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By K-O. Mickelsson, S. Töyrä, H. Esbensen

Accurate information of physical, chemical and metallurgical quality characteristics such as moisture content, iron grade and particle size are crucial for successful process control and for producing products within customer specifications. Correct moisture content of pellet feed is an important variable for successful balling of iron ore pellets and to minimize power consumption in the sintering process. Control of the filtering process in the pelletizing plant is therefore essential for both productivity and high product quality. The current measurement systems for moisture content at LKAB are based on two types of manual grab sampling, subsequently analyzed with rapid moisture determination methods. Previous studies of the measurement systems have indicated high sampling variability resulting in lowered possibilities for successful process control. The objective of the present study is to evaluate an alternative filter sampling approach and testing of on-line Infra-Red analysis (IR-analysis). On-line IR-analysis has the advantage of eliminating physical sample extraction and allowing for continuous monitoring of moisture content. However, this approach is sensitive to the surrounding environment, making careful calibration and control crucial for the quality of measurement results. Furthermore, as IR-sensors only target the surface of the conveyed pellet feed, several incorrect sampling errors need to be considered and counteracted to eliminate sampling bias and reduce the remaining measurement variability. Variographic characterization was applied to the two current grab sampling approaches of combined filtered material, to the alternative filter sampling method, and to the On-line IR-analysis. The results indicate that both the sampling of separate filters (using composite sampling and ISO-standardized moisture analysis), as well as a calibrated and well- maintained IR-sensor can improve the relative variability significantly, by lowering the total measurement system variance from 60% to 25%.

Jan 1, 2018

By H Matsuno, N Oyama, T Yamamoto, K Nakajima, Y Iwami, N Saito

Recently, the quality of sinter feed ore used in sintering process has deteriorated. In particular, Fe has decreased and gangue component has increased in the sinter feed ore. Increase of gangue is not only the factor to influence sinter qualities, but also the factor to increase coke ratio in the blast furnace operation as the increase of slag ratio. Therefore, to cope with the deterioration of iron ore qualities, studies on alternative iron ore resources and development of its utilisation technology have been required.In that kind of new iron ore resources, authors focus on high-grade magnetite fine. High-grade magnetite fine decreases sinter productivity by the decrease of permeability of sintering bed. Therefore a new study for using large amount of magnetite fine is required. In the past, there are some studies about the effect of mixing ratio and size of magnetite fine on productivity and quality, but there are few studies about magnetite fine segregation in charging.In this research, the melting behaviour and interfacial reaction calcium-ferrite, which has important role as bonding agent among iron ores, melts into hematite substrate and magnetite substrate was studied. As the results, it was defined that upper segregation of high-grade magnetite fine is suitable for productivity of sintered ore. Based on this knowledge, the control method of high-grade magnetite fine segregation by magnetic force at charging was studied with DEM (discrete element method) and its verification experiments for magnetic segregation control was conducted in the laboratory.CITATION:Iwami, Y, Yamamoto, T, Oyama, N, Matsuno, H, Saito, N and Nakajima, K, 2017. Improvement of sinter productivity by control of magnetite ore segregation in sintering bed, in Proceedings Iron Ore 2017, pp 61–68 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By Kikuta K

ISP (Imperial Smelting Process) produces zinc and lead simultaneously from zinc and lead sulphide concentrates and recovers copper and precious metals into a lead bullion. The strength of sinter is important to keep permeability in the shaft of the Imperial Smleting Furnace. The residual sulphur content of the sinter is also important as it causes metal losses into slag. The paper describes an investigation into the sintering operations to improve sulphur elimination and sinter strength. The micro structure of the sinter and the effect of the blast rate, sintering temperature etc have been studied.

Jan 1, 1993

By Ramanathan Ayothiraman, Anurag Singh

"An experimental program was undertaken to investigate the effects of randomly distributed basalt fibre on the index and engineering properties of Dhanori clay and to compare its performance with the properties of soil reinforced with polypropylene fibre. In the present investigation, 7 groups of soil samples were prepared at four different percentages of basalt fibre and polypropylene fibre content and tests were done for measuring their consistency limits, compaction characteristics, unconfined compression strength and consolidation properties. The test results indicate that the inclusion of basalt fibre in Dhanori clay resulted in significant improvement in properties. The improved properties are not comparable with polypropylene fibres, nevertheless, the improvement by basalt fibres is able to meet the typical design target values and the cost is very much less than synthetic fibres. More importantly, basalt fibres are environment friendly.INTRODUCTIONConstruction of buildings in low lands with engineered filling, flexible and rigid pavements for highways/airfields, and embankments for highways/railways are also part of major infrastructural development in addition to construction of tall buildings, bridges/fly overs, major dams and underground structures. The later projects require different improvement techniques than that is adopted in the former projects. Ground improvement techniques such as use of reinforcement inclusions within soil found as an effective and reliable technique. Especially such modification by fibre reinforcement, is primarily possible in engineered filling, pavements subgrade and embankments, where surface mixing is easier; and may not be feasible when stabilization/modification is required for deeper depths. In comparison with conventional reinforcement using geosynthetics (strips, geotextile, geogrid, etc.), there are some advantages in using randomly distributed fibre as reinforcement. In past few decades, the discrete fibres are simply added and mixed randomly with soil, in much the same way as cement, lime, or other additives.There are several studies (Ziegler et al. 1998; Puppala et al. 2000; Bei-xing et al. 2004; Cai et al. 2006; Tang et al. 2007, 2012, 2016; Abdi et al. 2008; Viswanadham et al. 2009; Le et al. 2015) that investigated the behaviour of polypropylene fibre-reinforced soil and reported that an increase in fibre content caused an increase in strength and shrinkage potential but brought on the reduction of swelling potential. The length of fibres had an insignificant effect on soil characteristics, whereas fibre contents proved more influential and effective. A study on rubber fibre conducted by Hambirao and Rakaraddi (2014) mentions that tensile cracking of clays can be improved with the inclusion of short rubber fibres, optimum fibre content was about 15 % of weight of soil. Several experimental studies (Babu et al. 2008; Chaple and Dhatrak 2013; Vibhakar and Nahta 2014; Soundara and Senthilkumar 2015; Goyal et al. 2015; Jayasree et al. 2014, 2015) were conducted on coir fibre-reinforced soil and concluded that it helped in reducing the swell potential and 1% fibre by weight of the soil almost doubled the CBR value. Martins et al. (2015) found that 4% of sisal fibre by weight of the soil reduced the visibility of cracks. Pillai and Ayothiraman (2012), Ayothiraman et al. (2014) and Sahu et al. (2016) have demonstrated that human hair fibres can be used to improve the properties of both fine grained and coarse grained soils."

Jan 1, 1900

By Jo Katembo, Patty Bwando, Patient K. Ilunga, Yves Kalubi, Emman Mulaj

"From 2010, the dolomite concentration in the ore fed to the Usoke Plant increased, resulting in a significant increase in the gangue acid consumption and Mg build-up in the circuit, and thus an increase in the Mg:Co ratio in the plant solutions. This affected the Co salt grade, reagent consumption, filtration and drying capacity. Efforts were put in place to minimise the acid consumption and consequently the Mg dissolution (such as use of pre-diluted acid), but the benefits were negligible. Various efforts were then initiated by CHEMAF to improve the cobalt plant productivity (quantity and quality) by process changes, dual precipitation and seed recycle. The positive results obtained in the laboratory were successfully implemented on plant scale. A change in the process from a single-stage precipitation with Na2CO3 to dual precipitation using a combination of Na2CO3 and NaOH improved the capacity of the Co salt filtration by 30%, the Co salt grade and drying capacity by 50%, and reduced the reagent consumption by 22%. Implementation of precipitate seed recycle increased Mg rejection by 40%, improving the Co salt grade from 20% to 25%, and yielding a further drop in reagent consumption. INTRODUCTION CHEMAF (Chemicals of Africa), a mining company located in Katanga province of Democratic Republic of Congo (DRC), has been operating since 2003. The Usoke hydrometallurgical plant treats the Cu-Co ore from the Etoile pit to produce Cu cathodes via a leach–solvent-extraction (SX)–electrowinning (EW) circuit and Co salt via a selective precipitation process. The plant was designed to treat run-of-mine (ROM) ore grading 6% Cu and 1.5% Co; but, in 2008, due to a decline in grades, a heavy-media separation (HMS) plant was commissioned to enrich the low-grade ROM (3.5% Cu and 0.5% Co) up to 8% Cu and 1% Co before feeding it to the hydrometallurgical plant. Co is recovered by precipitation of Fe and Al with limestone, followed by Co precipitation as Co carbonate using sodium carbonate (Na2CO3), also known as soda ash. 85% of the final effluent from cobalt precipitation is recycled back to the plant as process water; the balance, 15%, is bled out and compensated for by fresh water top up to control and retard the rate of sodium sulfate build up."

Jan 1, 2015

By A Specht, A Müller, V Montenegro, S Winkler, E Klaffenbach, A Schmidt

In the process of primary copper smelting in flash smelting furnace (FSF), the ratio of iron to silica (Fe/SiO2 mass ratio) primarily determines the slag viscosity and magnetite formation. Viscous slag does not only cause difficulties in daily operation, such as in tapping, it also increases the copper losses to slag. Thus, keeping the Fe/SiO2 mass ratio at the desired level is an important aspect of FSF and slag cleaning furnace (SCF) operation. In this study, the improvement of the Fe/SiO2 mass ratio was conducted in two steps: First, the optimal Fe/SiO2 mass ratio was derived based on thermodynamic data. Based on this analysis, appropriate control limits were determined. Second, this range of favourable Fe/SiO2 mass ratios was implemented into operation by an advice-based control system, which suggests the addition of silica based on the analysis of SCF slag. As this approach was successful, the same advice-based control system principle was adapted for the coke addition to the SCF. After testing the new advice-based control for several months, the production data confirm the predictions by thermodynamics: since the prediction was implemented as an advisor, the copper and magnetite content in SCF slag is significantly reduced and viscous slag is reported less often by operations.

Aug 21, 2024

By Lucien P. Weber

Over the last few years, increased customer demands as well as strong competition from substitute materials have accelerated the development of advanced technologies to improve both the performance and the cost-effectiveness of steel H-piles. On the material side, the development of an in-line heat treatment, combined with the most advanced steelmaking and rolling techniques, allowed to create a new generation of high-strength low-alloy steel grades, called HISTAR, achieving yield points up to 500 MPa (~72 ksi) and yet maintaining excellent weldability properties thanks to a low carbon equivalent. The topic of this paper is to illustrate the performance of H-bearing piles in HISTAR steel grades. In 1989, a major test program was started at different locations in Hong Kong, which is renowned for its difficult soil and severe driving conditions. After the successful completion of these tests, the HISTAR bearing piles were accepted by the local building authorities. Thanks to their cost-effectiveness, the HISTAR bearing piles have subsequently been used with great success in areas with appropriate soil conditions, especially in Asia and more recently in Europe.

Jan 1, 1997

By Lachezar Tsotsorkov

Being a mining company, Assarel-Medet has a significant impact upon the environmental components. In order to meet the legal requirements and the requirements stipulated by the effective permits as well as to reduce the environmental imprint throughout the years, the policy of the company to implement a number of projects to improve the environmental components quality and the environmental state in the company?s region. The projects associated with atmospheric air quality management and reduction of the impact exercised by Assarel-Medet JSC by implementing various measures to eliminate the potential sources of the impact, preventive and rehabilitation initiatives as well as organizational and administrative activities are among the most important ones. A stable improvement of atmospheric air quality in the region and minimization of the company impact upon the ground air state in the region was observed in the period from 2005 to 2012 due to the applied measures. This project is a contribution to the environmental protection, in particular to atmospheric air protection, by applying integral monitoring and modeling methods to identify the negative impact by the mining companies and plan measures to reduce and restrict it as well as to improve the quality of the environment and living area of people working and living in the impact range as an element of sustainable development.

Aug 1, 2013

By Bernd Kos

The management of waste materials in the aluminum industry is as important as in other basic industries. Due to the high value of the-by products of the melting process and their toxic properties we took the challenge to develop a process technology to reduce the environmental impact and to help industry to get a better yield of their by products/raw materials. In melting operations metal losses due to oxidation are nearly unavoidable, the amount of such losses, however, can be controlled. Aluminum dross actually is a by product and any shop would like to get rid of it in the most economic way. This by product still contains up to 70% valuable metal! In the present work we describe possibilities to separate metal and residues for further processing. Recycling of metal concentrates, selling of dross and dumping of the residues have been the typical solutions up to now. But there are technologies available which are designed to reduce the waste to a minimum or even avoid it altogether. Such alternatives are processing of the dross into materials which can be reused in other industrial processes in order to avoid any dumping. This can be done by separating the metal and the residues by centrifuging and further use of the residues in the chemical or refractory industry. ECOCENT means economical and ecological recovery of aluminum by centrifuging of hot dross. This process, developed by FOCON Austria, is based on the idea of treating the hot dross as quick as possible in a single operation to avoid exothermic losses, intermediate storage and unnecessary handling as well as to save energy. In the ECOCENT process the hot dross is fed without any fluxing salt additions into a converter where the relevant parameters for separation, like temperature and viscosity, will be adjusted. Further big lumps of dross are ground into smaller pieces in order to improve the later separation of the metal. After homogenizing and adjusting the temperature, the hot dross is poured as quickly as possible into a centrifuge. In the ladle or alternatively the mould of the centrifuge the centrifugal forces are used for the separation of aluminum from aluminum oxide, the major constituents of dross. The separated pure metal can either be discharged liquid or as solidified aluminum ring. The design of the device for the production of liquid or solid metal is almost identical. As soon as the centrifuging is finished the liquid aluminum can be poured back into the furnace or can be used for ingot pouring. After the pouring of the metal the "dry" residues are removed just by turning the ladle. Alternatively the aluminum solidifies in the mould and is discharged as a compact ring. The separation of the residues from the aluminum ring is automatic. Due to the batchwise operation the composition of the metal is the same as in the skimmed furnace of origin. The complete treatment cycle needs about 40 minutes. The recovery rate of aluminum is better than 90% of pure metal. This technology is highly flexible by its nature and can easily accomodate various operational requirements. The consumption of energy is more than 50% lower compared to conventional dross processing as the ECOCENT process is using the inherent energy of the hot dross. These extremely good results are not dependent on the aluminum content of the dross even from very dry dross most of the metal can be recovered. The main advantages compared to conventional dross processing are the high recovery rate, the known analysis of the metal and the immediate reuse of the recovered aluminum. The high recovery rate and the pure metal result in a short amortization period. The compact ECOCENT unit needs a minimum of space since extensive handling can be avoided. The electronically controlled process needs no cooling water and is simple, safe and environmentally sound. The residues are free of fluxing salts, their content of metallic aluminum is low and the environmental problems are thus greatly reduced.

Jan 1, 1995

By M. S. Tsai

Recovery of uranium from wet-process phosphoric acid is a newly developed source of uranium. Many processes have been developed but the OPAP (octylphenyl acid phosphate) process is still the valuable one because the OPAP reagent compound has the high extraction ,power and cheap cost. The OPAP process was already studied by murthy(1) in 1970 and its complete process flow sheet was first fulfilled by F.T. Hurst(2) in 1974. WCFC(3) (western Co-op Fertilizer Ltd.) in cooperation with ESI (Earth Science Inc.) set up the OPAP uranium recovery pilot plant in Canada in 1978. We have studied the OPAP process since 1974 and first improved the OPAP extractant by proper adjustment of the DOPAP/MOPAP mole ratio with CH3OH-H20 method, resulting in shortening the phase separation time and avoiding the precipitation occurrence in our process. Second, we utilize the reduction and oxidation occurring by DC power supply on either side of the membrane to achieve the extraction and stripping at the same time. An improved OPAP process in which high recovery yield of uranium and acid uncontaminated by iron has been developed in our laboratory.

Jan 1, 1982

By Walter Hartig

Rogesa is operating two medium sized Blast Furnaces, No. 4 and No. 5 at Dillinger integrated steel works plant. The history of the results of the cooling concepts of the intersection between tuyère belt and bosh shows failures at both furnaces. At the 3rd reline of No. 5 Blast Furnace in 2010 changes were made to improve the cooling efficiency of the mentioned area. Two rows of copper cooling plates were installed. After commissioning and a short operating time hot spots occurred in the area of the cooling plates. The decision was taken to develop a new cooling concept together with Paul Wurth Umwelttechnik GmbH, Essen-Germany by replacing the cooling plates by one row of a short copper stave. The duration of the shutdown to perform the work was only 17 days including salamander casting. The operational results after the commissioning are very satisfying with outstanding performance of the new bosh cooling system.

Aug 1, 2018

By G. Deschenes, W. Yen

Ammonium thiosulphate is a non-cyanide lixiviant for gold leaching. The major problem is the high reagent consumption. A combination of 0.3M (NH4)2S2O3, 0.03M CuSO4, 3M NH3 was used to leach a copper-bearing gold ore at pH 10.2 for 24 hours. 30 kg/t of thiosulphate was consumed. Oxygen and copper species were found to be responsible for thiosulphate decomposition. The thiosulphate consumption could be reduced to around 17 kg/t by adding chelating agent, reducing copper sulphate concentration to 0.001 M and replacing CuSO4 by NiSO4. The increase of pulp density might reduce the thiosulphate consumption to around 17 kg/t. By regulating the oxygen supply, the thiosulphate consumption could be reduced to 10 kg/t.

Jan 1, 2002

By Mario A. Terceros Herrera, Mario Terceros Arce, Antonio Marinucci

A Smart Cell is a closed-type tip post-grouting device that is attached to the bottom of the steel reinforcement cage of a drilled shaft and is used to enhance performance and to reduce uncertainty thereof. Control of the grout is maintained within the device during injection and a uniform stress is imparted across entire base area simultaneously, inducing a pre-mobilization load into the shaft as well as the soil. This paper describes the construction and tip post-grouting of drilled shafts from two bridge projects in the Santa Cruz, Bolivia region along the Paraí River. During the grouting process at each project site, there were noticeable differences in the grouting pressures achieved and responses observed, even within short distances between shafts. For this project, the greater benefit of using the Smart Cells was the reduction of risk and uncertainty of performance due to the highly variable soil conditions. Ultimately, since the response of each shaft was observed during grouting and because a “minimum” value of shaft resistance (i.e., pre-mobilization of load) was measured, there is a greater reliability with the anticipated performance of the shafts when axial loading is eventually applied.

By B. A. Kutlin

29% of the total ore mined in the Russian Federation for copper production is finely disseminated copper-zinc-pyrite ores of the Ural Region. Physical and chemical characteristics of pyrite copper-zinc ores make for difficulties in obtaining high indices during processing. At present, the authors have elaborated the technology to improve the quality of copper concentrates up to 20.0% for the ones obtained during pyrite copper-zinc ore processing (based on the example of the ore mining and processing enterprise ?Uchalinsky GOK?, Russian Federation). There are examples of use of fair-sized pneumo-mechanical flotation machines by modernization of processing plants. Keywords: copper-zinc-pyrite ores, Ural region Russian, selective flotation, pneumo- mechanical flotation machines

Sep 1, 2012

By G. Bartolacci, G. Couture, Levasseur. B., A. Lockhart, D. Nathan

"Pulp and froth zone characterization in a flotation circuit to improve transport of valuable minerals remains a challenge. Even though some significant breakthroughs have been made in the development of collectors in terms of selectivity, the control of gangue drainage is still the main bottleneck to achieve the production of a clean concentrate.Over the last decade, COREM’s team has been working on technologies to improve the selectivity of flotation circuits by tuning their hydrodynamic conditions using online instruments such as the bubble viewer, Jg sensor and gas hold-up. As part of its research program, COREM also developed the half-life column that establishes the relationship between the collection zone (bubble-particle attachment) and the cleaning zone (foam) of a flotation machine. In recent years, COREM has continued the development of the prototypes to make them more robust and improve the accuracy of their measurements.Recently, these hydrodynamic instruments were installed in an industrial process at Raglan Mine in order to diagnose and control the impact of hydrodynamic parameters versus the recovery and the quality of the Ni concentrate produced. Sampling campaigns of hydrodynamic parameters demonstrated that froth height could be optimized in order to increase recovery and quality of the concentrate at the same time. The specific effect of the froth height impacts both the pulp and the froth zones. Along with the impact on the drainage of the concentrate, it was observed that froth height also contributes to enhance the collection of particles in the pulp leading to an increase in metallic units.IntroductionOnce the particles of the minerals of interest are attached to the air bubbles injected in the pulp, the flotation process is driven by air dispersion parameters and froth properties. The pulp is usually responsible for the collision between air bubbles and hydrophobic particles of interest while the froth zone aims to upgrade the selectivity of the particles floated through drainage of the unwanted hydrophilic particles. Over the last four decades, flotation hydrodynamics has been extensively studied. Superficial gas velocity (Jg), gas hold-up (eg), Sauter mean bubble diameter measurements (d32) and bubble surface area flux (Sb) are among the most assessed parameters in flotation plants worldwide either to quantify the gas dispersion parameters or to optimize them (Fournier et al., 2015). McGill University has developed several sensors able to measure these parameters at industrial scale (Tavera et al., 1996; Finch et al., 1999; Chen et al. 2001)."

Jan 1, 2017

"Mine ventilation is in every underground mine a crucial process to ensure mine safety as well as acceptable working conditions. On the other hand is also a major cost factor depending on air requirement and air resistance. Due to the fact that the special layout of mines develop over time, ventilation systems change as well. This may result in complex systems which are suffering severe problems and low efficiency. With attention to the mine safety and costs, ventilation systems have to be controlled repeatedly and optimized continuously to fit changing conditions. The project “Improvement of ventilation systems in narrow vein mines” has been commenced with measuring and data collection in the Bogala Mine, Sri Lanka. This over 150 year’s old graphite mine consists of about 20 levels. The resulting ventilation system is highly complex and suffers problems like high temperatures and humidity as well as a mixing of fresh and used air on lower levels. To solve these problems and to optimize the system the complete ventilation system had been measured on-site first. The gained data have been used for simulations to develop and select an optimal and cost efficient solution. OBJECTIVE As an important process in mining ventilation is a major cost factor and can determine the economic feasibility of a mine. Due to the production mine layouts develop over time and mines increase in size and depth while the ventilation system becomes more complex and may suffer severe problems and inefficiency. Therefore mine ventilation systems have to be controlled and optimized regarding the general requirement of mine safety and health of the miners as well as the costs. Depending on the deposit type, depth, mining method, climate and as well corresponding laws and regulations the possible solutions are varying strongly. The work carried out paid special attention to the improvement of ventilation in narrow vein mines in tropical climate, in this case the graphite mine “Bogala” in Sri Lanka, South Asia."

Jan 1, 2015

By A. Halim, J. Gustafsson, A. van Wageningen, J. Johansson, · J. Lööw, K. Kocsis

A major part of the European Union’s (EU) project Sustainable Intelligent Mining System (SIMS) is investigating the development of diesel-free/carbon–neutral underground mines in order to ensure sustainable underground mining in the future. Replacing diesel machines with electric vehicles in underground hard rock mines has been widely acknowledged by the mining industry worldwide as a critical step to improve working conditions by reducing diesel exhaust–related contaminants, to reduce mine ventilation electrical power cost by reducing mine airflow quantity, and to reduce mine greenhouse gas emissions. All of these are major requirements to achieve sustainable future underground mining practices. A field trial of Epiroc’s 2nd generation of Battery Electric Vehicles (BEVs) at Agnico Eagle Finland’s Kittilä mine was conducted during 2019–2020. Vehicles tested were MT42 mine truck, ST14 Load-Haul-Dump (LHD), and Boomer E2 jumbo drill rig. This paper outlines the improvement of the working conditions observed in the field trial, and the opinions of the mine personnel at Kittilä mine on using BEVs instead of diesel machines. Measurements of atmospheric contaminants and air temperatures taken during the field trial clearly demonstrated a significant improvement of working conditions when BEVs were operating as opposed to diesel machines. This field observation was supported by the opinion of the majority of the Kittilä mine workers. However, some remaining concerns must be addressed before BEVs can replace diesel machines.

Oct 25, 2021

By Xinyang Wang

It is believed that sulfur and volatile matter con-tents in coals are the main intrinsic properties to cause the self-heating of coal. Their oxidation at lower temperatures than that of fixed carbon to initiate coal's self-heating should be quantified. This study is aimed to improve the previous mathematical model developed by the authors for studying the coal's propensity for spontaneous combustion. It enhances the model's ability to consider the effects of sulfur, volatile matter and moisture contents in the coal three important factors affecting the coal's self-heating process. Sulfur exists in coal primarily in the form of pyrite which will be oxidized rapidly under suitable conditions. Volatile matters, higher in low rank coals, are more easily to be oxidized. Heat of water condensation provides initial energy for low temperature oxidation. Heat release rates for pyrite oxidation and moisture condensation are built in the model. Finally, the simulation results in terms of time versus temperature on pyrite oxidation and moisture condensation are validated with the adiabatic testing data respectively.

Jan 1, 2013

By Xinyang Wang

It is believed that sulfur and volatile matter contents in coals are the main intrinsic properties to cause the self-heating of coal. Their oxidation at lower temperatures than that of fixed carbon to initiate coal's self-heating should be quantified. This study is aimed to improve the previous mathematical model developed by the authors for studying the coal's propensity for spontaneous combustion. It enhances the model's ability to consider the effects of sulfur, volatile matter and moisture contents in the coal - three important factors affecting the coal's self-heating process. Sulfur exists in coal primarily in the form of pyrite which will be oxidized rapidly under suitable conditions. Volatile matters, higher in low rank coals, are more easily to be oxidized. Heat of water condensation provides initial energy for low temperature oxidation. Heat release rates for pyrite oxidation and moisture condensation are built in the model. Finally, the simulation results in terms of time versus temperature on pyrite oxidation and moisture condensation are validated with the adiabatic testing data respectively.

Jan 1, 2013

By Xingang Wang

Spontaneous combustion is one of the most important safety issues in the global coal industry. It is considered to be a trigger for explosions in underground mines, especially for gassy mines. This thermal event is not easily detectable in the gob and sealed area. It is also a tough job to find the most likely hot point accurately. Admittedly, determination of the propensity for spontaneous combustion before mining activity should be a necessary step in the design of a mine and ventilation plan. However, due to the complexity of the chemical and physical properties of coal, spontaneous combustion has not been fully understood. According to a proximate analysis of coal, it is believed that sulfur and volatile matter in coal are the main intrinsic factors that cause the self-heating of coal. Their oxidation at lower temperatures than that of fixed carbon to initiate coal?s self-heating should be quantified. This study aims to improve the previous mathematical model developed by the authors for studying a coal?s propensity for spontaneous combustion. It enhances the model?s ability to consider the effects of sulfur, volatile matter and moisture content in the coal ? three important factors affecting a coal?s self-heating process. Based on the law of energy conservation, heat release rates for pyrite oxidation and moisture condensation are built into the model. Finally, the simulation results in terms of time versus temperature are calibrated with adiabatic testing data extracted from the literature for pyrite oxidation and moisture condensation, respectively. From the modeling results, it is found that the higher the pyrite content the coal contains and the more moisture that condenses in an environment with high relative humidity and initial temperature, the higher the potential for spontaneous combustion.

Jan 1, 2014