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By D. Markwart, B. Volk

Anode effects are a phenomenon of the aluminium electrolysis process which produce potent greenhouse gases called PFCs (CF4, C2F6). With concerns surrounding global warming, and increasing regulation of GHG emissions, anode effects have become a significant sustainability issue for aluminium producers. In modem smelters, sophisticated computer control and automated alumina feeding systems allow for very tight control of the alumina concentration in the electrolyte and thus very low anode effect frequencies. Older smelters, however, do not have these systems and must either invest heavily to obtain them, or find other, innovative ways to reduce anode effect frequency. This paper will present the integrated approach to anode effect reduction used in the Vertical Stud Soderberg (VSS) potlines at Kitimat Works. Through an innovative combination of simplified signal analysis, modified alumina feed control logic, anode effect prediction, and anode effect prevention using a pager based communication system, Kitimat W arks has been able to make significant reductions to its anode effect frequency.

Jan 1, 2006

By C. Liu

Zeta potentials and settling rates of an oil sands tailings sample taken from Syncrude Canada Ltd's Aurora Stacker Pilot Operation were studied. Two clay minerals, kaolinite and illite, were also studied since these are the major constituent minerals in the fine oil sands tailings. Process water, decanted water as well as distilled water were used. It was observed that the zeta potentials of the tailings solids showed maximum negative values in process water at pH 8-10, which coincides with the pH of commercial hot water bitumen extraction process. The settling rates of the tailings sample were very low, at 0.008 m/hr in decanted water and 0.04 m/hr in process water. The rates were increased to 1.0 m/hr in decanted water and 0.13 m/hr in process water at an addition of 50 g/t Ciba AF1235. Although the settling rate was higher the supernatant was cloudier in decanted water than in process water. Further increase in the dosages of Ciba AF1235 did not increase the settling rates in decanted water but gradually increased it in process water, reaching 0.46 m/hr at 100 g/t. The results indicated that lower concentrations of Ca2+ and Mg2 (in decanted water) benefited settling rates but did not benefit supernatant clarity. Test results also indicated that Ciba AF1235 caused selective flocculation of the tailings sample, since the top sediments had higher illite and lower quartz contents than the bottom sediments.

Jan 1, 2006

By M McLean

This paper deals with change strategies on brownfield and greenfield sites in extractive industries. It draws upon contemporary experiences across Australian, Indonesia and Papua New Guinea (PNG). Change strategies can be used when owners of an extractive industry operation want to optimise their resource. This paper draws upon many tried and proven theories and practices, including the findings of the Tavistock Institute (Trist, Emmery, Bamford, Jaques), as well as the concepts of Adult Learning espoused by Malcolm Knowles and is supported by learnings of Australian based management consultants. This paper reviews a range of approaches that have succeeded in the integration of systems, machines and people, with the key corporate objectives of: increasing productivity; decreasing cost; improving on-time delivery performance and achieving long-term survival. Such integration needs to be measured to show the outcomes from the change strategies and the authors have worked within many measurement regimes and metrics but for the most part, found that JaquesÆ set of metrics being æquality, quantity, resources and timeÆ has gained currency across many Australian operations. This paper contends that investing money in machines alone without a commensurate investment into the people side is counter-productive. Further, if there is not an understanding of processes, ie stable and capable, core and support processes, then all that new technologies will do, is to make what is done badly, only quicker. Recent interventions for the most part, have been cognisant of this balanced approach towards change management. The change strategies described are across extractive industry implementations, using a number of tools and techniques drawn from Continuous Improvement and Six SigmaÖ (registered trade and service mark of Motorola Corporation, USA).

Jan 1, 2006

Pyrometallurgy has played a very important role in southern Africa for at least four centuries. It continues to do so, and recent years have seen many exciting developments in pyrometallurgical technology. The wonderfully diverse rich mineral deposits in this area of the world have provided some unique opportunities for industrial processes to be established. The ?Southern African Pyrometallurgy 2006? conference was set up to showcase southern African pyrometallurgical operations, and to provide a forum for the exchange of ideas between people working at various types of smelters. Papers have been obtained from a wide variety of pyrometallurgical plants in southern Africa. These descriptions of plant operations (as well as some history, and highlights of current work) will provide useful reference information for some time to come. Contributions are also included from universities, research organizations, and engineering companies, so that the full spectrum of pyrometallurgical activities can be covered. The plant descriptions will be published on a website, where they can be updated as and when required, with the eventual goal of having a description of every smelter in the region. The conference venue was selected to be the 'Cradle of Humankind' world heritage area, about 40 km from Johannesburg. Not only does this keep the conference within easy reach of the city and yet far enough out into the countryside to allow people to focus on the conference, it is also within easy reach of many pyrometallurgical plants. There is a particular significance to the choice of location, in that the Swartkrans area close to the Sterkfontein Caves is the site of the earliest evidence of the deliberate controlled use of fire by human beings (about 1.3 million years ago), and this is obviously a necessary precursor to pyrometallurgy. The area also lends itself to a very wide range of outdoor, social, and cultural activities to supplement the technical content of the programme. It is hoped that activities such as a hot air balloon safari and visits to the world-renowned Sterkfontein Caves and Wonder Cave will help to make the conference a memorable one for those able to attend. I trust that the ongoing value of the papers and presentations will make all the hard work of the many contributors most worthwhile.

Jan 1, 2006

By Mike Rogers

Platinum production in Southern Africa amounted to 80% of world production in 2005with a small increase from 5 117 000 ounces to 5 275 000 ounces. For the seventh consecutive year the platinum market is on course to record a moderate deficit in supply. This is reflected in the price increase from a trading range US$860 to US$880 in June 2005 to an excess of US$1 200 in September 2006. Southern Africa, with its extensive platinum reserves, will continue to be the dominant platinum producer and has a number of new mines in an advanced stage of planning. The slogan ?Platinum Surges Ahead? was selected to describe the exciting and vibrantnature of all aspects of platinum mining, beneficiation and marketing. This conference will cover these aspects from exploration and orebody delineation, through mine design, development and operation to mine closure; mineral beneficiation, marketing and compliance with the Mining Charter will also be subjects for discussion and debate. It is also anticipated that the issue of overall increases in productivity, through the introduction of technology, will demonstrate Southern Africa?s status as a premier mining district. It is my pleasure to welcome delegates from abroad and locally, on behalf of the SAIMM, to the Second International Platinum Conference ?Platinum Surges Ahead?. I trust that you will find the proceedings informative and value adding and will participate in the discussions and debate in order to obtain maximum benefit from the conference. I am sure that the post-conference tours will be interesting and of great benefit to participants. Finally, a big word of thanks to the members of the Organising Committee, the management and staff of the SAIMM, and to our willing sponsors, without all of whom this conference would not have been possible.

Jan 1, 2006

The mining industry is an important economical factor in Vietnam. Mining is presently being conducted at about 60 locations and at over 1000 mines. Petroleum extraction and coal mining are the most important parts of industry though metals such as zinc, tin, chromites, iron are also extracted. Last year the sector produced 20 million tons of crude oil, 26 million tons of coal and 500,000 tons of apatite. In particular, Vietnam is one of the world?s largest producers of anthracite, and it is one of the top producers of ilmenite and zircon in the Asia-Pacific region. The government intends to increase the mining production on all levels, however, at present one can observe adverse impacts of the mining activities on the natural environment such as insufficient waste dump rehabilitation, occurrence of acid mine drainage, mining subsidence and emissions as well as lack of appropriate water treatment facilities. This paper describes the current mining situation, future perspectives, the major environmental challenges of the country and approaches to solve these problems. Particular emphasis will be given to the research project ?RAME ? Research Association on Mining and Environment in Vietnam?, a venture carried out by universities, research centres and industry. This project is worked out in collaboration with the national Vietnamese coal and industrial minerals company VINACOMIN.

Jan 1, 2006

By Dan Brown

Deep foundation contracting for transportation projects in the United States has typically followed the design-bid-build model in which contractors bid on a specific work product according to relatively inflexible prescriptive specifications. With continuous flight auger piling and the many types of proprietary drilled displacement auger piling, there appear to be advantages to contracting this work according to a different model. This paper provides a discussion of the use of a performance specification for this work in which the contractor has greater freedom to choose the most appropriate foundation system and also greater responsibility for the performance of the completed foundation. With public agencies subject to open bidding, this type of contractual arrangement presents opportunities to encourage innovation. There are also challenges for implementation in public works projects, notably the selection of qualified contractors and the verification of performance requirements on production foundations.

Jan 1, 2006

By Xiang Sun

Microwave heating has been used in numerous industrial processes due to its great advantages when compared with conventional heating methods. However, microwave heated products can be affected by non-uniform temperature distribution resulting from the mechanisms of microwave heating. To overcome this problem, a critical step is to have a temperature-time profile. In order to characterize and evaluate microwave heating effects, an accurate temperature measurement is needed. This paper discusses the possibility of applying several temperature measurement techniques in microwave processing. Both contact and non-contact methods are introduced and compared.

Jan 1, 2006

By A. Zarei-Hanzaki, S. M. Fatemi-Varzaneh, M. Haghshenas

The microstructure in modified semi-solid ALTHIX (A356) alloy consists of aAl phase with Al/Si eutectic structure. Silicon phase in eutectic structure is coral like with fine fibers. The lack of good ductility in this alloy is related to the presence of silicon fibers. Accordingly many investigations have been recently conducted to modify the Si morphology through Thermomechanical processing on this alloy. In the present work an ALTHIX (A356) alloy was deformed at 450°C, 500°C and 540°C through different strain rates. Consequently the silicon fibers were broken into small particles. The results indicated that the Si particles may coarsen according to Ostwald ripening mechanism at 540°C deformed by rate of0.0005 sec-1 & 0.0001 sec-1-

Jan 1, 2006

By Florian König

It is well known that the bearing capacity and stiffness of displacement piles may increase significantly with time, a phenomenon usually referred to as set-up. In cohesive soils the set-up is commonly explained by consolidation processes in which the dissipation of the excess pore pressures around the pile leads to an increase in effective radial stresses. Recent case histories show that set-up may also occur in sand over a period which exceeds by far the consolidation process. Therefore, other effects apart from the dissipation of excess pore pressures must contribute to this long-term set-up effect. This paper presents the results of a series of multiple pile load tests on prefabricated concrete piles which capture the effect of pile set-up empirically. The main characteristics of the set-up trend are shown with respect to soil type, pile dimensions and distribution over the pile length. Possible reasons for pile set-up like consolidation and stress relaxation after the end of driving are examined using a finite element model which simulates the pile installation process.

Jan 1, 2006

By J. Kirsch

Keywords: Pyrometallurgy, pneumatic transport, pneumatic transport Dense-phase pneumatic injection has begun to replace more traditional furnace-feeding systems. The paper describes the technology as it is applied to processes where the back pressure at the point of injection is greater than 50 kPaG. It reviews earlier systems of injection and more recent developments that address concerns for instantaneous control in modern smelters. The new technologies fall into two groups, (1) modified pressure-difference control (sub-divided into simple and complex) and (2) mechanical-feeder-based control. Features of current injection systems include feed splitting in two forms, passive and active, and co-current injection.

Jan 1, 2006

Ceremonies for the induction of four mining industry pioneers into the National Mining Hall of Fame will be held Saturday, Sept.9, 2006 at the Museum Convention Center in Leadville, CO. The four inductees are Earl H. Beistline (1916 to present), R.A.F. Penrose (1863-1931), Robert M. Reininger (1912-2006) and John Stanton (1830-1906). The inductions will bring to 193 the number of mining “greats” whose engraved photographs and biographical sketches are installed in the National Mining Hall of Fame.

Jan 1, 2006

By S. B. Kang

Magnesium has poor ductility at temperatures lower than 225°C and, as a result, Mg alloy sheets are produced via fairly complex thermomechanical processes consisting of numerous sequential steps of hot (warm) rolling with low reduction and intermediate recrystallization annealing operations. In context of the present study, a simple technology for the fabrication of magnesium sheets by hot (warm) rolling was applied to various magnesium alloys. The misch metal addition in those AZ alloys was done to evaluate the deformation behavior. Tensile tests were carried out for those AZ alloys after applying different heat treatments. The precipitation of ß phase (Mg17Al12 phase) induced different microstructures with various cooling method from solution treatment temperature, and also with various annealing treatment temperatures.

Jan 1, 2006

By Toshiyuki Kozuka

CdTe semi-conducting materials have been expected as solar cell materials because its theoretical energy conversion ratio is very high. The actual efficiency still low, however, many research works have been done in order to improve the efficiency. And crystal orientation is one of possibilities for that. In this work, a new method using intense magnetic field for a control of texture of CdTe crystals will be proposed, where the CdTe film was electro-deposited under an intense magnetic field. CdTe is less affected by magnetic field, because of its cubic structure, but Cd or Te has hexagonal structure, which is sensitive for magnetic field. In this paper, crystal orientation of Cd or Te film, which can be utilized as basic layer for CdTe deposition, will be developed.

Jan 1, 2006

By Ö. Uysal

This study deals with the presentation of the mechanized longwall mining project introduced some years ago to increase productivity and output of Aegean Lignite Establishment (ELI) owned by Turkish Coal Enterprises (TKI.) and the comparison of this method with a planned alternative new mining method called ?shortwall mining? where continuous miners will be introduced as primary coal excavation machines. Following the planning phase, production costs have been calculated for both mining methods on the basis of a panel having a height of 7.5 m. In addition to cost analysis, both methods have been evaluated using ?the multi-dimensional objective system?. In this evaluation the value synthesis has been carried out according to scoring models. Lastly, the advantages and disadvantages of both production methods have been stated by analysing them according to related criteria. In the light of outputs gathered from the analyses, it has been determined that the shortwall mining method will out perform the longwall method. Keywords: continuous miner, shortwall mining, longwall mining, multi-dimensional objective system.

Jan 1, 2006

By Michael J. Brown

It is often necessary to undertake some form of pile testing to verify design calculations. Historically this has been limited to static and dynamic tests. Newer rapid testing methods such as Statnamic are seeing more frequent use. This form of testing can be advantageous due to short set up time and test duration. Although the methodology suffers from a lack of formalised guidance and may prove difficult to analyse in certain soil conditions. This paper investigates the suitability of Statnamic testing and analysis for a range of soil and pile types as well as different installation methods through a number of case studies undertaken in the UK. Recommendations are made on test specification and analysis.

Jan 1, 2006

By M. T. Baquera

A comparison of microstructures associated with W single-crystal ([001], [011], [111]) rods prior to deformation (as grown), and after quasi-static compression (at a strain rate of ~1/s) by transmission electron microscopy (TEM) shows several orders of magnitude difference in dislocation density. Dislocation substructures were not significantly different amongst the deformed sample orientations. In contrast, [001] W rods penetrated into steel targets, at impact velocities of ~1.3 km/s, exhibited heavy dislocation densities and dynamic recrystallization as very distinct microstructural regimes accommodating the penetration process. Twinning on {112} also occurred as a precursor to, or remnant of, these microstructures near the projectile head. These results suggest that deformation accommodating the extreme strains and strain rates associated with the penetration of a single-crystal rod into a metal target is not adequately represented by conventional deformation

Jan 1, 2006

By Hong Liang-shi

Olivine lithium iron phosphate (LiFePO4) is considered as one of the most promising materials for lithium-ion secondary batteries because of its high theoretical capacity, low cost, good safety, benign environment and good cycle performance. In this paper, carbon-free and/or carbon-coated olivine lithium iron phosphate composite ultrafine powders were successfully synthesized from aqueous precursor solutions of (NH4)2Fe(SO4)2?6H2O, H3PO4 and LiOH?H2O by co-precipitation method. The obtained LiFePO4 or LiFePO4/C powders were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). Their electrochemical performance was investigated in terms of cycling behavior. As confirmed by X-ray diffraction and scanning electron microscope, the material obtained by co-precipitation within the temperature range of 60ºC to 100ºC and then followed by moderate heat treatment are a single-phase olivine LiFePO4with the particle size of about 300nm. An improved carbon-coated olivine LiFePO4/C material was prepared by adding conductive carbon materials, such as glucose, activated carbon and acetylene black, into the precursor. The carbon dispersed in the materials increases the electronic conductivity of LiFePO4/C composite, and consequently, leads to high rechargeable capacity of the material. The carbon-coated material with carbon amount of 7.64%wt obtained from glucose has the first discharge capacity of 150.3mAh/g at the rate of 0.1C and 129.3mAh/g at the rate of 1.0C, respectively. After cycled for 50 times, the capacity retention rate is 95.13% at the rate of 1.0C in the voltage range of 2.5 to 4.3 V vs. Li/Li+.

Jan 1, 2006

By Masaki Imamura

A novel hydrometallurgical process for copper concentrate treatment has been developed by Niihama Research Laboratories of Sumitomo Metal Mining Co., Ltd. The process has numerous advantages with respect to the operational and environmental aspects. For example, copper is leached effectively from chalcopyrite concentrates by chlorine gas under atmospheric pressure. The copper in the leach solution is then separated from iron and silver by solvent extraction and undergoes electrowinning for its recovery as a highly pure copper metal; this does not require any further purification. Moreover, iron metal can be produced from the purified raffinate by electrowinning without generating a large volume of goethite or hematite, which are solid wastes generated due to iron rejection in common hydrometallurgical processes. This process can also realize the efficient recovery of precious metals. The results of batch testing and continuous-operation testing are presented in this paper.

Jan 1, 2006

By J Knoblauch, D, P J. J Strobos, C Foggo

The Sally Malay Project is located 120 km north of Halls Creek in the eastern Kimberley region. Since commissioning, ongoing improvements on the plant have resulted in recoveries now greatly exceeding the initial design targets. The continual optimisation endeavours of the Sally Malay metallurgy department included an automation project that was done in close collaboration with Mintek. In this team effort, several problem areas were addressed and the FloatStar advance control system was successfully commissioned to stabilise and optimise the flotation circuit. The remote location of the Kimberley Nickel Mines operation, fly-in, fly-out roster and the current mining boom makes the acquisition of experienced flotation staff difficult. The implementation of an automated flotation control system reduces this burden and contributes to the training of inexperienced staff. This paper illustrates not only the process control improvements achieved as a result of the installation of the FloatStarÖ advanced control system, but also how it has assisted operational personnel with their understanding of the process.

Jan 1, 2006