Search Documents

By Michael Stelter

Lead alloys are a typical material for anodes in technical electrowinning processes. The life time of those anodes differs from 2 years to more than 5 years in tankhouse practice depending on the type of alloy, the mechanical damaging and last but not least the chemical corrosion in the electrolyte. Different types of alloys, such as PbSb, PbCa, PbAg, PbSnCa or PbAgCa have been developed and used in the past, their rate of corrosion being more or less a philosophic discussion. Comparable investigations on the corrosion behavior in dependence of the concentrations of alloying metals, the grain structure and the mechanical and thermal treatment during production have not been conducted before. In the last years the Institute for Nonferrous Metallurgy and Purest Materials of the TU Bergakademie Freiberg investigated the corrosion behavior of the typical lead alloys for metal electrowinning under comparable conditions. Correlations between different alloys, mechanical treatments like rolling or thermal treatment like annealing to the rate of corrosion were made, leading to the conclusion that grain structure and grain size are of eminent importance for the rate of corrosion in technical electrolytes. From these results new and optimized lead alloy anodes can be produced with an increase in life time of the factor 3 ? 5. The optimized lifetime in terms of corrosion stability can not protect from mechanical damaging in tankhouse practice, but with a careful practice the increase in lifetime can save a lot of money and problems.

Jan 1, 2006

By M. R. Julien, A. Maqsoud, J. Martschuk, B. Bussière

Acid mine drainage (AMD) from mine wastes is one of the most challenging environmental problems currently facing the mining industry. When mining wastes have the potential to produce AMD, the effluents produced have to be managed to meet existing regulations on water quality. The LTA impoundment (property of Barrick Gold Corp.) located near Malartic, Quebec, contains sulphide tailings that have the potential to generate an acidic leachate. The closure option selected by Barrick was to construct a cover with capillary barrier effects (CCBE), in which the moisture- retaining layer is made of non-acid-generating tailings. Since its construction in 1996, the cover has been monitored to evaluate its performance. For that purpose, various parameters have been measured, including the volumetric water content and matric suction in the different layers of the cover. This paper presents some of the main results from the monitoring program that started eight years ago. The results show that the cover is able to maintain a high degree of saturation in its moisture- retaining layer, acting as an oxygen barrier. The actual performance of the CCBE on the flat surface of the 60 ha site is better than expected at the design stage. The only concern with the LTA cover is the effect of slopes that can reduce the performance of the CCBE during dry periods. However, these effects appear only for short periods of time, and are limited to very localized areas, so that they do not significantly affect the overall performance of the CCBE and its ability to limit the production of AMD.

Jan 1, 2006

By Marc D. Melker, Geoffrey R. Lane, Michael Jahraus

"The Cresson gold deposit is located in the Cripple Creek district of Colorado. The deposit is composed of volcanic intrusive rocks and volcanogenic sediments where gold mineralization is associated with veins and cavities within a diatremal breccia.The purpose of the current study was to:1. Determine the penetration potential of the Cripple Creek Breccia.2. Assess the relationship between penetration and gold recovery within the Breccia.Two methods were applied using a cyanide solution containing ultraviolet sensitive dye to elucidate pathways of penetration within the rock. The first involved stagnant soaking of twoinch square pieces within the solution. The second method involved column leaching of ~100kg of Breccia crushed to P80 12.7 mm (0.5 inch). Samples were selected at specified intervals to capture the penetration progress of the solution. Photomicrographs and image analysis were utilized to illustrate and quantify the degree of penetration.Results indicated that the maximum penetration for the Cripple Creek Breccia (85 to 97%) due to a porous and permeable groundmass, containing large non-porous lapilli fragments. In addition, ~90% of leachable gold was recovered with only ~50% rock penetration.INTRODUCTIONDye penetration studies were first developed at SGS-Lakefield Research for the purpose of determining the fluid penetration amenability of differing rock types. The method was to place a large rock or drill core in a pan with 1 to 2 inches of a pre-mixed, water based fluorescent dye. The sample was sequentially cut after prescribed time periods to reveal a fresh surface. The cut surface was photographed under long wave ultraviolet light, and the same piece returned to the dye and allowed to sit until the next prescribed cutting."

Jan 1, 2006

By J. M. Lottering

Paper written on project work carried out in partial fulfilment of B Eng (Chem) degree Operational factors influencing the electrostatic separation of mineral sands were investigated in a laboratory separator. Measurements were collected online by means of an optical sensor using diffused reflectance spectroscopy to determine the mineralogical composition. The results have shown that the roll speed and potential were the dominant operating variables, collectively explaining more than 83% and 68% of the product grade and yield, respectively. In contrast, the feed rate, temperature and position of the plate did not affect separation. The effect of the ambient relative humidity, ranging from 10% to 45%, could not be assessed conclusively and at best appeared to have a weakly beneficial effect on the product grade. Keywords: process modelling, high tension roll separator, mineral sands

Jan 1, 2006

By St. E. Deák

This paper focuses on maintenance of underground salt air curative quality using environmental friendly solutions. Possible ways to preserve its curative properties, in relation with the admissible salt air quality parameters, are analyzed. In situ investigations regarding microbiological impregnation in walls and the air inside the Romanian salt sanatorium were initiated. The results of a pilot project, which is in progress at Praid salt mine, are presented. After the end of the investigation at this site, investigations will continue in other Romanian salt mines, such as Slanic Prahova, Targu Ocna and Cacica.

Jan 1, 2006

By I. Ciabatti

Inorganic salts of hexavalent iron (ferrate (VI)) are versatile reagents for water and industrial effluent treatment because of the strong oxidising effect of the ferrate ion (FeO42-) and the well-known coagulation properties of the resulting ferric ion. Among other applications, ferrate can effectively remove arsenic, cyanide and phenols from industrial effluents. Furthermore, ferrate salts can be prepared from ferrous sulphate, a common byproduct of the steel and titanium industries, and possibly from other iron wastes. Notwithstanding their many potential advantages, the industrial-scale application of ferrate salts, such as potassium ferrate (K2FeO4), for effluent treatment has been hindered by the difficulties inherent in their synthesis and stabilisation. Within a project co-funded by the European Commission, the large-scale synthesis of stabilised potassium ferrate was realised through a new synthesis process, and different applications of the resulting ferrate to effluent and wastewater treatment are under investigation. This paper reports the results of the application of stabilised potassium ferrate for the purification of textile effluents. Laboratory and pilot-scale tests were carried out and the performance of the ferrate was compared to that of chemicals currently used in wastewater treatment. According to these experiments, potassium ferrate is a promising reagent for an effective treatment of textile and other industrial effluents.

Jan 1, 2006

By Brian Wyatt, Neil Webb, Marcel Roche, John Thirkettle

Recent developments in survey techniques and measuring equipment now allow for an accurate assessment of external coating condition and cathodic protection performance. These developments build on 20 years of experience of using Direct Current Voltage Gradient (DCVG) and Close Interval Potential Survey (CIPS) methods. The techniques use the latest advances in measurement systems coupled to a bespoke data processing system. The paper describes tests and trial surveys carried out on a hydrocarbon transmission pipeline in West Africa during 2005. The survey works described and conclusions drawn are from the data collected. Of particular interest are the apparent capacitance effects which are thought to occur under disbonded coating and the characteristics that these may show on the integrated CIPS and recorded DCVG profiles. This paper was originally presented at the Cefracor conference in Aix, France, in June 2006 The pipeline was originally installed on a phased basis between 1989 and 1994. The external coatings were three layer polyethylene factory coating and shrink sleeve field joint coating. An impressed current cathodic protection system was installed. The pipeline has subsequently been affected by disbondment of the coatings. It was a primary objective of the trials to attempt to identify such affected areas. In addition to a technically detailed account of the survey works undertaken and the results obtained the authors will consider the practical and commercial aspects of these surveys with input that provides a perspective from the specifier, pipeline surveyor, pipeline operations personnel and the pipeline owner. It is intended that the data presented will provide greater awareness of the benefits and limitations of the techniques used and their role for both stand-alone interpretation and the integration of the survey information with other inspection methods used for external corrosion assessment. The application of the described techniques is well developed and proven to locate and characterise through?coating defects and to provide a full audit of cathodic protection status. However, the possibility of the techniques being able to indicate disbonded coating is unproven and further tests and trials are planned which may allow a greater understanding of the electrical characteristics which are believed to be associated with disbonded coatings which may or may not be filled with an electrolyte. Further work is currently planned in West Africa, South Africa and Scotland in order to improve the understanding of this technique and to determine if the reported indications do actually represent a method of locating disbonded coatings. Keywords: External Coating, Cathodic Protection, DCVG, CIPS, corrosion assessment.

Jan 1, 2006

By J. W. Hohn

The precipitation of Fe(III) to form ferrihydrite in the presence of arsenic is the United States EPA's Best Demonstrated Available Technology for treating arsenic-containing hydrometallurgical solutions and waste streams. This technology has been widely adopted throughout the world and developments have been well reviewed. The adsorption and long-term stability of ferrihydrite can be improved by co-precipitating Fe(III) and Al(III) together to form an aluminum-modified ferrihydrite. Arsenate adsorption into ferrihydrite and modified ferrihydrite as a function of pH, Fe/As or (Al+Fe)/As mole ratio, and the initial As(V) concentration is presented and compared. The results of long-term aging of both adsorbents at 70°C for over a year are also summarized.

Jan 1, 2006

By Koichi Kobayashi

Performance-based approach to design of structures including foundations was adopted after enforcement of the revised Building Standard Law in Japan in 2000. The use of piled-raft foundation is favorable for medium-rise buildings in soft ground because of its good performance. In the design of the piled-raft foundation (Architectural Institute of JAPAN2002), vertical load is usually carried by the raft foundation, while the pile is primarily meant to control settlement of the structure. Shaft friction is expected to be larger in a nodular pile(Karkee, et.al., 1998) since it has larger surface area than a straight pile, and such piles are frequently used in piled-raft foundations. Since few structures with piled-raft foundation exist currently, the settlement characteristics of piled-raft foundation have not been fully clarified. To design piled-raft foundations with better confidence, the mechanism of vertical bearing capacity and the spatial distribution of settlement should be clarified, for which the actual behavior of the building-foundation system needs to be evaluated. This paper presents observations of settlement of a building with a piled-raft foundation at a soft ground site. The building is a steel structure covering an area an 766 m2, and consists of two-storey office block and one-storey warehouse block. The filled ground of about 5-m thickness at the ground surface is underlain by approximately 4-m thick alluvial sand layer below which lies about a 17-m thick alluvial clay layer with SPT N-value less than 2. The piles used in the piled-raft foundation are 12-m long nodular piles with nodal diameter of 500 mm (pile shaft diameter is 400 mm). The bored pre-cast piling method (Karkee, et.al., 1998) was used to install the piles. To evaluate the foundation settlement, the method of analysis of three-dimensional frame system, utilized widely in Japan, was adopted in combination with the foundation system. Basic assumptions were: (i) total ground settlement is evaluated as the sum of immediate settlement and consolidation settlement, (ii) immediate settlement is evaluated from the Mindlin?s solution in which strain dependency of shear modulus of soil is considered, (iii) settlement in clayey layers is evaluated by the one-dimensional consolidation theory, and (iv) shear spring between soil and pile shaft is represented by a hyperbolic function. The applicability of the method of analysis was verified by comparison with results of field monitoring of building settlement.

Jan 1, 2006

Basic parameters affecting the stability of foams have been studied. We used the thin film pressure balance (TFPB) technique of Scheludko and Exerowa (1959) to measure the surface forces in foam films stabilized with various frothers such as pentanol, octanol, MIBC, and PPG. The results were compared with the froth stabilities measured using the shake tests and the film elasticity calculated using the model developed by Wang and Yoon (2006). It was found that the froth stability is controlled by both film elasticity and surface forces (or disjoining pressure), the relative contributions from each changing with frother concentration and type.

Jan 1, 2006

By L. Hacini, N. Van L ê, P. Bacher, D. Thibault

Manufacturer welded components may suffer from high level of residual stresses which can cause premature cracking and decrease the life of the components if they reach values close to the yield strength of the material. In the present work, a robotized hammer peening technique is simulated by an impact machine and the residual stresses generated by the indentation are measured. To better understand phenomena behind residual stresses relaxation by hammer peening, the impact energy level was changed. 304L steel plates were hammer peened with 10 impacts. The contact between the hammer and sample surface was always at the same location. The strains on the surface close to the impact location were recorded during the test using strain gauges to follow residual stresses variations. At the end of the test residual stresses were measured indepth using hole drilling technique at 8mm from the impact center. The micro-hardness was monitored to evaluate the affected zone by the hammer peening. This approach gave a good estimation of the energy and number of blows to be used for efficient relaxation of the manufactured parts.

Jan 1, 2006

By M. Rosales

By a physical and mathematical modeling, the behavior of the tri-dimensional waving, and the movement of the gases at the Teniente Converter was studied. The mathematical model considers the condensed phases of white metal and slag, along the gas phase, and includes the k-e model for the turbulence description. Both the physical model and the mathematical model allow to conclude that from a fluidynamic stand point the Teniente Converter clearly can melt 3000 tpd of concentrates. Also, both models are suitable to predict the slag fluidynamics and its spacial distribution inside the Teniente Converter, and the splashing in the tuyere zone as well.

Jan 1, 2006

By B L. Dickson, E, M F. Lee, P A. Mikula

Computational techniques are needed to assist in the analysis and interpretation of the increasing amounts of geoscientific and mining related data and information that are routinely gathered at mine sites. New interpretation methods are needed to provide an integrated approach so as to establish relationships (cause and effect) or to be predictive about possible outcomes based on acquired data. Traditional multivariate statistical methods are often confused by variable relationships that are non-linear, data distributions that are non-normal, and by the data themselves that may contain missing values, text and both continuous and discontinuous numeric values. Modern data mining methods are available to understand the relationships within and between diverse data sets, and identify relationships or trends associated with processes, measurements and mine design parameters in mines. The self-organizing map (SOM) is a data mining approach with the advantage that all input data samples are represented as vectors in a data-space defined by the observations (variables). The SOM procedure is an exploratory analysis tool that highlights patterns and relationships. Results are internally derived, in an unsupervised fashion based on measures of vector similarity. Our SOM outputs are highly visual, which assists in understanding and illustrating the dataÆs structure and internal relationships. Two studies are presented. The first uses SOM to investigate the relationships between a range of measured and derived rock property parameters and their observed behaviours during mining. Our aim was to determine whether a SOM analysis would allow a better understanding of observed and predicted rock behaviours from their rock properties. The SOM analysis showed that there were indeed relationships between æbrittleÆ, æsugaryÆ, æslabbyÆ and æsqueezingÆ rock behaviours and a number of the input parameters. The computed SOM æstructureÆ was then used to assess the likely behaviour of unknown samples by assigning them into behavioural fields based on their measured and derived geotechnical responses. The second study was aimed at assessing whether a SOM analysis of microseismic data at the Kalgoorlie Consolidated Gold MineÆs (KCGM) Mt Charlotte mine can contribute towards understanding and potentially forecasting/minimising seismicity at the mine-design stage. The database comprised 40 sample æclustersÆ of microseismic parameters from the MS-RAP software package, which were derived from 2500 individual seismic events. The SOM analysis showed that some of the initial mining conditions are related to the seismic parameters. In each of the studies, the SOM procedures assisted in understanding the data and provided new insights. Because of its æordered vector quantisationÆ foundation, the SOM procedure is a substantial improvement over traditional statistical methods in three main areas:its ability to analyse data from disparate sources, including different data types; its ability to analyse sparse data sets with missing values; and its ability to analyse and visualise non-linear relationships within a data set.

Jan 1, 2006

By T Goswami

The conventional practice in open cut coal strip mining has been to blast the overburden or coal layers in separate blast events. This is done in order to maximise the benefits from throw blasting and also to limit coal losses. Each blast event usually has a particular design of hole diameters, burdens and spacings, explosive charges and blast timing in order to achieve the required blast outcome for either the overburden or coal. This means that each blast has to be separately cleaned on the surface after excavation of the previous blast. Hole locations then have to be individually surveyed and marked, holes drilled, explosives and initiators loaded and the blast fired. Each of these actions takes considerable time and resources and therefore impacts on mine productivity. The mine has to be cleared for each blast event and every blast presents a new potential source for noise, dust or vibration disturbance to the neighbouring population. Exposed highwalls are also subjected to vibration and damage from each subsequent blast event

Jan 1, 2006

By W. Beres, R. E. Miller, B. Shiari, L. R. Zhao

A dynamic multiscale simulation method has been developed to study the material scratching processes on nanoscale single crystals. The model simultaneously captures the atomistic mechanisms near the free surface and the long range mobility of dislocations and their interactions, without the computational cost of full atomistic simulations. The method also permits the simulation of system sizes that are approaching experimentally accessible systems, albeit in 2D. Simulations are performed on single crystal aluminum to study the atomistic details, surface evolution, and generation and propagation of dislocations for a variety of scratching depths at room temperature. Simulations demonstrate the power of the developed method in capturing both long-range dislocation plasticity and short-range atomistic phenomena during tool advance. Variations of scratching normal and tangential forces are investigated and related to plastic deformation and dislocations generation during the simulation process.

Jan 1, 2006

By M. Potesser

One of the main targets in the automotive mass industry and supplying industry is the weight reduction of the vehicle for decrease of the fuel consumption. For that reason combinations of different kinds of materials and connections of, for example, steel and aluminium are developed or are already successfully field-tested. A determining factor concerning the quality assessment of the welded joint during hybrid welding is the characterization of the intermetallic Fe-Al layer regarding strength, hardness, morphology and mainly the different phases in which Fe occurs together with the Aluminum (FeAl, Fe2Al5, FeAl3.). A combination of conventional light microscopy, SEM - EDX - analysis, the usage of an atomic force microscope including a Nanoindenter and theoretical thermodynamic calculations turned out to be highly effective. Based on the attained results, the constitution of the intermetallic FeAl layer, influenced by silicon, manganese and zinc, can be predicted.

Jan 1, 2006

By Ali Porbaha

The use of soil nailing technology as a cost effective alternative for excavation support and slope stabilization has substantially increased in the United States during the last decade. For example, in the past thirteen years, more than 185,800 square meters of soil nail walls have been constructed in California alone. The conventional soil nail systems pose difficulties when ground conditions are subject to caving, for instance for silty sand (sugar sand) or cobbles and boulders. The construction industry has developed self drilling hollow bar systems (or pressure injected bored, IBO) that combine both drilling, placing and grouting in a single operation as a solution to speed up construction. While the system is extensively used for temporary applications, nevertheless, some concerns, particularly about corrosion, has limited the use of this technology as a permanent system in North America. This study presents several issues related to self drilling soil nail systems, the results of a field investigation and a summary of the research project.

Jan 1, 2006

By R. Edinger

Aerospace and space products depend, probably more than any other products in industry, on advanced materials. While there are many ways of producing aerospace parts, in many cases the process does not allow the design of the metallurgical properties according to the part or product requirements in accordance with its mechanical configuration. Key to the next level of innovative manufacturing is the capability to control the amount of energy applied to the process, as well as the addition of materials in form of vapor or solid particles such as powder in order to build up the metallurgical composition required. With the development of a high speed pulsed laser-electron beam source, the LASTRON(TM) technology, we deliver the basic requirement for a digital manufacturing process of aerospace and space products. This technology, combining Laser and electron beam, finds application in welding, drilling-machining, and is currently modified to allow digital coating (PEB-PVD) methods. In addition to the coating, a powder metallurgical process, called Rapid Manufacturing (RM), will allow the precision melting of parts based on CAD/CAM files. The RM process and the digital coating will allow the production of graded aerospace alloys in parts for jet engines and aero-structures.

Jan 1, 2006

By A M. Garforth

Insurers are hesitant to provide coverage for Open cast Pit side wall collapse, and even the consequent damage to plant and equipment in the pit as well as the resulting interference with the mining operations. After a general introduction to relevant principles of insurance, this paper addresses some of the major reasons for that reluctance based upon the authors? extensive claims experience, examines what limited coverage can still be obtained and looks to the future possibilities. Confidentiality of sources and examples referred to in this presentation is a natural imperative so that a bibliography is not provided but reference is made to relevant sample insurance policy wordings.

Jan 1, 2006

By K P. Crameri

The Beta Hunt orebody is situated on the south western limb of the Kambalda dome. It is one of the nickel occurrences in the area which fall into the category of æKambalda Style OrebodiesÆ. These orebodies are renowned as being continuous uniformly mineralised ribbons of nickel sulfide mineralisation. Interestingly, Beta Hunt does not conform to this notion of continuity and uniformity and is in fact highly irregular in its ore distribution due largely to the influence of post depositional structure. In an attempt to understand the ore distribution at delineation stage rather than development stage a detailed footwall topography model is created using all available drilling data. To augment this drilling data, the routine use of downhole EM and borehole radar has been introduced to provide data beyond the confines of the drill core to enhance the geological interpretation of the footwall topography and the distribution of the mineralisation. The implementation of a detailed footwall model and the use of downhole geophysics has proved to be very effective in resolving the orebody complexity issues. Ongoing development of the methods used will continue to refine the interpretation of the geology to enable more efficient extraction of the orebody.

Jan 1, 2006