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By Y. M. Zhu

Lead in environment often causes a serious health hazard. The removal of Pb2+ from aqueous phase is a beneficial project. In this paper, deposited Saccharomyces cerevisiae (S.c.) was chosen as adsorbent, Pb2+ ions as adsorbate, and the process of biosorption was studied. The dynamics of the adsorption was investigated. The adsorption mechanism of Pb2+ by S.c. cells was also investigated by detecting microstructure, zeta potential under different pH value, FT-IR spectra of the S.c. particles before and after biosorption. It was shown that the biosorption of Pb2+ by deposited S. c. is a rapid process, and the adsorbing equilibrium is reached within 10 minutes. The Zero point of zeta potential of S.c. cells is pH=3.3. When 2.0<pH<3.3, there exists biosorption (biosorption rate 76%~88%), which means static bio-sorption been not the only kind of biosorption. FT-IR spectrum analysis showed that groups on bacteria surface were mainly characteristic groups of protein and amylase; oxo-groups and nitric-groups on S.c. cell surface could chelate with heavy metal ions. Chemical adsorption might exist in the process.

Jan 1, 2014

By Javier Enrique Basurco Cayllahua

In this work, a gram-positive bacteria was used as biosorbent to elucidate the aluminum load capacity under different conditions related to metallurgical and chemical plants. The sorption data followed the Langmuir, Freundlich, Dubinin-Radushkevich isotherms. In order to determine the best isotherm fit, three error analysis methods were used to assess the data: correlation coefficient (R2), residual root mean square error (RMSE) and Chi-square test. The error analysis established that the Dubinin-Radushkevich model fits better the aluminum biosorption data. The maximum sorption capacity was found to be 41.59 mg.g-1. The maximum removal of aluminum was 95% at pH around 5. The experimental kinetics data was evaluated considering two models (pseudo-second order and pseudo-first order). This study indicated that the R. opacus is an environmental friendly biosorbent.

Jan 1, 2009

By Klara Kodrikova, Vera Kasparkova, Michaela Uhlirova, Karel Kolomaznik

"Potentially hazardous wastes from leather industry (blue shavings) are processed into various biostimulators within two steps. The first step takes place at high pH (11-12) and hydrolyzation is implemented with potassium alkali, in the second step the pH is lowered to 9 with phosphoric acid after enzymatic dechromation occurs. The resulting hydrolyzates were analyzed in the sense of molecular weight distribution and tested as biostimulators on rape (Brassica napus). The hydrolyzates can be also directly used as universal NPK fertilizers. It has been proved that the nitrate content in the edible parts of tested vegetables (radish, lettuce, and cucumber) was approximately 200 times lower compared to the vegetables fertilized with an inorganic nitrogen fertilizer. The harvests of vegetables fertilized with the hydrolyzate and the inorganic nitrogen fertilizer were almost the same.IntroductionDuring processing raw hide into leather (tanning processes), only 20% of the collagen material is used for the final product. The remaining 80% ends up as waste, both tanned and non-tanned. Non-tanned waste such as calcimine can be used for production of artificial collagen casings for sausages, gelatine and also in pharmaceutical industry as collagen capsulates. Further processing and recycling of tanned leather waste (especially chrome shavings) is more complicated. Although many technologies producing various quality collagen hydrolyzates have been developed and tested in laboratories, few have been implemented on industrial scale. A promising turn came in the works of ERRC USDA [1,2]. They worked out an enzymatic dechromation technology (hydrolysis) and achieved a considerable decrease of the amount of relatively expensive proteolytic enzyme, which solved the difference between the quality and price of the final product. The American experience of enzymic hydrolysis were applied on industrial scale in the Czech Republic, where a plant was built with daily processing capacity of 3 tons of chrome shavings. The experience of real operation was published in [3] and the cooperation between the Czech Republic and USA partners resulted in a patent [4]. The main asset of the patent was the use of volatile organic bases in the hydrolysis process giving high quality and cheap hydrolyzates with low ash content."

Jan 1, 2008

By J. L. Huisman

Bio(hydro)metallurgy is the latest development in the ongoing search for efficient and economic metal winning processes. In addition to bioleaching, other biotechnology-based applications are becoming more and more accepted. In this paper the THIOMET process for general effluent treatment is described. With this process, it is possible to produce sulfide on-site and on-demand and to use the sulfide to precipitate metals, even selectively when required. The process is ideally suited as a treatment to remove metals after, for example, an acid regeneration process. Another process is proposed that deals with stainless steel pickling bleeds. Such effluents typically contain nitrate, iron, nickel, chromium(VI) and other species. This one process handles these compounds, as well as other metals.

Jan 1, 2006

By Patiño E

Bioleaching is an established technology for the pre-treatment of refractory gold ores and concentrates and the leaching of whole ore copper heaps. In many cases, it offers economic, environmental and technical advantages over pressure oxidation and roasting. However for bioleaching to compete successfully with others pre-treatment processes it needs to be optimized with regard to the parameters that affect the bioleaching reactions and the growth of the microorganism involved. In this sense, this paper focus on the thermodynamic approach applied in bioleaching through of the definition of the growth system and it is thermodynamics analysis, the effect of heat production and energy dissipation on growth and thermodynamic analysis of growth kinetics and the effect of nonstandard conditions.

Sep 12, 2005

By L. Bernoth, I. Firth, S. Rhodes, P. McAllister

As biotechnologies emerge from laboratories into main-stream application, the benefits they offer are judged against competing technologies and business criteria. Bioremediation technologies have passed this test and are now widely used for the remediation of contaminated soils and groundwaters. Bioremediation includes several distinct techniques that are used for the treatment of excavated soil and includes other techniques that are used for in situ applications. They play an important and growing role in the mining industry, for cost-effective waste management and site remediation. Most applications have been for petroleum contaminants, but advances continue to be made in the treatment of more difficult organic and inorganic species. This paper discusses the role of biotechnologies in remediation and pollution control from a mining-industry perspective. Several case studies are presented, including the land application of oily wastewater from maintenance workshops, the composting of hydrocarbon-contaminated soils and sludges, the bioventing of hydrocarbon solvents, the intrinsic bioremediation of diesel hydrocarbons, the biotreatment of cyanide in water from a gold mine, and the removal of manganese from acidic mine drainage.

Jan 1, 2000

By John F. Spisak

Versatile living organisms, historically exploited as functionaries in the food processing, pharmaceutical and chemical industries, have not been successful in achieving similar or significant acceptance within the minerals industry. The current biotechnical revolution coupled with its expanded understanding, dictate that a flagging minerals industry reconsider the use of biotechnology in metallurgical applications. Living resources, either singly, in commensal association or in complex communities, are capable of duplicating fully integrated and complex processing functions. Organisms can mine and extract metals, detoxify chemical effluents and synthetically produce compounds. They have been criticized as exhibiting poor kinetics, excessive energy consumption and environmental sensitivity. However, expanding knowledge reveals that these organisms are surprisingly adaptable, variable and extremely durable. Applied biotechnology in specific cases offers favorable economic returns, environmental benefits and aesthetic value. Selective implementation of living systems can offer opportunities for reduced labor, increased productivity and technological advance. Success will not come easily. Capital must be risked, controversial decisions made and new ground plowed. Traditional, specialist thinkers will of necessity give way to interdisciplinary expertise and unorthodox methodology if success is to be achieved. Those who vigorously persevere, however, are likely to be rewarded with a dynamic and profitable new role in a restructured minerals industry.

Jan 1, 1985

By S. K. Kawatra, T. C. Eisele

"Recent advances in microbiology have made the application of biotechnology to metallurgical processes possible. Hydrometallurgy stands to gain the cost from the use of microorganisms, as they are useful for both dissolution aids and for removing metals from solution. The development of genetic engineering techniques promises to greatly increase the importance of bioprocessing of metals and minerals by the year 2000.In this paper, the basic effects of microorganisms on metallurgical processes are reviewed, and the applications which are currently either in use or near being used are presented. Representative data collected at Michigan Technological University is also given.IntroductionMany hydrometallurgical operations exist which are thermodynamically possible, but which are industrially impractical due to slow kinetics, high reagent costs, or the need for a highly corrosive environment. However, recent discoveries in microbiology indicate that in many cases these difficulties can be reduced greatly by the action of bacteria and other microorganisms (1-8).A major advantage of using living organisms in hydrometallurgy is that once the culture is established the microorganisms produce their own reagents either from the material being processed or from low-cost nutrient supplements. They thus allow extremely complex chemical reactions to be carried out at reasonable cost. The major drawback of using microorganisms is their inability to tolerate extremely high temperatures, excessive concentrations of toxic metals, or very highly acidic, alkaline, or corrosive conditions. However, the complex reactions which bacteria make possible frequently eliminate the need for such extreme conditions. Also, in recent years a number of organisms have been isolated from such exotic environments as hot springs and deep-ocean vents which can tolerate temperatures higher than was previously thought possible for any organism, and can catalyze a number of metallurgically important reactions (8)."

Jan 1, 1988

By A. Kapoor

Gold mill effluents contain toxic pollutants such as cyanide (CN), thiocyanate (CNS), ammonia (NH4-N), and a variety of toxic metals. Various practical and economical technologies are in use for the removal of CN and toxic metals from gold mill effluents, however, the removal of CNS and NH4-N is challenging. The presence of CNS and NH4-N may make effluents toxic to aquatic life. The new Canadian Metal Mining Effluent Regulations will require mine effluents to be nontoxic. As a result, there is a need to develop practical and economical technology for CNS and NH4-N removal. The Mine Effluents Program in the Environment Group is presently evaluating biotechnology processes for the removal of CNS and NH4-N from gold mill effluents. The processes being evaluated are attached growth systems such as a Rotating Biological Contactor (RBC) and completely mixed suspended growth systems such as a Sequencing Batch Reactor (SBR) operating in a batch mode. The research to date at MMSL has shown that the RBC is very effective in removing CNS and NH4-N from simulated effluents. The NH4-N removal project showed that the RBC is capable of removing 0.8 g NH4-N/m2 of RBC disk area per day at an average temperature of 4.5 oC and hydraulic loading rate of 0.02 m3/m2/d. The RBC was also found to be very effective in removing CNS (feed = 200 mg/L and effluent < 1 mg/L) at 8 oC and a hydraulic loading rate of 0.02 m3/m2/d. The SBR was effective in removing CNS and NH4-N (generated from CNS degradation) at SBR operating conditions of two-12 h treatment cycles and a temperature of 12 oC. The end product of CNS and NH4-N oxidation was NO3-N, which is relatively non-toxic.

Nov 1, 2002

By Lee R. Martin, Michael R. Taber

Bird Balls™, the latest development in the ongoing battle at mine sites across North America, help to eliminate accidental avian mortality caused by birds ingesting cyanide leachate. Bird Balls™ are a 4-inch sphere made of high-density polyeth­ ylene (HDPE). They weigh 40 grams and are black in color to provide optimum life in UV intense environments. A floating blanket of bird balls totally excludes birds from a liquid surface. Federal agencies that enforce the Migratory Bird Treaty Act do not specify how to keep migratory birds out of leachate basins. Some state agencies, however, specify that a physical barrier must be in place to exclude migratory birds if cyanide levels are high enough to cause mortality. Industry standards for protecting waterfowl now include Bird Balls™ as well as net­ting, detoxification, and heap leach systems designed in such a manner that no exposed solution ponds or channels exist. Hazing is no longer an option. A bold statement to make? Perhaps, but W. R. Jeffress (1990) covers the subject well when he stated that, "Hazing techniques as a whole have not been effective in excluding waterfowl or other species of wildlife from toxic heap leach solution ponds or tailings impoundments. Research and devel­opment of the new 'Star Wars' hazing techniques, such as laser netting and radar systems, are interesting concepts and will pos­sibly offer an alternative to total physical exclusion or neutral­ization in the future. All of these methods are going to have to be thoroughly tested." For those who may want further docu­mentation, we have included a special reference section cover­ing hazing. R. J. Hallock (1990) stated that, "The Fish and Wildlife Service is particularly interested in migratory birds. In fact, a large portion of our effort, nationwide, is focused on migratory birds. Bird habitats are managed directly through the National Wildlife Refuge System and indirectly through other agency programs. We also have a responsibility to protect birds under the Migratory Bird Treaty Act. Most birds attracted to mine ponds are covered under this Act. The only migratory birds not protected under the Migratory Bird Treaty Act are English Sparrows, Starlings, and Pigeons. Since this is a treaty with five nations, the concept of acceptable losses does not apply. It is not a negotiable situation. There are a few exceptions noted in the Act, including prescribed hunting of selected waterfowl, scien­tific collection, and game bird farming. There is no exception for the loss of migratory birds exposed to solutions of cyanide."

Jan 1, 1996

By J. D. Bateman

DURING the summer of 1942 several chromite deposits were discovered in the Lac du Bonnet district about eighty miles northeast of Winnipeg. The deposits are confined to the Bird River complex, a folded composite sill of basic and ultrabasic igneous rocks of early Precambrian age that lies to the north of Bird river (1). The outcrop of the sill represents the trace of an easterly plunging anticline, the south limb extending from the northeast bay of Lac du Bonnet eastward to Bird lake, and the other limb, 6 to 12 miles north, lying between Maskwa river and Euclid lake. The south limb of the sill is 20 miles long, and the northern counterpart 15 miles; but its continuity is interrupted by faulting and by the intrusion of younger granite, so that the total length of outcrop of both limbs does not likely exceed 25 miles. The sill is intrusive into early Precambrian greenstones and associated sedimentary rocks. The chromite discoveries have been made at several localities on both limbs of the sill, and in each case at the same geological horizon. The sill comprises an upper layer of hornblende gabbro and a lower layer of serpentinized peridotite, and altogether is from 500 to 3,500 feet thick. The chromite zone is within and near the top of the peridotite layer, and thus about midway of the sill, both of the limbs of which stand nearly vertical. This geological relationship was established early in the exploration of the initial discoveries and served as the basis for successful predictions of later discoveries. The chromite zone probably persists throughout the length of the sill, but its width and chromite content are not everywhere the same. The initial exploration along both limbs of the sill has shown a combined total length of about 12,000 feet of chromite ore varying in width from 6 to 12 feet. In many places the overburden is thick and obscures the continuity of the chromite zone; but as investigation proceeds the known deposits will be extended and new ones will be found. Thus, although a total length of 12,000 feet of ore has been investigated up to the present time, there is an indicated length of approximately 31,000 feet along which the ore is more than 4 to 5 feet wide. This estimate is based on geological considerations and represents a total tonnage in the order of 15,000 tons per vertical foot of depth.

Jan 1, 1943

By Cyril S., Smith

WE cannot but marvel at the fact that fire is necessary for almost every operation. It takes the sands of the earth and melts them-now into glass, now into silver, minium or other lead or some substance useful to the artist or physician. By fire, minerals are disintegrated and copper produced; in fire is iron born and by fire is it subdued; by fire, gold is purified; by fire, stones are burned for the binding together of the walls of houses.... Fire is the immeasurable, uncontrollable element, concerning which it is hard to say whether it consumes more or produces more." Thus wrote Pliny in his "Natural History," that great collection of fact and error which constitutes the principal contemporary description of Roman technology and which until the seventeenth century was the authority most often quoted and requoted by those who wrote on metals, as on many other subjects.

Jan 1, 1940

Jan 1, 1889

By H. E. Mussey

When the American Institute of Mining Engineers visited the Birmingham district in May, 1888, the four Ensley furnaces (Fig. 1) then completed were referred to as monumental.&apos; Their dimensions are givcn in Table 1. Mr. Gordon stated, with considerable satisfaction, that on the preceding day one furnace had produced 165 tons. The blast was

Jan 1, 1925

By Frank C. Roberts

Neglecting the hydrogen and hydrocarbons, 1 will assume the following analysis as a fair average composition, by weight, of the waste gases escaping from a coke-burning blast-furnace: CO2............17.25 CO,............25.25 N,.............57.50 100.00 The 25.25 CO requires for combustion 62.6 of air, or 11.398 of oxygen, necessitating the passage of 48.202 nitrogen into the products of combustion. The latter, therefore, have the following composition: CO2,,............ 56.9 N,............105.7 Tile total specific heats of these quantities of the respective gases are 12.31 and 25.79, giving for the combined product, 38.1 approximately. That is, the product of combustion will absorb 38.1

Jan 1, 1889

By Fred W. Gordon

The heading of this paper was prompted by the knowledge that experience, up to this time, seemed to indicate that smaller furnaces were preferable for smelting the material of this section. Since the reasonable success thus far achieved by the first furnace of this plant tends to change the above opinion, and unsettle the generally-accepted views of furnace-men as to "weak " coke, a few words as to the design of the plant and the mode of operation adopted may prove interesting.

Jan 1, 1889

By James A. Barr

Ferrophosphorus, an alloy of phosphorus and iron or perhaps a physical mixture of definite compounds of iron and phosphorus, has become of increasing importance as the use of the basic open hearth has extended. Commercial ferrophosphorus is a porous, brittle metal of crystalline structure and often with a bluish metallic luster. A typical analysis is as follows: Per Cent. Phosphorus......................................... 18.0 to 22.0 Iron............................................... 80.0 76.0 Oxygen............................................ 0.2 Sulfur............................................. 0.3 Silicon............................................. 0.1 Carbon............................................ 0.1 Manganese......................................... 0.2 This alloy was first made in an electric furnace, as it was thought that the high heat of the electric arc together with the reductive effect of carbon was necessary. About 1898, J. J. Gray, Jr., was producing a high-phosphorus pig iron in his furnace at Rockdale, Tenn., by using high-phosphorus, local iron ores. As these high-phosphorus ores were difficult to obtain, he conceived the idea of increasing the phosphorus content of the pig iron by the addition of phosphate rock to the furnace burden. When the phosphorus content of the pig was kept low and only small amounts of phosphate rock were added to the burden, no particular troubles were encountered, but when he increased the amount of phosphate rock to produce an 18 per cent. alloy, his furnace troubles rapidly multiplied. After many failures and freeze-ups, he was partly successful in making short campaigns on 18 to 20 per cent. "ferro." At first, when the furnace got in bad shape on ferro, he would switch to a regular pig-iron burden until the furnace was brought around sufficiently to start on ferro again. About this time, Mr. Gray applied for and obtained his first patent. As he grew more skilled in the furnace operations, he was enabled to extend the furnace campaigns and produce ferrophosphorus continuously for the life of the furnace lining. These improvements were made the subject of another patent issued in 1916.

Jan 1, 1925

By Wilbur A. Nelson

In 1839, Gerard Troost,1 the first State Geologist of Tennessee, reported the occurrence of zinc ores in east Tennessee, in connection with the iron ores at Embreeville; in 1844,2 he refers to the zinc deposits of east Tennessee, especially the apparently rich deposits occurring in Jefferson and Claiborne Counties, while his ninth annual report 3 s a description of the zinc deposits of Jefferson County and a description of the most improved processes by which zinc is extracted from its ores. Yet, only during the last few years have these ores been successfully worked. As far as can be learned, prior to the systematic development of the Mascot district in 1911, no large-scale or successful operation of any of the zinc deposits was carried on. But in that year, after several companies had made considerable progress in developing the Mascot area and had proved a relatively extensive body of low-grade sulfide ore, the American Zinc Co. entered the field. It introduced modern methods of prospecting and mining and from the first was successful. Too great credit cannot be given this company for its pioneer work in a previously unimportant field. Throughout the history of its operations, the American Zinc Co. has confined its efforts to underground mining of the sulfide ore, sphalerite. This company has found that successful results in zinc mining in east Tennessee can be achieved only by expending large sums in prospecting and blocking out bodies of pay ore in sufficient magnitude for large-scale operations. At Mascot are located the mines of the American Zinc Co. of Tennessee, the mines being situated along the Southern Railway in the Ilolston River Valley, Knox County, about 13 miles northeast of Knox-ville. At first only open pits, which were worked for oxidized ores, were operated and the production was small. In 1900, the Roseberry Zinc Co. was organized and sank to a depth of 187 ft. what is now known as No. 3 shaft of the American Zinc Co. The upper 30 ft. was in residual clay,

Jan 1, 1925

By R. C. Canby

The difficulty of exact neutralization by ammonia of the acid solution obtained in the determination of arsenic by the method of fusion with carbonate of soda and nitrate of potassium, led me to try the effect of neutralization by oxide of zinc. I obtained most satisfactory results, and found a great saving of time. The oxide of zinc being added in excess, there is no delicate testing with lit? mils paper and tedious alternate adding of dilute ammonia arid acid until the proper point is reached. The excess of oxide of zinc, too, seems to hold, from the filter, the gelatinous silica and alumina, which are usually precipitated upon neutralization, and thus to render the washing of the precipitated arseniate of silver almost invariably much more rapid. Except the substitution of the neutralization by oxide of zinc for the more tedious method by ammonia, the details of the process are practically the same as those published by Mr. Richard Pearce, of Argo, Colorado (Proceedings of the Colorado Scientific Society, vol. i.), who shows what very accurate results can be obtained by the fusion process. I have made numerous tests of comparison between the two methods of neutralization, and find that those by the oxide of zinc agree almost exactly with the old method. Increasing the quantity of nitric acid, even to considerable excess, to be neutralized by the oxide of zinc did not affect the precipitation of arseniate of silver. The process may be outlined as follows : Take 4 to 1 gramme finely pulverized ore, and mix in a porcelain crucible with eight to ten times its weight of a mixture of equal parts of carbonate of soda and nitrate of potassium (Kerl. Metallurgische Probirkunst gives 4 to 5 nitre to 14 soda). Gradually bring to fusion and keep so, three to five minutes. Cool. Disintegrate in hot water. Filter and wash with hot water. Acidify the filtrate with nitric acid, and boil to expel carbonic acid and nitrous fumes. Cool. Add an excess of an emulsion of oxide of zinc. The bottom of the beaker should have quite a layer of oxide of zinc, after stirring.

Jan 1, 1889

By Truman H. Aldrich

The red, or fossiliferous, ore is found in the Clinton group of the Silurian formation. This group is from 100 to 500 ft. thick in Alabama, and its outcrops have been mapped by the State or the U. S. Geological Survey. In some places, it is entirely missing (doubtless islands in the Silurian Sea). In Etowah County, in part of Greasy Cove and vicinity, the upper seam is a coral reef impregnated with the red ore; in this same county, step faults bring up the ore in three or four practically parallel ridges. In Blount County and on Raccoon Mountain, the ore runs under the carboniferous rocks and outcrops in the valleys. When examining the logs of holes drilled for oil, wherever the drill has gone deep enough, the writer has found the Clinton group underlying the Warrior coal field. The following records of holes drilled primarily for oil, given in Bull. No. 22, Geological Survey of Alabama, show the presence of either ore or red rock, and suggest vast resources yet to be outlined and developed for ore in the future. The locations are given by number on the map. Hole No. 1 was drilled 6 miles southeast of Russellville, Franklin County, by the Woodward Oil & Gas Co. It passed through 160 ft. of the Clinton, but only a small show of red ore was found at 1280-1400 ft. A test well, No. 2, drilled near Atwood, Franklin County, in sectioil 26, township 8, range 14, penetrated the Clinton at 1608 ft. and found 38 ft. of limy red rock, also 8 ft. of some blood red ending at 1820 ft., making 46 ft. of red rock in all. It is reported that some good ore was cut through but this work was done by a churn drill. At least 400 ft. of the formation was classified as Clinton. Well NO. 3, called Frankford Well, was bored by S. A. Hobson and associates in the northwest quarter of section 7, township 6, range 12, Franklin County. At 927 ft., it is supposed to have entered the Clinton; the log is as follows: Ft. Sandy limestone with reddish, high ferruginous argillaceous inclusions 10 Same growing more ferruginous................................ 18 Hematitic limestone......................................... 30 Same with slightly less iron.................................... 23 81

Jan 1, 1925