Search Documents

By T. Gerritsen, R. MacRosty, R. Pula

For several years Hatch has been installing fibre optic temperature sensors on the copper cooling elements of smelting furnaces to improve monitoring capabilities in critical locations. The metal/matte tapblock is a key area to monitor in the furnace as it undergoes severe wear from the molten material repeatedly drained through it. The high wear rate around the tapblock means downtime is necessary to perform refractory repairs. A good understanding of the tapblock condition allows the operation to maximize safety and production; consequently the metal/matte tapblocks have been the focus of this study. Fibre optic technology allows the installation of numerous sensors in locations that are very sensitive to refractory thickness, thereby providing information previously unavailable with traditional measurements. The transient nature of the thermal response to tapping and the three-dimensional geometry of the tapblock confound the interpretation of refractory thickness from temperature measurements. This paper focuses on the analysis of both plant data and thermal modelling simulations and details the progress made in relating the temperature measurements to the refractory thickness in front of the copper tapblock.

Jan 1, 2014

By D. Z. Wei

Amine collectors with different structures and length of carbon-chain have been widely used in oxide minerals flotation. In this paper, we synthesized one kind of binary amine, N-dodecylethyl- enediamine, and studied its flotation performance. From the results, we can see N-dodecylethylenediamine which has excellent frothability, is a new type of chelating surfactants. And it also has fine catchability to quartz and hematite. The recoveries of quartz and hematite increase with the augment of N-dodecylethylenediamine concentration. When the dosage of collector reaches 100g/t, the recoveries of quartz and hematite achieve 95.30% and 87.89% respectively. Meanwhile, the influence of pH on the flotation recovery of hematite is studied and test results showed that, as pH increases, the flotation recovery rises until pH=9. And the recovery reaches its maximum in alkalescence. The collector has better flotation capability to quartz than to hematite. And the maximum recovery of quartz is gained in alkaline media, which reaches 97.87%. Finally, the flotation mechanism of N-dodecylethylenediamine is discussed through the measurement of infrared spectroscopy.

Jan 1, 2014

By Wilky Desrosin, Alicia E. Ares, Carlos E. Schvezov

"In the present research the horizontal directional solidification Zn-Sn alloys (Zn-4wt. %Sn, Zn- 6wt. %Sn, Zn-10wt.%Sn and Zn-30wt.%Sn) was carried out by extracting heat in two opposite directions. For this purpose, ceramic molds, a muffie, a horizontal furnace with two heat extraction systems at the ends, a measurement, acquisition and recording temperature system, eight K-type thermocouples and an electronic recorder were used. The main parameters involved in the columnar-to-equiaxed transition, CET, were: the moment of start and end of solidification at each position under consideration, cooling rates, the average temperature gradients and critical temperature gradients at the CET, the average speed of liquid and solid interphases left and right, advancing in opposite directions. Also, solidification kinetics was found to be different between horizontal solidification two-way heat extractions, with preliminary results of the vertical unidirectional solidification. In the solidification experiments, the velocity and accelerations of the liquidus and solidus interphases usually occurs at the end solidification zone of the samples.IntroductionSolidification of metal alloys, which starts in the external equiaxed region (chill), results in two basic types of structures in a single solidified alloy sample: columnar and equiaxed. The presence of both structures indicates the occurrence of the colunmar-to-equiaxed transition phenomenon[!].Studying the colunmar-to-equiaxed transition, CET, is of great technological interest for the evaluation and design of the mechanical properties of the solidification products. To this end it is necessary to understand the mechanisms by which it occurs. As found in previous studies [2-5], the CET occurs by competition between columnar and equiaxed growth. Mainly is controlled by the parameters of casting, such as the alloy composition, the density of the present nuclei in the liquid, the cooling capacity of the metal I mold, and the degree of convection in the liquid [7-10]."

Jan 1, 2014

By J. K. Williams, M. P. Wells

"As part of the planning system at each division of Nchanga Consolidated Copper Mines, Limited, the Mine Planning Department is required to produce a detailed production schedule for each shaft.Because of the difficulties in producing a schedule which satisfies all the mining constraints, and because of the large clerical effort involved, the full range of possible schedules can never be considered.It has been found possible to produce a schedule using linear programming which satisfies the majority of the many varied mining constraints. Computer programs have been written to enable the mine planning department to use this mathematical system without assistance.The system has a large degree of flexibility to enable the planner to include conditions which cannot be incorporated readily in the linear program. This system permits the more efficient production and evaluation of schedules and reduces the amount of clerical effort."

Jan 1, 2014

By Y. B. Zhang

China is rich in iron ore resources, but most of these ores are low-grade, polymetallic and refrac-tory ones. Furthermore, with the rapid development of chinese iron & steel industry, the comprehen-sive recovery of these ores is becoming more and more important. The tin, zinc-containing complex iron ores are typical polymetallic and intractable ones, and great reserves of them are found in China. At present, they have not been efficiently utilized. In this paper, based on the investigation of basic physicochemical properties of the tin, zinc-bearing iron concentrates, taken from a mineral processing plant, the mineralogy reason that these concentrates are so intractable and refractory is found out, using advanced microscopic testing methods, such as optical microscope (OM), Scanning Electronic Microscope (SEM), X-ray diffrac-tion (XRD), etc. It is found that the symbiotic relationship of iron, tin and zinc metallic minerals are very complicated, and magnetite in the concentrate is closely symbiotic or enwrapped by fine cassi-terite and sphalerite. So it is difficult to separate tin and zinc completely from the iron concentrates by simple regrinding and physical separation method. This investigation provides theoretical guid-ance for developing new approaches for utilizing these concentrates.

Jan 1, 2014

By Adriaan van Seters

"Abstract The content of Eurocode 7 – Part 1 and Part 2 – with respect to piled foundations is outlined. The important role of pile testing is presented and the derivation of the characteristic value of pile bearing resistance is explained. Recommendations for the use of correlation factors are given. The ongoing work of the Evolution Groups on piling is to prepare a revision of Eurocode 7 after 2019. Future topics and changes are highlighted.General outline of pile design by Eurocode 7In his paper for this conference Frank (2014) outlined the various aspects of standardisation for pile foundations, which involves Eurocode 7 as leading for pile construction in Europe. Standards for pile testing and execution of piling works were established in the last 15 years.This paper focuses on the design of piled foundations according to the design code Eurocode 7, which consists of 2 parts:EN 1997-1 Geotechnical design - Part 1: General Rules (CEN, 2004);EN 1997-2 Geotechnical design – Part 2: Ground investigation and testing (CEN, 2007) In Eurocode 7-1, Section 7 – Pile Foundations - deals with the design of piles. The safety concept for pile design is given in Section 2 – Basis of Geotechnical Design - for the three Design Approaches.In Section 7 presents the design of piles according to four methods:1. Results of static load tests2. Empirical or analytical calculation methods3. Results of dynamic load tests4. Observed performance of a comparable pile foundation.Guidelines for the ground investigation for piles is provided in Eurocode 7-2, Annex B.3. In the Annexes of Eurocode 7-2 examples of analytical methods to determine the bearing resistance of a single pile based on the results of various ground investigation techniques are given. Thus calculation models are presented based on design using the results of Cone Penetration Tests (D.6 and D.7) and Pressuremeter Tests (E.3). The Annexes of Eurocode 7-2 are informative.For the interpretation of Eurocode 7, reference is made to Frank et al (2004) and Bond and Harris(2008)."

Jan 1, 2014

By G. R. Forbes

Flotation froth machine vision systems provide consistent real-time measurements pertaining to the state of the flotation cell being monitored. Typical measurements include froth velocity, froth colour, froth texture and froth stability. This paper presents the results from test work conducted on the molybdenite rougher circuit at the Kennecott Utah Copper Concentrator during February 2006. Machine vision results show that it is not possible to accurately determine bubble size distribution information for the molybdenite froth, despite using state-of-the-art methods. Instead, it is necessary to make use of texture measurements to classify the various different froth states. Numerous combinations of texture measurements and classifiers are used to determine the best combination. Results show that the Fourier ring based texture measurements perform the best when both K nearest neighbour and Gaussian mixture model classifiers are used. The concentrate grade of the flotation cell is modelled using combinations of froth velocity and froth texture descriptors. The results show that by using a linear combination of these descriptors rather than either one by itself it is possible to account for a much larger percentage of the variation observed in the concentrate grade data. Adjusted R2 values of 92% and 84% are achieved when modelling the copper and the molybdenite concentrate grade respectively.

Jan 1, 2014

By Tamara Matveyeva, Tatiana Ivanova, Nadezhda Gromova

"The paper presents the results of study of the sorption and flotation properties of the reagents of plant origin - tannin and natural extracts of the oak bark and stems of plants, with a view to their application as a low-cost environmentally friendly modifiers of iron sulfide flotation for the recovery of minerals containing precious metals. The technique of preparation of plant extracts with a fixed content of extractable tannins has been developed.The mechanism of flotation reaction of tannin extracts has been identified as based on their adsorption on the surface of pyrrhotite and arsenopyrite to form strong complexes with iron (III) at concentrations below micelle concentration. It has been found that adsorption of plant extracts occurs without displacement of primarily adsorbed xanthate, and preliminary adsorption of xanthate did not preclude fixation of tannin on the mineral surface.It has been shown that plant extracts having hydrophilizing properties at low concentrations could be applied as selective depressants for pyrite, pyrrhotite and arsenopyrite in a weakly acidic, neutral or weakly alkaline medium. The use of plant modifiers could help to increase the quality of gold- and platinumcontaining concentrates and reduce the ecological impact on the environment."

Jan 1, 2014

By Yiling Zhang, Paul A. Salvador, Gregory S. Rohrer

"Photocatalysis utilizes solar energy to produce hydrogen by splitting H2O. When a thin film of photocatalyst TiO2 is supported on a ferroelectric BiFeO3 substrate (band gap ~2.5 eV), the TiO2/BiFeO3 heterostructure is capable of photochemically reducing Ag+ to Ag0 in aqueous solutions under blue light with enhanced efficiency. The observation of spatially selective silver patterns on surface of the heterostructure after reaction suggests that photogenerated electrons and holes in ferroelectric BiFeO3 are driven in opposite directions to reduce their chance of recombination. Comparisons of the amounts of reduced silver on TiO2 film grains with distinct phases/orientations show that the reactivity is mildly preferential on anatase TiO2 phase and does not strongly depend on crystallographic orientation of BiFeO3.IntroductionTitania (TiO2) is capable of photocatalytically converting H2O to hydrogen and oxygen under the irradiation of ultraviolet light. [1, 2] One of the limiting factors for titania to be used as an effective photocatalyst is its band gap. Because the absorption edges of rutile and anatase titania are at 3.0 eV and 3.2 eV, respectively, they can only absorb light in the UV portion of the spectrum, which is about 3% of the available solar energy. [3-5] This limitation has motivated attempts to modify the absorption edge of titania so that it can absorb visible light.One strategy is to substitute a portion of the titanium and/or the oxygen with other atoms. There are numerous reports on visible light absorption of titania by doping and co-doping of Cr, V, Mo, Sb, Fe, N, S, C, and F. [6-34] Another strategy is to add an adsorbed molecular species that absorb visible light and donate an electron or hole to the titania, such as organic dyes [33, 35, 36] and Ce3+/Ce4+. [37, 38]The strategy in the present work takes the approach of depositing a pure titania thin film on a visible light absorbing substrate BiFeO3 to induce visible light activity of the heterostructure. BiFeO3 is a semiconductor with a band gap of about 2.5 eV [39-41] and is photocatalytically active in visible light. [42, 43] It is also ferroelectric with spontaneous polarization along pseudo-cubic <111> directions of 6.1 µC cm-2. [44] The spontaneous polarization gives rise to internal electric fields that drive photogenerated charge carriers, namely electrons and holes, in opposite directions to reduce their chance of recombination. [45-47] Additionally, the separation of electrons and holes leads to the spatial separation of reduction and oxidation half reactions so that the back reaction of intermediates is also suppressed. Such charge carrier separation has been reported in TiO2/BaTiO3 heterostructures with UV light illumination. [48-51] The TiO2/BiFeO3 heterostructures in this work combine both advantages of the relatively narrow band gap and the internal fields in BiFeO3 to enhance the overall photocatalytic activity."

Jan 1, 2014

By Joseph Daly

This is the detailed evaluation of the establishment and implementation of an ‘oil recycle plant’ located on site at Boggabri Mine NSW, (Australia); its production, its use and its value. Also discussed in detail is the quality of the raw material produced, and the process and initial application of this raw material generated as well as the analysis of such, as a component within bulk explosive as applied to the mining industry as compiled during analysis. Laboratory analysis prior to field testing is also discussed including independent external laboratory analysis as well as the environmental benefits and a business case for recycled oil in blasting. This paper includes technical details of the product including densities, velocity of detonation and other associated key performance indicators. The intention is to off-set the amount of Distillate (Diesel) utilised as a component of bulk explosives, with a raw recycled oil and thus reducing both the environmental carbon footprint as well as production costs with regard to introduced petrochemical production and utilisation; an oil that is an existing recourse of controlled waste not only difficult but expensive to otherwise dispose of, whilst keeping the entire process ‘on-site’. Though recycled oil in blasting is not an entirely original idea, the key feature of this paper is the ability to complete the entire process on-site.

Jan 1, 2014

By N. Henderson, J. Weyer, J. F. Brune

"The mining industry worldwide is currently facing a significant restructuring process. In most underground mines, widespread mechanization of the mining processes increases production while reducing staff numbers. At the same time, mining depths as well as the lateral spread of the mine workings are increasing. This ever-changing mining environment requires sophisticated solutions for the design and operation of underground mines. In fact, a reduced number of mining engineers is taking responsibility for everincreasing mine operations. This applies not only to the excavation of the minerals, but also to all other aspects of the mining operation, including health and safety, disaster management, and mine rescue organization.Most mining engineering graduates entering the industry lack experience in mine emergency management. Young engineer trainees must learn mine emergency management and rescue work in addition to their normal training experience on the job. Often, and unfortunately, emergency and rescue training at different mining companies is not carried out to the highest level and standard and with the best possible training outcomes. The tasks and challenges a young engineer faces while being trained in a new position do not leave much room for additional training in mine rescue and emergency management. At the same time, experienced, ’old hands’ are retiring and cannot easily be replaced due to limited graduation numbers.Strategies are being developed at mining universities worldwide to train mining engineering students in handling mine emergency situations and to provide hands-on experience for managing potential accident and disaster scenarios underground. Two of these strategies, from the USA and from Central Europe, are presented in this paper. These specific strategies have to be seen under special consideration of the local and regional boundary conditions, but might serve as case studies for mining schools and universities in other countries."

Jan 1, 2014

By Bill Kendall

"In coal mines, handheld air, electric and hydraulic powered drills are used along belt conveyors, in single entry development, in entries where there are obstructions, and in longwall recovering bolting. In hard rock mines, pneumatically powered jackleg drills are typically used in narrow vein mining. Drilling and bolting in narrow confines has traditionally been performed with pneumatically or hydraulically powered hand-held drills or newer electrically powered hand- held hammer drills due to their low cost, simplicity of operation, and extreme flexibility due to their small size. Mechanized equipment has typically been too large, too expensive, inefficient due to the confined space, and too restrictive due to lack of flexibility for use in narrow confines.Although the handheld equipment is effective, it requires operator exposure to certain inherent hazardous conditions in use. These include falling rock from the roof, rib and face; tripping hazards; bending twisting lifting hazards; high noise levels and chemical fumes from the pneumatic exhaust. The operation of the hand held equipment can adversely affect the long-term health of the operator - continual jackleg operation frequently results in longterm damage to hearing, shoulders, arms and wrist joints and back injuries. This results in a reduction in life style for the operator and higher personnel turnover rates for the mining company.Hand-held drills also typically have limited thrust and torque capability that limits their ability to push long resin bolts, inadequate torque to properly install resin bolts or to properly torque mechanical or tensioned rebar bolts. Hand-held drills do not offer any type of protection for the operator from roof or rib falls. They do not offer any means for handling roof or rib mesh. Since the operator stands on the ground the maximum safe drilling height without use of a ladder or "riding the drill" is limited to 2.44 m (8 ft)."

Jan 1, 2014

By Peng Zhang

In previous research, the laminated overburden model from the LaModel program was effectively integrated with Analysis of Retreat Mining Pillar Stability (ARMPS) through ARMPS-like input to create a laboratory version of the new ?ARMPS-LAM? program. This program takes the basic ARMPS geometric input for defining the mining plan and loading condition, and then automatically develops, grids, runs, and analyzes a full LaModel analysis of the mining geometry to output the section stability factor (SF), all without further user input. The initial ARMPS-LAM results were encouraging with a case history classification accuracy of 55% to 71%; however, a few of the input variables that were nominally included in the SF calculation showed independent significance in the classification accuracy. Therefore, in order to further improve the accuracy of the ARMPS-LAM program, an investigation of the SFs calculated by the new ARMPS-LAM program and the ARMPS program is detailed in this paper. The initial results of a linear correlation between the ARMPS-LAM SF and the ARMPS SF showed a strong correlation (R2 = 0.88), with the ARMPS-LAM SF averaging about 8% higher. The difference in SFs between the programs were further investigated, and, ultimately, the results indicated that the laminated overburden model as implemented in ARMPS-LAM distributes relatively more load on the section pillars for depths less than about 1,000 ft and less load for depths more than 1,000 ft. The results of this research highlight the potential for improving the ARMPS-LAM program in the future by implementing a more accurate loading calculation on the section pillars.

Jan 1, 2014

By William Skinner, Jonas Addai-Mensah, Keith Quast, David Robinson, Jason Connor

A review of the laboratory- and pilot plant-scale physical separation techniques for the beneficiation of nickel (Ni) laterites shows limited efficacy. To date, the only upgrade technique adopted commercially, prior to hydrometallurgical processing of Ni laterites, is the removal of a barren, coarse size fraction in the feed by classification. In the present work we investigated two low grade (~ 1%), goethite-rich Ni laterite ores’ upgrading by magnetic separation, attritioning/coarse, (lower Ni-grade) gangue rejection and flotation techniques. Low intensity (0.1T) dry magnetic separation at ambient temperature of raw samples and those pre-heated at temperatures up to 450 °C showed evidence of pay metal Co and Mn bearing asbolane and/or lithiophorite minerals pre-concentration in the magnetic fractions. Ni distribution, however, did not show any noticeable magnetic upgrade but followed the weight distribution. Other ore pre-treatment methods (e.g., desliming and sulphidisation) followed by froth flotation with anionic and cationic reagents also led to noticeable (~35%) Ni upgrade. This is due to the deportment of Ni across several gangue host mineral phases (i.e. Fe oxide/hydroxide and a range of silicate/aluminosilicate minerals). From chemical analysis, after disaggregation of ~ 1% Ni grade feed ore, coarse (-600 + 38 µm) and fine (-38 µm) fractions of ~0.6% and 1.3% Ni grades respectively, were also produced, suggesting that a significant upgrade in Ni content can be achieved by rejecting the + 38 µm fraction with the loss of <40% of the Ni. The ore mineralogy, particularly the complexity and high number of un-liberated Ni-bearing phases, greatly compromises physical separation methods for these ores, with the possible exception of screening after disaggregation of the fines inherent in the run of mine ores.

Jan 1, 2014

By Shinji Sassa, Naoki Takahashi, Eiji Kohama, Wakaki Tsuda, Hidenori Takahashi, Ikuo Towhata, Yoshiyuki Morikawa

"Abstract Deep mixing method has been employed increasingly in recent years as a countermeasure against subsoil liquefaction. Column-type solidification, however, has been thought to have little effect as a liquefaction countermeasure, because the shear deformation of unimproved soil between the columns cannot be reduced. In recent years, experimental results have been reported that imply that solidified columns can reduce the shear deformation of unimproved soil around them. A new arrangement has been proposed to mitigate lateral flow induced by liquefaction. In this study, a series of dynamic centrifuge model tests was conducted to verify the lateral flow resistance of stabilized columns. The results indicate that stabilized columns can reduce the lateral flow of liquefied ground if the column displacement and the column head rotation are restricted. This paper concludes that it is important to restrict the displacement and the rotation of the column head by surface improvement to mitigate the lateral flow of liquefied ground.INTRODUCTIONDeep mixing method has been employed increasingly in recent years as a countermeasure against subsoil liquefaction. The solidified body formed by the deep mixing method is usually block or lattice shape, composed of solidified columns that overlap each other horizontally. Lattice-type solidification has been shown to be effective as a liquefaction countermeasure despite the presence of unimproved soil inside the lattice wall, because the shear deformation of the interior soil is restrained by the wall (Suzuki et al., 1989). On the other hand, it has been thought that column-type solidification cannot reduce shear deformation of unimproved soil around columns, because the displacement of a solidified column is less restricted than that of a lattice wall. Column-type solidification has been reported to have little effect as a liquefaction countermeasure, but to be superior in terms of construction cost and applicability around existing underground structures (Koga et al., 1986). However, there are experimental results implying that solidified columns have reduced the shear deformation of unimproved soil and mitigated its liquefaction (Yasuda et al., 2003; Tanaka et al., 2003). Yamamoto et al. (2006) conducted dynamic analyses of ground improved with lattice- and column-type solidification. Their results showed that column-type solidification with an improvement ratio of more than 35% reduces excess pore water pressure generated by earthquakes. Furthermore, the new column arrangement shown in Figure 1(a) has been proposed to mitigate lateral flow induced by liquefaction. It was developed and has been verified using dynamic model testing in a 1 g field (Takahashi et al., 2010a; 2010b; 2013; Towhata et al., 2010). The stabilized columns in this configuration interrupt lateral flow in any direction, unlike those placed in square and triangular arrangements."

Jan 1, 2014

By Roger A. Blais, Michel David

"Matheron&apos;s geoslalislical method for the estimation of ore reserves has been developed to the point at which real-life problem may be handled effectively. The steps involved in the method are:(i) obtalning the variogram,(ii) fitting a model, and(iii) producing block estimates.All three steps may cause difficulty, and would-be users need a deep understanding of the theory if failure is to be avoided.To illustrate these points, specific cause are considered:(i) two almost equidimensional porpbyry deposits, one drilled randomly and the other regularly; and(ii) two iron formation, one drilled extensively and being mined, while the other is still at the stage of early estimation."

Jan 1, 2014

By V. V. Lodeischikov

This paper covers some problems of treatment of complex gold ores and concentrates containing copper, lead, zinc, antimony and uranium. All these metals may present in ores both as major and associated components. The paper suggests recommendations for early determination of relative value of the metals in ores, which largely contribute to the selection of concentration and metallurgical flow sheets. The focus of this work is on treatment of complex ores in gold plants. The metal extraction technologies used by such gold plants are typically aimed at maximum gold recovery. Therefore, production of base metals as by-products requires significant updating of the existing process flow sheets based on economic, environmental and other considerations. At the same time, cooperation between gold plants and base-metal plants is of great importance. This paper provides an overview of worldwide existing and innovative processes of base metals extraction from complex and refractory gold ores.

Jan 1, 2014

By Geraldine Rosenthal, Gadi Yohan, Roman Benram

Description of Project: Tamar Group’s civil division was awarded a contract to implode the Sun Hotel, an abandoned 14-story building located along Bat Yam’s coastline, roughly two kilometers south of Tel Aviv, Israel. On Nov. 6, 2012, Tamar Group’s experts positioned explosives in strategic locations of the building, targeting its central pillars, which then caused the building to collapse within seconds. Tamar Group used a relatively small amount of explosives in order to generate a well-controlled blast. This is the largest scale demolition carried out in Israel to date.

Jan 1, 2014

By Tristan H. Jones

Rib-related accidents in underground coal mines continue to cause injuries and take lives at a rate of 1.3 fatalities per year for the last 17 years. Prevention of these accidents cannot simply be a matter of installing more rib support, though the eventual final solution will undoubtedly include that component. Ultimately, rib safety will be brought about through an understanding of the causes and mechanisms that cause rib fatalities, and by fine-tuning mining methods and procedures that are currently in place. This paper investigates the factors likely to be most influential in the occurrence of rib fatalities. A careful analysis has been conducted of the rib fatality reports documented by the Mine Safety and Health Administration between 1996 and 2013. The primary outcome is the determination of the relative impact of each type of rib fatality factor and a better understanding of the impact each factor has. Among the rib fatality factors considered, the influence of rib profileis considered for the first time. Mining height, rib stratigraphy, mining cycle, and the standing position of a miner next to a pillar are also considered. Questions are also raised about the current interpretation of rib fatalities due to mining depth, with the indication being that mines operating at the greatest depths may actually have the most respectable rib fatality record among all mining depths. Additionally, a new method of considering rib exposure is developed. Based on the results, recommendations are made for future work. By gaining a better understanding of how particular factors contribute to rib fatalities as opposed to rib failure or stability, it is hoped that future efforts can be more precisely directed towards the desired outcome of fatality reduction.

Jan 1, 2014

By M. Bhattacharya, A. Dutta, P. Barat

"Pinning of dislocations at nanosized obstacles like precipitates, voids and bubbles, is a crucial mechanism in the context of phenomena like hardening and creep. The interaction between such an obstacle and a dislocation is often explored at fundamental level by means of analytical tools, atomistic simulations and finite element methods. Nevertheless, such studies fail to predict the effect on the overall plasticity on account of insufficient information about the underlying statistics of this process comprising a large number of dislocations and obstacles in a system. Here we propose a new statistical approach, where the statistics of pinning at idealized spherical obstacles is explored by taking into account the generalized size distribution of the obstacle along with the dislocation density within a three-dimensional framework. The application of this approach has been demonstrated for dislocation pinning at nanovoids in neutron irradiated type 316-stainless steel.IntroductionPresence of nanoscale obstacles like precipitates, voids and bubbles play a crucial role in determining the deformation behavior of a crystalline solid on account of the interactions between the line defects and such localized obstacles. In the context of the glide motion of dislocations, the obstacles can offer resistance to a moving dislocation, thereby causing a hardening effect [l-3]. In some other cases, inclusions like voids and bubbles can affect the rate of dislocation climb through diffusive [4] and non-diffusive [5] mechanisms. Over the last few decades, numerous studies have been performed to gain an insight of the dislocation-obstacle interactions at a fundamental level. These include the interactions responsible for the hardening effect, in addition to those pertaining to the non-conservative motion of dislocations.Although the elementary mechanisms of the various dislocation-obstacle interactions have been vastly explored and understood by means of analytical theory and numerical simulations, it remains difficult to quantitatively understand their effects on the macroscopic deformation behavior. This is due to the fact that their influence on the gross plastic deformation of a bulk sample would be the collective outcome of a large ensemble of such interactions. As a result, it becomes infeasible to predict the bulk deformation behavior of a material until the statistics of pinning of the dislocations at the localized obstacles is available. In the context of precipitate hardening, some well known attempts to extract the pinning-statistics were made by Friedel-Fleischer [6] and Mott [7] by analytical means, which were later tested through simplified 2-dimensional in-silica modeling [8]."

Jan 1, 2014