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By Xiangru Chen, Honggang Zhong, Qijie Zhai, Qingqing Sun

"A horizontal directional solidification equipment, with an in-situ pouring system, was employed to physically simulate the solidification behavior of continuous casting. In this paper, the 2304 duplex stainless steel (DSS 2304) was investigated using this equipment due to its microstructure produced by continuous casting process was usually not satisfied. The grain size combined with the position of columnar to equiaxed transition (CET) of DSS 2304 were observed and the results showed these microstructure characteristics were very close to those of the continuous casting slabs. In addition, the influences of pouring temperatures and cooling conditions on the CET behavior were investigated. The results revealed that the length of the columnar grains decreased with decreasing the pouring temperatures and flow rates of the cooling water. Besides, the content of austenite decreases with increasing the distance from the chilled sidewall.IntroductionDuplex Stainless Steels (DSSs) have been widely used in industry for their excellent mechanical strength and superior corrosion resistance in Cl- environments when compared with other stainless steels [1,2]. Their good performances are mostly on account of the duplex phase structure-ferrite (d) and austenite (?) and the high proportion of alloying elements. Although, DSSs have good ductility, but worse formability compared to the austenitics, and this is the key to restrict DSSs application [3]. This is due to the differences properties between the two phases. The hot workability of ferrite (d) is better than austenite (?) and exhibits a lower flow stress during hot rolling processing [4]. The early workers had revealed that coalescent force of phase interface, microstructure, difference of mechanical property between two phases and the precipitations are the main factors affecting the formability of DSSs [5,6]. Another important reason that affects the alloy’s mechanical properties is columnar to equiaxed transition (CET) [7]. It often occurs during continuous casting solidification process and induces inhomogeneous mechanical properties and the microstructure varies with different processing parameters, such as pouring temperatures, cooling conditions (water flow rates in the cooling zones) and casting speed [8]."

Jan 1, 2012

By Richard Jack De Klerk

The standard industrial method of arsenic removal from acidic aqueous processing effluents involves coprecipitation of arsenic with ferric iron (Fe/As>3) by lime neutralization in continuous circuits. To better understand current industrial practice, continuous circuit coprecipitation experiments were performed to identify industrially relevant process parameters and co-ion solutes that contribute to improved arsenic removal and retention. The coprecipitated solids were subjected to accelerated ageing at 20°, 40° & 70°C and arsenic behavior was monitored and modeled. Staging and the presence of calcium ions were found to have the most significant impact on arsenic retention. In this paper the techniques used and major results obtained are discussed.

Jan 1, 2008

By R. J. Grace

Carbon in the form of coke is used as a reactant in various chemical and metallurgical processes, The high cost of by-product coke along with its periodic lack of availability and high investment necessary for additional by-product recovery facilities indicate the need for a low-cost production unit based on a new procedure for coke manufacture, Traveling-grate coking-stokers were developed by Shawinigan Chemicals Ltd. to produce coke required for carbide manufacture, They were adapted to kilns so that the hot volatile gases could be used for lime burning, Their operation has been described in various patent disclosures (1, 2, 3), and their application to rotary lime burning kilns has been described by Andersen (4). Details of the process and plants have also been published by Kurt Baum (5,6).

Jan 1, 1958

By Horrocks KRS, Smitham JB, Ellison JF

This paper describes the development and installation of equipment for continuously measuring separating density in the dense medium cyclone circuits of the four million tpa Port Kembla B/C plant coal washeries. Monitoring equipment consisting of magnetic coils and differential pressure cells were installed in U-tubes taking the full flow of magnetite from the drain sections of the product drain and rinse screens. The monitoring equipment measures overflow magnetics concentration and overflow density continuously and has operated since 1989. From these measurements and calibration trials, the separating density of operating cyclone modules can be inferred reliably. Variographic analyses of the data show that medium density control to +/- 0.002 RD units and separation density control to +/- 0.007 RD units are achievable. Either method for measuring separation density can be used with approximately the same accuracy, although the overflow density measurement technique suffers from the need to have regular flushing of the Dp cells which complicates the signal analysis. Data from the plant shows that separation density can be controlled by regulating medium density, but the assumption of a constant offset between medium density and separation density is erroneous.

Jan 1, 1993

By Filip Rochette, Yvan De Busscher

Extraction of minerals can be achieved by a variety of technologies; one of them is ion exchange. There are several ion exchange configurations and mechanical set-ups available, but only one technology will provide more process performance and flexibility compared to the other. The multiple column Continuous Countercurrent Ion Exchange (CCIX) technology provides the highest form of process flexibility with also the highest mineral recovery feasible through ion exchange. In comparison with a fixed bed system, the PuriTech CCIX system offers the benefits of continuous counter-current contact mode. This way the resin capacity is fully exploited leading to reduction in resin inventory and, at the same time, in chemicals and water consumption, and product dilution. For any set of operating conditions the mass transfer zone has a characteristic length (MTZL). The MTZL can be expressed in duration, column length, or volume, but is the measure of the quantity of resin in the system that is doing "work" at any given moment in the process. The objective of continuous ion exchange processing is to eliminate all resin volume from the process equipment that is not within a mass transfer zone. In most commercial ion exchange processes for the recovery of metals, CCIX engineering can eliminate as much as 20 - 80 % of the ion exchange resin inventory. Consumptions of water and chemicals are typically brought down around 40% or more. For each type of resin the selectivity/affinity towards a particular metal depends on the basic process conditions such as pH, concentrations of other competing metals in solution. By changing the pH in the ion exchange process phase, the selectivity of the resin can be changed. By doing this, a split elution, or extraction of metals separately can be achieved and the effect of other competing metals (cross-contamination) can be reduced. For example the DOW resin XUS43578 is commonly used for the recovery of copper or nickel/cobalt separation.

Jan 1, 2016

By Clement K. Chase

ION exchange recovery of uranium has been proved successful in many operating plants in various parts of the world. First used in column plants processing clear liquors, ion exchange has more recently been applied in basket resin-in-pulp systems. A logical further development is the application of truly continuous processing techniques to the ion exchange recovery of metals, since previous systems have been semicontinuous at best. Column ion exchange is a valuable technique and has been used extensively in South Africa and elsewhere. However, it requires clear liquors. To produce these clear liquors, considerable investment in filter plant and clarification equipment is necessary. In the cases where it is very difficult or impossible to produce clarified liquors, column ion exchange is not so useful. Moreover, some liquors suffer from post-precipitation after clarification, which can become a serious problem.

Jan 9, 1957

By L. E. Baker, M. J. Leck

OSIRIS is a continuous monitoring system for respirable dust which has been specifically designed for mining and related industries. By using the latest microprocessor technology, OSIRIS provides a sophisticated dust measuring system which is a cost effective alternative to regular gravimetric sampling. The system is certified intrinsically safe for use underground. Up to eight underground OSIRIS sensors can be controlled and monitored by a single IBM PC computer located at the mine surface. This computer provides continuous and instantaneous information about the dust concentrations at the sites being monitored. Information is available in tabular and graphical form. The paper gives details of proving trials of the OSIRIS system in some UK coal mines. During these trials, adjacent OSIRIS sensors placed on the same underground roadway cross-section gave virtually identical results. Throughout a good correlation was obtained with conventional gravimetric dust samples. The OSIRIS equipment proved both reliable and easy to operate. OSIRIS was designed and developed by the Safety Engineering Laboratory of the UK Health and Safety Executive. It is now available commercially and is being

Jan 1, 1987

By J. H. Daniel

Dust-related respiratory disease remains the major health concern in mining, and health agencies are proposing more stringent standards. The U.S. Bureau of Mines (USBM) is investigating techniques to continuously monitor respirable dust in real-time during the coal or ore extraction process. Continuous monitoring will allow mine operators to evaluate hazardous dust concentrations and adjust the operations to produce less dust. Mine instrumentation applications include machine-mounted and hand-held monitors, personal monitors, and area/environmental monitors. Six dust detection methods have been considered to meet application requirements. These are: light-scattering instruments, a smoke-particle detection technique, correlation of pressure drop across the collection filter with amount of dust deposited, the Tapered-Element Oscillating Microbalance (TEOM) instrument, a method that relates the amount of dust collected on a filter with the vibration of the filter, and beta attenuation measurement of dust. Studies to date have identified the TEOM instrument and the technique of correlating the amount of dust collected with the vibration ofthe filter as having the most promise for success. Development of the machine-mounted monitor is the highest research priority. The application options and progress to date in developing continuous monitoring instrumentation are presented.

Jan 1, 1995

By Francois J. E. Scholtz, Raymond J. Davidson, Peter Greenhalgh, R. Paul Riley

A 1 t/d continuous elution pilot plan is being operated by General Mining at their Grootvlei Gold Mine using the technology developed at the Anglo American Research Laboratories. Flowsheet design and plant erection was carried out by Van Eck & Lurie and completed in December 1989. Following the conclusion of six test runs designed to optimise reagent additions, it was shown that elution efficiencies of 98-99% could be achieved using reagent additions as· low as 16 kg/ton of carbon NaCN and 28 kg/ton NaOH while consistently producing eluted carbon containing less than 50 g/t gold. Significant savings were indicated when compared and power were indicated when com­pared with the traditional batch AARL, Zadra and Micron alcohol elution procedures.

Jan 1, 1990

By Kimura. E.

Continuous estimation of phosphorus content of molten copper is required to produce phosphorus deoxidized copper in a continuous casting operation. The phosphorus content of molten copper was related to its electric resistivity, which was measured by the four-probed technique with a specially-shaped cell. In a laboratory scale, the linear relationship between the above factors was confirmed in the temperature range of 1083OC through 1200°C. The phosphorus concentration range measured was from 40 to 500 ppm. The phosphorus content was monitored successfully by measuring the electric resistivity of the molten copper in the distributor of a continuous caster in an industrial scale.

Jan 1, 1992

By T. Y. Chong, J. A. Folinsbee

Since milling began in 1909, the PJV Dome mill has been expanded several times, to the current throughput of 11,500 tonnes per day. PJV recovers free gold using crushing and grinding followed by gravity concentration. The remaining gold in the gravity tails is recovered by cyanide leaching followed by Carbon-In -Pulp processing. Prior to 1993, cyanide tailings were impounded in the tailings pond where cyanide was allowed to degrade naturally. Effluent was discharged seasonally during the summer and early autumn to maintain the water balance. In 1993, an Effluent Treatment Plant (ETP) was designed and constructed for the purpose of removing dissolved metals and suspended solids. In 1997, an INCO SO2/Air cyanide destruction process was added to the ETP. Even though the ETP was successful in meeting the cyanide, metals and total suspended solids (TSS) discharge limits, often the treated effluent failed to pass toxicity tests. Following successful laboratory and plant scale testing, the addition of the chelant EDTA (ethylene diamine-tetra-acetic-acid) was commenced in the 1999 operating season. To date, discharged effluent has passed all toxicity tests. This paper describes the evolution of the ETP from its early conception to the various phases of upgrade needed to meet the MISA discharge limits.

Jan 1, 2005

By J. E. Murphy

The Bureau of Mines demonstrated ferric chloride leaching of galena concentrate on a continuous bench-scale basis. Leaching was performed at 95° C and with a contact time of 15 min. The ferric chloride leaching solution was continuously fed to a leaching tank at a constant rate for periods up to 45 h. In each test a constant redox potential was maintained in the slurry exiting the leaching tank by controlling the concentrate feed rate. In the 45-h test, lead extraction exceeded 99.5 pct, and the lead chloride produced was 99.97 pct pure.

Jan 1, 1984

By R. C. Emmett, D. A. Dahlstrom

Application of continuous filtration to precipitate dewatering requires not only careful equipment selection, choice of appropriate media, but also close control of precipitation technique itself.

Jan 1, 1961

By Jesse R. Jacobson

A large casino complex in Cherokee, North Carolina recently underwent a $633 million expansion that involved substantial foundation challenges. The site is located in a valley on the southern edge of the Great Smoky Mountains National Park, where subsurface conditions typically consist of varying thicknesses of fill overlying alluvium, residuum, partially weathered rock and rock. The fill and alluvium contain cobbles and boulders as large as several feet in diameter. The residuum and partially weathered rock are very thick in some areas, and the depth at which consistently high quality rock is encountered is highly variable. To reduce the foundation costs for the expansion, continuous flight auger (CFA) piles were proposed in lieu of micropiles. CFA piles are not generally used in this geologic environment and concerns regarding their selection included: (1) an uncertainty that CFA piles could be successfully constructed given the difficult conditions and (2) a lack of regional data regarding unit resistance values and load transfer characteristics. To address these concerns, a design-phase test program was undertaken to evaluate pile constructability, develop an understanding of the load transfer behavior, and establish the required pile lengths. The program included soil test borings, shear wave velocity measurements, timed auger probes, instrumented pile load tests and observation of exhumed piles. It was demonstrated that CFA piles could be advanced through the fill, cobble/boulder-laden alluvium, residuum and into the partially weathered rock, albeit with some limitations. Under axial loading, the pile response was very stiff and relatively high unit resistance values were measured. Pile instrumentation allowed for the evaluation and use of design pile lengths shorter than that tested, and the overall reduction in pile lengths yielded a 40 percent reduction in foundation cost. In general, CFA piles were determined to be a suitable, economical foundation alternative.

Jan 1, 2011

By G. G. Richards

"The slag fuming process has operated for close to 70 years to recover zinc from lead blast furnace slag. The process is normally carried out through the batch treatment of slag by submerged injection of coal and air. Within the bath the coal acts as both a reductant, to reduce Zno to zinc vapour, and a fuel, to maintain bath temperature during the endothermic reduction process. The partition of coal between the slag, combustion and bypass is dependent on factors such as bath depth and injection pressure. The option of continuous fuming has been pursued at the D. Blagoev smelter in Bulgaria using heavy fuel oil as reductant/fuel. There has, however, been little attempt at commercial continuous fuming with coal. This paper presents an analysis of a coal-based continuous slag fuming furnace. The data on the Plovdiv fumer is used as a reference point. Critical design criteria for continuous fuming include the slag feed rate, degree of coal combustion and furnace size. Mathematical modelling analysis suggests that continuous fuming with coal can achieve respectable zinc/coal ratios.IntroductionThe slag fuming process was developed in the early part of this century to recover zinc from non-ferrous smelting slags [1-3]. The majority of installed furnaces were put in place to fume zinc from lead blast furnace slag on a batch basis. In most cases coal is used to effect reduction of zinc oxide, but one furnace uses natural gas [4] and, in a curious twist, a continuous fumer was developed based on fuel oil [5].Given the general nature of blast furnace lead smelting, it is not surprising that slag fuming has remained a batch process, in spite of the advantages that could be gained by moving to continuous fuming. Blast furnaces are usually operated as relatively independent units, and tapping has traditionally been done into ladles. The presence of a crane aisle makes direct coupling of the blast furnace to a slag fumer difficult, especially in a retrofit situation. Furthermore, steady-state blast furnace operation is not easy to achieve. The size of these furnaces and the nature of their feed make it difficult to guarantee constant operation."

Jan 1, 1996

By L. Magne, M. Maldonado, R. Varela

Real-time optimization of flotation circuits demands for accurate and reliable measurements to support the decision making process. The collection zone gas holdup is an important variable in this context as integrates the effect of machine and chemical factors on the bubble size and velocity distributions. It has been demonstrated that gas holdup not only correlates with bubble surface area flux, which defines the particle collection rate and recovery in the collection zone, but also with water overflow, a variable which has been related to the froth zone recovery. Therefore, on-line gas holdup measurements provide a reliable alternative to judge efforts leading to the optimization of flotation cells and columns. Estimation of gas holdup in flotation from electrical conductivity measurements has been proposed and extensively used in lab and industrial installations. The approach is based on the application of Maxwell's model, which relates the concentration of a dispersed phase in a continuous medium to measurements of the conductivity of the liquid medium and of the mineral pulp with and without air bubbles included. These measurements require a conductivity cell which covers a representative volume of the flotation cell, and creates a homogeneous electric field throughout this volume that ideally is not affected by the conductivity of the medium. The development of such a cell in the limiting space and geometry of a laboratory flotation cell has been problematic, but a multi-electrode arrangement offers a promising alternative. Electrodes were installed in the flotation cell of a Denver unit; the results of preliminary testing are discussed with a focus on its performance in the measurement of two- and three-phase dispersion conductivity.

Jan 1, 2015

By R. Pérez, James A. Finch, F. Tavera, Cesar O. Gomez

"Gas holdup is a variable which affects the operation of flotation columns. On one hand, gas holdup is a function of bubble size (a function of sparger type, frother characteristics and concentration, and air flowrate), tailings flowrate, solids content, and mixing patterns in the collection zone. On the other, gas holdup defines flotation kinetics and carrying capacity. Therefore, gas holdup is a useful variable to control and diagnose the operation of a flotation column, but the lack of a reliable sensor for on-line gas holdup monitoring has prevented its use in industry.This work describes the principle and the practical difficulties associated with the development of a gas holdup sensor based on the measurement of the electrical conductivity of dispersions. Two different approaches have been devised. These approaches will be described and test results presented of prototypes in laboratory and industrial columns.Background.Several years ago, a research program was initiated at McGill to use electrical conductivity as the basis for developing sensors for process measurements in mineral processing. Electrical conductivity is an intensive property which is a function of the concentration of the different phases present in a dispersion. The initial focus was on the detection of the interface between two dispersions with different characteristics (i.e., that between the collection and froth zones in flotation columns or that between clear water and sedimented solids in thickeners). The technique works in this case by searching for the location at which a sudden change in specific conductivity occurs, as a consequence of different gas holdup or solids content, and absolute values of the specific conductivity of the dispersions involved are not necessary1,2."

Jan 1, 1995

By L. E. Dalverny

This Bureau of Mines report describes the deployment, 5-month operation, and lessons gained from a continuous gas monitoring system using sampling-tube bundles at an underground mine fire in West Virginia. Research information gained indicates the utility of relating certain gas concentration ratios to events during fire development, mine reventilation, and mine recovery. In addition to monitoring the quality of remote fly ash seals, the system provided timely warning of dangerous gas concentrations which developed during surface and underground recovery activities. An evaluation of system components is supplemented by recommendations for improvements.

Jan 1, 1975

By C. M. Sliepcevich

This paper is a brief status summary of investigations by the authors over the past decade to develop a continuous process for recovering' high purity metal powder from pregnant solutions by gaseous reduction at elevated temperatures and pressures. Although these studies included extraction of other metals such as nickel, silver, and gold, this presentation will be confined to the hydrogen reduction of acidic and ammoniacal solutions of copper. The continuous hydrogen reduction process (CHR) described herein enjoys the environmental advantages of other hydrometallurgical processes but, in addition, provides a substantial benefit in fuel economy over competing processes. As was recognized by Schaufelberger in 1956, for a given amount of fuel a continuous hydrogen reduction process has the potential for producing four to six times as much metal as an electrolysis process (1). Although hydrogen reduction of metal salt solutions has been known for more than a century, extensive development work leading to commercialization was not initiated until the 1950's. Since then, commercial applications relative to other extractive techniques have been minor and have been confined to batch or to continuous, completely-mixed autoclaves. By contrast, the process described herein utilizes a continuous, tubular reactor which is operated in modified plug flow so that only limited and localized backmixing occurs. Thus, gradients in concentration, temperature, and pressure exist over the length of the reactor, the presence of which can be utilized to advantage for achieving high conversions and product quality (2, 3).

Jan 1, 1975

By Jouko L. Lehtonen

Sheet pile walls can be sealed watertightly using various methods. The objective of this paper is to introduce a new innovation comprising the use of continuous cement grouting during embedding. The method has been tested on a field test site and installation and permeability features have been observed and analyzed. Installation can be carried out using traditional sheet piling machinery, merely some additional grouting equipment is needed. Installation speed of grouted sheet piles corresponds to that of conventional embedding. The permeability of the tested method is satisfactory in applications where e.g. polluted soil or water has to be isolated from the surrounding environment. In addition, this method can be used for conventional retaining walls where very low permeability is required or for reduction of soil vibration, e.g. close to a railway embankment. The new method to grout simultaneously and continuously during embedding has been developed based on respective innovations on impact driven steel piles.

Jan 1, 2006