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By Shen Zhengchang, Dong Ganguo, Chen Dong, Zhang Ming

"It is advantageous to process low grade ores with large scale flotation cells. Large-scale flotation cells have been enhanced with effective volume scale-up. In this paper, the latest and largest flotation cell with effective volume of 680 m3 in China is investigated. The hydrodynamics and flotation kinetics characteristics are conducted using CFD simulation. The similar circulating flow is formed compared to the previous BGRIMM (Beijing General Research Institute of Mining and Metallurgy) flotation cell and it is a suitable fluid dynamics environment. It is demonstrated that the flotation cell produces good gas dispersion and solid suspension. It is indicated that kinetic eddy dissipation plays a key role on collision kernel and collision probability profile. The higher collision probability profile appears at the impeller and stator regions aiding good metallurgical performances. The properties of the large-scale flotation cell are assessed using hydrodynamic numbers. The variation of hydrodynamic numbers such as the power number Np, the Froude number Fr, the air flow number Na, etc with flotation cell volumes show similar properties to previous flotation cells proven to be good in engineering applications. This research would aid structure optimization of the 680 m3 flotation cell.INTRODUCTIONFroth flotation is one of the mains method used in the mineral industry, which is used to process the most of metallic minerals. The proportion of low grade ores has increased with the minerals exploited around world. The increased capacity of concentrators demands large-scale flotation cells. Therefore, flotation equipment has seen a significant increase in size, for which large-scale flotation cells have prominent advantages in improving metallurgical performances, reducing area of plant blueprint printer, lowering the power consumption of the unit ore, decreasing labor cost and overall capital cost. Since the end of 1940’s, flotation cell sizes have continuously increased. To the end of 1990’s, flotation cells with the effective volume of 200 m3 were developed. In the last two decades, flotation cells have achieved a dramatic increase in size. In 2003, an industrial experiment on 257 m3 Smart Cell flotation cells was carried out in Minera Los-Pelambres, Chile. In 2007, the first 300 m3 Tank Cell flotation cell was designed and obtained industrial application in Macraes gold ore, New Zealand. And 320 m3 BGRIMM flotation cells are also in good operation in Toromocho Copper Mine, Peru and Wunugetushan Copper Mine, China. However, flotation cells are conventionally designed using empirically derived relations and geometric similarity. The continual scale-up of flotation cells is still a significant developing process. A 500 m3 Tank Cell was designed for the industrial experiment in Finland and a 620 m3 Tank Cell have also been completed the design. A 660 m3 Super Cell also was manufactured for the industrial experiment released in IMPC 2014. So, the flotation cells with volume exceeding 600 m3 become a pioneering research field for researchers worldwide."

Jan 1, 2016

By C. E. Jordan

The U.S. Bureau of Mines investigated flotation hydrodynamics to improve the recovery of coarse phosphate. Fluid velocity profile measurements were used to characterize the hydrodynamics within commercial phosphate flotation cells and laboratory flotation cells. The effects of agitation, aeration, and pH on coarse phosphate recovery were measured in the laboratory flotation cells and correlated with the hydrodynamics measurements. Test results revealed that the agitation energy and aeration level had a significant effect upon flotation response. By optimizing these two parameters, 92 pct of the phosphate was recovered in a rougher flotation concentrate grading 28 pct P2O5?

Jan 1, 1994

By Nathaniel Arbiter

A fully-instrumented driving mechanism has been constructed to study the power, aerating and solid suspension characteristics of several laboratory flotation machines. Machines operating over normal flotation speed ranges give constant power numbers in liquid' systems indicating that they operate under fully baffled turbulent flow conditions. Owing to lack of geometrical scaling, power numbers for different sizes of cells of the same make are different. Even larger differences occur between cells of different manufactures. For a given impeller, varying the tank size did not significantly affect the power consumption. Tank geometry and baffling has a slight effect on power consumption with shrouded impellers. For a given impeller speed, suspension height decreases while power increases with increasing mass of solids in suspension. While power consumption is hardly affected by particle size and clearance between the impeller and tank bottom, the suspension height significantly increases as clearance increases and as particle size decreases. Aeration was found to affect not only power but also the suspension characteristics of the machine. For closely sized particles drastic sedimentation occurred when a critical value of the air flow number was exceeded. The critical air flow number decreased with increasing particle size. This effect was less marked with a wide particle size range. The self-aerating capacity of flotation machines increases with cell size at a given speed for the same impeller-shroud system, but decreases in the presence of frother and solids. Equations have been established for correlating all of the studied variables. Data taken from the literature were also correlated with these equations.

Jan 1, 1968

By P. Songfack

In this work, the slurry flow in the ball mill is solved with Navier-Stokes' equations and the marker and cell technique (MAC), which tracks the fluid-free surface. Considering different planes in the radial and axial directions, this numerical approach leads to the direct calculation of the slurry velocity profile, mill holdup, and volumetric flow in the ball charge and pool. The MAC technique takes as input, the results of a direct three-dimensional simulation of the motion of grinding media, and in turn, provides a detailed knowledge of the hydrodynamics of slurry flow through the porous structure of ball load. This technique is a new approach to the mass transport problem that overcomes the limitations of indirect studies such as residence time analysis and holdup measurements.

Jan 1, 1994

The objective of this paper is, firstly, to summarize several field developments utilizing the art of hydraulic fracturing as it has been extended into various mining applications. Secondly, to summarize the understanding of the hydraulic fracturing processes; and lastly to discuss researchable areas and possible future applications. Hydraulic fracturing was developed as a method of stimulating production of oil from oil producing formations. The primary paper by Clark (1) in 1949, describes the process of placing a hydrostatic pressure of sufficient strength on the producing formation of an oil well that the rock apparently cracked, and then, on allowing the well to flow back, a higher rate of recovery of oil was enjoyed. The interpretation of the process mechanism was that the formation rock was cracked to a considerable distance from the well bore, increasing the drainage area; thus, the productivity of the well was measurably improved. Figure 1 is illustrative of this process. This development was of major significance to the oil producing community and considerable research and development ensued. Improvements in method, engineering development of equipment, and research to ascertain the optimum application of fracturing practice led to a highly sophisticated, but specialized technology. The Production Research Division, Continental Oil Company, vigorously pursued research in this area in the 1950's with a resulting number of process improve¬ments. The research group, published a significant number of technical papers on these various researches. One of the developments was the process aimed at controlled orientation of the fractures, either in the vertical (2) or horizontal (3) orientation.

Jan 1, 1969

By Frank C. Schora

The Institute of Gas Technology for many years has dedicated a large portion of its research effort to the development of a practical solid-fuel-based gasification process to produce a synthetic natural gas equivalent. The work is being done to prepare for the day when supplemental gas will be needed. This program, initially supported by the American Gas Association, and now by both the Department of Interior's Office of Coal Research and the American Gas Association, has developed the IGT Hydrogasification Process. This process, now entering the pilot plant stage, is based on the high-temperature, high- pressure hydrogenation of coal with a hydrogen-steam bearing gas. Product gas from this step is cleaned and catalytically methanated to produce a high-Btu gas. Estimated production costs indicate the process will be competitive with natural gas in certain areas of the country when required.

Jan 1, 1969

By Yurniko Nakamura

Hydriding properties and crystal structure of a Ti-V- Mn solid solution alloy have been studied by P-C isotherm measurements and neutron and X-ray powder diffraction. The absorption P-C isotherm at 298K shows two plateau regions at 0.01MPa and 1MPa. The X-ray diffraction data have demonstrated that three phases with a BCC, a pseudo-cubic FCC and an FCC structure form subsequently with increase of the hydrogen content. Crystal structure of the latter two phases has been determined by Rietveld refinement of the neutron diffraction data. The FCC phase is the di-hydride of CaF2 type with hydrogen occupation in the T sites. The pseudo-cubic FCC phase is the mono-hydride of NaCl-type with hydrogen occupation in the 0 sites, which has not been reported so far. The lattice constants of the mono-hydride (Ti1.0V1.1Mn0.9)H_2.7 are a'=0.407 nm for two axes and c'=0.390 nm for the third axis. The a'axis is shorter by 4% than the c'axis. This pseudo-cubic FCC lattice is formed by contraction of 5% of the a axis and expansion of about 30% of the c axis from the original BCC lattice.

Jan 1, 2002

By David R. Sadedin

The highly negative Gibbs free energies of hydrogen atom reactions suggest that refractory oxides such as titanium dioxide should be easily reduced by hydrogen atoms. These reactions appear to be most favourable at low temperatures; oxides should be reducible even at room temperature. Since hydrogen atoms are produced in plasmas containing hydrogen a number of investigators have used hydrogen plasmas of various sorts to test these possibilities for reducing refractory oxides, in particular TiO2. None of these attempts has succeeded, a small degree of reduction being achieved in only a thin layer near the surface. A deeper consideration shows that several factors complicate the reactions expected on the basis of the negative Gibbs free energy. One factor is that the back reaction by water molecules produces molecular hydrogen, not hydrogen atoms, and the metal atoms that have been reduced may be immediately re-oxidised. In plasmas there are complications due to diffusion, thermal and charge boundary layers and charged particle reactions. Interpreting the results of hydrogen atom reactions is difficult. Hydrogen is not detectable by electron dispersive spectroscopy and amorphous products are not determinable by x-ray diffraction. Another consideration is economics. The cost of producing hydrogen atoms has a large bearing on the metals for which hydrogen atom reduction may be competitive. In this paper these factors are discussed, some necessary basic studies are highlighted and the general principles of a laboratory reactor are given, together with the results of tests using ZnFe2O4, ZnO and TiO2 as test oxides.

Jan 1, 2006

By E. V. Potter, E. T. Hayes, H. C. Lukens

LARGE volumes of hydrogen are liberated at the cathode during electrolytic precipitation of manganese. Most of the gas escapes from the electrolyte, but a considerable amount may be entrapped in the manganese plate. Gas has been observed to escape from manganese melts in puffs that ignite at the surface. It has been reported that castings made with electrolytic manganese tend to rise in the molds; for this reason the manganese is often treated to remove hydrogen before the melt is made or it is premelted and used as cast manganese in making the alloys. The effect of hydrogen on the properties of manganese and its alloys is not known, but its effect on iron and iron alloys has been studied extensively.1.2 The close relationship between iron and man¬ganese suggests that hydrogen may have a similar effect on the properties of manganese and its alloys. The purpose of this investigation was to determine the amount of hydrogen or other gases in typical commercial electrolytic manganese sheet and to investigate ways of removing it most conveniently. APPARATUS The apparatus used is shown schematically in Fig. I. It consists of a chamber A in which the metal sample is placed, a vacuum or pressure gauge B, volume gauge C, vacuum pump D, hydrogen container E, auxiliary gas chamber F, and furnace G. The specimen chamber was made of two concentric quartz tubes. The outer one, a, connects with the closed gas system and is surrounded by the furnace G. A second tube, b, fits closely inside a and has a small end that projects into the space for the specimen and holds the thermocouple for measuring the temperature of the sample. The inner tube is joined to the outer tube outside the furnace, with rubber tape and sealing wax, to prevent gas leakage into or out of the closed system. This type of specimen container is loaded very easily and can be used several times if molten metal does not come in contact with the quartz. An ordinary mercury manometer B is used to measure the pressure in the system. The volume gauge C is essentially another mercury manometer, but the volume of the column is much larger than normal and the height of the mercury can be varied by raising or lowering the well H. In this apparatus the tube had a volume of I00 c.c. for a 60-cm. length. For larger changes in gas volumes; auxiliary containers F were used to increase the volume of the system by known amounts. Valves were arranged so that these auxiliary containers could be filled from the system and evacuated by the pump as often as necessary to accommodate the increases in the volume of gas in the system. The furnace G, used to heat the samples, was equipped with an automatic temperature controller, which maintained the desired temperatures within ± 5°C.

Jan 1, 1945

By J. C. Thornley

Service failures of seemingly conventional galvanized bolts, in normal operation, on transmission towers in New Brunswick have been found to be the result of hydrogen cracking. In both these cases, similar failures elsewhere can be avoided by suitable clauses in the purchase specifications. In the first case described, the manufacturing procedure was responsible for strengthening and embrittling a standard, soft, constructional steel. In this case, a fracture mechanics analysis predicted critical crack depths for final fracture very similar to those found in practice. This case reveals an apparent cooperative connection between hydrogen embrittlement and strain ageing in plain carbon steels. In the second case described, the steel was simply a high strength steel which should not have been made into galvanized bolts.

Jan 1, 1979

By Frederick Rhines

THE investigations of Wyman1 have demonstrated that copper deoxidized with several of the commonly used agents that confer immunity to ordinary hydrogen em-brittlement can still be embrittled if it is annealed alternately under oxidizing and reducing conditions. During the oxidizing cycle, oxygen diffuses into the copper and frequently deposits a subscale composed of the oxide of the residual deoxidizing agent. Upon subsequent reduction with hot hydro-gen, the copper becomes ruptured along the grain boundaries to a depth sharply limited by the previous penetration of oxy-gen as delineated by the inner boundary of the subscale. Obviously the sensitivity to this kind of hydrogen embrittlement is engendered by the introduction of oxygen during the oxi-dizing anneal, but beyond this the mecha-nism of the process, and hence the controlling factors, remain obscure. There are several possibilities: (I) oxygen dissolved in the copper matrix of the subscale may, upon cooling prior to the hydrogen anneal, precipitate as cuprous oxide which is subse-quently reduced by hydrogen as in the familiar case of hydrogen embrittlement; (2) oxygen in solid solution in copper may itself confer susceptibility to embrittlement by hydrogen; (3) the normally refractory oxides such as those of aluminum, silicon and titanium may themselves he reduced by hydrogen when in contact with copper; or (4) the precipitated oxides of the sub-scale may be complex compounds such, perhaps, as Si02-Cu20, which are partially reduced by hydrogen. These possibilities have been examined, and it has been con-cluded that the first three and possibly the fourth are operative collectively or indi-vidually under more or less predictable conditions.

Jan 1, 1940

By C. E. Sims, C. A. Zapffe

MANY hundreds of publications have appeared during the past 78 years that treat the subject of hydrogen in iron and steel,105 but conclusions regarding the functions of hydrogen in causing some important defects in steel are still unsatisfactory to many; and other hydrogen-caused phenomena yet remain to be identified with this gas. The most widely discussed of these defects is hydrogen embrittlement, but the conception, perhaps the popular one, that embrittlement is due to hydride formation does not conform to the known facts.104 The true identity of hydrogen embrittlement seems instead to lie in a mosaic nature of metal crystals, which is a concept not yet accepted by most metallurgists. A study of hydrogen embrittlement therefore provides new viewpoints in regard to the crystalline substructure of steel. A second widely discussed hydrogen-caused defect is the "flake" or "shatter crack." Although it is generally agreed that the presence of hydrogen is a prerequisite for their appearance, it is also realized that internal stress plays a decisive part. The relationship of hydrogen to internal stress has not been explained very clearly; nor is it always clear what the relationship is between a "flake" and a "snowflake," or between a "fish eye" and a "shatter crack." More importantly, the relationships among hydrogen embrittlement, hydrogen-caused fissures such as "flakes" and the ultramicroscopic structure of steel have scarcely been recognized. The present investigation attempts to provide an explanation for the embrittlement of steel by hydrogen by showing cause for accepting the "block" concept of metal crystals, and then to show how the numerous hydrogen-caused defects are interrelated in the light of this concept. EVIDENCE OF SUBSTRUCTURE IN METAL CRYSTALS It appears that the concept of a crystal as an aggregate of smaller multi-atom units must be accepted in some form if the behavior of metals is to be understood. The abundant literature on the evidence of an ultramicroscopic "mosaic" structure in metals and other crystalline substances suggests that the physicist has provided the metallurgist with an invaluable new insight. The exact picturization that any one physicist provides may be open to question, but the fact that there is some such fundamental substructure seems undeniable. The present work makes no pretense of comprehensively treating the imperfection structure theories. Nor will conclusions be drawn here regarding the exact nature of the substructure of crystals. However, the acceptance of some imperfection theory of fundamental attributes seems so necessary to an understanding of the behavior of hydrogen in steel that the following brief

Jan 1, 1941

By Yves Dardel

INTRODUCTION SINCE the first determination of Dumas1 in 1880, many authors have tried to measure the solubility of hydrogen in solid aluminum, or at least the amount of dissolved gas in it. However, the interpretation of the results which have been obtained is still difficult. Sieverts,2 then Baukloh and Oesterlen,3 during their gassing experiments could not determine any solubility of hydrogen in solid aluminum. On the other hand, Portevin, Chaudron and Moreau,4 leaving the determination of the hydrogen solubility beyond the scope of their experiments, measured only the amount of gas that they could extract by high voltage positive ion bombardment and found up to 151 cm3 of gas per 100 g of metal. Winterhager,5 by repeated vacuum extraction during severe cold rolling, extracted up to 161 cm3 per 100 g. In both series of experiments, the extracted gas contained chiefly hydrogen with a small amount of nitrogen, carbon monoxide, carbon dioxide and methan. Later, Schmidt and von Schweinitz6 as well as Chaudron and Moreau7 showed the importance of the adsorbed layer of hydrogen, the extracted quantities being proportional to the surface and not to the weight of the sample, when its cleaning was not perfect. In earlier experiments, Steinhauser8 extracted from more massive samples nothing but a little amount (< 0. 5 cm3 per 100 g) of hydrogen, carbon monoxide and methane. Thus, according to these experiments the quantity of dissolved gas is probably very small and the effect of the surface could falsify the results of the extraction. However, owing to the care taken by Chaudron and his coworkers, it was clear that all the hydrogen extracted could not come from the superficial layer, or that the links which bound hydrogen to the surface were so strong that the usual method of cleaning could not destroy them. After the main parts of the experiments reported here had already been carried out, Eborall and Ransley9 published the results which they obtained with an analysor having an accuracy of 0.03 cm3 per 100 g, while that of the usual apparatus was only about 0.2 cm3 per 100 g. During all their experiments the adsorbed layer would have been a difficulty, for the value of the adsorbed hydrogen was approximately equal to that of the dissolved amount. [ ] Since always keeping the same adsorbed layer is very difficult, an error in the correction for the adsorption can be made when using the apparatus of Eborall and Ransley, as well as the earlier apparatus,

Jan 1, 1948

By R. S. Busk, E. G. Bobalek

THE relation between gases and metals has been a subject of increasingly active investigation during the past years, principally devoted to the study of metal-hydrogen systems. It has been found that hydrogen is soluble in most molten metals to an appreciable extent and somewhat soluble in most solid metals.1,2 In every known case there is a sudden decrease in solubility at the melting point. Thus a freezing mass of metal containing hydrogen in excess of the solid solubility must in some way expel that excess during the freezing process. This leads to internal blowholes, and such effects as pinhole porosity. Gas trapped in metal that is to be fabricated by a working process such as extrusion or rolling may be the cause of blisters. For some cases, notably in copper and iron alloys, the presence of hydrogen can lead to extreme embrittlement of the metal. The aluminum-casting industry has long recognized the importance of hydrogen in its techniques. Excess gas in molten aluminum alloys often leads to the formation of "pinhole porosity" in the solid casting.3 To prevent this hydrogen pickup it is necessary to avoid overheating the melt and to protect it from such sources of hydrogen as water. In spite of all precautions, it is sometimes necessary to extract hydrogen from the melt just before pouring by bubbling with a gas such as chlorine or nitrogen. Recently it has been found that somewhat similar effects are possible with magnesium alloys, in that the presence of hydrogen can induce or aggravate microporosity.4-6 This paper is primarily concerned with a presentation of some facts concerning the solubility of hydrogen in magnesium and its alloys, with some discussion of the significance of these facts in a practical sense. In any study of gas-metal systems it is important to bear in mind a clear distinction between adsorption on surfaces and absorption within the lattice.1 Considerable attention has been directed toward determining whether hydrogen is truly soluble in any solid metal, or whether the gas extracted from a sample was present at surfaces (external and internal) only.7 Most present day evidence supports the idea of true solution in addition to adsorption. A second important factor when dealing with gas solubility is the dependence of such solubility on external pressure. For diatomic gases such as H2, solubility in both liquid and solid metals apparently is proportional to the square root of the pressure, indicating a breakdown to a monatomic gas before diffusion into the lattice .2 For true equilibrium values of solubility, therefore, the pressure at the metal surface must be constant and, preferably, known. Very little has been published concerning the hydrogen-magnesium system. Winterhager has presented the most

Jan 1, 1946

By W. McCombe, G. Remple, L. Zunti, M. Bernardin, L. Nightingale-Mercer

"The McClean Lake Mill is located approximately 700 kilometres north of Saskatoon, Saskatchewan, Canada and is operated by AREVA Resources Canada Inc. (AREVA). The mill was designed to process high grade uranium ores, and has been undergoing a multiyear expansion to increase its production capacity to 24 Mlbs U3O8 per annum, while also undergoing upgrades to allow it to safely transition to processing high grade ores from the Cigar Lake Mine. During the metallurgical test work on the Cigar Lake ores, it was identified that some ore zones in the Cigar Lake deposit have a propensity to generate hydrogen gas during acid leaching. Hydrogen is a volatile and explosive gas, which poses obvious safety concerns in the leaching circuit. Uranium processing is further complicated by the fact that an oxidant in the form of oxygen gas or hydrogen peroxide is required to regenerate iron in the leach, which further increases the risk from hydrogen gas. During 2013 Hatch and AREVA designed and engineered a number of novel upgrades for the leaching circuit to mitigate the risk of hydrogen gas evolution in the process. Best in class technology was utilized in addition to control and operating strategy changes to ensure the leaching circuit can be safely operated with ores that can evolve hydrogen gas. This paper reviews the design concepts and modifications implemented on this unique and challenging project.INTRODUCTION The McClean Lake mill was originally designed to process high grade uranium ores, however until 2014 the average ore grade processed was 1%. The facility has been undergoing a multiyear upgrade and expansion to increase its production capacity from 12 to 24 Mlbs U3O8 per annum, while also undergoing upgrades to allow it to safely transition to new high grade ores, averaging 18% U, from the Cigar Lake Mine. During the last round of metallurgical test work on the Cigar Lake ores, it was identified that some ore zones in the Cigar Lake deposit had a higher propensity to generate hydrogen gas during acid leaching than previous test work had indicated. Hydrogen gas is a volatile and explosive gas, which poses obvious safety concerns in the leaching circuit."

Jan 1, 2017

By W. McCombe, G. Remple, L. Nightingale-Mercer

The McClean Lake Mill is located approximately 850 kilometres north of Saskatoon, Saskatchewan, Canada, and is operated by Orano Canada Inc. (Orano). The mill was designed to process high grade uranium ores, and a multi-year expansion was completed in 2014 to increase its production capacity to 24 Mlbs U3O8 per annum. The mill also underwent various upgrades to allow it to safely transition from processing low grade ores to high grade ores from the nearby Cigar Lake Mine. During the metallurgical test work on the Cigar Lake ores, it was identified that some ore zones of the deposit have a propensity to generate hydrogen gas during acid leaching. Hydrogen is a volatile and explosive gas, which poses obvious safety concerns in the leaching circuit. Uranium processing is further complicated by the fact that an oxidant in the form of oxygen gas or hydrogen peroxide is required to regenerate iron in the leach, which further increases the risk posed by hydrogen gas. During 2013 Orano and its consultant Hatch designed and engineered several novel upgrades to the leaching circuit to mitigate the risk of hydrogen gas evolution in the process. Best in class technology was utilized in addition to control and operating strategy changes to ensure the leaching circuit could be safely operated with ores that evolve hydrogen gas. This paper reviews the design concepts and modifications implemented on this unique and challenging project, and also provides an update on the operational reality of hydrogen in the circuit gained through five years of operational experience with hydrogen evolving ores.

Jan 1, 2020

By D. Scott Scovira, Thomas Gustavsson

Exiting WW2, the potential of nitrates and hydrogen peroxide for application as industrial explosives both became known. The technology stream advanced the development and uptake of nitrate-based explosives to the point that they are the current global standard for blasting. Recently environmental issues are influencing the strategic agenda of extractive industries. The mid-2010s saw renewed interest in hydrogen peroxide explosives to eliminate NOx fume. Carbon reduction initiatives in the 2020s provided additional impetus to investigate hydrogen peroxide-based explosives. Hypex Bio is at the forefront of developing and delivering bulk gas sensitized Hydrogen Peroxide Emulsion (HPE) for blasting. HPE consists of hydrogen peroxide along with smaller amounts of fuel and emulsifier. The consistency of HPE is similar to industry- standard nitrate-based emulsions. It is compatible with existing priming and initiation systems. HPE does not contain nitrates and thereby does not produce post blast nitrous oxide fumes nor discharge of nitrates or ammonia to mine water. Importantly, HPE contributes to reduction in total carbon emissions as compared to nitrate-based explosives.

Feb 1, 2025

By Johan Hillman, D. Scott Scovira, Thomas Gustavsson, Alexander Bihlar

Hydrogen Peroxide Emulsion (HPE) explosives are an alternative to conventional commercial explosives. HPE does not contain nitrates or ammonia thus eliminating post-detonation NOx fumes and aqueous nitrate discharge. Production of HPE is less carbon intensive than industry standard ammonium nitrate-based emulsions (ANE) and employment aligns with end users seeking to meet Scope 3 ESG emission targets. Swedish tunneling contractor Implenia Sverige was awarded the Högdalen Depot Expansion Project by the City of Stockholm. Implenia Sverige partnered with Hypex Bio to be the first to pilot the application of a nitrate-free explosive system in a large-scale civil construction tunnel. The purpose of the joint project was to evaluate the operational suitability of replacing conventional nitrate-based bulk explosives with HPE in a large-scale tunnelling project. When the project commenced in September 2023 both standard nitrate-based emulsions and HPE emulsion were used in parallel (Tunnel Right and Tunnel Left) to enable operational, performance, and environmental comparison. Identical drill patterns and initiation techniques were applied to both tunnel headings. Performance data collected included round advance, usage, and perimeter quality. Implenia managed all drilling and charging operations and Hypex Bio provided technical support, including technicians and chemists. HPE is viscous and pumpable using conventional emulsion pumping delivery systems. Variable density functionality enabled loading different charge weights into cut, lifter, production, and perimeter holes. The primary rock type was hard sedimentary gneiss with approximately 150 MPa [21,755 psi] Uniaxial Compressive Strength (UCS). Fracture systems with infilling occurred in both tunnel directions. Rock quality factor was “Good to Very Good” on the RMRb (Rock Mass Rating) scale. Epiroc Boomer rigs were used to drill rounds averaging 4.9 m [16 ft] deep with high accuracy and precise reference positioning.

Jan 26, 2026

By D. Scott Scovira, Thomas Gustavsson

The potential of hydrogen peroxide explosives was introduced to Thomas Gustavsson and Robert Håkland by Dr Miguel Araos through his development of hydrogen peroxide gel compositions (HPG). In 2020, Thomas and Robert developed a concept project with Boliden Minerals and received Swedish government funding to evaluate HPG technology in a mine environment. The project showed HPG reacted violently with mine mineralization and concluded that HPGs did not offer a commercial solution due to safety concerns. Thomas and Robert engaged with Stefan Nilsson to develop hydrogen peroxide emulsion (HPE) compositions and the process techniques to manufacture them. In 2021, laboratory work produced a promising low carbon intensity, nitrate free, ammonia free, emulsion formulation based on industrial grade hydrogen peroxide and a fuel-emulsifier phase. Design and construction of an HPE pilot plant and underground charging unit commenced. The manufacture of hydrogen peroxide emulsion shares several similarities with the production of nitrate-based emulsions in that the plant is a facility to blend a strong oxidizer solution with a liquid fuel phase into a finished emulsion. A key differentiator between HPE and nitrate-based emulsion is that the manufacture of HPE is a cold production technology in that neither the oxidizer phase (HP) nor the fuel-emulsifier phase requires high temperature heating to prepare raw materials. A successful proof-of-concept HPE evaluation ran from April 2022 to October 2022 at Boliden’s Kankberg underground mine in Sweden. This evaluation demonstrated HPE technology's safety, performance, production, handling, and indicative environmental benefits.

Jan 21, 2025

By L. McFarlane, D. Rollwagen

"Madawaska Mines produces a uranium precipitate (83-85% u3o8) using a magnesium oxide slurry to precipitate the uranium from solution. The solution, at approximately 9""0 g/l u3o8 is neutralized to a pH of 7.0. At the Eldorado Nuclear Refinery in Port Hope, the precipitate is not acceptable as a single feed to the refinery process. It was discovered that a 2% silica impurity caused emulsion problems in the solvent extraction column.After extensive studies of possible solutions, such as two-stage precipitation and solvent extraction, an acceptable solution was found. The selective precipitation of uranium at a pH of 3.5-4.0 using Hydrogen Peroxide produces an almost silica free product of higher purity (90-93% u3o8) to that of straight magnesium oxide precipitation. Introduction Madawaska Mines Limited is located four miles southwest of Bancroft, Ontario. The annual production of u3o8 is approximately 610,000 pounds. To produce the final product or yellowcake, nine separate steps are required. These are (1) grinding, (2) dewatering, (3) leaching, (4) acid filtration, (5) clarification, (6) ion exchange, (7) precipitation, (8) washing, and (9) drying and packaging. To illustrate these steps, a complete flowsheet of the mill is displayed on page three.The yellowcake is sent to Eldorado Nuclear Limited in Port Hope, Ontario for further concentrating and refining. As part of their routine specification check, a test called the amenability test is performed. This test indicates how a particular dissolved yellowcake product reacts to solvent extraction. The Madawaska yellowcake did not pass the test."

Jan 1, 1982