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By Andrew Wessman

Keywords: Recycling, Electrodeposition, Recovery, Dilute, Dissolved Metal Ions In order to facilitate the recovery of pure metals from solutions containing a mixture of dissolved metal ions, a pulsed electrodeposition method was developed. Using this method, it is possible to selectively remove metal ions from solution based upon the electrochemical potential of the particular ion desired. The use of pulsed electrodeposition rather than direct current electrodeposition creates an electrodeposited material with better morphology, increases electrical efficiency of the process, and avoids problems with short circuiting between electrodes. Using this method, it is possible to recover dissolved metal ions in a purified form in one simple step, and therefore maximizes recovery of the metal ions while obtaining them in a saleable form. This method is likely to be useful in improving the recycling process for numerous complex metal mixtures and alloys.

Jan 1, 2005

By Ronald E. Heuer

A 1995 RETC paper of similar title presented a method for estimating rock tunnel water inflow based on semi-empirical correlations with borehole water pressure tests. Since that time the author has found the method to be very useful, and it has been used by others in the industry. This current paper is an update which is intended to: A. More clearly explain assumptions and limitations of the method. B. Describe some case history examples. C. Respond to questions which have been raised; and extend the method to other considerations including distribution of inflow along the tunnel, panning requirements, interpretation of tunnel probe hole water inflow, and estimation of potential effectiveness of pre-excavation grouting to reduce water inflow.

Jan 1, 2005

By P Dare-Bryan

Many mines have an interest in improving fragmentation at their sublevel caving operations in order to produce better ore recovery, lower dilution and less overbreak. The primary requirement for the extraction phase is to understand and optimise the flow of the fragmented rock in the rings including interactions with the caved material. Rock fragment formation is critically controlled by the blasting phase and can potentially be improved by optimising the dynamic energy distribution throughout the ring through the crafting of explosive charging, priming position and initiation timing. The modelling of fragmentation and damage due to explosive loading of complete rings is inherently and irrevocably a three dimensional problem that is difficult to address. We have therefore initially utilised an analytical code to predict vector peak particle velocities and energies that are restricted to the plane of a ring. Dynamic energy distributions based on common timing and priming practice have been compared with other possibilities using conventional pyrotechnic detonators as well as initiation designs based on accurate electronic detonators. The energy distribution can be quite subtly tailored to increase energy in appropriate regions or to decrease energy in the brow region for example to potentially reduce instability and the probability of misfires. We have also recently developed the capability to efficiently model particle flow using four-sided polygonal elements. Despite the 2D limitations of such a model this results in more realistic fragment interaction and stacking than can be achieved using conventional rigid circular elements. Modelling of a typical sublevel caving ring utilising these elements activated by the correct dynamics offers considerable potential for understanding the influence of the blasting energetics and timing on the complex flow and extraction process.

Jan 1, 2005

By P. K. Naik, B. Das

Flotation studies were carried out to recover carbon values from blast furnace flue dust containing ~30.34% carbon, 4.6% volatile matter (VM), and 65.03% ash. The variables chosen for the experiments were dispersant (sodium hexametaphosphate), pH, collector (diesel oil), and frother (MIBC). The experiments were designed according to a 24 full factorial design method and regression equations for the recovery of carbon and product grade were determined from the data. Experiments were performed to optimize recovery and grade using the steepest ascent method. The maximum recovery of carbon was 90.0% with a concentration of 56.5%, whereas the maximum obtainable grade of carbon was 66.35% with 50.45% recovery.

Jan 1, 2005

"The application of telerobotics to mining is currently being introduced into production systems around the world. Mining companies in Canada, Sweden, South Africa, and Australia have tended to lead the international charge to this form of technology for mining. While this introduction is taking place, a few basic questions have yet to be answered. How many machines can a single operator run? How many types of machines can a single operator run?A Canadian Research Chair in Robotics and Mine Automation has been established at Laurentian University to investigate these questions and many more through a series of experiments in a telerobotics laboratory that connects Laurentian teleoperation workstations to model mining machines at Cambrian College’s eDome. The laboratory supports many experiments allowing researchers to physically run multiple robot scenarios differing the numbers and types of machines at one quarter scale. Further experiments are being designed to investigate the potential for managing time delays in telerobotics. This paper describes the laboratory, experiments, and some preliminary results."

Jan 1, 2005

Sapporo-Iwanai district is located at the intersection of the northeast Japan arc and Kuril arc, associated with the subduction zone. This area is characterized by Miocene submarine volcanism followed by Plio-Pleistocene subaerial volcanism.   Koryu, a small epithermal Au-Ag deposit, occurred in Pleistocene (1.4 - 0.85 Ma) within Miocene sedimentary rocks near a subaerial andesitic volcano, while Toyoha, a large epithermal Pb-Zn-Ag (-Au) deposit, also occurred near a subaerial andesitic volcano. Although most of the base metal deposits formed in middle-late Miocene, Toyoha formed in Plio-Pleistocene (2.93 - 1.60 Ma) within Miocene volcanic and sedimentary rocks. This epithermal mineralization was partly overprinted by xenothermal Cu-Sn-In(-Au) mineralization (2.68 - 0.49 Ma).   Hydrothermal alteration differs vastly between Koryu and Toyoha: host rocks at Koryu were not intensively altered, although wall rocks adjacent to veins were silicified, while those at Toyoha show intensive and extensive neutral-pH alterations. Geological and chronological studies show that middle~late Miocene (12.5 - 8.4 Ma) alteration was pervasive and overprinted by Plio-Pleistocene (2.93 - 0.49 Ma) alteration. The base metal veins in the middle-late Miocene were not well developed, but were large in number with great depth.   These studies show that the hydrothermal activity at Koryu is rather small and short-lived, while that at Toyoha is large, long-lived and characterized by overprinting of different hydrothermal systems. The subaerial magmatic activities yielded not only the andesite lavas, but also generated hydrothermal solutions for the formation of both Koryu and Toyoha. The metals were possibly derived from such magma. At Toyoha, the hydrothermal solutions could also remobilize metals from old ores.   The size, life span of magmatic-hydrothermal system, and overprinting on the old mineralizing systems could constrain the type of metal deposits (precious and polymetallic deposits) nearby subaerial andesitic volcanoes in Plio-Pleistocene.

Jan 1, 2005

By G. Wozniak, R. Rostanski, H. Pfanz, G. Aschan, E. Sierka

"Industrial wasteland is a typical element of the landscape of all the industrialised regions in Europe. There are many examples from Poland as well as from other European countries that post-industrial sites have been undergone natural colonisation and succession to establish in some cases ecosystems of greater biological diversity than the original ecosystems. The post-industry sites regardless of any reclamation carried out, undergo natural successional processes. The respective biological diversity (number of species, and number of plant assemblages) reflects the micro-variety of the specific habitat. This paper summarizes the results of investigations, which have been carried out since 1989 on coal mine water sedimentation pools in the Upper Silesia Industry Region. The aim of this study is to demonstrate the diversity of spontaneous plant communities recorded on post-industrial waste sites. In the course of the long time fieldwork, plant assemblages representing nine phytosociological groups have been identified."

Jan 1, 2005

Designing for early access to deep orebodies is an essential driver for improved project payback. Vertical shaft sinking techniques have been developed to allow concurrent mine level excavation while continuing to sink. Project cash flows can also be improved when simultaneously deepening existing shafts beneath operating hoisting systems. Further economic advantage has been realised through creative sinking sequencing in twin ventilation/service shaft projects. A fourth technique to reduce project schedules involves partial shaft barrel equipping allowing unrestricted access to construct stations and continue with level installations. This approach reduces interference with barrel sinking activities to insignificant proportions. This paper reviews how these approaches have added significant value to actual shaft sinking projects, as assessed from a contractorÆs perspective, and discusses some of the practical issues to be addressed when planning future projects. Designers need to take cognisance throughout all project engineering phases of the adage that you are only sinking when cleaning the face. Cleaning can only be sustained when there is sufficient hoisting capacity.

Jan 1, 2005

By V. Vorontsov

Catalysts Mo-Ni-S were prepared by combining MoS2 and NiS in weight ratios 1:1, 1:2, 1:4 and 2:1, each of which was admixed with 5%wt Ag and 5%wt YSZ to increase three-phase boundary surface area of the electrode. For comparison catalysts comprising Co-Mo-S in weight ratio of 1:1 of CoS to MoS2 admixed with 5%wt Ag and YSZ and pre-sulfided NiMoO4 were made. The catalysts were examined for electrochemical oxidation of hydrogen sulfide in solid oxide fuel cells (SOFC) at 850°C temperature. The catalyst prepared from 1:1 (wt. %) NiS:MoS2 demonstrated highest performance. Current density up to 1,330 mA/cm2 and power density up to 300 mW/cm2 were achieved using pure H25 gas, which are the highest among the reported H2S-powered fuel cells ever published in the literature. Anode materials of different NiS:MoS2 ratios have been characterized by means of X-ray diffraction (XRD), simultaneous TG/DSC analysis and Neutron Activation Analysis (NAA). TG/DSC and NAA results show that addition of NiS and Ag increases fuel cell performance due to improved structure/integrity of the anode. It has also been demonstrated that MoS2 is a suitable anode material in H2S-powered SOFC, with high activity towards H25 oxidation and thermally and chemically stable up to 850°C.

Jan 1, 2005

By A. M. Galperin

Back analysis is a very important procedure for proper understanding of physical processes. Back analysis can be used to establish the role of different factors, define parameters to be calculated and formulate the behavior of natural or physical processes based on field experimental results. It is evident that, in order to obtain the necessary data for back analysis, field observations are required. For the Michailovsky region (Kursk Magnetic Anomaly, KMA) the long-term strength characteristics of the clay covering the quarry slopes were established with the help of back landslide calculations. The obtained data allowed quantification of the shearing resistance parameters at the presence or absence of intermittent dips of discharge in the pit bank massif structures. Based on the results of investigation for material composition, strength and deformation of finely dispersed (clay-chalk) deposits in the Kursk Magnetic Anomaly including measuring of the settlements of filled structures, complex probing and laboratory determination of water-physical and mechanical properties of "man-made" soils, engineering-geological zoning of filled structures was carried out.

Jan 1, 2005

By Kenneth N. Han, Peter Nam-soo Kim

A kinetic model for leaching of particulate metals in a batch system has been developed. The leaching mechanism has been analyzed by solving a series of ordinary differential equations relating heterogeneous reaction kinetics at the solid/liquid interface to mass transfer of reactant and products. Special emphasis has been given to the effect of changing of the surface area of the leaching substrate and initial particle distribution on the overall leaching rate. The dissolution of gold powders in acidic solution with bromine as an oxidant has been used as a model system. The effect of particle size, chemical reaction order, rate constant and mass transfer coefficient on the overall rate of dissolution of metal powder has been analyzed and discussed.

Jan 1, 2005

By K Ellis, B Lumsden

A full-scale statistically-based on/off plant trial of a new flotation conditioning technology designed to improve fine mineral recovery was undertaken to determine whether the recovery of selected fine sulfide minerals can be increased. The technology is selective for certain sulfide minerals only, including chalcopyrite and sphalerite. The technology has been shown to selectively aggregate the fine chalcopyrite and sphalerite minerals giving increased flotation recovery. The plant trials have shown an increase in the mineral recovery, without decreasing selectivity. Size by size recovery shows a significant increase in the fine (

Jan 1, 2005

By Christophe Thiébaut

Keywords: Pyrochemistry, Salts Treatment, Distillation The pyrochemical purification of metal generates spent salts. When this metal is an actinide such as plutonium, the slags cannot be discarded and are thus disposed in nuclear facility. In order to handle with these slags, the decision has been taken to reduce stored quantities. The development of a pyrochemical treatment is in progress in the CEA Valduc centre. The feed salt, typically composed of various Pu and Am species contained into monovalent or divalent chloride matrix, is first oxidized to convert the actinides into oxides. Then the chlorides are separated from the actinide oxides by vacuum distillation. Temperatures higher than 750°C for monochloride salts mixture NaCl/KCl and higher than 1100°C for divalent CaCl2 base salts, are required to produce an industrial flow of vaporization. Inactive qualification of the process for NaCl/KCl base salt has been carried out with lanthanide surrogates. Then, a pilot equipment, called distillator has been designed and built for production-scale distillation of NaCl/KCl and CaCl2 oxidized plutonium salts. Industrial flows of vaporization have been obtained with this pilot equipment : about 4 g/cm²/h for NaCl/KCl at 800?900°C and 1 Pa, and more than 1,5 g/cm²/h for CaCl2 base salts between 1000?1200°C at 0.1 Pa. The last step, now in progress, is the integration of the distillator into a glove box.

Jan 1, 2005

By Karim El-Ouassiti, Marc Minville, Stéphane Chabot, Claude Bazin, Valérie Ouellet

"Alumina is the main source of aluminium and it is extracted almost exclusively from bauxite ores found in the Southern hemisphere. Clays are abundant minerals that contain from 15 to 40% w/w of alumina from which it can be extracted by various processes. This paper reviews the processes used for the extraction of alumina from clays and discusses results obtained with a clay sample from the Murdochville area in the Quebec Province. The application of a conventional process to this clay did not yield an acceptable recovery although smelter grade alumina was produced. A modification to the process allows increasing alumina recovery from 85% to more than 92%. The application of the improved flow sheet to other alumina carriers failed to yield comparable recovery, showing that an optimum processing path for the recovery of alumina should be found for individual clay materials.INTRODUCTIONMost of the aluminium smelters are fed with alumina extracted from bauxite found in the Southern hemisphere. Bauxite is processed by the Bayer process that uses a caustic leach of the ore. In the middle of the century, the US Bureau of mines, motivated by the fear of an alumina delivery disruption, conducted several research projects aiming at producing alumina from non bauxitic ores. These projects led to the development of various acid leaching processes (Habashi, 1993). The sulphuric and hydrochloric acid leaching processes were brought to pilot plant evaluation (Bengtson, 1979), while nitric and other leach liquors were tested in the laboratory (Phillips and Wills, 1982; Habashi, 1983). Although clays are abundant and inexpensive minerals, the studied processes remained uncompetitive with the alumina extraction from bauxite (Hudson, 1987 page 42; Peters et al., 1962) for which reserves are estimated to support alumina production for the next 50 years (Oye et al., 1999). On the other hand, the local extraction of alumina from clays could significantly reduce the transportation costs of alumina to smelters and provide an alternative source of alumina supply from the Southern hemisphere countries. Also, the extraction of secondary products for some types of clay (Nasyrov et al., 1999) containing significant amounts of potassium and sodium could provide an additional return that may improve the economics of alumina production from clays."

Jan 1, 2005

By Christopher J. Oates

Overview ? Mining Codes ? Best Practice ? Mining Standards Guidelines ? Get it right from the start ? External Auditors ? The 5% rule ? MMCRM's - The Key Components ? The MMCRM Report / Certificate ? MMCRM's & Round Robins ? Summary

Jan 1, 2005

Heatings, fires and explosions in New South Wales (NSW) and Queensland coal mines since 1972, are reviewed. Geological and mine settings are outlined. Where available, gas analysis and critical decisions are discussed. This paper updates work by NSW Department of Mineral Resources (1995) and the Queensland Department of Mines and Energy in a report on fires and explosion in Queensland coal mines (Richardson and Ham, 1996). Incident data has important applications in terms of evidence-based risk assessment and identifying key issues to be integrated into competency based training programs. Predictive indicators are reviewed in terms of coal parameters in seams where the incidents occurred.

Jan 1, 2005

By R-H Yoon

Increasing the upper particle size limit of flotation would allow operators to increase mill throughput, save operating costs, simplify flow sheets, and increase rate of return. However, coarse particle flotation is difficult for various reasons, of which bubble-particle detachment has been identified as the major limiting factor. In the present work, the process of bubble-particle detachment has been studied by directly measuring the forces required to detach air bubbles from hydrophobic solids. The measurements were conducted using a hanging balance apparatus. The measured forces were converted to detachment energies that can be compared with the work of adhesion, which in turn is a function of hydrophobicity, surface tension and contact area. The results were converted to detachment energies using the Young-Laplace equation for capillarity. In the present work, the solid surfaces were hydrophobised by coating them with octadecyltrichlorosilane and cetyltrimethylammonium bromide. The results show that bubble-particle detachment occurs in two steps. In the first step, air bubbles are deformed, while the three-phase contact (TPC) line is pinned, until contact angle reaches advancing angle. In the second step, the TPC line moves along the surface until solid/air interface is replaced by solid-liquid interface. In general, the energies of detachment measured in the second step are in good agreement with calculated work of adhesion. Thus, the energy required during the first step effectively represents an energy barrier for bubble-particle detachment. It has been found that the energy barrier varies with surface roughness and surface tension. The results of the present investigation suggest, therefore, that coarse particle flotation can be improved by control of particle hydrophobicity, surface roughness, and surface tension.

Jan 1, 2005

CSIRO Minerals, in association with the AJ Parker CRC for Hydrometallurgy, has an active program of hydrometallurgical research in which physical and computational modelling are used to better understand and improve a range of different unit operations. The modelling is based on flow simulation (Computational Fluid Dynamics or CFD), but incorporates other physical and chemical phenomena of importance, such as droplet break-up and coalescence, species transport and reaction. This paper reviews some of the major projects that have been undertaken at CSIRO Minerals and will illustrate the critical importance of hydrodynamics to the performance of unit operations and the improvements that can be made to performance using such modelling techniques. Unit operations that are discussed include solvent-extraction, gravity thickeners, flotation cells, bio-heap leaching and stirred tanks.

Jan 1, 2005

By Steve Kral

The coal mining industry in the western United States is seeing the same boom as the rest of the country and the world. Most coal mines in the West are operating flat out as the nation’s appetite for energy continues to grow. And many of the coal mines have either increased their production capacities or are in the process of doing so. However, transportation issues along with environmental restrictions are keeping many mines from expanding even further. Some coal companies held off on further expansion plans until Congress and President Bush could agree on a national energy policy, one that recognizes coal as the nation’s leading source of electricity. In August, Congress passed and the president signed into law such a measure (see Washington Survey, page 7). The legislation includes research funding for clean coal technologies. So western and eastern coal could become even more important in the national energy picture. This is particularly true as supplies of natural gas diminish and the price of oil continues to increase.

Jan 1, 2005

By Chen Song

Keywords: Mixed extractant, Copper, Cobalt, Nickel, Synergistic effect During separation process of copper and cobalt from nickel sulphate solution, the effects of constitutions and compositions of mixed extractant D2EHPA and PC88-A or Cyanex 272, has been studied. In one step extraction cycle, the following results are obtained:[Ni]/[Co]>4000 and [Ni]/[Cu]>40000 in nickel sulphate solution, [Co]/[Ni]>1000 and [Co]/[Cu]>30000 in cobalt chlorinate solution, [Cu]/[Ni]>10000 and [Cu]/[Co]>200 in copper sulphate solution. It was elucidated that the above-mentioned synergistic mixtures can effectively separate cobalt and copper from nickel sulphate acid solution and achieve a greater synergistic effect.

Jan 1, 2005