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By Xun An

Slag from an electric slag cleaning furnace was injected with methane and air mixtures to facilitate the recovery of copper and cobalt. The effects of methane-to-air ratio, gas flow rate and temperature on the reduction and metal separation were investigated. The results showed that over 90 percent copper and up to 60 percent cobalt could be recovered from the slag with a gas utilisation of around 70 percent, as calculated by thermodynamic simulation. Methane-to- air ratio was a major factor affecting the rate of reduction under the present experimental conditions. Further, injection of gaseous reductants greatly enhanced the coalescence and settling of entrained metal droplets. A reduction mechanism is proposed and the factors influencing the coalescence of copper droplets are discussed.

Jan 1, 1998

By Takahiro Miki

In order to use metallurgical grade silicon (MG-Si) as a starting material for solar cell, phosphorus has to be removed from silicon because phosphorus is a n-type dopant. On the other hand, silicon, ferrosilicon, and silicomanganese are widely used as deoxidizers in steel refining processes. Since most of the phosphorus introduced during the deoxidation process is brought into final products, it is important -to lower the phosphorus content of these alloys. Hence, thermodynamics of phosphorus in such metals is important for the evaluation of dephosphorization processes. In the present study, thermodynamic properties of phosphorus in molten Si-P alloys at 1723- 1848K and those of Si-Fe-P and Si-Mn-P alloys at 1723K have been determined by equilibrating respective metals in a controlled phosphorus partial pressure. The results are expressed as follows.

Jan 1, 1998

By R. Q. Honaker

Recent research has shown that enhanced gravity separators provide the opportunity to effectively clean I mm x 37 micron coal. At Southern Illinois University, a detailed experimental program was performed on a continuous Falcon Concentrator, which was found to achieve separations at mass throughput capacity values in excess of 100 tonnes/hour. The apparent particle separation density for I mm x 73 micron coal was about 1.60 with relatively high efficiency (Ep = 0.12). Typical ash and sulfur rejection values of 85% and 70%, respectively, were achieved while recovering 85% of the combustible material. Metallurgical and efficiency data from the evaluation are presented in this publication.

Jan 1, 1998

Newmont Gold's methods for deposit modeling vary, depending on geology, mining and processing methods, economic feasibility and availability of historical information. It is argued that successful modeling requires understanding these factors, knowing the strengths and weaknesses of the various modeling techniques and being flexible in selecting the appropriate methods. Newmont is one of the world's largest gold mining companies, with operations in the United States, Peru, Mexico, Indonesia and Uzbekistan. And it is active in exploration worldwide. At the end of 1996, Newmont declared a total reserve of 1.15 equity kt (37.1 million equity oz) of gold and 2.17 equity Mt (2.39 million st) of copper. The gold deposits managed by Newmont totaled 752 Mt (829 million st) of ore containing 1.28 kt (41.3 million oz) of gold averaging 1.71 g/t (0.05 oz/st). In addition, Newmont is developing a porphyry copper-gold deposit that totals 9.1 Gt (1 billion st) of ore containing 380 t (12.1 million oz) of gold and 4.82 Mt (5.32 million st) of copper. (In May 1997, Newmont Gold Co. merged with Santa Fe Pacific Gold Corp., thus increasing Newmont's reserves to 1.72 kt or 55.2 million oz of gold and 2.17 Mt or 2.39 million st of copper.)

Jan 1, 1998

By M. J. Shields

There are numerous suggestions in the literature on methods of obtaining representative samples of waste rock or mill tailings. Some suggested methods would result in thousands of samples and very high costs for a large facility. There is no general rule that can (or should) be followed, such as collection of a given number of samples per mass of material, per acre of impoundment, or per foot of drillcore. Each site is different, and the adequacy of sampling must be tailored to the site. A logical approach is to let the variability at the site dictate the number of samples that should be collected and analyzed, and then to quantify and evaluate the results by means of standard statistical methods.

Jan 1, 1998

By P Geddes, K Grohs, C K. McKenzie, M Morrish

Low grade surface gold mining at the Acacia Resources, Union Reefs Gold Mine in Australia's Northern Territory, involves the excavation of benches in three slices after blasting. Blast patterns span zones of high and low grade ore, as well as zones of waste, and selective excavation is required in order to maintain economical head grades for the carbon-in-leach processing plant.

Jan 1, 1998

By V. N. Kolesnikov

The gold-silver deposits of the northern Primorye region are located in the eastern part of the East Sikhote-Alin volcanic belt, where the belt overlaps the Kema island-arc terrain of the Aptian-Albian age. There have been four deposits and numerous mineralization points found in the NE-trending Kema metallogenic belt that is about 1000 km long and 100 km wide. The known mineralization is of epithermal type, controlled by faults, and concentrated in quartz, quartz-fluorite-adularia, and, less commonly, sulfide-quartz vein systems hosted by the Upper Cretaceous-Lower Tertiary volcanic rocks. The vein systems extend for hundreds meters along strike, varying from tens centimeters to 50-60 meters in width. They are surrounded by wide zones of low-temperature hydrothermal alteration containing some gold-silver mineralization for which the commercial value was not studied during the early exploration. The ore bodies contain from 1 to 50-80 ppm of Au and from 1 to 1000 ppm of Ag. Gold is native, associated with quartz, and represented by particles from tens of microns to 1 mm in size. Silver occurs in native form as a constituent of argentite, pyrargyrite, stephanite, and other sulfosalts. The test work carried out for three vein systems 20 years ago showed that gold might be easily and almost completely recovered from the ore by cyanide treatment. The paper describes the geology and mineralogy of the deposits, Salut and Primorskoye, that are the most studied properties of the Kema belt. It also presents the data available on disseminated gold-silver mineralization in stockworks, altered explosive breccias, and wide zones of low-temperature hydrothermal alteration. This mineralization should be explored for possible exploitation as large open-pit, heap-leach deposits.

Jan 1, 1998

By Isrun Bohlinger

Resources recovery of brasses for semifinished products often results in the formation of hard spots impairing the quality of following abrasive and/or surface finishing processes. A short survey is given on the recycling processes, followed by the actual knowlegde of genesis, composition, and possibilities of avoidance of hard spots. Informations on genesis and composition of hard spots are completed by data from recent experiments.

Jan 1, 1998

By A. Anttila

The grinding mill is probably the most common unit operation used in mineral processing. There is, however, much which can still be done in the way of optimization. This paper discusses the results of a well controlled pilot scale test in which the performance of a tumbling mill with a conventional rubber lining equipped with lifter bars is compared to that with a smooth rubber lining of the magnetic type. The results indicate that the smooth lining is about 14 percent more effective with respect to energy consumption. By optimizing the size of the grinding media, the mill capacity can be increased in many grinding operations. In this specific case the -20 mm ball charge required 26 percent less grinding energy than one with a -30 mm ball charge. The energy savings can. in most cases, be converted to increased capacity. The wear of the grinding media is difficult to assess over a short period test but the results suggest it is somewhat less when a smooth lining is used. The wear of the linings has not been included in this study but it is generally accepted that the use of the magnetic lining reduces the lining costs dramatically. Computer simulation using the Millsoft code, developed by Mishra e.a. confirms and explains the increased effectiveness of comminution when smooth lining and smaller grinding balls are used.

Jan 1, 1998

By B. Basim

Novel chemicals that can be used for increasing the efficiency of fine coal dewatering were developed at Virginia Tech. Reagent A was tested on three different coal samples in laboratory vacuum filtration tests. These included flotation products from Middle Fork plant, Elkview Mining Company, and CONSOL, Inc. The tests conducted with the Middle Fork coal sample (100 mesh x 0) showed that cake moisture can be reduced by more than 10% beyond what can be achieved without using dewatering aid. This improvement was achieved at 1 lb/ton of Reagent A and 0.1 inch cake thickness. At 0.5 inches of cake thickness, the improvement was limited to 8% at the same reagent dosage. The results obtained with the Elkview coal (28 mesh x 0) showed similar advantages in using the novel dewatering aid. Depending on the reagent dosage, cake thickness, drying cycle time and temperature, it was possible to reduce the cake moisture to 12 to 14% range. In addition to achieving lower cake moisture, the use of Reagent A substantially decreased the cake formation time, indicating that the reagent improves the kinetics of dewatering. The test results obtained with CON SOL coal were not as good as with the other coals tested in the present work, which may be attributed to possible oxidation and/or contamination.

Jan 1, 1998

Within CRLÆs lifetime there have been a number of products that have proceeded through their life cycles. In each case market forces and technological advances have forced the cessation of the product. The company has then had to develop alternative outlets for its copper. Sometimes it has produced a similar product to fill the same market. In other cases the extra copper is sold as cathode. Today, CRL produces no semi-fabricated copper products and all cathode is sold. More recently, CRL has ventured into the sale of technology and manufacture of cathode motherplates. This area, whilst it is not what had been a traditional area of core business, has been found to be profitable.

Jan 1, 1998

By A. Rawat

The removal of oxyanions of arsenic present in mine process water and drinking water to a regulatory level is a challenging problem. Recently a patented adsorbent lanthanum oxide has been developed which has shown strong specificity for the anions of arsenic. In this paper the kinetic and thermodynamic aspects of arsenic adsorption on to lanthanum oxide are discussed. Adsorption tests were performed at different temperatures using synthetic solutions of arsenic of varying concentrations. From the kinetic data and adsorption isotherms thermodynamic properties such as Gibb's free energy, standard enthalpy of adsorption, standard entropy, isosteric heat of adsorption and activation energy were determined. The results showed that temperature had a positive effect on the rate and degree of adsorption:The activation energy decreased with increase in the initial concentration thus indicating solute-solute interactions in the system. Also, the isosteric heat was found to decrease with increase in the adsorption density implying a heterogeneous adsorbent surface.

Jan 1, 1998

By R Lethlean

The mining industry in its drive to optimise equipment use and minimise cost simply to remain profitable in an uncertain commodity market needs to develop a greater understanding of equipment capabilities and cost. The factors influencing mobile equipment fleet cost and performance commence at the time of mine planning and continue to exert an influence over the life of the mine. These factors must be understood at the early stages of any operationÆs planning process as they continue to impact both positively and negatively on fleet performance and operating cost throughout the life of the mine. The key factors examined in this paper include: grades; rolling resistance; fragmentation and truck loading.

Jan 1, 1998

Rehabilitation, reclamation and restoration are all terms used to describe the repair of land after mining. Here, restoration is used to mean restoring the land's original use, capability or productivity. Effective restoration is dependent on good planning before mining commences and must include a clear definition of post-mining objectives. The physical condition of the land within the mining licence was that of an imperfectly drained soil in permanent pasture, supporting a seasonal supply dairying unit. During the mining process, the soil layers were separated, with the topsoil stockpiled separately. As part of the restoration process, the land was recontoured to encourage surface drainage, with topsoil spread evenly over the recontoured tailings. Low grond pressure machinery was used to minimise soil compaction, with light discing and harrowing used to increase water infiltration. A permanent pasture was sown, with weed species controlled by spraying, both before and after pasture establishment.  Soil testing has been used extensively to ensure there were no nutrient deficiencies that good compromise pasture establishment and performance. Controlled grazing practices were used to ensure that the sown pastures became well established.

Jan 1, 1998

By J. C. Ashby

Electric utility response to certain amendments of the Clean Air Act has resulted in a production of several types of alkaline coal combustion byproducts. Alkaline combustion byproducts are gaining increasing usage for acid mine drainage mitigation as research leads to a better understanding of their beneficial applications. Since January of 1997, Mettiki Coal Corporation has been injecting alkaline flue gas desulfurization material from Virginia Power's Mt. Storm Unit #3 wet limestone scrubber into abandoned portions of the active Mettiki mine. This paper provides an overview of the key design, transportation, regulatory, and environmental issues faced in the project.

Jan 1, 1998

By Árpád B. Palotás, Adel F. Sarofim, John B. Vander Sande, Paolo Ciambelli, Lenore Rainey

"The evolution during oxidation of the internal structure of soot and carbon black particles was studied using high-resolution transmission electron microscopy (HRTEM) and an image analysis system. Increasing ordering to the carbon structure with increasing oxidation is observed. Measures of the increased order are increases in the fractional coverage of a cross section of the particles with a layered structure, a decrease in the mean interlayer spacing, and a decrease in the spread of the interlayer spacing. The changing structure of the carbon black impacts its properties, such as the rate of oxidation.There is considerable interest in the study of the structural changes of carbonaceous materials as a function of oxidation. Davis et al.1 measured the variation of carbon dioxide surface area of various coals as a function of residence time in a flow reactor. HRTEM measurements revealed that crystallite dimensions and interlayer spacings are altered by combustion. Ishiguro et al.2 showed that oxidation alters the structure of diesel soot. The aim of our current research is to develop a better understanding of the microstructural reordering of carbon blacks with implications to their properties. The carbon blacks used in this research have already been studied and their reactivities as a function of oxidation measured.3The methodology used in this work has already been described in detail elsewhere.4 This paper presents an application to quantify the structural changes of carbon black particles as a function of oxidation and graphitization. The technique used is based on the use of HRTEM (high-resolution transmission electron microscopy) and computational image analysis.It is well-known that carbonaceous materials like graphite, soots, coals, chars, etc., possess characteristic structural appearances which can vary from mostly random or amorphous to a perfectly ordered graphitic crystalline structure. The carbon structure has been variously described as turbostratic5 or as crumpled sheets6 to indicate that parallel layering, reminiscent of graphite, is observed over dimensions of nanometers but that these planes or crystallites show disorder over larger scales. The degree of order of such structures is strongly dependent on the thermal treatment of the material as well as the composition of the source of the carbonaceous material. The value of electron micros¬copy in studying the morphology of such materials has been well established,2,7,8 although only a few attempts toward quantification have been made.The sample observed was carbon black CB330 from De¬gussa. One set of carbon black samples were oxidized in a thermo-gravimetric analyzer (TGA) in air at 575 0C, so that the conversion varied from 0 to 96%. Another set of carbon black samples were graphitized (Graphpac-GB by ALLTECH) and then oxidized in the TGA at 680 °C until 92% burnout was reached. The latter samples are called GB 0% and GB 92%, respectively.For the HRTEM observation a small portion of each sample was ultrasonically dispersed in ethanol. The suspension was deposited dropwise on a copper TEM grid coated with a lacey carbon film. The examination of the samples was carried out on areas that extend over the holes in the supporting film in order to avoid interference from the amorphous carbon background film An oriented gold crystal was used as a calibration standard and subjected to the same techniques as the carbon black samples."

Jan 1, 1998

By Alfred W. Eustes III

The first of a series on the evaluation of rock cutting tools, this paper discusses the results of full-scale laboratory drilling tests that compare the performances of several polycrystalline diamond cutter (PDC) coring bits. The tests were performed in welded tuff as part of a site characterization program. Number of cutters, size of cutters, air course design, and other parameters were evaluated as they affect penetration rate, but this paper focuses mainly on the relationships of torque vs. thrust (weight-on-bit), specific energy vs. penetration rate, and thrust vs. penetration rate. These relationships change in diagnostic ways according to bit type, bit condition, and type of welded tuff.

Jan 1, 1998

By P. M. Tait, N. A. Warner

"The refining of thermally produced zinc is currently performed using a highly energy intensive and arguably outmoded process, distilling zinc under atmospheric pressure at temperatures of 900°C to 1000°C. In order to produce refined zinc more profitably and with less environmental impact a new process has been proposed. This process is generic to all thermal zinc smelters and aims to match the purity of zinc from current technology (99.99%-99.999%). The objective is to perform all separation processes using only the heat contained in the smelter product stream. Vacuum conditions are extensively used lowering operating temperatures and enhancing separations. As part of this process zinc is distilled under vacuum from high concentration obtaining a refined product with respect to lead content. A mathematical model has been developed from fundamental principles to describe this stage, the distillation of zinc across a temperature difference between two circulating zinc streams in open channels under vacuum. Heat for the distillation is supplied by the liquid phase, necessitating a large recycle to maintain high operating temperatures, and keep zinc concentrations high. In determining this model and the operating conditions required, relationships between temperature, pressure and composition are considered.IntroductionCurrent technology (the Refluxer) used to refine thermally produced zinc is both expensive and highly inefficient. At present 80% of the worlds zinc is produced via the electrolytic process reflecting the poorer performance of the thermal route, the zinc-lead blast furnace and Refluxer. A new process is proposed to overcome the drawbacks of current processes. These drawbacks are both economic and environmental. The Refluxer requires 6.6 GJ of energy to refine one tonne of SHG zinc 1, other disadvantages of the Refluxer stem from high operating temperature, around 900°C, and liquid zinc being highly corrosive towards ferrous metals. The Refluxer is constructed from silicon carbide sections which join together by means of flat machined faces making liquid metal leaks inevitable. The Refluxer columns are very sensitive to thermal cycling, thermal shock and mechanical vibration, which easily lead to structural failure. To avoid thermal stress on the columns the feed rate and feed temperature need to be kept constant which means the feed baths to the columns must be able to accept solid and liquid feed as the Refluxer has to operate when the smelter is shut down."

Jan 1, 1998

By T. V. Durkin

Approximately 1,390 t (44.7 million ounces) of gold have been produced in South Dakota since 1875. South Dakota's mining laws attempt to strike a balance between economic development and environmental protection by promoting mining as an industry while requiring prevention of pollution and reclamation of affected lands to a beneficial use. The mining laws have evolved since their inception in 1971, especially in response to gold mining. The laws have remained flexible to meet changing regulatory needs. Gold production has continued relatively unabated, even in the face of public scrutiny, two mining moratoriums, and isolated environmental problems. The department's system of "one-stop-shopping" for environmental permits streamlines the permit process, fosters quick resolutions to compliance problems, and helps keep enforcement actions out of the courts. Specific case histories at heap leach mines within the Black Hills are presented.

Jan 1, 1998

By D. Koren, D. Carson

Disposal of smelter slag may be subjected to regulatory leach tests to deter- mine whether they produce a leachate containing contaminants in excess of stated limits. Contaminants that are most often of concern for smelter slags are As, Cd, Cr, Cu, Ni, Pb, and Zn. The present regulatory tests are based on the assumption of storage in a municipal landfill dump, where wastes are in contact with organic acids. Since slags are not normally stored in such an environment, these tests do not adequately assess the true leachability potential of the slags. Ten slags from six major Canadian nonferrous sulfide smelters were studied. Leaching was done following regulatory and modified tests, including leaching in columns with synthetic acid rain for a 25-week period. The slags were characterized by mineralogical analysis before and after leaching with synthetic rain. The synthetic mineral equivalents (hereafter referred simply as phases) in the slow cooled slags consist of fayalite grains and dendrites, amorphous glass, some spinel and small quantities of complex sulfidic prills and metallics. The phases in the quenched slags consist of amorphous glass, some spinel and small quantities of complex sulfidic prills and metallics. Some metal dissolution took place during leaching. However, for all leaching tests, the concentrations were always below the regulated limits. In general, the content of the potentially leachable elements remains unchanged in the fayalite, in the amorphous glass and in the spinel, whereas the quantity of sulfidic prill and metallics decreases after leaching. Therefore, most of the deleterious element dissolution comes from the sulfidic prills and metallic phases. Metal dissolution increases by crushing the slag, probably due to an increased exposure of the sulfidic prills to the leaching solutions.

Jan 1, 1998