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By V. E. Antonov

Hydrides of iron and iron-based alloys are thermodynamically stable only at hydrogen pressures in the gigapascal range and rapidly loose hydrogen under ambient conditions. At low temperatures, however, these hydrides can be retained in a metastable state at atmospheric pressure after being cooled under the high pressure to liquid nitrogen temperature. This review will discuss the current state of studies on phase transformations in the Fe-H and related systems and also on the composition, crystal structure and physical properties of the hydrides, both under high hydrogen pressures and in the "quenched" metastable state at ambient pressure. The studies at ambient pressure include magnetization measurements, X-ray and neutron diffraction, Mossbauer spectroscopy and inelastic neutron scattering. In the sections on Mossbauer and structural investigations of hydrides of Fe-Cr and Ni-Fe alloys new experimental results will be presented.

Jan 1, 2002

By J. K. Brimacombe

Plant trials have been conducted at the Tacoma Smelter of ASARCO to assess the effect on tuyere blockage and refractory erosion at the tuyere line, of increasing the injection pressure of air into a Peirce-Smith con¬verter. Four tuyeres each having an ID of 19.1 mm (3/4 in) were installed toward one end of the tuyere line of the No. 4 Converter. Air and oxygen-enriched air were injected at 414 kPag (60 psig) through these tuyeres and at the usual 83 kPag (12 psig) through the remainder of the tuyeres in an otherwise normal converter campaign. The test campaign consisted of 88 charges and lasted for 89 days. During this period, punching of the high-pressure tuyeres was found to-be unnecessary; and when, as a precaution, the tuyeres were cleaned by hand at the end of a charge, they were always open. Also it was observed that the flow of high-pressure air remained constant. Accretion formation around the tip of the high-pressure tuyeres varied from charge to charge and was influenced by the matte grade and the level of oxygen enrichment.

Jan 1, 1983

Control shearer-generated airborne respirable dust on longwall mining sections. Approach Previous Bureau studies have shown that using high-pressure water can have a significant impact on the amount of airborne dust released into the face airflow while cleaning and controlling the airflow in the immediate cutting zone. The basic concept to improve the drum water spray system was to utilize high-pressure (1,200 psi) inward-facing drum sprays to improve the dust knockdown efficiency of the spray system and confine the dust to the face area. This system would minimize the exposure of the shearer operator through dust avoidance and decrease face dust levels by suppressing the amount of respirable dust that becomes airborne. System Design In-mine tests were designed to provide information that would permit evaluation of the operation with different spray orientations and water spray pressures. This was achieved by comparison with a conventional baseline wet-cutting system consisting of 26 low-pressure bit sprays, located on the hit blocks to provide pick-point flushing. Total drum water flow was 60 gpm and was maintained continuously throughout all tests. The high-pressure inward-facing drum water spray system consisted of sprays located in each bit block, oriented 15° and 30° toward the face. The inward-facing water spray system was operated at either 800 or 1,200 psi.

Jan 1, 1989

Improve the strength and other properties of steel alloys. Approach Research by the U.S. Bureau of Mines indicates that steels melted and solidified under high nitrogen pressure acquire yield and tensile strengths that are up to four times the strengths of comparable stainless steel alloys without nitrogen. Fatigue strength, creep strength, and other mechanical properties are also improved. Strengthening occurs by two mechanisms: (1) increasing dissolved nitrogen in the lattice and (2) formation of dispersed metal nitride phases. Nitrogen Alloying Nitrogen alloying of a steel is generally done by introducing metal nitrides during melting of the steel. The concentration of nitrogen is limited to its equilibrium solubility at 1 atmosphere. For face-centered-cubic (fee) iron, that solubility is approximately 0.4 weight percent (wt%). For body-centered-cubic (bee) iron, solubility is 0.05 wt%. This solubility limitation can be overcome by melting the metal in a pressurized vessel. European steelmakers currently have metal-processing systems that can melt and pour tons of steel under nitrogen pressures exceeding 4 megapascals (MPa) (40 atmospheres). They have achieved nitrogen concentrations as high as 1.0 wt% in these (stainless) steels. The tensile strength is approximately twice the tensile strength of similar steels without nitrogen.

Jan 1, 1992

By Tim Lundquist

Disa Technologies Inc. provides innovative, sustainable solutions for mineral processing and remediation through its patented High-Pressure Slurry Ablation (HPSA) technology. HPSA processes solid feed material in slurry form, propelled by high pressure pumps through opposing nozzles that generate impinging jets within a collision housing. This process induces particle-to-particle collisions in a high energy zone, creating intergranular fractures along grain boundaries. In our batch scale and continuous operating testing, we have found that controlling key processing variables such as nozzle velocity, slurry solids percentage, and the number of passes can allow for controlled size reduction and maximum mineral liberation. Since 2018, Disa Technologies has demonstrated the versatility of HPSA by testing it on diverse materials, including phosphate, copper, uranium, vanadium, zinc, rare earth elements, lithium, nickel, mineral sands, gold tailings, and more. The intent of this paper is to present an overview of our test results describing in detail impacts on size reduction, recovery, and grade with a focus on HPSA's adaptability across ore types. Looking forward, it explores the potential to process materials such as DR-grade iron, clay, PGMs, bauxite, and various tailings. Additionally, it examines planned advancements in HPSA technology, including optimized nozzle spacing, higher capacity models, improved tonnage-to-footprint ratios, enhanced maintenance features, and expanded nozzle configurations.

Jan 1, 2025

By S. J. Gerdemann

The U.S. Bureau of Mines is studying the kinetics of wet oxidation of sphalerite concen- trate (ZnS) as a possible process for a gravity-pressurized reactor (GPR). At tempera- tures in excess of 200' C, a sphalerite water slurry will react with 0, to form zinc sul- fate (ZnSO,). However, the pressure required to keep the water from boiling at these temperatures has kept this reaction from becoming a viable continuous process. The GPR can easily obtain the high pressures required for this reaction. The reaction rate is complicated by the solubility of 0, in water and the further oxidation of ZnSO, to insoluble zinc oxysulfate (Zn4(OH),S04.4H20). The effects of pressure, temperature, and particle size on the rate of reaction were investigated. Reaction rate was found to be limited by the amount of oxygen in solution. However, at 250" C and 1500 psia, over 90 pct of the zinc was solubilized in less than an hour. The conditions for maxi- mizing the Zn++ in solution, while minimizing oxysulfate formation, are discussed.

Jan 1, 1993

By Isobel Yeo, Luca Cocchi, Sven Petersen, Nico Augustin, Sean Plunkett, Ingo Klaucke

Exploration for seafloor massive sulfides is currently mainly focused on investigation for active hydrothermal vent fields. However, most of the resource potential is thought to be related to inactive, large deposits that had enough time to accumulate sufficient tonnage. At the same time, ageing of these deposits will ultimately result also in burial acted by either sediments and/or volcanic deposits. We currently lack the technologies to explore for these deposits in a time- and cost-efficient manner. In the fall of 2012 we used a number of AUV-based technologies to explore and image a sulfide occurrence at the Palinuro Volcanic Complex in the Tyrrhenian Sea (Mediterranean Sea; Fig. 1) where sampling and drilling have documented a buried polymetallic barite-pyrite dominated site (Petersen et al., 2014). Sulfide mineralization is here covered by volcaniclastic and pelagic sediments and only red sediment staining and the presence of few tubeworm bushes indicated recent hydrothermal activity - black smoker venting is absent. We used AUVbased high-resolution bathymetry, sidescan sonar imaging, subbottom profiling, as well as magnetics to describe, in a quantitative way, the previously known sulfide-bearing areas as well as to successfully explore for new hydrothermal sites including large chimney structures (Figs. 2). Additionally chemical sensors (CTD, Eh, turbidity) investigated the water column for signs of hydrothermal activity in areas not previously investigated, but at the end, only weak anomalies were found in the southern part of the summit.

Sep 1, 2014

By R. Howard

"In projects involving resource development and plant optimization, the use of in-mine geophysics can deliver considerable benefit. The value proposition lies in using very high resolution downhole measurements to model process-plant outcomes. The calibration procedure used to convert in-situ physical properties into process engineering parameters is illustrated using two iron ore projects. Data correction was related either to orebody structure or mineral formation. The deliverable from this approach is a series of high-definition sections indicating the variability of ore delivered to a front-end separation plant and parameters for mine scheduling and stockpile design needed for maximum product yield.RÉSUMÉ Dans des projets de développement des ressources et d’optimisation de l’usine, l’utilisation de la géophysique minière peut engendrer des bénéfices considérables. La valeur de la proposition réside dans l’utilisation de diagraphies à très haute résolution afin de modéliser les résultats de l’usine de traitement. La procédure d’étalonnage utilisée pour convertir les propriétés physiques in situ en des paramètres d’ingénierie de procédés est illustrée en se basant sur deux projets de minerai de fer. La correction des données porte sur la structure de la masse minérale ou de la formation minérale. Les livrable attendus de cette approche sont une série de sections à haute définition, signalant la variabilité du minerai livré à une usine de séparation de première ligne, des paramètres pour l’échéancier de la mine et la conception des haldes requis pour une production optimale."

Jan 1, 2016

By C M. Côte, P Bolz, R Chrystal

The design of final landforms is an integral part of mine closure plans in Queensland and aims to ensure the rehabilitated land is safe, stable and non-polluting. Landform stability in this context is commonly assessed using Landscape Evolutions Models (LEM) which are physical models simulating sediment erosion and deposition around individual landforms over long timespans (up to thousands of years). The most used LEM for assessment of rehabilitated landforms in Queensland is SIBERIA (Willgoose, Bras and Rodriguez-Iturbe, 1991; Tucker and Hancock, 2010). SIBERIA models are complex, require very detailed input data and simulate erosion and deposition over time frames that extend decades beyond closure. They are not suitable to assess erosion risks during the operational phase of a mine and to support the development of erosion and sediment control plans. Other types of erosion models, such as the Revised Universal Soil Loss Equation (RUSLE, Wischmeier and Smith, 1978) or Water Erosion Prediction Project (WEPP, Nearing et al, 1989) calculate soil loss on a monthly or yearly basis and are much better suited to erosion management during the operational phase. They are simpler to implement and can support the design of control measures. For instance, designing a sediment basin requires quantification of sediment loads, which can be produced by these models. In Queensland, the legislation around sediment and erosion control for open cut mines is currently tightening. Soil erosion remains a major concern due to potential impacts on the receiving environment. It requires management during operation and for closure consideration alike and it is critical that erosion and sediment control plans are developed with the most appropriate tools. Globally, RUSLE is the most widely used soil loss model (Borrelli et al, 2021). This is because it is an empirical model with relatively simple input requirements: biophysical data such as soil properties, vegetation cover, topography and rainfall variability, which can be directly measured or derived from regional or national databases and/or spatial data sets that are available in most parts of the world. The second most used model is WEPP (Borrelli et al, 2021) but compared to RUSLE, there is a large drop in the frequency of its use. This is because WEPP is physically-based and has more complex data requirements. WEPP integrates hydrology, hydraulics, erosion mechanics and land cover to predict soil erosion and sediment transport on hill slope profiles and small watersheds (Stolpe, 2005). It requires some biophysical parameters in formats different from those of RUSLE, as well as detailed hydrologic and catchment data. Nevertheless, it has been used in landform design for mines across Australia to determine final landform stability (eg Howard and Roddy, 2012; Costin, 2020). In this study, we assess which tool would be the most appropriate to support development of erosion and sediment control plans from operation to closure. We use RUSLE and WEPP to predict soil loss from a mine site, compare the results from both models and outline the advantages of each method.

Aug 2, 2023

By B G. Lottermoser

Field and laboratory data combined with computational modelling have been used to predict the pit water quality for the Highway Reward mine. Open pit mining of the Highway Reward copper-gold deposit has produced a final mining void with a diameter of 600 m and a depth of 280 m. This void will be left to fill with ground and surface water once pumping of pit water ceases. Several leaching tables were constructed to simulate weathering reactions and surface water run-off in the major pit wall units during a 200-day leaching experiment. To date, about three-quarters through the experiment, combined run-off from these cells has reached a pH

Jan 1, 2003

By Dewey W. Marino

Conventional remote sensing applications for the exploration of natural resources has largely been the domain of low resolu­tion Earth orbiting systems such as Landsat™ which can sample a broad range of the spectrum. As the classic application of remote sensing, it has proven its worth through the discovery of numerous mineral deposits worldwide. Often this technique relies more on the spectral content of the imagery for narrowing potential sites on the ground, but often cannot reveal the detailed context of the observed response. As the dawn of the new era in remote sensing grows closer, high-resolution imagery is proving its worth for the definition of mineral potential and its cost sav­ing advantages for mine management.

Jan 1, 1998

By C. Melvin Lepper

High-resolution shallow seismic reflection methods are being used by the Bureau of Mines to map underground geologic features in coal mines. These features include faults, channel sand, washouts, rolls, and steep dips. The seismic method is proving useful for locating all of these at reasonable cost and with better definition than available with drill programs alone. This report provides a capsule description of the techniques and their application to mine planning.

Jan 1, 1976

By A. R. Wagner, E. Berkman

The use of high-resolution seismic surveys in coal exploration and mine development is becoming established as a standard technique in the industry. Their most significant contribution is in the effectiveness of reducing the number of core holes needed to understand the complex geological nature of coal by identifying geologic faults and mapping coal seam continuity and relative coal thickness. With these goals in mind, a high-resolution seismic survey was conducted in 1980 in the Wasatch Plateau coalfield of Utah. As a result of the success of this initial survey, numerous additional surveys have been performed over the past six years.. The interpretations of these subsequent surveys have led to the location of faults, fluvial channel sandstones, and coal thickness trends. This paper presents a review of high-resolution seismic technology as applied to coal exploration followed by three case histories, two of which illustrate the utility of the technique related to coal thickness determination and faulting and one that serves as an example of pitfalls in interpretation.

Jan 1, 1987

By R A. Stevenson

The purpose of this paper is to outline a recent development in ground fault protection. The paper deals with the A problems of both grounded and ungrounded systems, with regard to hazards to personnel and equipment, and shows that the increased sensitivity and speed of operation of this new detector results in increased safety to personnel and reduced stresses on equipment, and permits the detection of leakage currents before they become serious faults. The detector can be applied to all distribution systems, either A.C. or D.C., up to 15 kv., and the detector itself can be tested at regular intervals without interrupting line circuits. T HERE is always controversy among engineers as to whether distribution systems should be grounded or ungrounded. There are many experi-enced engineers on both sides of this controversy, and each have valid reasons for their choice

Jan 1, 1964

The transgressive sedimentary sequence of the Notnnea Basin contains rhyolitic lavas and less voluminous mafic and intermediate volcanims of shoshonitic affinities which erupted simultaneously during the late Cretaceous. The shoshonitic volcanism shows a trend from early inafic to younger evolved intermediate lithologies. The rhyolites are consistently calc- alkaline. There is no evidence of 'mixing, of, the two magma types. The shoshonitic volcanism is the result of a short-lived subduction event related to sprcadime in the New Caledonia Basin and involved reactivation of an earlier Mesozoic subduction zone.

Jan 1, 1995

The transgressive sedimentary sequence of the Noumea Basin contains rhyolitic lavas and less voluminous mafic and intermediate volcanics of shoshonitic affinities which erupted simultaneously during the late Cretaceous. The shoshonitic volcanism shows a trend froIn early mafic to younger evolved intermediate lithologies. The rhyolites are consistently calcalkaline. There is no evidence of mixing of the two magma types. The shoshonitic volcanism is the result of a short-lived subduction event related to spreading in the New Caledonia Basin and involved reactivation of an earlier esozoic subduction zone.

Jan 1, 1995

By Thomas Pea, Heiner Kontrus, Jérôme Steinkühler

In tunnel condition assessment, the trend is towards comprehensive 3D measurement combined with high quality image texture to document and quantify damages to the tunnel surface and to create a cohesive data base of the structural conditions throughout its lifespan. The faster such measurements can be made on site, the less it impacts traffic conditions of the highly sophisticated subway systems. The Dibit high-speed 3D scanning system which is based on Photogrammetry and LiDAR technology enables data acquisition in tunnels at a speed of up to 60 mph. Given the high rate of speed the system can operate, tunnel shutdowns can be drastically reduced, and tunnel safety increased. The photorealistic texturing of the 3D-model allows the identification and analysis of smallest material damage (e.g., cracks ≥0.3 mm wide). The publication illustrates technical details and 3D results of the innovative system from measurements that were performed in the subway tunnels of the Bay Area Rapid Transit System in San Francisco, CA (total length 66.23 km).

Jun 13, 2021

By Walshe J. M.

The slow-speed compressor is giving place to the high-speed type, with its greater economy of material and space; and, where very large units are required, the turbo-compressor is supplying the need. In the very large air-supply stations on the Rand, turbocompressor units of a capacity of 20,000 and even 50,000 cubic feet, requiring 4,000 to 13,000 horsepower, are quite a commercial proposition, and have proved a practical success. Air-compressors of this size are, however, very exceptional, and the high-speed reciprocating compressor is quite capable of dealing with the highest outputs so far required in this country and, in the hands of manufacturers experienced in the design of high-speed steam-engines, a very high standard of reliability and efficiency in operation is obtained. The so-called “high-speed” or more correctly quick-revolution type of compressor is now extensively used in mines and collieries; for the air-pressures required for power purposes in mining work, two-stage compression, with an intercooler between stages, is the design usually adopted in best practice. It is not the writer’s intention to describe a variety of high-speed air-compressors but to select as an example of this type of compressor the one with which he is most familiar, and which is probably more largely used than any other, namely, the double-acting two-cylinder two-crank type with automatic light-plate air-valves, and with the working parts lubricated on the forced-lubrication principle. Sectional drawings, efficiency curves, air-cylinder diagrams and other data accompany the descriptions and photographs of compressor design, components and mine applications

Dec 1, 1916

By M. D. Lawton, P. Steen

"Drilling results from the established levels at AngloRouyn Mines Limited had indicated inadequate tonnages to meet the planning schedule. It was decided to develop the main zone of the orebody below the bottom working level of the mine. The orebody dips north at an average of 50 degrees and plunges to the west at about 10 degrees. Due to the need for rapid development of this area, a decision was made to use trackless equipment.This paper describes the method used and highlights the use of small 5-ton diesel trucks as carriers for the 2-cu.yd LHD machine. The method achieved advances of about 1,000 feet per month, at a dip of 12 degrees over a length of close to 2,000 feet, using as few as 20 men per day."

Jan 1, 1971

By E. A. Smith, E. R. Parker

METALLURGISTS and engineers have always been interested in the mechanism of high-speed deformation because metals are rapidly deformed in various applications and manufacturing processes. The deformation of metals by impact loads has recently engaged the attention of a number of investigators. Many of their results have not been disclosed but some of the published investigations1-8 have shown that the tensile strength, yield strength and elongation generally increase with increasing strain rate. The investigation reported herein is an attempt to determine the reason for this increase in strength and elongation. Single-crystal copper specimens were broken in tension at impact velocities up to 100 ft. per sec. The distribution of slip bands in the fractured crystals was found to depend upon the strain rate. In the bars broken at high speeds, the slip bands appear to be more numerous. This might account for the higher strength as well as the greater elongation. EXPERIMENTAL PROCEDURE Single crystals of copper (approximately 99.98 per cent) were made in graphite molds by the conventional method of lowering the mold out of the hot zone of a hydrogen furnace at a rate of one inch per hour. Solidification progressed from the bottom upward, forming a single crystal. The crystals were about 0.30 in. in diameter and 4 in. long. They were made into test bars by sliding threaded steel bushings over each end of a crystal and then flowing silver solder between the crystal and the bushing. The inside diameter of the bushings was slightly greater than the diameter of the crystals, to allow space for the silver solder. The bushings were placed so that the gauge length of the crystals was one inch. The assembly is shown in Fig. I, with two views of a fractured crystal. Annealed polycrystalline copper bars of similar shape were machined from solid stock. X-ray measurements were made on all single crystals to determine their orienta¬tions. The results are shown in Fig. 2, where the location of the axis of each specimen is indicated on a standard projection. The bars were broken in a commercial variable-velocity tension im¬pact machine, which has been described in detail elsewhere.7,8 The stress and strain were recorded by means of wire strain gauges and a special commercial oscillo-raph, also described in detail elsewhere.9,10 The equipment and method can be briefly described as follows. The impact machine consists of a motor-driven flywheel containing a two-pronged hammer. This hammer is held retracted in the flywheel

Jan 1, 1944