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By Lene Hansen

Sulphuric acid plants now and then see unexpected increases in SO2 emissions. Our experience is that it is not always easy for the acid plants to pin point the exact reason for the SO2 increase. Sometimes a catalyst bed is sacrificed even though reliable emperature readings and gas analyses could have verified satisfactory activity, hence the leaking heat exchanger is never discovered and after the shutdown the SO2 emissions are still too high. This paper will look into some basic catalyst management tools: Good record keeping is a necessity for collection of representative catalyst samples, reliable operating data is an inevitable starting point for all analysis and trending of operating data is a must for plant optimisation and troubleshooting. In addition these catalyst management tools will give a continuous updated knowledge of the catalyst status in each bed providing the basis for a more effective replacement strategy. The most typical reasons for increasing SO2 emissions will be presented together with easy guidelines for cross-checking of operating data, temperature optimisation and good record keeping.

Jan 1, 2009

By L. Hansen

Sulphuric acid plants now and then see unexpected increases in SO2 emissions. Our experience is that it is not always easy for the acid plants to pinpoint the exact reason for the SO2 increase. Sometimes a catalyst bed is sacrificed even though reliable temperature readings and gas analyses could have verified satisfactory activity. Hence the leaking heat exchanger is never discovered and after the shutdown the SO2 emissions are still too high. This paper will look into some basic catalyst management tools: good record keeping is a necessity for collection of representative catalyst samples; reliable operating data is an inevitable starting point for all analysis; and trending of operating data is a must for plant optimization and troubleshooting. In addition, these catalyst management tools will give continuous updated knowledge of the catalyst status in each bed, providing the basis for a more effective replacement strategy. The most typical reasons for increasing SO2 emissions will be presented together with easy guidelines for cross-checking operating data, temperature optimization and good record keeping.

Jan 1, 2009

By Haydn H. Murray

The three major catalyst markets that utilize industrial minerals as raw materials are petroleum refining, chemical processing, and emission control. Because of economic, competitive, and regulatory pressures, catalyst producers are pushed to develop products with improved performance to meet changing environmental standards. Also, refiners are demanding new families of cracking catalysts that will crack residual fuels. In 1987, worldwide cracking catalyst sales amounted to $457 million (Occelli, 1988a). Recently enacted federal and state laws to improve air quality have prompted strong growth for environmental catalysts, which in 1989 accounted for more than a third of the $1.9 billion catalyst market in the United States (Farrauto, Heck, and Speronello, 1992). A catalyst is a material that promotes or enhances a chemical reaction but does not itself enter into the reaction. One of the more important mineral groups used as catalysts is clays. The first recorded use of clay as a catalyst was its use in the dehydration of alcohol (Bondt et al., 1797). Clay minerals that are used as catalysts are kaolinite, halloysite, smectite, palygorskite, and sepiolite. Minerals used as catalysts, catalyst supports, or as a raw material to make zeolites are kaolinite, halloysite, sodium montmorillonite, calcium montmorillonite, hectorite, palygorskite, sepiolite, talc, calcined kaolinite, gibbsite, chlorite, and titanium dioxide.

Jan 1, 1994

By P. E. Nolan

The disproportionation of carbon monoxide is an important aspect of reduction processes, in the production of carbon filaments for composites, and in the removal of CO from CO,. It can also be a hindrance, causing carbon fouling of equipment and metal dusting. The reaction is thermodynamically favored at lower temperatures, but it occurs slowly. Catalysis of the reaction by transition metals has been examined. A materials science approach to the selection of a catalyst material and of optimum operating conditions is being taken in the present work. Of particular interest is characterization of a catalyst that can be repeatedly regenerated to prevent deactivation in long term use. Experimental data on a less studied catalyst, ruthenium, are reported.

Jan 1, 1992

By M. Moinpour, Y. K. Rao

The catalysed direct reduction of copper sulphide with carbon and lime was investigated in the range 850-1000 degrees C using Cu2S-CaO-C and Cu2S-4CaO-4C reaction mixtures. The effects of the catalytic additives K2CO3, Li2CO3, Na2CO3, NaF, Na2SO3 and the ternary eutectic (K,Li,Na)2CO3 were determined. Potassium carbonate, sodium fluoride and the ternary appear to be the most effective catalysts for the direct reduction process. The rate enhancement of the catalysed carbothermic reduction of copper sulphide in the presence of lime was explained in terms of the catalysis of the Boudouard reaction

Jul 1, 1991

By M. Rebolledo, N. Mora, G. Zarate

For decades, the mining industry has been focussed to find an efficient and economically attractive process for the leaching of chalcopyrite. Jetti Resources has developed a novel hydrometallurgical alternative to extract metals of value from mineral ores that the mining industry has struggled to process. Jetti’s catalytic technology, whilst being especially advantaged for extracting copper from low-grade and highly refractory minerals, such as chalcopyrite, seamlessly integrates with existing heap leaching methods and downstream processing operations. The technology uses a catalyst which weakens the metal-sulfide bond in the crystalline structure of the chalcopyrite mineral and alters the structure of the passivation layer allowing the leaching process to continue. Metallurgical test work was conducted to examine the effect of ore variability, in terms of grade and copper deportment. The results presented in this study highlight the amenability of the technology and demonstrate that it is possible to enhance leaching performance of copper primary sulfides over a wide range of copper grades, from 0.1 to 2.2%. Further, it is concluded that despite the copper grade, the tests with increasing chalcopyrite content render copper recoveries up to 4 times higher compared to the tests under non-catalyzed conditions. Jetti’s catalytic technology is currently being evaluated at larger scales, namely a commercial dump leach operation and 50-tonne crib tests. The results obtained thus far are compared to the results from conventional sulfide heap leaching tests. INTRODUCTION For decades, the mining industry has been focussed to find an efficient and economically attractive process for the leaching of chalcopyrite. Chalcopyrite (CuFeS2) is the most abundant and recalcitrant of the copper sulfides (Singer, 2017). Owing to its abundance and economic importance, it is the most demandable natural source for copper worldwide. In fact, the projected demand for copper is further expected to rise much higher beyond the current demand by the year 2020 (Panda et al., 2015). Therefore, it becomes imperative to find low intensity hydrometallurgical technologies for the extraction of copper from chalcopyrite in ores of such low-grades that are un-economic to concentrate and to augment the supply by extracting copper from ores with complex mineralogy that cannot be concentrated (Watling, 2013).

Jan 1, 2019

A strategy is presented for a relatively. "low-tech" means for decontamination of streams . containing .low concentrations of toxic metals. Metal ion solutions were . circulate through fluidized beds of activated carbon which support bio-films ?of bacteria .that naturally excrete exopolysaccharides. The attached 'biomass is shown to significantly enhance nickel, cadmium and silver extraction from dilute solutions (5- l00mg/l). By heat treating (at 300º C) the metal/biomass/carbon particles, bio-sorbed silver was subsequently fixed to the carbon surface. This approach to metal decontamination may therefore also provide a route for dispersing and fixing catalytic metal particles over an activated carbon surface.

Jan 1, 1991

By S. Fuchida, Y. O. Zubair, C. Tokoro

Mining of As-bearing minerals had resulted in the release of arsenic species predominantly As(III), which is known to be more toxic, and undue exposure to it is detrimental to human organ systems. Many materials have been examined for As(III) removal, but it is still challenging to advance sustainable materials for effective removal of As(III). In this paper, a more eco-friendly and superparamagnetic Fe0-Fe3O4 composite was synthesised and evaluated for heterogeneous catalytic oxidation and removal of As(III) with peroxymonosulfate (PMS, KHSO5). The kinetic removal studies showed that removal of As(III) was probably through a chemical process and the Elovich model best represented the experimental data. The removal capacity for As(III) on Fe0-Fe3O4 with PMS (1.76 mmol/g) is superior to that without PMS (0.83 mmol/g). Combined results from XPS and ESR showed that As(III) was fully transformed to As(V) through catalytic oxidation by Fe0-Fe3O4/PMS and afterwards enhanced its removal. The removal mechanism of arsenic was ascribed to the formation of outer-sphere (electrostatic attraction) and inner-sphere complexes. The adsorbent can be separated easily from water due to its excellent magnetisation (64.5 emu/g) and also has good reusability potential as more than 85% of the initial concentration of As(III) was immobilised after five consecutive cycles. Keywords: Arsenite, Fe0-Fe3O4 composite, catalytic oxidation, removal mechanism

Jan 1, 2020

To extract the gold from refractory gold concentrate with high sulfur and arsenic, the gold concentrate was catalytically oxidized to expose the gold for cyanide leaching. The effects of reaction temperature, initial nitric acid concentration, reaction time and initial gold concentrate concentration on the conversion rate were studied. The results show that the appropriate conditions for the catalytical oxidation of this gold concentrate are: reaction temperature of 65 oC; initial nitric acid concentration of 25% (wt.); reaction time of 1.5 hours; initial gold concentrate concentration of 10% (wt.). Under such conditions, the conversion rate of gold concentrate is 92%. The solution can be used to prepare nano-iron oxide red pigment. Gases released in the process can be recycled and reused by oxidation absorption. A chemical background of catalytic oxidation is proposed.

Jan 1, 2014

By Buks Kruger

"After the milling and flotation of the platinum bearing ore, the flotation concentrate is electrically smelted in 6-in-line electric arc furnaces and the resulting furnace matte treated in Peirce Smith converters to remove the iron sulphide. The iron free (less than 1% Fe) converter matte is then granulated and sent to the Base Metals- and Precious Metals Refineries for further processing.During the smelting and converting processes two distinct gas streams are produced.The Peirce Smith converter off gas contains 4% - 9% SO2 which is treated in a conventional Sulphuric Acid Plant to produce sulphuric acid (H2SO4).The electric furnace off gas contains 0.9% SO2 and was (until September 2002) vented through a 91 meter high stack to atmosphere.Off gasses which contain less than 3% SO2 is difficult to handle and quite a few processes had been developed over the years to cope with this gas. A broad spectrum of process suppliers and technology approaches is available and the different technologies can be divided into a few main approaches i.e.Scrubbing of the off gas with an alkaline solution to produce an environmentally friendly and stable waste product which can be discharged onto a tailings dam or permanent landfill site.Physical absorption of the SO2 into a chemical solution to produce high quality chemically pure process chemicals.Catalytic reaction of SO2 with O2 to produce SO3 which is absorbed in water to produce sulphuric acid of less than 90% strength.In October 2002 Impala Platinum commissioned a Sulfacid Plant at its Smelter in Rustenburg which recovers the SO2 from the electric furnace off gasses into a weak sulphuric acid solution.The Sulfacid Plant technology is widely used in the paint pigment industry. This is, however, the first application of the technology on electric furnace off gas.The furnace off gasses contains flue dust which is removed in electrostatic precipitators. The gas exiting the precipitators normally still contains between 40 mg/Nm3 and 60 mg/Nm3 dust and passes through a quench-scrubber before entering the reactors. The quench-scrubber cools the electric furnace offgas down from ± 200 °C to 60 °C and act as a final dust removal stage."

Jan 1, 2003

By W Lu, D Wang

Study of coal oxidation at low temperatures forms the basis of investigating the inherent properties of spontaneous combustion of coal. In general, the process of coal oxidation at low temperatures is very complex, involving many factors. Experiments examining the properties of oxidation and ignition of coal have been carried out. Based upon the results of these experiments, the catastrophe properties in the process of coal oxidation are analysed and the mechanism of catastrophe is proved for the ignition of coal. A folding catastrophe model is also established for the process of coal oxidation. Results obtained show that the process of coal oxidation to ignition is discontinuous, where the coal-environment system yields structure destabilisation. The system can jump from one stable attractor to another. The research results presented in this paper help to show the irregularities of coal oxidation at low temperatures and how to pursue effective control measures.

Jan 1, 2005

By Karl Zipf

In highwall mining, once a sufficient number of web pillars are developed, they can fail catastrophically in a domino-type failure, posing a safety hazard to highwall miners and sterilizing mineable reserves. Three recent case histories of catastrophic web pillar failure in U.S. and Australian mines are documented and analyzed with two design approaches. The conventional design approach uses only a strength criterion, while the postfailure design approach uses both strength and stability criteria to insure an acceptable failure mode should strength failure occur. Catastrophic highwall web pillar failures can cost money through equipment losses, production losses, coal reserve sterilization and lost opportunity costs. Coal recovery may be higher. but the benefits of higher recovery must balance the potential costs of failure. Application of the conventional or postfailure design approach will decrease coal recovery and revenues, but the risk of potentially costly failure is much less.

Jan 1, 1999

By Jeff Whyatt

Deformation of underground salt, trona and potash mines is generally time dependent, providing for gradual adjustment of strata to mining induced stresses. Time dependence can allow for higher extraction ratios provided eventual failure can be tolerated. However, this eventual failure can be violent if creep deformation can shift stress and potential energy to strong, brittle geologic units. The mine failure case studies reviewed here illustrate this process. Yield pillars and defects in bridging strata figure prominently in these cases. Yield pillars provide local and temporary support to the roof, temporarily delaying the cave; and allowing extraction ratios and overburden spans to increase beyond the long term capacity of overlying strata. Defects (faults, voids, thinning) of strong overburden strata reduce the critical span, sometimes to less than panel width. Analyses of many of these cases have focused on a cascading pillar failure mechanism, but recent work and this review point to failure of strong overburden strata as the essential element. The suddenness of failure and attendant seismic events pose hazards to miners and, in some cases, to those on the surface. Characterizing these failures is a first step towards recognizing and managing the risk of catastrophic collapse in underground mines.

Jan 1, 2008

By H He, S Tillotson, S Gibbons, J Shaw

"Water evaluation and management during mining exploration and operational activities is crucial to minimise direct and indirect operational costs and also in delivering mining companies the less tangible, but equally critical æsocial license to operateÆ.Mining is often carried out in remote areas, where the mine will be the most significant and visible user and potential contaminator of water resources. However, wherever it is located, a mineÆs use of water must be managed in the context of two key aspects: the natural parameters of the resource; its abundance, its temporal variability and its chemical and physical qualities other users of the resource; other industry, potable water supplies and ecological requirements of local habitats.It is vital, therefore, that this commodity be assessed to an appropriate degree to help establish the viability and sustainability of the mining project and identify those other stakeholders who may be affected by the mining companyÆs activities.This paper outlines the background to catchment-scale model and presents a cost-effective method for establishing a robust water baseline and creating a water management tool to be used throughout whole mine life cycle. Numerical surface and groundwater modelling has long been established as a tool for reactive management, following collation of yearsÆ worth of data. Now, using freely available remote sensing data and desk study information, analytical modelling techniques can be used cost effectively to provide mining companies with a tool for assessing and managing their water consumption requirements at the outset of a new project venture.The paper includes a selection of case studies to show how the use of analytical modelling can be used as an evaluation and management tool to help not only assess general watershed parameters and water availability but also how it can be used as a tool to provide decision makers with the information to complete æwhat if?Æ scenario assessments. The case studies illustrate how a combined hydrological and hydrogeological model may enable identification of sensitive receptors, water competition issues and contaminant migration pathways to help manage the risks associated with water consumption and its potential contamination from exploration and operational activities.CITATION:Gibbons, S, Shaw, J, Tillotson, S and He, H, 2013. Catchment-scale water modelling and its role in risk management during mining exploration, in Proceedings Water in Mining 2013, pp 175-188 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 26, 2013

By P C. J Blackney, I M. Glacken

Spotted Quoll is a massive sulfide nickel deposit located in the Forrestania greenstone belt in the Archaean Yilgarn block in Western Australia. Discovered in October 2007, mining has progressed from open pit to underground and currently uses longhole open stoping with paste fill as the primary stoping method. Immediately prior to 2019, the Mineral Resource estimate (MRE) was defined by a single grade domain of nickel greater than or equal to 0.8 per cent, irrespective of the host lithology, a legacy of the original ore wireframe being built using explicit methods. While a number of obvious structural offsets were honoured in this nickel grade domain, only one modelled fault was used to undertake domaining of arsenic. From 2019 onwards, implicit modelling in Leapfrog Geo™ was used to construct a mine-scale geological model, which triggered the definition of a high-grade core of massive/matrix nickel sulfides surrounded by a low-grade halo of stringer/disseminated nickel sulfides in the surrounding rock. As part of the evolution of the geological model and with the aid of Seequent Central™ to allow collaboration between site-based mine geologists, Perth-based resource geologists and Melbourne-based consultants, a detailed review of the structural mapping was carried out as additional information from underground development became available. This allowed numerous faults and shears to be identified – particularly in the lower half of the mine. These were used to define further structural domains and to refine the understanding of the nickel and arsenic grade distributions in the mineralised envelope. The increased definition to the domains provided by the geological model resulted in a significant improvement in the accuracy of the Mineral Resource estimate, as measured by reconciliation using voids of the mined stopes determined from the cavity monitoring survey (CMS).

Mar 22, 2022

By Tim O’Neil

Caterpillar has introduced its 5090B front shovel, to work with 40 to 70 st (36 to 63 t) trucks. The new unit replaces Cat’s 5080 hydraulic excavator. The 5090B offers more engine horsepower, higher flow, greater digging forces, higher swing torque, faster swing speed and more drawbar pull than its predecessor. It can also handle larger bucket sizes than the previous model. These improvements enhance productivity and make the 5090B a high-volume material handler for hard rock and aggregates producers.

Jan 1, 2003

By William Gleason

"Caterpillar is the largest manufacturer of mining equipment in the world. In hundreds of surface mines around the globe, Caterpillar’s flagship 793 haul trucks can be found moving material for copper, coal, gold, iron ore and other mines. Likewise, its iconic yellow bulldozers are at mine sites the world over — the company recently announced the sale of its 40,000th large dozer. And since its acquisition of Bucyrus in 2011, Caterpillar has positioned itself to become a worldwide leader in the underground mining sector as well.But don’t think that the company is resting on its reputation. As evidence of its commitment to the global mining sector, as well as its confidence in the future of mining, Caterpillar invited mining trade press, including Mining Engineering, to its Tinaja Hills Training Center near Tucson, AZ in November to introduce the latest editions to its mining portfolio. The two-day event focused mostly on the newest electric drive haul trucks, the Cat 796 AC, which will operate in the 326-t (360-st) class, and the 798 AC in the 360 t (400 st) weight class.Caterpillar representatives also spoke about new offerings in the underground space as well as the newest version of the D11 large dozer.“It has been 10 years since we launched the F Series,” Jean Savage, Caterpillar’s vice president, surface mining and technology said. “Since then, we have been on a journey to serve our mining customers and we wanted to have trucks in every application. Today, we are launching two new trucks that will allow us to fill out our portfolio.”While Caterpillar previously offered the broadest range of off-highway haul trucks to the mining industry, it was noticeably absent from the 326-t (360- st) and 360-t (400-st) weight classes."

Dec 1, 2018

Evver since it first displayed an autonomous mining truck at the 1996 MinExpo show in Las Vegas, NV, Caterpillar has been building the blocks to a fully autonomous mine. In May, the company unveiled another block in that progression, the new Cat MineStar System that it says is ?the industry?s broadest, most comprehensively integrated miner operations and mobile equipment management system.? The full system is comprised of five capability sets ? Fleet, Terrain, Detect, Health and Command ? to help operators define the size and scope of their management system based on the needs of their mining operations. Michael Murphy, technology and autonomy manager for Cat Global Mining, explained that the customers were not ready for an autonomous mining truck in 1996, but that many customers wanted the building blocks to eventually get to autonomous mining. After 15 years of work, Murphy said the building blocks have come together in the form of the Cat MineStar System.

Jan 1, 2011

By William R. Yernberg

Caterpillar introduced 21 new products during Caterpillar Press Days ‘96, held in June at the company’s proving grounds near Tucson, AZ. The event, billed as the largest product introduction ever held by Caterpillar, was attended by press from around the world. Most of the new products were demonstrated at Caterpillar’s Tinaja Hills Training Center in the Sierrita Mountains south of Tucson. Under the scorching Sonora Desert sun, the press was treated to demonstrations of the new equipment. After a display of the equipment’s power and capabilities, the press was given an opportunity to operate the new models and, in some cases, compare them with the old.

Jan 1, 1996

By William Gleason

"With desert temperatures climbing high at Caterpillar’s Tinaja Hills Demonstration and Learning Center near Tucson, AZ in September, a group of editors were given a reprieve from the sun and stepped inside the new Cat Minestar Command Center. The movie theater-like temperatures inside were a welcome relief, and the computer screens stationed around the room were an indication of not just how much things have evolved in the mining equipment sector, but also a peek into the future of where mining is headed.Equipment manufacturers like Caterpillar have always had to deal with peaks and valleys in demand that come with mining, perhaps never more so than in the last five years. Sudhanshu Singh, global product manager for Caterpillar, said that in one month in 2012, at the height of the mining Super Cycle, Caterpillar produced more than 150 large mining trucks (haul trucks that carry 136 t/150 st or more). By contrast, Caterpillar produced about 80 of those trucks in the full year of 2016. Between 2012 and 2016, Caterpillar saw its profits drop by 40 percent.“This shows how cyclical the industry is, and it is a testament to the strength of Caterpillar to be able to tolerate the wide swings,” said Singh. Demand for commodities is once again on the rise as are commodity prices with many signs pointing toward a recovery for the mining sector, and Caterpillar has positioned itself for the recovery. During its 2017 press event in September, company officials emphasized that Caterpillar has added strength in its technology divisions by forming new partnerships and adjusting its operating plan.“At the heart of our enterprise strategy is the operating & execution (O&E) model, a strategic framework to identify areas of the business that either create or consume the most value,” said Caterpillar chief executive officer, Jim Umpleby. “Using the O&E model as a guide, we gain a deeper understanding of where we have a competitive advantage, which is key to generating high returns.”"

Jan 11, 2017