances gained from the historical BMM® database is used. Data is presented in an ore loss and dilution exercise for a bench undertaken at KCGM to understand the potential effects on reconciliations. Improvements that have flowed from implementing blast monitoring include improved reconciliations when combined with other grade control improvement projects. The increase in liaison between the geology and blast personnel at KCGM has been a significant improvement gained from the implementation of the blast monitoring program. This has allowed a better understanding of blast movement and the effects on ore dilution and ore loss by the mine geology team. In addition, the discussion of blasting tie-in plans between geology and blasting personnel has been improved which leads to more favourable blasting practices that take ore movement into account.

Aug 22, 2011

By G Capes, L Morizzi, N Mitkas, E Jones, D Grant

This paper describes the mining setting for the sub-level open stoping (SLOS) mining method used at Olympic Dam (OD), and investigates the range of stope performance conditions encountered over 30 years of production, using a qualitative description of the factors influencing performance. Utilising a continuous improvement tool, the Plan-Do-Check-Act (PDCA) process, and a forward-looking rock mechanics program, the intent is to identify the key factors driving productivity and performance to create a stable and achievable long term mine plan.

Mar 15, 2021

Miners and mineral explorers are concerned at the increasingly hostile environment being generated towards their industry and their profession. There is little official or public recognition that the mining industry is essential for the maintenance of the country's standard of living; a large part of this hostile feeling is caused by the assumption that mining destroys large tracts of our attractive countryside. This paper presents a historic review of the impact on the countryside of the major land using groups commencing with the Polynesian migration. European farming practices, subsequent expansion of the urban dweller and the land management practices of the two Government Departments, Lands and Survey and New Zealand Forest Service who between them control half of the total land area, are discussed. Estimates of total land area to date, directly and indirectly affected by mining have been calculated and a broad estimate of 18 000 ha or 1/1500 of total land area is indicated; current annual mineral production requires some 240 ha. These gross areas take no account of subsequent land rehabilitation, its improvement upon the original in some cases and the recreational, historic and aesthetic areas gained. Comparisons are then drawn with some current land practices in New Zealand.

Jan 1, 1977

By Sherwin F. Kelly

SINCE we used Chief Buehler's name last year to give our annual report a semblance of respectability, we can follow the good precedent thus established by telling of the work his Missouri State organization has been carrying on, as reported by H. S. McQueen. Considerable value is set upon their magrletorneter working which has covered over 13,000 sq. mi.), for the indications it gives of the major structural features of the region. Numerous geological problems have been tackled Ly resistivity techniques, among which are the locating and outlining of filled sink deposits of sulphides, of iron ore, and of fire clay; tracing of faults and solution channels; mapping of the preglacial structural pattern; measurement of depth of overburden; and

Jan 1, 1937

By E. Hardwick, K. C. Sole, Y. Jurrius

"The Luilu cobalt plant at Kolwezi, Democratic Republic of Congo, has been operating since the late 1950s, using a conventional precipitation flowsheet for removal of impurities from the cobalt process stream. Most impurities are, however, incompletely removed using this technology. Copper and zinc, both of which quantitatively deposit at the cathode in the cobalt electrowinning process, are two of the main impurities contaminating the cobalt metal product. Ion exchange offers a modern approach to removing these impurities from the cobalt advance electrolyte.Following a laboratory testwork programme to identify a suitable ion-exchange system, an on-site pilot-plant trial, treating 1500 to 3000 L/d of electrolyte, was operated for a period of six weeks to optimise the operating conditions and to determine full-scale design criteria. Copper removal was carried out using a fixed-bed lead-polish configuration with the Lanxess iminodiacetic acid resin, TP 207. Zinc removal was subsequently carried out in a similar configuration using the Lanxess aminophosphonic acid resin, TP 260. The optimised system proved capable of removing both copper and zinc from 20 to 30 mg/L to <1 mg/L from plant electrolyte containing ~20 g/L Co. Selective elution allows co-loaded cobalt to be returned to the main circuit and value to be obtained for the copper impurity. The process shows operational and economic advantages over the traditional flowsheet. Full-scale implementation of the developed process is in progress and some design considerations are discussed."

Jan 1, 2014

By L Cooper, J Sharma, M J. Hendry

Thick clay tills below potash mine tailings and brine ponds are important natural barriers protecting fresh water aquifers in Saskatchewan. Centrifuge modelling was applied to assess geochemical processes and impacts of dilute brine (0.1 M NaCl) migration through clay till core samples obtained from non saline, unoxidised clay till at a mine site. At accelerated gravity of 876 + g, during each day of centrifuge modelling, flow driven through a 52 mm length core simulated transport through a 45 m thick clay over ~2100 years. Hydraulic conductivity, monitored continuously before and during brine permeation, was low and relatively constant (8.5 + 10-12 m/s), confirming that confining stresses prevent permeability increase. Core density and porosity measurements confirmed that reactive transport occurred under realistic in situ conditions. Breakthrough (defined by C/C0 = 0.5) of non-reactive Cl- occurred at 25 days. The slight delay for Na+ breakthrough, associated with small increases in Ca2+ and Mg2+ concentrations in the effluent were attributed to ion exchange, but carbonate reactions were relatively unimportant. Cation exchange analysis of core samples was inconclusive without corrections for porewater Na+ and carbonate dissolution. Geochemical processes that were observed during centrifuge modelling were successfully simulated using the 1D geochemical transport code PHREEQC. Solute transport was dominated by diffusion with limited ion exchange to delay Na+ migration. Brine would not break through a 45 m thick clay for tens of thousands of years. Based on these findings, the thick clay till at this site, if laterally extensive and undisturbed by drilling activity, is likely to act as an effective natural barrier to vertical brine migration over the long term.

Jan 1, 2003