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By Jiann-Yang Hwang

Microwave heating has been proved an effective method to rapidly heat iron oxide. This offers an opportunity to apply microwave heating in the steelmaking process. The reduction reaction of iron oxide is traditionally achieved at high temperature with reducing gases such as H2 and CO generated from various sources, including coke, coal, and natural gas. This study investigates the differences in iron oxide reduction using conventional and microwave heating under H2 and CO atmospheres. A special microwave thermal gravimetric device was designed and built to facilitate the investigation. With this device, iron oxides can be heated by electric resistance heating, microwave heating, or a combination of methods. The incoming CO and/or H2 also can be preheated to simulate a potential utilization of recovered heat. The iron oxide weight and temperature can be monitored during an entire reduction period. A series of reduction experiments have been conducted. The results are presented and discussed.

Jan 1, 2006

By Jin Liu

To improve value metals recovery, a new operating concept for the Inco flash furnace was investigated, in which the flash furnace coke addition practice would aim at establishing a reducing barrier on the surface of the molten bath. The descending partially oxidized sulfide mineral particles would reach the supernatant coke layer prior to the formation of slag. The key for success depends on the effectiveness of the coke layer to produce a sulfur deficient matte while maintaining furnace production capacity. The mechanism and rate of carbon reduction of the phases formed in the flash flame, i.e. sulfide (matte) and oxysulfide was investigated by means of crucible graphite reduction test work. The objective of these tests was to measure the rate of solid graphite reduction of matte, oxysulfide, slag, and matte+slag mixture at different temperatures. These tests were expected to permit understanding and explaining the reduction mechanism of each material by comparing the respective reaction rates, product reaction gas compositions, reduced material assays, and other relevant parameters. Direct visual inspection of the test crucibles would provide additional information.

Jan 1, 2006

By A Sadri, S Smith

In the metal and mineral industry, different empirical techniques are used to estimate the remaining thickness of the lining within an operating furnace. The disadvantage and costly factor when using these methods is that production needs to be halted. Hatch has developed an accurate and reliable technique based on stress wave propagation principles to determine the condition of the remaining lining whilst the furnace remains online and operational.The technique involves test data collected and compiled to generate 3D imagery used to assist operators and maintenance planning personnel with valuable information showing areas of metal penetration in the lining, remaining lining thickness, exact location of voids, cracks, poor contacts and deterioration due to chemical attack. In this paper, the principals of the AU-E technique will be explained both theoretically and practically. In addition, the use of ultrasound technology for determining the condition of copper cooling elements will be briefly addressed.

Jan 1, 2006

AustraliaÆs current interest in renewable energy is based on a desire to reduce the countryÆs greenhouse gas emissions. Wood from sustainable sources offers a unique opportunity to combine greenhouse gas benefits with other significant environmental and social benefits, including salinity mitigation, carbon sequestration, soil replenishment and rural industry. The challenge is to make renewable energy from wood in a cost competitive manner, so that this broad range of benefits may be best realised. Bioenergy and carbon products are of great interest as new, commercial forestry products that can drive large-scale environmental tree planting:In Western Australia, Enecon has worked with Western Power Corporation to build the first full-scale plant for integrated processing of mallee eucalypts, to produce activated carbon, renewable power and eucalyptus oil. It is intended that this plant is the first of a number of such plants to help catalyse environmental tree planting in Western Australia. New technologies being developed overseas may provide competitive bioenergy in areas where traditional markets for wood do not exist. For example, pyrolysis converts wood into a bio-oil that may be transported to remote sites for power generation in gas turbines. Pyrolysis also produces wood char. Pyrolysis and wood-to-ethanol technologies, coupled with short rotation coppicing trees, offer the long-term prospect of large-scale production of renewable fuels around the country.

Jan 1, 2006

By T Baumgartl, D Mulligan, R Haymont

Mining at the Mt Leyshon Gold Mine in semi-arid north Queensland stopped in 2002. Newmont Australia has recently initiated a thorough post-closure water management study of the site by revisiting the existing information and conducting new water-related investigations. The focus of this paper, which is the first publication on post-closure environmental management of the site, is an overview of the site water quality in view of the sources and spatial distribution of polluted mine water, and also the performance of cover systems in controlling water flux though mine wastes. Since the mine closed the rehabilitation of waste rock dumps and tailings dams have significantly improved water quality in the surface receiving waters. However, the Scats Stockpile, the Heap Leach and Old Plant areas, which can potentially produce acidic waters, enriched with heavy metals and arsenic, are the top management priority. Modelling of the potential transport of contaminants in groundwater needs further investigations. A detailed examination of the waters in seepage sumps showed high concentrations of manganese, cobalt, nickel and selenium, which were previously overlooked. The study also showed distinctive chemical signatures for waters at different locations: the waters draining from scats, supergene materials and waste rocks have distinctly lower pH and higher concentrations of dissolved iron, sulfate, heavy metals, Mg, Mn, U, Se and As. While, the tailings sumps are more alkaline, and are enriched in Na and Cl. The southern tailing sump is characteristically As rich. The waters draining from the supergene materials have higher Cu concentrations. Assessment of the cover monitoring systems showed that although covers pass the design criteria, automated recording of data may ignore any failure of the monitoring system. Recalibration of the moisture sensors not only showed realistic moisture values compared to rainfall data but also showed that the permanently installed system records values that are higher than those of the mobile system. Event-driven recording of data overlooks infiltration events. Besides, with a higher time resolution (daily measurements) the breakthroughs could be clearly detected. Modelling of the water balance in covers is underway and an example is given here. Newmont is currently reviewing water management options and is willing to share the lessons learned.

Jan 1, 2006

By Wolfgang Van Hooff

Encouraged by a strongly growing and evolving market for granulated products, Paul Wurth continuously improves its granulation and dewatering technologies to provide customers with state of the art installations. Continuously developed know-how about the granulation process of iron blast furnace slag enabled application to non-ferrous materials such as Ni-Slag, Pb-Slag, Blister Copper, Cu-Matte and even TiO2-Slag, which rank among the most difficult materials to granulate. This paper identifies how critical objectives in granulation and dewatering technologies applied to different molten materials with respect to various product quality objectives can be addressed. The differences between hot and cold water granulation systems are explained, including the step from cold runner to granulation water tank. Development of a flow and pressure controlled blowing box is the latest step to optimize the granulation process in order to meet the latest standards in terms of quality, power consumption and environmental protection.

Jan 1, 2006

By C. O. Aksoy, P. M. Ozfirat, M. K. Ozfirat, C. Tatar, C. Pamukcu

"Temporal and other factors contributing to the occurrence of occupational accidents at an underground coal mine in Turkey between 1992 and 2000 have been analyzed. The time period of the study spanned the transition from hand-worked mining methods (1992 to 1996) to hand-worked mining methods and mechanized mining methods (1997 to 2000).The mine selected for the study employed an average of 5,835 men per year on three separate eight-hour production shifts for 302 d/y (Sundays are not worked, and there are 11 holiday days per year). Production on an annual basis averaged 190,000 tons per year between 1992 and 1996, and 300,000 tons per year between 1997 and 2000.The purpose of the study was to determine which, if any, of the factors studied contributed to the occurrence of accidents so that the mine could take the necessary steps to reduce the risk to the workforce. Regression analysis was used to determine the strength of the relationship between each factor studied and the number of occupational accidents.The strongest relationships observed were between the age of the employee, the day of the week, and the total yearly labour."

Jan 1, 2006

By Daniel Bennett

There are few methods currently applied towards on-line bulk mineralogical analysis. Yet on-line knowledge of process mineralogy could potentially provide large benefits, such as increased extraction efficiency or resource optimization. The work described in this paper involves the development of radio frequency methods for bulk mineralogical analysis. Some resonances that occur in the radio frequency spectrum are mineral specific, and potentially allow quantitative estimation of mineralogy in an ore stream. Results will be presented on the specific detection of chalcopyrite. Initial quantitative measurements investigating matrix effects have indicated the feasibility of on-line mineralogical estimation using radio frequency techniques.

Jan 1, 2006

By P. Mills

More than 95 percent of all the barite mined and produced is used in the petroleum industry as “drillers mud.” The remaining barite is used in the industrial and medical markets. Therefore, the amount of drilling activity is a good indicator of the health and growth of the barite industry. The four major barite-producing countries in the world are China, the United States, India and Morocco. In 2005, the average number of drilling rigs exploring for oil and gas increased by about 15 percent over the average number in 2004. This increase in oil and gas exploration has resulted in a higher demand for barite and an increase in barite production.

Jan 1, 2006

By Jeremy Gregory

The disposal of end-of-life electronics is an issue receiving increasing scrutiny. This paper evaluates several alternatives for recycling cathode ray tubes (CRTs) within monitors and televisions. The primary recycling options for the glass, reuse in new CRTs or as a smelter flux, are examined from economic and environmental standpoints. The economics are modeled using a cost model that includes dependencies on processing costs, transportation logistics, and incoming material composition. The environmental consequences are modeled using life cycle assessment methodologies to determine the energy embodied in each processing alternative. Results map out preferred processing alternatives across a range of technological and operational conditions. The results indicate that economic costs and environmental consequences are heavily impacted by transportation. The preferred destination of CRT glass for a recycler is highly dependent on the proximity of the consumer to the recycler, although it is generally economically advantageous for the recycler to extensively dismantle the CRTs.

Jan 1, 2006

The U.S. Department of Labor?s Mine Safety and Health Administration (MSHA),through its winter alert program, warns U.S. mine operators and miners at underground coal mines of workplace hazards that can arise when the weather turns colder. MSHA records indicate that, historically, most explosions in underground coal mines occur during winter months. ?The changes in weather can increase the risk of fatal accidents,? says David G. Dye, Acting Assistant Secretary of Labor for Mine Safety and Health. ?Each miner and mine operator must take individual responsibility to eliminate the kinds of hazards that can cause fatal accidents in the workplace. Safety is not the other guy?s job?safety begins with you.? In fact, MSHA?s slogan for this year?s campaign is ?Winter Alert Starts Now and Safety Begins with YOU.? This message reminds miners and mine operators of the risks of colder weather and educates them about helping to reduce risks and hazards. ?Safety requires the joint effort of both management and labor,? Dye says. ?Everyone at the mine site must see safety as an individual value and act to ensure a safe working environment.?

Jan 1, 2006

Bendigo is AustraliaÆs second-most productive goldfield, having produced some 22 million ounces of gold between 1851 and 1954. Bendigo Mining Limited (BML), the sole lease-holder of the Bendigo Goldfield, is developing a mine that is planned to produce ore from beneath the historical workings for at least the next 25 years. The high-grade Bendigo reefs occur in the proximity of the chevron anticlines, which characterise the goldfield. Typically the reefs display relatively small cross-sectional areas and large (subhorizontal) strike dimensions. They occur in clusters due to interrelated structural controls. Most of the gold occurs as visible grains and laminae, and as such grade estimation is not amenable to ænormalÆ sampling and estimation techniques. The initial phases of exploration and development of the mine focused on understanding and resolving these sampling and estimation issues. In 2005, BML reviewed and updated the March 2004 Feasibility Study, refining the life of mine development strategy. The strategy fundamentally aims to exploit the 11 million ounce Inferred Resource and additional exploration potential by developing the current Kangaroo Flat Mine to produce ore at an initial rate of 450 000 t/yr in 2006/07, expanding to 600 000 t/yr by 2009/10; and developing the Eaglehawk Mine to produce 1 Mt/yr by 2011/12. Ore will be processed initially at the Kangaroo Flat site, and from 2011/12 also at the Eaglehawk Mine 1 Mt/yr processing plant. The two mines will connect underground in 2009. Total ore treatment capacity will be 1.6 Mt/yr, producing 600 000 oz/yr from a head grade of 12.7 g/t gold. The project is planned to operate for 25 years, processing 33.6 Mt of ore producing 13.7 Moz of gold. To achieve this production rate, the exploration and ore delineation programs will require up to 16 diamond drill rigs producing over 200 km of core per year. At the same time, approximately 8 km of on-reef development must be monitored and typically 18 stopes managed concurrently. The processing plants will be located in geographically constrained areas, which will limit the ability for selective stockpiling and campaign treatment.

Jan 1, 2006

By Pengfu Tan

Xstrata Copper at Mount Isa in Australia has operated one copper Isasmelt furnace and four P-S converters. The phenomena of foaming occur in above 10% of converter operations. A thermodynamic model of copper P-S converter and a viscosity model of converter slag have been developed to simulate the slag blow and copper blow. The model predicts the chemistry and viscosity of copper skims during copper blow. The effects of oxygen potential, charge of dirty materials, slag carry-over, under-blowing, over-blowing, and temperature on the foaming and viscosity of copper skims have been discussed. Some improvements of the industrial operations have been presented.

Jan 1, 2006

By Florian Kongoli

While calcium ferrite slags have been successfully used in continuous copper converting for the last 30 years, ferrous calcium silicate slag was proposed about 8 years ago as an additional alternative for copper smelting. Although both slags are normal extensions of each other their phase relations have not been completely clarified. In this paper the liquidus relations of both slags have been quantified at various areas that cover both of them. The existing experimental data have been first reviewed and discussed in relation to the solidification procedure. An original physical model is then used to predict various diagrams of the liquidus surface of both slags. It is shown that the ternary liquidus diagrams normally used for FeOx-SiO2-CaO system are not suitable for industrial slags. The new model diagrams of Fe/CaO versus SiO2 and Fe/SiO2 versus CaO as well as Fe/CaO versus Temperature and Fe/SiO2 versus temperature are proven to be much more convenient for ferrite and ferrous calcium silicate slags. Based on these diagrams the effect of SiO2 and CaO on the melting temperature is quantified. The effect of Cu2O is also quantified through the model. Some Fe/CaO versus Cu2O and Fe/SiO2versus CaO at various copper contents are predicted and the results show good agreement with the experimental data. It is also shown that in the presence of liquid copper, Cu2O is dissolved in the slag depending on the oxidation degree of the system and might lower the liquidus temperature. Some discussions are also presented taking into account plant observations and important conclusions are drawn for copper smelting and converting

Jan 1, 2006

By Steve Kral

In 2002, many in the mining industry — companies, academia and government — realized that the industry would soon be facing a serious shortfall in salaried and hourly employees. Depending on whose numbers are to be believed, 20 percent to 50 percent of current mining professionals are expected to retire within five to 10 years. And there are not enough students currently enrolled in mineral-related programs to the fill the need. Part of the impending shortage in professionals was brought on by the industry’s negative image, which discouraged students from enrolling in mining engineering programs. Another part was that the industry was in the doldrums and was seen by the public as a dying industry.

Jan 1, 2006

Thank you for your introduction and the opportunity to speak at such an important forum. I feel honoured to be the Tas McKee speaker for this yearÆs conference. I can honestly say that Tas McKee typified the spirit that has ensured the survival of the mining industry despite the modern-day challenges that we encounter. He was one of the most influential people in the New Zealand minerals industry. In 1938, with his father and brother, Tas established Lime & Marble Limited. Over its history, this company evolved from its original base of marble mining to diversify into gold mining and exploration for other industrial minerals, uranium, precious and base metals. He was truly a pioneer that persevered against the odds.   That leads me to the subject of my discussion today. I am going to delve into todayÆs challenges as they apply to gold companies. While we gold miners should be generating record returns, the gold industry shareholder return performance in this buoyant market has barely equalled that of the gold price. It is a dilemma but one that can be resolved with the right strategy.

Jan 1, 2006

By V. Saltas

In the present work, dielectric spectroscopy experiments were conducted on bentonite samples collected from Milos Island, in order to study their electrokinetic behavior in correlation with water content and mild heat treatment. Low-frequency dielectric spectroscopy has proved to be a power tool in the study of the electrical behavior of clay-water systems, because polarization and relaxation processes typically affect response at frequencies below 100 kHz. Therefore, dielectric and conductivity measurements in the frequency range of 10mHz to 1MHz were carried out by means of a high-resolution broadband spectrometer on bentonite samples, at various levels of hydration. The evolution of dielectric response was also examined after annealing of the samples. Experimental data were computer fitted with the empirical Havrilliak?Negami dielectric relaxation function on which a conductivity term was superimposed. The evaluated parameters of the fitting function are shown to be strongly affected by the water content of the measured samples.

Jan 1, 2006

By D. McConchie

BauxsolTM, prepared by treating bauxite refinery residues with Mg2+ and Ca2+, has an excellent ability to remove arsenic from acidic waters. The addition of BauxsolTM to sulphidic waste rock at the Gilt Edge Mine, South Dakota, reduced As concentrations in leachate water from 35 mg/L to < 0.005 mg/L; the concentrations have remained below 0.005 mg/L for the five years since the treatment was initiated. However, ordinary BauxsolTM does not effectively remove As from near-neutral water and it needs to be acid-treated or blended with small amounts of reagents, such as jarosite or ferrous sulphate, to increase the proportion of positively charged binding sites on the particles. The use of a jarosite/BauxsolTM blend can effectively treat ponded water, and As(V) concentrations can easily be reduced from over 1 mg/L to < 0.001 mg/L; As(III) has to be oxidised to As(V) for effective removal. Metal contaminants in the jarosite are trapped by the BauxsolTM and only very small amounts of the As, or other elements bound during treatment, are liberated using a TCLP leaching test. The exhausted treatment reagents meet the criteria for classification as an inert solid and do not need to be disposed of in a secure repository.

Jan 1, 2006

By Esher Hsu

In Taiwan, around 8,000 tons of batteries are consumed per year but only 17% of which were collected and transported to oversea for recovery. The dumping used batteries have become a potential environment problem. How to increase the collection efficiency of used batteries is an important issue for EPA in Taiwan. Besides, some treatment plants are on process to get permission for recovering used batteries. The objective of this study is to estimate the recycling cost of spent consumer battery and explore the feasibility of recovering used consumer batteries in Taiwan based upon the principle of cost-efficiency. The recycling cost including collection cost and recovery is estimated based on a survey. Results would provide some suggestions to Taiwan EPA regarding feasibility of recovering used batteries in Taiwan.

Jan 1, 2006

By Yavuz Ali Topkaya

Rare earth ferrosilicide is a versatile alloy mainly used to control the detrimental effects of sulfur in steel and to modify graphite structures in cast iron. The aim of this study was to determine the optimum conditions to make rare earth ferrosilicon alloy using a preconcentrate produced from a bastnasite type of ore present in the Beylikahir-Eskisehir region of Turkey. This concentrate contained 23.5%REO, 41.37% CaF2, 10.69% BaSO4, 8.50% CaCO3, 4.18%Fe2O3, 2.83% Al2O3, 2.74% SiO2, 1.20% P2O5 and small amount of other oxides. The initial metallothermic reduction of this concentrate using ferrosilicon and aluminum in a graphite crucible placed in a muffle furnace gave very low recoveries due to the difficulties encountered in adjusting the slag composition, temperature and amount of additives. Therefore, two batches of rare earth oxide concentrate containing 61.1% and 81.7% cerium oxide, respectively, that were procured from a Turkish glass producer, were used to optimize with respect to temperature, duration, slag-making additives and amount of reducers. In these experiments, smelting and reduction was done in an induction furnace with graphite crucible, and, ferrosilicon and aluminum were added after melting the charge. As a result, there was no difficulty in obtaining a rare earth ferrosilicon alloy containing 35-55% RE, 5-25% Fe and 20-40% Si, with about 80% metal recovery. When the optimum conditions were applied to the preconcentrate, alloys of similar compositions were obtained with 70-80% recovery. Experiments were also done with mixtures of preconcentrate and rich concentrate, and, recoveries as high as 95% were obtained. Only in this case, to increase the recovery, mixtures had to be charged to the empty graphite crucible after heating the crucible to the required temperature.

Jan 1, 2006