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By Peter Wells, Laxman M. Amaratuga, Todd M. Kanhai

"Certain mining methods (eg. Cut-and-fill) result in the contamination of run-of-mine ore with shotcrete. This shotcrete remains mixed with the ore throughout processing. Experimentation performed by Falconbridge Limited revealed that underground contamination of ore by shotcrete (eg. as little as 1% by weight) has led to ill-effects on the nickel recoveries from the flotation process in the mill. The nickel recoveries of contaminated samples were lower than tests without the shotcrete Contamination.To optimize flotation circuits it is important to know why the contamination has created these effects and also to find a method to abate or remove them. Laboratory testing showed that the age of the shotcrete was a factor in it’s effect on nickel recoveries. Younger aged shotcrete gave nickel recoveries lower than baseline nickel recoveries with no contamination. Older shotcrete gave nickel recoveries similar to the baseline.Literature on other cementitious material contaminations on ore revealed that a possible means of remediating this problem is the use of acid in the flotation. The initial pH in the flotation pulp was designed to be pH 9.2, but with the young shotcrete contamination the pH was in the neighbourhood of 10.5. Acid addition may act as a means of lowering the pH to the optimal operational value. Laboratory test work showed that acid addition brought nickel recoveries closer to the baseline."

Jan 1, 2000

By Jim Galvin

4 and 6 point timber chock constructions are used extensively on both a systematic and spot basis by Australian longwall operators to support tailgate roadways. In 1996, the School of Mining Engineering at UNSW published design and performance criteria for timber chocks constructed from Australian hardwoods. The research was funded by the Australian Coal Association Research Program (ACARP). In 1997, ACARP awarded funding for a stage 2 testing program. This testing focussed on examining the effect of using thinner timber elements in chock constructions to improve OH&S and comparing the full-scale performance of traditional 4 point chocks to Link-n-Lock constructions. It was established that chocks constructed from thinner elements have failure loads much less than thicker elements. However up to the failure loads of the thinner elements there was no significant difference in the response to convergence of chocks constructed from 25, 50 or 100mm thick elements. Chocks constructed from 150mm thick elements have a similar ultimate strength to the 100mm thick elements. However, they have a significantly lower resistance to load, thereby permitting more convergence to occur. There is more potential for chocks comprised of thin elements to be constructed 'out of plumb' and so suffer eccentric loading. The full scale testing program established that at any given level of convergence up to 10% strain, the timber in a Link-n-Lock chock generates twice the support resistance of the same quantity of the same timber in an equivalent size 4 pointer chock. On the basis of support resistance per cubic metre of timber, there is only a marginal difference in the performance of 1.0m Link-n-Lock chocks and 1.2m Link-n-Lock chocks constructed from select Blue Gum. The cost per tonne of support provided by a Link-n-Lock chock is effectively half of that provided by a 4 pointer chock of equivalent dimension and timber. Up to a strain level of 4%. Link-n-Lock chocks constructed from 1.2m long elements are slightly more cost effective than the same chocks constructed from 1.0m long elements. Thereafter, there is no significant difference in cost per tonne of support resistance. Beyond a strain level of about 4%, Link-n¬Lock chocks constructed from landscape grade Blue Gum are just as cost effective as Link-n-Lock chocks constructed from structural grade 4 Blue Gum.

Jan 1, 2000

By J. Smolensky, M. Paul

The Nordhalde is a waste rock pile resulting from uranium mining near Ronneburg, Germany. The pile contains over 27 million m3 of waste rock. Typical seepage water has a pH of 2.7 and a sulfate concentration of 10,000 mg/L. Geochemical investigations of the Nordhalde from 1993 to 1996 included drillholes, test pits, ABA and metals analyses, column tests, and a detailed review of the construction history of the pile. In 1996, eight drillholes were instrumented for monitoring oxygen and temperature. Monitoring continued for a fill year. Hourly temperature and pressure readings were taken by automated data recorder. Oxygen concentrations were measured three times per week, and periodic gas samples were obtained for complete analysis. The resulting data set is believed to be one of the most comprehensive of its kind. Effects noted elsewhere, such as thermal convection, are evident. However, unlike other data in the literature, the NordhaIde data shows a strong seasonal effect, with convection dominating oxygen transport only in the winter months. Analysis of the data allowed the amount of contaminants associated with ongoing and historical oxidation to be compared, and results were used to assess the potential effectiveness of proposed remediation measures.

Jan 1, 2000

By Carol Cox Russell

More than two thousand abandoned mines within the Animas watershed in Southwestern Colorado are being prioritized for remediation by the Animas River Stakeholders Group (ARSG). Phased collection and assessment of information progressed from large scale to site specific. Prioritization was based on existing or potential environmental impact and technical feasibility of remediation as measured by dissolved Cd, Cu, and/or Zn in the discharge; indicators of habitat degradation; aquatic life in streams; cumulative impacts at the point of compliance; cost effectiveness; treatiblity/feasibility; and cultural and historic preservation.

Jan 1, 2000

By R G. Jeffrey

The Northparkes, Endeavour 26 orebody is a porphyry copperûgold deposit and comprises a moderately to well jointed rock mass characterised by gypsum veining, the intensity of which decreases with depth. The top 480 metres of the orebody is currently being mined by block caving, the undercut dimensions measuring 196 metres in length by 180 metres in width. Continuous caving was never achieved after the completion of the undercut thus cave inducement techniques were sought to maintain caving so as to safely sustain production. The use of hydraulic fracturing as a cave inducement tool was successfully trialled in December 1997 using existing exploration boreholes located midway up the current lift. Subsequent fracturing campaigns have enjoyed various degrees of success and have yielded in excess of seven million tonnes of ore at a significantly lower cost than conventional cave inducement techniques. Monitoring of both the hydraulic fracture system and the rock mass response has provided considerable insight into the geometry, growth and influence of hydraulic fracture networks above the Northparkes block cave, and has initiated additional research into the use of hydraulic fracturing in other mining methods.

Jan 1, 2000

By R. K. Mehta, U. Cetin

The Nevada Test Site is located approximately 100 km (65 miles) northwest of Las Vegas, NV. The site was primarily used by the Department of Energy for the field testing of nuclear weapons and has been contaminated by several million cubic feet of low-level radioactive wastes, heavy metals, explosive materials, and volatile and nonvolatile organics. The transportation and leaching of these contaminants are creating serious environmental problems. The purpose of this study is to examine pozzolan, a natural alumina-silicate mineral, as a possible replacement for the existing impermeable clay barriers. In the first phase of this study, radionuclide sorption characteristics of pozzolan were investigated. This paper presents the results of the adsorption tests for the target radionuclides.

Jan 1, 2000

By Tobias Hansson

The quality of Lime Cement (L/C) columns is to a great extent dependent on the installation procedure. At a site in the south of Sweden, the client reported problems with the installed columns. To evaluate the operator and equipment dependent part of the installation, Hercules Grundläggning AB was appointed as a competitor to the site contractor. The purpose was to install a number of L/C columns with equal installation parameters for both contractors. A total of 65 test columns were installed in June 1999. The geology is a typical Swedish organic soil profile with a top layer of peat overlying gyttja and clay. Two different binders were used in the comparison; blast furnace slag with cement and lime with cement. After installation, the quality of the columns was monitored by penetration tests and a column sampler for extracting whole columns. The column penetration test were performed 28 and 134 days after installation and extraction 134 days after installation. Inspection and tests of the extracted columns showed that by using a fully computer controlled procedure, the contractor produces columns of superior quality and homogeneity.

Jan 1, 2000

By Ronald Klepper

In hydrometallurgy, pure gases like oxygen and hydrogen are used for oxidation and reduction. The gases are expensive and therefore should be used efficiently. Non reacted gas can be recycled into the liquid. Historically vortex gassing has been used; Le. a mixing impeller close to the liquid surface entrains gas from the headspace into the liquid through a gas vortex. Novel and more efficient methods are surface gassing with up pumping impellers and self- inducing gassing impellers. These alternative impeller systems are well established and common in the chemical industry, but have not been used until recently in hydrometallurgy. Gassing impellers act as internal compressors and increase the interfacial surface for a much higher mass transfer compared to alternate methods mentioned. In the paper results from lab and pilot tests and data from operated plants will be presented. The reactions with gases normally take place under moderate to high pressure, therefore a safe enclosure with mechanical seals and the safety "philosophy" is important. Experienced life and replacement cycles will be reported.

Jan 1, 2000

By Jingbo Liu, Zhimin Wang, Wenchao Li

"IntroductionThe advantages of non-stoichiometric perovskite material are highlighted in many papers[l]and many of this family of materials are well-suited to integration into microsensor devices. Among them, barium titanate is the most promising due to it's piezoelectric, pyroelectric, dielectric properties. Through modification, BaTiO3-based materials can be utilized in many kinds fields, such as surface wave probe; pholoconducting devices, field-effect transistor, permanent memory permanent storage, and ultrasonic transducerl2-3l. In this Paper, a series of BaTiO3-based polycrystals were synthesized by sol-gel processing which appears to be a very promising method for the manufacture of ceramic, because it offers significant advantages such as high purity, chemical homogeneity, controlled particle sizes of ceramics, and lower processing temperatures [4]. In a sol-gel process, alkoxides of the constituent elements show different reactivity toward water so that the preparation of multi-component homogenous system is difficult. In the experiment, inorganic salt was substituted for some of the alkoxides. Acetic acid which is employed for the solvent and catalyst, acts as donor ligand to titanium alkoxide and controls, the hydrolysis polycondensation reaction. Taking these aspects into consideration, we select the system Ba(OAc)2, , La(OAc)3, Ti(O11Bu)4 and acetic acid which is used as both solvent and homogeneous catalyst for the first time.ExperimentalA series of La3+-doped BaTiO3-based nano-crystals were prepared with sol-gel technology using various parameters. The precursor solution was prepared in the presence of barium acetate, lathanium acetate, and titanium tetrabutoxide monomer in butyl alcohol. According to the flow chart (fig. I.), Ba(OAc)2, La(OAch dissolved in the glacial acetic acid (0. lmol/40ml) in a three-neck flask were mixed with a solution of titanium tetrabutoxide monomer in butyl-alcohol(l 7ml/20ml) at room temperature and under constantly, vigorous stirring conditions. In most cases, the resultant solution was golden yellow and stable in the air. To this precursor solution, containing Ba, La, Ti in the desired ratio, water was added incrementally for hydrolysis under continuous stirring until sol was formed. After aging for more than 2 hours, sol was transformed to gel at room temperature. If heated during aging, the gel was formed in a shorter time. The wet gel was allowed to dry at 50°C for more than 10 hours. The dried gel was transparent or light yellow. In order to obtain BaTiO3-based nano-crystals, the amorphous dry gel was calcined at 600°C, 700°C, 800°C, 900°C, 1000°C respectively[5]. The ceramic humidity sensor was formed through the cold-pressed, aged, capsulated routes. The dried gels were crushed in an agate mortar and then pressed into discs of ? 1.5 X l.5mm (l.5mm diameter and l.5mm thickness), then held at about 16.5 MPa pressure for 3 min [6]. The disc was sintered at 1350°C and 1400°C for I hour respectively. During the processing, an Ag-Pt electrode was inserted in the sensor [7]. (See the flow chart.)"

Jan 1, 2000

By A. L. Anderson, J. T. Rybock

KEECO has developed the Silica Micro Encapsulation (SME) technology for the treatment of acidic, metal-laden waters. Utilizing a silica-based chemical formulation that entails chemisorption and micro-encapsulation of heavy metals in a permanent silica matrix, encapsulated particles settle quickly and are effectively isolated from the surrounding environment, producing a stable sludge that is characteristically non-hazardous. In a number of independently-verified pilot and full-scale applications (including the Bunker Hill Mine, Leviathan Mine, Wheal Jane Mine, and Meldon Quarry), SME has been proven highly effective. The technology has been featured in a number of mining publications and selected for innovative technology awards.

Jan 1, 2000

By R A. Medower

This paper provides a glimpse into the future of minerals processing with emphasis on æAutomation InnovationsÆ for the new millennium, particularly those involving advanced process control and innovative new applications of process control technology in 2007.

Jan 1, 2000

The effect of microwave radiation on the processing of Palabora open pit ore has been investigated. Significant reductions in Bond work index are demonstrated for microwave treated samples. Reductions in work index were found to be sensitive to applied power level and method of application. After single stage magnetic separation tests, improvements in recovery of FeO were noted. However, these were curtailed by oxidation of the magnetite species as a result of continued heating. The effects of microwave radiation upon the recovery of copper after froth flotation were also quantified. Small initial increases in recovery of copper were note dafter microwave treatment. However, with prolonged exposure, recovery was found to decrease. Overall recovery of copper was not affected except for samples treated for extended duration. The influence of microwave treatment upon the conventional Palabora grinding circuit has been quantified with the use of USIMPAC software. Conclusions are made regarding the economics of microwave treatment for this ore. Keywords : Microwave; Grinding; Magnetic Separation; Flotation; Economic Analysis

Jan 1, 2000

Sulphide minerals, such as pyrite and sphalerite, are leached by ferric sulphate. This reaction produces ferrous sulphate and other dissolved products. The ferrous sulphate is re-oxidized to ferric sulphate by bacteria. These reactions can be written as: [ ] However, in 1964 Silverman and Ehrlich proposed that this is not the only role that is played by bacteria. These researchers proposed that T. ferrooxidans enhances the rate of oxidation of pyrite above that achieved by chemical reaction with ferric sulphate at the same solution conditions. This enhancement in the rate of dissolution was proposed to occur by direct microbiological action, possibly by the extra cellular secretion of an enzymatic oxidant. Since the Silverman and Ehrlich proposal, different authors have made opposing claims concerning the action of T. ferrooxidanson pyrite. This ?direct mechanism? of bacterial dissolution of pyrite can be given by the following reaction: [ ]

Jan 1, 2000

By Edward J. McNamara

People in the real estate industry are fond of saying that the three most important features of a piece of property are, in order, location, location, and location. This is perhaps the reason that the owners of a well known high-end restaurant chain chose to spend $15 million dollars to renovate 5000 square feet of basement in a 22-story commercial building in the heart of New York City's Time Square. The goal was to create a music club with a stage area and dance floor with a mezzanine level surrounding the dance floor. In order to create the 50' x 40' dance floor and 20' x 40' stage area, 3 concrete columns were removed. New transfer girders were used to transfer the loads of these columns to new steel columns. For the mezzanine, nine columns had to be underpinned. All work continued while the restaurants, shops and offices above carried on business as usual. This paper details some of the means and methods utilized as well as the challenges faced by Underpinning & Foundation Constructors, Inc. in underpinning the columns and installing the new transfer steel.

Jan 1, 2000

The National Mining Hall of Fame will hold its 13thAnnual Induction Banquet during MINExpo International 2000 in Las Vegas, NV. The gala black-tie (optional) event will honor eight legendary leaders of the mining industry. The event will take place at the Las Vegas Hilton Hotel on Sunday, Oct. 8. The induction ceremonies will salute mining greats elected by the board of governors from a list of nominees submitted by mining industry partners and the public. The members of the Class of 2000 will join 151 other inductees enshrined in the Mining Hall of Fame in Leadville, CO. The evening will begin at 6 pm with a cash bar reception followed by the banquet and program at 7 pm. Keynoting the banquet program will be Harrison (Jack) Schmitt. He was the geologist/astronaut of the Apollo 17 mission to the moon in 1972 (see related story on page 26). And he is the only scientist to “kick rocks on the moon.” Schmitt is also a member of the Mining Hall’s board of governors. Schmitt was also the keynote speaker at the First Annual Induction Banquet in Denver, CO in 1988.

Jan 1, 2000

By Glenn Melchert, Paul Eger, Jon Wagner, Dave Antonson, John Folman

Current approaches to reclaiming acid generating tailings include permanent water cover or encapsulation with various synthetic liners and/or clay. Although these methods can be effective, some ongoing maintenance will be required in perpetuity to ensure that water levels are adequately maintained or that the integrity of any capping system is protected. The successful creation of wetlands in tailings basins offers the possibility of creating a stable environment for the tailings with minimal maintenance. Acid-generating tailings from a massive zinc sulfide deposit in Winston Lake, Ontario, were placed in small cylindrical tanks to examine the feasibility and effectiveness of creating wetlands and mitigating acid and metal release. Two uncovered controls were established in addition to the five treatments, which were done in duplicate. Each wetland tank was 117 cm in diameter and contained 6 1 cm of tailings. Treatments included 61 cm cover of wetland soil, 61 cm of glacial till, 61 cm of tailings, and two tanks with 71 cm of water. One of the water covers included the aquatic macrophytes: Elodea canadensis, Potamegeton sp., and Ceratophyllum demersum. Cattails (Typha latifolia) were planted in the plots with substrate cover, and the initial water level was set at ten centimeters. The pH within the tailings in the treated tanks generally ranged between 6.0 and 6.5 and zinc concentration ranged from 0.02 to 0.1 mg/L. The drainage from the controls had an average pH of 3.3, and 7,700 mg/L of zinc.

Jan 1, 2000

By G. T. Adel, J. D. Miller, C. L. Lin

Washability analysis determines the maximum separation efficiency that can be achieved in the operation of coal preparation plants. Unfortunately, there are no on-line techniques for determining this most fundamental information. It now appears possible to determine coal washability on-line through the use of x-ray computed tomography (CT) analysis. This paper presents the results for the development of a CT-based, on-line coal washability analyzer. The development of appropriate hardware and software necessary to adapt a CT analyzer for use in determining coal washability is discussed. Testing of the analyzer using well-characterized coal samples is presented.

Jan 1, 2000

By Dajian Wang

To obtain the thermodynamic properties of a multicomponent liquid alloy system over the whole range of concentration at an arbitrary temperature, the free volume cell theory has been applied to derive the formula of activity coefficients of liquid solutions based on the infinitely dilute solutions at some temperature. The linear logarithmic relationship between activity coefficients of binary dilute solutions and reciprocal of absolute temperature have been verified, and are in good agreement with the experimental values from the literature. The Monte-Carlo algorithm was used to calculate the nonlinear end value equations of binary systems, then the free volume parameters obtained were correlated with the activity coefficients of liquid binary, ternary, and quaternary systems at an arbitrary temperature. Three dimensional a-X-T diagrams of some binary systems representing the temperature and concentration dependence of activities were plotted. The calculated results regarding non-ferrous alloy systems have been statistically examined with the experimental values from the literature. Hence, this simple approach could be useful for analyzing thermodynamic properties of liquid alloy systems.

Jan 1, 2000

By S Dirdjosuwondo, R Plaisance, L Thoma

PT Freeport Indonesia, a subsidiary of New Orleans-based Freeport McMoran Copper and Gold of New Orleans, operates a large mining complex on the Western half of the Island of New Guinea in Tembagapura, Irian Jaya, Indonesia. The IOZ (Intermediate Ore Zone) mine, one of the underground orebodies, is mined by block caving. The area affected by the cave collects a large quantity of rain and ground waters mixing with fine rock particles. The mixture, commonly called æwet muckÆ, sometimes spills into drawpoints and makes the working environment hazardous to the loader operators. Wet muck is observed in an increasing number of drawpoints in the IOZ mine and remote LHD (Load-Haul-Dump) technology has been implemented to handle the ore. The driving force for this automation project has been the safety of the loader operators. The system has been developed mainly in-house and incorporates state-of-the-art features. Up to eight remote loaders and nine rock breakers are controlled from an underground control room located approximately 400 metres from the active extraction panels. The two underground crushers and nine conveyor feeders are also operated remotely from an adjacent control room. The development of FreeportÆs remote system has taken time and considerable effort. Not only the success of the IOZ mine was at stake but also the fulfillment of environmental commitments pertaining to the mill tailings. Approximately eight per cent of the mill feed must come from underground skarn deposits to neutralise the acid-generating tailings generated by the huge Grasberg open pit ores.

Jan 1, 2000

By L. F. Ruppert, W. D. Watson, S. J. Tewalt, L. J. Bragg

The U.S. Geological Survey recently completed a digital coal resource assessment model of the Upper Pennsylvanian Pittsburgh coal bed which indicates that of the original 34 billion short tons [31 billion tonnes] of coal, 16 billion short tons [14 billion tonnes] remain after subtracting mined-out coal. When technical, environmental, and social restrictions are applied to the remaining Pittsburgh coal model, only12 billion short tons [11 billion tonnes] are available for mining. Our assessment models estimate that up to 0.61 billion short tons [0.55 billion tonnes], 2.7billion short tons [2.4 billion tonnes], and 8.5 billion short tons [7.7 billion tonnes] could be available for surface mining, continuous mining, and longwall mining, respectively. This analysis is an example of a second-generation regional coal availability study designed to model recoverability characteristics for all the major coal beds in the U.S.

Jan 1, 2000