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By J. Gurland

THE microstructure of sintered carbides consists of particles of metal carbides, such as WC and TiC, embedded in a metallic binder which is usually a cobalt—or nickel-rich solid solution. One of the important factors influencing the strength of the alloys is the degree of dispersion of the carbide particles in the binder matrix. While it is generally accepted

Jan 1, 1960

By M. Lindgren, M. Latva-Kokko

Process performance can be significantly influenced by proper design of hydrometallurgical reactors. Optimal reactor configuration is case specific and depends on process requirements such as reaction rate limiting factor and particle size distribution. Choice of materials and manufacturing methods also play important roles in highly corrosive and abrasive environment often involved in hydrometallurgical industry. In this paper performance of different reactor designs has been compared in some typical hydrometallurgical applications. Results show that significant improvement in energy consumption, gas utilization efficiency and equipment lifetime can be achieved with process specific reactor design.

Jan 1, 2014

By R. Mensah-Biney

The kinetics of gold-bromide loading onto activated carbon has been investigated in a batch stirred reactor. The amount of gold adsorbed by the carbon was correlated with time based on a second-order equation. The rate constant for gold-bromide species onto activated carbon ranged from 0.27 to 1.2 x 10-3 (kg/t)-l(min)-l from a solution containing 25 ppm of Au, with 0.8 g carbon per liter of solution at 30° C. The equilibrium saturation capacity (Q.) was 36±3.0 kg/t from the same system. The rate of loading increased with decreasing particle size, decreasing pH, increasing temperature, and decreasing concentration of gold in solution. The calculated activation energy E. was 8.8 kcal/mole, significantly higher than those reported for physical adsorption. The equilibrium saturation capacity (Q.) increased with increasing concentration of gold in solution, but was independent of other variables such as temperature, agitation speed, particle size and pH. These rate constants and equilibrium saturation capacity for the gold-bromide species are higher than those reported for the gold-cyanide systems.

Jan 1, 1996

Backfil ling of excavated Sub Level Open Stopes has been underway since March 1989 and as at December 1992 some 1 100 000 cubic metres of Cemented Aggregate Fill have been placed. During these three years significant developments in fill quantities, types and cost have taken place.Operational improvements have reduced the quantity of Cement Aggregate Fill by 40 per cent. These results have been achieved by:ò rescheduling stopes,ò designing smaller primary stope, and ò use of uncemented rockfill.Unit cost for Cement Aggregate Fill have fallen in the order of 50 per cent through:improving fill hole reli ability,simplified barricade construction procedures, reducing the cement content,ò substituting dune sand for deslimed mill tailings, ò improved maintenance at the Backfill plant, and ò renegotiated site freight agreement.This paper will review the historical developments of backfill use at Olympic Dam.

Jan 1, 1993

This Bureau of Mines report on underground mine communications addresses methods and equipment to meet the communication requirements of working sections and places of coal and metal-nonmetal mines. A review of the status of trapped miner detection is also presented.

Jan 1, 1977

By A. Kotze, D. Messina, E. Nagels, Y. Cryns, S. Arnout

The FlashPhos process aims to recover white phosphorus (P4) from sewage sludge by drying, flash combustion/gasification, and carbothermic refining steps. This study evaluates the material behaviour of sewage sludge ash melting and reduction in a refining furnace for the novel FlashPhos process. Thermodynamic modelling in FactSage 8.2 is combined with experiments from a tube furnace to determine the possible phosphorus recovery and minor element behaviour. For the two studied sludges, a yield of 40% and 75% white phosphorus is achieved after 1 hour at 1600°C, corresponding with a 60% and 25% loss to the metal phase. This is slightly above the calculated equilibrium yield of 28%–73%, which depends mainly on the Fe/P ratio of the sludge. Temperature is found to have a significant influence on the final phosphorus yield when leading to incomplete melting of the ash. A clean slag is produced in the process free of heavy metals making it suitable to be used as a cement-like binder material. The main heavy metals that co-evaporate with the phosphorus are Zn, Pb, As, Sb, and Sn. Additional processing steps will be required to remove these to produce a pure P4 product. The metal alloy consists of mostly Fe and P with smaller amounts of other components such as Mo, Cr, Cu, Mn, Sn, Sb, and V. The final slag consists of CaO, SiO2, MgO, and Al2O3 with virtually complete removal of P and heavy metals.

Oct 2, 2025

By Jozef Descour, Kazunori Nishioka, David M. Neil

Designers, engineers, and contractors are using three-dimensional seismic tomography for geotechnical site investigations and during tunnel excavation for hard rock and soft ground applications. Utilizing multiple types of seismic signals produced by a TBM, drill, or impact breaker, the reflection of different velocity features are processed into a holographic image of the actual structure to be encountered. The Mill Creek Phase 3 alignment in Cleveland, Ohio, was imaged to define existing conditions along a 1,200-ft section of a proposed 6.1-m (20-ft) diameter CSO tunnel and, specifically, a zone of expected anomalous conditions where drilling was inconclusive. In Japan, Kajima Corporation used TRT™ to image a number of tunnels including the Fujikawa and Kanaya tunnels in a combination of methods to map structural features along the alignment.

Jan 1, 2001

By T G. Neville, G Terrey, J Burns

This paper explores recent industry training programs and lessons for supervisors. The Belbin Team Role model was used to increase participants’ awareness of behaviour and its application. The application of the Belbin model to underground, open cut mine and quarry supervisors is discussed.The key to team success may rest with the expertise and experience of its members, but increasingly effectiveness depends on how team members understand, acknowledge and support each other’s behavioural strengths. Discovering strengths is a challenge, both for their measurement and for the encouragement of team members to use the knowledge of themselves and others in the team. Using behavioural models provides a constructive approach and a language for supervisors as they build personal motivation and engagement.Prima facie, the mineral industry’s work may be too vigorous for teams and their managers could be more prone to use ‘solo’ or traditional management styles. Managers and supervisors must know when work allocated to a team is appropriate or where individual effort should be applauded and rewarded. For practical people with well-developed technical skills, improving the soft skills necessary for a supervisor requires some reflection and effort. The Belbin behavioural model can be an effective tool for recognising characteristics that can assist teams to be more productive.Experiencing the Belbin Team Role model as part of an industry qualification is important for supervisors studying to refine their team leadership skills. Data are available for participants to assess the nature of their teams and to confront the appropriateness of the behavioural mix for the work of the team and its individual members.So what are the next steps? All team development must have a place in the strategic thinking and plans of the enterprise. This needs a visible presence of senior managers and supervisors in managing a team culture with practical links to workplace priorities and professional development with continuous improvement.CITATION:Burns, J, Terrey, G and Neville, T G, 2016. Supervisors and teams at work, in Proceedings International Mine Management Conference, pp 125-138 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 22, 2016

By Peter C. Hayes

"The high temperature reduction of solids through the use of reactive gas atmospheres has application in a wide range of industrially important processes. Whilst significant advances have been made in understanding and describing these processes, some key aspects of the chemical reactions and reaction mechanisms operating in these systems, for example, the transformation from metal oxide to metal, remain poorly understood. A number of different product morphologies have been identified in these reaction systems and the reaction rates have been shown to be critically dependent on the product structure.Theoretical examination of the elementary process steps taking place in the region of the gas/metal/metal oxide interface, combined with electron microscope studies of the resultant product microstructures, have enabled the key process and material variables responsible for the development of the various product morphologies to be identified. By considering i) established criteria for the stability of moving interfaces in a thermodynamic potential gradient, ii) the relative rates of chemical reactions on the oxide and metal surfaces, and iii) key process phenomena and physico-chemical properties of the solid phases, the mechanisms and conditions for the formation of various product morphologies are identified. Interestingly the analysis points to direct analogies between these phase transformations and, the phenomena and microstructures observed in metal solidification, and the potential to develop generic models of these fluid/solid reaction systems."

Jan 1, 2013

By John Newby, Ulf Gwildis, Ken Massé, Guillaume Roux

How to connect an effluent conveyance tunnel to riser shaft and diffuser arms of an outfall system is dictated by the ground conditions, which ideally include rock or soil strata of low permeability. Where such favorable conditions are beyond reach, both the complexity of designing and the risk of constructing this crucial system connection increase disproportionally. This paper describes the considerations that went into the approach of connecting a 5-m-diameter TBM drive with the in-river riser shaft of the Annacis Island WWTP New Outfall System in the highly permeable Fraser River sands at hydrostatic pressures exceeding 3 bar.

Jun 23, 2024

By C. Tissot, R. Palmer

"Due to the low concentrations of gold, direct measurement of gold concentration in ore on belt has not been seriously considered to now. Pre-concentration or sorting strategies have largely consisted of particle sorting based on secondary characteristics such as colour, which can be successful in select cases. CSIRO has produced sample measurement results using gamma activation analysis of ~300 gm samples with accuracies of around 30 ppb at best. With this encouragement, a feasibility study into gold ore measurement on belt for the purpose of sorting pods of gold ore has been undertaken. The study described here included, prototype design options with existing industrial Linacs, extensive Monte Carlo modelling of measurement sensitivity and shielding, further sample measurement, a study of the interaction of target measurement accuracy and sorting efficiency, and a rough estimation of potential economic benefit. The projected model sensitivity of around 0.1-0.15 ppm (1 standard deviation) in 10 seconds for 1 ppm average feed result in good bulk sorting performance and intriguing economic potential.INTRODUCTION Pre-concentration or sorting strategies for gold ores have largely consisted of particle sorting based on secondary characteristics such as colour or density, which can be successful in select cases (Klein, 2010). No method is available to measure gold content for sorting in particles or even in bulk on belt, principally due to the low concentrations of gold present. In fact, in many cases it is difficult to do rapid bulk grade measurements of base metal ores with concentrations many orders of magnitude higher. By a fortunate quirk of nature gold is particularly amenable to gamma activation analysis (GAA). CSIRO has performed extensive work in GAA of samples of crushed ore (Tickner, 2017). This has resulted in the Photon AssayTM technique that is currently being commercialised through the CSIRO spinoff company Chrysos. The technique relies on the recent availability of industrial high intensity X-ray sources such as Linacs which are currently being used in industry for security, medical and sterilisation applications. This development has led to CRC ORE funding a feasibility study to determine whether on-belt measurement of gold concentration is possible at a rate and accuracy sufficient to be useful for bulk sorting, where pods of ore are diverted rather than individual rocks. The study in the first instance is based on Monte Carlo modelling that has successfully predicted the performance of the sample based gold measurements. As well as the measurement feasibility consideration was also given to the likely heterogeneity of gold ores and hence the degree to which useful separation could be achieved. This is then tied to a back of the envelope evaluation of the order of magnitude economics of bulk sorting in an example deposit."

Jan 1, 2017

By H. Matsuda, T. Iwashita, H. Awata, H. Liwei, D. Hirabayashi, Y. Saito, S. Ozawa, Y. Goto

"The present study is concerned with investigating the effect of chemical treatment on enhancing the HCl absorption capacities of coal burnt ash and slag. It was found that the HCl absorption capacity of coal burnt ash discharged from fluidized bed combustor was improved by hydration with water and 5% polyethylene glycol solution. This phenomenon was based on an increase of the specific surface area of treated coal burnt ash. The HCl absorption capacity of hydrated ash with polyethylene glycol solution was almost equivalent to that of standard CaO and Ca(OH)2. In particular, the specific surface area of hydrated ash with polyethylene glycol solution was found to be 19 m2/g, which was more than over eight times larger than that of raw sample. Hydrated slag treated with lON sodium hydroxide solution also showed high HCl absorption capacity, with highly improved surface area. It was found that the absorption capacity of slag for HCl depended on the treatment time, showing the maximum absorption capacity for 12 hours of hydration treatment.IntroductionA large amount of coal burnt ash, slag and dust are discharged from such industrial processes as coal combustion and metal refinery etc., and it becomes an serious problem to recover and diminish these solid wastes because of the shortage of dump sites and subsequent metal elution to the environment. Figure 1 shows the present situation of reutilization of coal burnt ash and slag in Japan [1,2]. It is shown in this figure that these solid wastes are recycled as materials in the fields of earthwork, agriculture and forestry etc. A part of these solid wastes, however, is still dumped to landfill. To decrease this dumped amount, the development of environmentally friendly reutilization technique for these solid wastes is of great importance."

Jan 1, 2000

By Terrence R. Lejcher

Strip mining has played a key role in the production of coal used to produce energy in this country. About 56 percent of the 1.3 x 106 hectares (3.2 x 106 acres) that had been disturbed by surface mining as of 1965 can be attributed to stripping (Udall, 1967). The runoff from these stripped areas is usually heavily polluted with high concentrations of total dissolved solids, iron, aluminum, manganese, sulfates, and has low pH values with high acidity. Another problem of a most serious nature in our large cities is the volume of treated solids to be disposed of after sewage treatment. Chicago is presently producing about 664 metric tons/day of dry weight solids (Horn and Earles, 1968). Disposal methods most commonly used include lagooning, incineration, and landfilling. The high cost of land in an urban community is prohibitive of lagoon storage. Incineration and landfill disposal create air and water pollution problems. Many countries including Australia, England and Israel have long realized the value of sewage solids if they are recycled back to the land. In the United States, the value of such solids in reclaiming strip mined land has been recognized by relatively few people. This paper is concerned with the use of anaerobically digested sludge to reclaim strip mined land.

Jan 1, 1972

By T. Thriveni, Ch. Ramakrishna, Ahn Ji Whan

Numerous reports and researches address the various environmental issues about the municipal solid waste incineration waste management of heavy metals and other particulate matters with the range of 10–2.5. Although in many developing and industrialization countries land fill with the disposal of municipal solid waste, open incineration has become a common practice. Bottom ash contains heavy metals including particulate matters. The investigation of size distribution for the heavy metals and particulate matters in the bottom ash is essential. However, ultra-fine particle size and heavy metal stabilization are the most important requirements for ecofriendly by products. There are wide variety commercial technologies available for monitoring PM 10, PM 2.5 and ultra-fine particles. In this paper, we reported the studies on physical and chemical characteristics of municipal solid waste incineration (MSWI) bottom ash containing particulate matter whose particulate sizes are lower than PM10, PM2.5 and heavy metal stabilization method by carbonation were investigated.

Mar 1, 2017

By E. H. Dix

All commercial aluminum contains small percentages of copper, iron, and silicon as unavoidable impurities. The purest metal obtainable commercially, special grade high purity ingot, contains a maximum of 0.50 per cent. impurities of which the usual minimum amount of copper is 0.01 per cent.; silicon, 0.12 per cent.; and iron, 0.20 per cent. This grade is too costly for most purposes. The two standard grades, Nos. 1 and 2, containing a minimum of 99.0 and 98.0 per cent. aluminum, respectively, are more generally used. Other grades of secondary aluminum often contain as high as 3 or 4 per cent. of impurities, which include 1 per cent., or more, of zinc. Specifications for high-grade aluminum-casting alloys generally allow a maximum of 1.7 per cent. for total impurities. The S. A. E. Specification No. 33, which is intended to cover alloys made from secondary aluminum ingot, gives the iron maximum as 1.5 per cent. and the maximum for silicon (including manganese and tin) as 0.75 per cent. The effect of even relatively small amounts of impurities on the physical properties of ingot aluminum is shown by the following cornparison of two lots of aluminum, which may be taken as representative of special grade and grade No. 2 ingot, respectively. AnalysEs Special Grade, Gbade No. 2, Per Cent. PeR CBnt. Copper................................. 0.01 0.32 Silicon................................. 0.12 0.32 Iron................................... 0.42 0.82 Aluminum.............................. 99.45 98.54

Jan 1, 1923

By A. H. Grobe, F. N. Rhines

AT elevated temperatures the oxide of silver is unstable in the air at atmospheric pressure, consequently no external oxide scale forms upon pure silver under conditions of high-temperature annealing When small quantities of certain alloying elements are present in the silver, the formation of a thin external scale is possible' and in addition there may form a subscale composed of the oxide of the solute element precipitated within the body of the silver Norbury2 and Leroux and Raub3 have reported internal oxidation (subscale formation) in alloys of silver with 2, 7 5, and 30 per cent of copper The presence of the subscale is believed to be responsible, at least in part, for the objectionable "fire mark" in Sterling silver' Several other alloys of silver, after oxidizing heat-treatments, are known to exhibit undesirable polishing characteristics that may be the result of internal oxidation Except for the absence of an external scale of silver oxide, it is to be anticipated that silver alloys will prove to be very similar in their oxidation behavior to the alloys of copper, the oxidation characteristics of which have been studied in some detail 5,6 The present research confirms this anticipation The oxidation of a series of 20 dilute alloys of silver has been studied metallographically, some types of subscale not encountered among the copper alloys have been found Instances of internal oxidation in alloys of most of the metals of the I-b and VIII groups of the periodic system are on record, but evidence of this type of oxidation in alloys of the metals of the intermediate groups is lacking A number of the metals of the intermediate group, among them cadmium, lead, tin, and zinc, appear to provide the conditions essential to subscale formation, i e , they form oxides with a relatively low negative free energy of formation, they dissolve other metals that form more stable oxides, and, presumably, oxygen will diffuse through them In a study of 4o alloys of these white metals only a few cases of internal oxidation have been found The probable reasons for this difference in behavior will be discussed presently EXPERIMENTAL PROCEDURE Silver -The silver alloys employed in the oxidation studies were prepared in heats of 30 grams each from high-purity silver (99 993 per cent Ag)* and the purest avail-

Jan 1, 1942

By E. H. Dix

All commercial aluminum contains small percentages of copper, iron, and silicon as unavoidable impurities. The purest metal obtainable commercially, special grade high purity ingot, contains a maximum of 0.50 per cent. impurities of which the usual minimum amount of copper is 0.01 per cent.; silicon, 0.12 per cent.; and iron, 0.20 per cent. This grade is too costly for most purposes. The two standard grades, Nos. 1 and 2, containing a minimum of 99.0 and 98.0 per cent. aluminum, respectively, are more generally used. Other grades of secondary aluminum often contain as high as 3 or 4 per cent. of impurities, which include 1 per cent., or more, of zinc. Specifications for high-grade aluminum-casting alloys generally allow a maximum of 1.7 per cent. for total impurities. The S. A. E. Specification No. 33, which is intended to cover alloys made from secondary aluminum ingot, gives the iron maximum as 1.5 per cent. and the maximum for silicon (including manganese and tin) as 0.75 per cent. The effect of even relatively small amounts of impurities on the physical properties of ingot aluminum is shown by the following cornparison of two lots of aluminum, which may be taken as representative of special grade and grade No. 2 ingot, respectively. AnalysEs Special Grade, Gbade No. 2, Per Cent. PeR CBnt. Copper................................. 0.01 0.32 Silicon................................. 0.12 0.32 Iron................................... 0.42 0.82 Aluminum.............................. 99.45 98.54

Jan 1, 1923

By Douglas R. Piteau

"Assessing the stability of a slope cut in rock is basically a problem of engineering geology - geology, because it involves a sound understanding of the important aspects of geology, such as geological structure, ground water, weathering and other natural phenomena, which all relate to or exist in a geological environment, and engineering, in that quantitative evaluations and calculations are necessary, these being based on mechanics and relating to the strength of the geological materials and the forces causing instability of the slopes. The engineering geologist must make every attempt to. provide, in a quantitative way, information on those geological factors which are necessary for making calculations of the probable stability of the slope. These include numerical assessments of quantities relating to the characteristics of structural discontinuities, rock types, topography, hydrogeology, tectonic history and other environmental factors. Based on the development and extension of these general principles, both preliminary and final slope stability studies of some open pits in South Africa, Swaziland and Zambia have been conducted. Some of the basic concepts and techniques developed to carry these studies out are described."

Jan 1, 1972

By L S. Shekhawat, M P. Roy, R K. Paswan, P K. Singh, A Joshi

Blasting in the mining industry is being transformed, and can no longer be treated as an art or a practice purely dependent upon experiences of individuals. Examples of key drivers that have demanded consistent and more accurate blast results are initiatives to control pit-wall damage to help mine steeper pit slope angles, to control damage to underground opening operating in close vicinity of the open pit mine. Such situation exists at Rampura Agucha open pit lead zinc mine, which is producing 5.7 Mt/a of ore and has started its underground part, which is slated to produce initially 2–2.4 Mt/a and 4.5 Mt/a in the near future. The open pit mine is currently working at 326 m depth and is designed to reach 421 m deep. It has been planned to operate the underground mine maintaining 50 m parting from the planned ultimate level of the open pit mine.Presently, open pit and underground mines are being operated simultaneously. The present average depth of underground working lies between 370 and 410 m below the surface level. Sometimes explosives up to 95 978 kg are being detonated in a blast round in open pit mine. These blasts are often apprehended as a danger to the safety and stability of underground openings. It was decided to document the impact of open pit blasting in the openings of underground workings, so that preventive measures may be taken for the safety and long-term stability of the underground mine. The impact of 86 open pit blasts has been documented in the underground openings and 258 blast vibration data has been recorded. The vibrations were recorded simultaneously in the roof, side walls and at floor levels. The highest levels of vibrations were recorded in the roof and the lowest levels at the corresponding floor levels. The pillars experienced lower level of vibrations than the roof. Blast designs were optimised at open pit mine to control vibration in view of long-term safety and stability of the underground openings. The vibrations generated due to detonation of explosives with shock tubes and electronic delay detonators have been recorded in underground openings for comparative assessment. Ground vibration recorded at roof, pillar and floor were analysed separately and threshold value of the vibration for the safety of underground workings has been determined based on the rock mass rating of the roof rock.CITATION:Singh, P K, Roy, M P, Paswan, R K, Shekhawat, L S and Joshi, A, 2015. Protection of underground mine structures due to adjoining open pit mine blasting, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 279–288 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Pramila Misra, Jibardhan Meher, Debadutta Das

The concentrated coal-water slurry has been receiving considerable attention recently due its ability to replace fossil fuels. Attainment of stable and concentrated slurry has been succeeded so far through several physical and chemical techniques. The present article reports the formulation and stabilization of a highly concentrated coal-water slurry formed from five varieties of non-coking coals with variable ash contents obtained from Eastern part of India, employing three varieties of starch esters, such as starch benzoate, starch formate, and starch carbamate as dispersant. The apparent viscosity of the modified coal-water slurry has been measured by varying coal loading, dispersant percentage, pH, temperature, etc. The apparent viscosity of the slurry has been found to be decreased substantially on addition of 0.8% of adsorbate in the slurry. The particle-particle interaction has been considerably decreased and stable concentrated coal-water slurry containing high weight fraction of coal (61.5-63.5%) has been achieved in each case. The slurries stay in a non-settling form for about a month with viscosity in a permissible low range. The coal-water slurry has been found to behave as a non-Newtonian liquid. Comparison of the zeta potentials of the naked and modified coals evidences that adsorption of the dispersants at coal-water interface results in inhibition of the agglomeration of coal particles through mostly steric repulsions.

Jan 1, 2014