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By C. A. Silva

The kinetics of chlorination of titanium-bearing raw materials has been investigated. For comparison purposes pellets of controlled macro-porosity, made of analytical grade TiO2 and anatase concentrate (Brazil) , have been exposed to different combinations of gas composition - CO, CO2, C12 -, gas flowrate and temperature. A thermogravimetric technique and an adapted grain model have been used in order to assess the influence of the several experimental parameters upon the chlorination behavior.

Jan 1, 1997

By Sigmund J. Sulinski

All Sanitary District contract documents for new tunnel construction permit the Contractor a choice of four (4) separate alternate tunnel sections. This is the result of a continuing District policy to encourage at all times the use of the most suitable construction techniques and to attract to District construction the broadest spectrum of proven capabilities. Figure 1 indicates the alternate tunnel sections allowed on District contracts as follows: 1. A horse shoe section, ribbed and lagged, and a poured reinforced concrete tunnel liner; 2. Circular section, ribbed and lagged, and a poured in place reinforced concrete tunnel liner; 3. Circular section, ribbed and lagged, and a precast reinforced concrete pipe liner grouted in place; and 4. Circular section, no temporary lining, and a precast reinforced concrete pipe liner to be jacked in place. The Sanitary District now has in operation 10,500' of 5'6" I.D. and 6,500' of 5'0" I.D. jacked tunnel. An additional 5,600' of 7'6" I.D. jacked tunnel is currently under construction.

Jan 1, 1997

By Guerney P. J

A suspension of finely powdered ferrosilicon in water is the dense medium used in the gravity upgrading of iron ore, diamonds and other minerals. Ferrosilicon can he lost in the plant through corrosion. The greatest corrosion losses occur when

Jan 1, 1997

By Y. M. Jubeli

"Gamma-ray spectrometry, an effective tool in geological mapping, was used to de?ne boundaries between various lithological formations in three adjacent areas of Central Syria, namely, the Syrian Desert, Ar Rassafeh Badiayat and the Northern Palmyrides mountains.This paper describes the role of an airborne gamma spectrometric survey which was originally undertaken to assist uranium exploration. Interpretation of the total count data obtained through the survey has led to signi?cant modi?cations and corrections to the previously published distribution map of the palaeogene phosphate rocks.Another important result of the survey is the discovery of four previously unknown phosphorite horizons in the Rasm Al-Aawabed area of the Northern Palmyrides. In addition, previously unknown phosphatic horizons are outlined in the other study areas. The importance of this technique as an effective prospecting method, not only for U but also for exploring for the economically important phosphorite formations in Syria, is emphasized. Furthermore, its role in geological mapping is stressed, especially in areas that lack suf?cient geological data."

Jan 1, 1997

By M. J. Laurila

On-line analyzers have made possible the use of Fuzzy Logic Control (FLC) for local control applications in coal preparation plants. This includes FLC control of complete circuits such as heavy media vessels, cyclones and froth flotation. These circuits can be controlled in real time in a feedback control loop with an on-line analyzer. Control strategies can be readily developed using Statistical Process Control (SPC) techniques which are first applied off-line in manual mode through the use of control charts and then this process is brought on-line using FLC in conjunction with an on-line analyzer to fully automate the circuit. This paper outlines the types of control strategies employed and presents examples of automatic verses manual control.

Jan 1, 1997

By Andreas Nolte

This paper includes a comprehensive report about the metallurgical utilisation of reusable products from electronic scrap recycling, car shredding industry, used glasses an various waste products, such as slimes and flue dusts, generated in a secondary copper smelter. Depending on the copper content, the type of copper compounds and the characteristics of accompanying substances, the materials are treated by smelting in furnaces, operating under reducing or oxidizing conditions. HKs pyro- and hydrometallurgical processes, blast furnaces, converters anode furnaces, tin lead alloy plant and tankhouse will be outlined. The reusable products are categorized according to the origin of the materials and then presented in the form of quantity and quality balances. Processing methods, process able quantities and quality requirements of inputs are described. The utilization degree of the most important metals (copper, tin, lead and zinc) is described with graphics. The report is rounded by information on operating licence according to the environmental regulations of the Federal Republic of Germany and data concerning supply and contracts

Jan 1, 1997

By Rafael C. Castro, John Overton, Gregg Sherry, David A. Sutter

This paper presents an innovative ground support solution developed to construct a tunnel cross-passage for the MUNI Metro Turnback (MMT) Project. A “soft center” jet grouting approach was designed to provide solid ground support while maintaining a soft center to allow for hand-mining of a 2.44 m (8 ft.) wide, 3.66 m (12 ft.) tall and 4.6 m (15 ft.) long cross-passage through soft Bay Mud. Prohibitive costs and schedule impacts associated with mining under compressed air (at the time being used for main tunnel construction) were the catalysts to search for alternative methods for cross-passage construction. Limited surface disruption, relatively low costs, ease of subsequent excavation, nominal schedule impacts and proven local success of jet grouting were key factors in selecting and designing this method of ground support.

Jan 1, 1997

Madison Enterprises Corp. and Matu Mining are currently ex- ploring the Mt. Kare property in Papua New Guinea. The Mt. Kare gold prospect has had a short but very active history, since the first discovery of gold in the area in 1986 the property has sccn: a 3 year gold rush during which 10,000 alluvial miners re

Jan 1, 1997

By Pertti Paavola, Hikki Rasanen

This paper describes a very exacting tunneling project. Planning and technical realization of this service and transportation tunnel was especially difficult as a matter of vibration control, because the tunnel is situated only a few meters under Maria Hospital, which is one of the most busiest hospitals in Helsinki. In this hospital there are many departments for bedpatients, research and treatment with high-tech equipment, operational surgery and a big laboratory. Besides access tunnels are situated near several apartment buildings. The functionality of the tunnel required the placement of the access tunnels to be straight towards these apartment buildings for which special care for blast induced air pressure had to be taken.

Jan 1, 1997

By John G. Oldsen

During the last several years, implementation of trusses, in lieu of wood cribs, has been successful for supplemental tailgate support in the Pittsburgh seam. This paper reviews the truss support system provided by the new high strength 0.6" tensioned cable truss, which is now also being used in cribless tailgates. Cable loading and roof deformation were monitored to evaluate roof and floor performance. The test results indicate that the cable truss system successfully controlled the roof and floor during the first and second panel extraction. This paper will describe the advantages of cable trusses and their load transfer mechanism as well as mine evaluation.

Jan 1, 1997

By Daniel W. H. Su

The importance of incorporating fundamental principles of rock material response and failure mechanics into a pillar strength design model has been demonstrated. To accurately assess pillar strength, a model should account not only for the characteristics of the coal, but also for those of the surrounding strata. The interactions between the pillar and the surrounding roof and floor dictate ultimate pillar strength. Confinement, or the lack thereof, provided by roof and floor frictional end-constraint is one of the most significant factors in the strength of very wide pillars. The best conditions for end-constraint occur with ideally strong roof and floor. In this paper, it will be shown that weak roof and floor may decrease the ultimate pillar strength by as much as 30% compared to ideal conditions. Field observations confirm this pillar strength reduction in the presence of weak roof and floor. Furthermore, rock partings within the coal have a variable effect on pillar strength, depending on the parting strength. A competent shale parting within the coal reduces the effective pillar height, thus increasing the ultimate pillar strength; a weak claystone parting slightly decreases the strength. Imposed load distribution also has a significant effect on pillar strength, such that asymmetric pillar loading, similar to that observed in pillars adjacent to high extraction mining, reduces the ultimate pillar strength below that of equivalent pillars subject to uniform load distributions.

Jan 1, 1997

By Brian W. Stump, David P. Anderson, John Wiegand

Mining explosions are designed for a variety of purposes including the fragmentation and movement of materials. The blast design is dependent on the particular application intended and the material properties of the rock. The range of mining applications from hard rock quarrying to coal exposure to mineral recovery leads to a great variety of blasting practices.

Jan 1, 1997

By I. Ohnaka

Although many works have been reported on the semisolid casting, the mold filling behavior of semi-solid alloys has not been so well understood. This paper compares the physical and numerical simulation results on the mold filling behavior. Physical simulation was performed by using solid-water mixture. The numerical simulation was made under the assumption of one phase flow with an effective viscosity. It was found that the solid particles stabilize the flow greatly if the kaction solid exceeds about 0.4, because viscosity increases greatly. The overall flow behavior can be estimated by the numerical simulation. Interesting flow behavior was also found which can not be observed in the case of one phase flow and which is difficult to simulate by the one phase flow assumption.

Jan 1, 1997

By Michael D. Justason

This paper details the static and Statnamic load testing on a 600 mm square pre-stressed concrete pile. The pile was located at Pier 15 on the 20 million-dollar Bayou Chico Bridge Project in Pensacola, Florida. The pile was 10.5 meters long and had a design load of 1.3 MN. Three static load test cycles were performed in November, 1996. The Statnamic load test was performed in January, 1997. The Davisson Failure load of the first cycle of the static test was 3.7 MN, and the Davisson Failure load of the Statnamic test was 3.2 MN. The load-displacement curves for the two types of tests were very similar, indicating that the Statnamic load test performed well in the sandy soils. Strain gauges embedded in the pile showed 35% skin friction and 65% end bearing for both test methods. Strain gauges were located at equal spacing at five elevations in the pile. A toe accelerometer verified the rigid body assumption of the Unloading Point Method currently used in the analysis of Statnamic load tests. The data collected from the pile instrumentation was of excellent quality and represents some of the best research to date comparing static and Statnamic load tests.

Jan 1, 1997

By J. W. Mahar, E. J. Cording, F. L. Gau

INTRODUCTION The Washington, D.C. rapid transit system (METRO) when completed will consist of 98 miles of double track rail. Fifteen miles will be tunneled in rock and 12 large underground rock chambers will be constructed at station locations. The University of Illinois is under contract to Metro to provide observations and instrumentation services in the initial phase of construction. The work is coordinated through DeLeuw, Cather & Co., the General Engineering Consultant to Metro. The program is designed to monitor construction conditions as well as to provide information useful for the design of future rock tunnels and rock chambers in the Metro system. This paper presents the results of observations in the rock tunnels constructed to date. Most of the observations are in a 5000-ft-long, 30-ft-wide, double track tunnel in downtown Washington, D.C. Observations were also made in single track tunnels, shafts, enlargement areas, and pilot tunnels, and are being made in a large rock chamber 700 ft long, 76 ft wide, and constructed at shallow depth in a schistose gneiss. One of the major objectives of the observational program was to determine the orientation and character of joints and shear zones and to evaluate their effect on support requirements for various tunnel orientations and configurations. The consistency of geologic features throughout the Washington area has made the results of the initial study applicable to evaluation of support requirements on future tunnel contracts. The first section of this paper summarizes the geologic conditions in the tunnel and their effect on overbreak and rock movement.

Jan 1, 1997

By Jay W. H, Brown L. J

Several case studies are examined in which analysis of treated ores and extracted metal species by Mossbauer spectroscopy provides information not available by other competing techniques. The cases include poorly crystalline, surface iron oxides in titanium minerals and chalcopyrite, gold in ores and bacterially oxidised ores and the adsorbed species from gold extracted from cyanide and chloride solutions onto activated carbon and polyurethane foams. Some limitations on the use of the technique in terms of sample size, sensitivity and counting time are also discussed.

Jan 1, 1997

By Walenty Frydel

The paper deals with highly efficient dust collecting systems of the 10-600 type which constitute new generation installations de- signed to eliminate dust hazard in headings driven with roadheaders. A vortex ventube controlling the air flow in the com- bined ventilation system by means of air vortex generated by the ventube drive unit is also presented. From the results of measurements of under-roof concentrations of methane it appears that the application of the vortex ventube makes it possible to decrease the under-roof accumulation of methane more than 10 times.

Jan 1, 1997

By Thomas P. Kwiatkowski, Len Cobb, Christopher D. Orlandi, Judith H. Jones

The Inland System supplies raw water to the industrial and domestic users in the City of Birmingham, Alabama. The Inland System, which is nearly 60 years old, consists of an approximately 57.9m (190 feet) high earthen dam across the Blackburn Fork of the Black Warrior River, a 39.6m (130 feet) high reinforced concrete intake structure, a 1524mm (60inch) diameter Dresser coupled steel transmission pipeline, and various distribution lines extending into Birmingham. The Inland System was owned, operated and maintained by the Industrial Water Board (IWB) of the City of Birmingham, an agency of the city government, from 1958 until 1994. In 1994, the City of Birmingham consolidated all water and distribution functions under the Birmingham Water Works Board (BWWB). In 1988, the IWB determined that the Inland System had reached a point where its reliability could not be assured without an in-depth evaluation and renovation. The IWB engaged Christy/Cobb, Inc. (CCI) of Birmingham as its consultant for the renovation work. CCI evaluated the Inland System and submitted a report to the IWB in April, 1992. The report contained several recommendations for capital improvements to the system including increasing the emergency spillway capacity, reconstructing the fuse plug, relocating public access to the lake away from the dam area, constructing a new intake structure, and constructing a tunnel through the dam abutment to deliver the water from the proposed intake structure to the existing 1524mm (60 inch) diameter supply line. The new intake structure and tunnel would provide for a future maximum demand flow rate as well as provide bypass and level control capabilities. CCI was authorized in 1992 to proceed with the engineering design for the renovation of the Inland System with emphasis on the spillway and intake structure. PROJECT DESCRIPTION The major component of the renovation of the Inland System was the new intake structure and tunnel through the dam abutment. CCI engaged Jenny Engineering Corporation (JEC) of Springfield, New Jersey as a consultant for the tunnel design. JEC was responsible for the design of the tunnel, the connecting shaft between the intake structure and tunnel, and the steel pipe final lining, while CCI was responsible for the intake structure and the connection to the existing supply pipeline as well as overall project management. CCI and JEC evaluated the project site in order to select the location for the new intake structure and set the alignment for the tunnel. A factor in the evaluation process was that the level of the lake could not be lowered to construct the new intake structure since the supply of water from the Inland System had to maintained. Therefore, a location was required which was

Jan 1, 1997

By G. Van Weert, A. van Sandwijk, O. W. J. S. Rutten

"Cathodic and anodic reactions in an acidic nitrate medium were studied in reference to the production of electrolytic manganese dioxide from pyrolusite' (Mn02) ores by reductive leaching. Two USA ores were investigated. The reductant for the pyrolusite ore is produced cathodically in an electrolytic cell and can either be nitrous acid (HN02) or nitric oxide gas (NO). In this work emphasis was placed on the nitrous acid leach. In a high-temperature leach in a nitrous/nitric acid medium, manganese and silver are solubilized and iron is not. Anodic electrowinning of manganese dioxide from the acidic manganese nitrate electrolyte yields flaky y-Mn02, similar to that produced from sulfate and chloride electrolytes. Cathodic regeneration of nitrorts acid was studied in a membrane cell in 1.0 M nitric acid and 0.0 to 0.1 M nitrous acid on a' platinized titanium cathode. At cathode potentials ranging from +950 to +700 mV (SHE), cathodic reduction to nitrous acid takes place, at cathode potentials < +700 mV, cathodic reduction of nitrous acid to nitric oxide takes place. A conceptual process is presented and discussed.IntroductionManganiferous-silver oresLarge reserves of manganiferous-silver ores are present in the Southwestern United States and Latin America. These ores are generally refractory to hydrometallurgical methods of treatment, due to the insolubility of the higher oxides of manganese (Mn 4+) in all common lixiviants such as cyanide solutions, dilute sulfuric acid, nitric acid, ammonia, salt solution, thiosulfates, etc. The silver is either bound by the insoluble manganese, or is rendered inaccessible to cyanide leach solution by the surrounding manganese mineralization.Higher oxides of manganese will dissolve if they are first reduced pyrometallurgically to manganous oxide (Mn2+). This is a widely used pretreatment for manganese dioxide ores and subsequent dissolution in sulfuric acid is common. In order to avoid the pyrometallurgical pretreatment with its large energy requirements and gaseous emissions, fully hydrometallurgical processes have been proposed. These processes are based on the presence of a reductant in solution, in order to reduce the insoluble higher oxides of manganese to soluble lower oxides. Aqueous S02 has been proposed and tested on industrial scale by the U.S. Bureau of Mines. After washing, silver could be extracted by cyanidation. The neutralization of the pulp prior to cyanidation however causes problems in filtration and the reagent consumptions are high [1]. More recently, acidified thiourea and bacteria were proposed for the solubilization of both manganese and silver in a single leach step. High extractions were obtained, but drawbacks of these methods are high reagent consumption or slow kinetics [2,3]. For the options of manganese recovery from the leach filtrate, precipitation with persulfate or ammonium carbonate and ion exchange have been proposed. The proposed options for silver reclaim are precipitation with either zinc or Na2S and adsorption onto activated carbon."

Jan 1, 1997

By C. E. Semler

A multiyear program involving online, in-vessel exposures at Barrick Goldstrike Mines Inc. (BGMI) has provided information and experience about the materials and designs for brickwork linings in pressure oxidation autoclaves. A variety of brick and mortar products was evaluated. Properties before and after exposure were used to document the performance. Some benefits include the development of a new silicate mortar, a better understanding of brick requirements and increased autoclave operating time between maintenance shutdowns. BGMI operates six pressure oxidation autoclaves at its Eureka County, NV gold operation. These autoclave process 15.8 k/ld (17,500 stpd) of gold ore. Figure 1 is a flowsheet of the six autoclave circuits. The gold ore is refractory, in which the gold particles are mineralogically encapsulated on a micro- and submicroscopic level. The autoclaves are 4.4- m- (14-ft-) diam and 26 m (85 ft) long (tip-to-tip). Inside of each is a full brickwork (brick plus mortar) lining that divides the vessel into five compartments. Each compartment has a motor-driven agitator that keeps the slurry suspended and disperses the oxygen to enhance reaction. During autoclave operation, the conditions are steady state at 210° to 232° C (410° to 450° F) and 61 to 62 kPa (420-430 psi). As shown in Fig. 1, there are other accessory vessels (splash and flash towers) in the autoclave circuits that are also brickwork-lined. The linings used to date, other than small test sections, have all been acid-resistant fireclay bricks, bonded with alkali silicate mortar, PbO- based mortar and/or vinyl ester mortar, but mainly alkali silicate mortar.

Jan 1, 1997